{"id":99578,"date":"2017-09-04T06:30:43","date_gmt":"2017-09-03T22:30:43","guid":{"rendered":"\/\/m.iemloyee.com\/?p=99578"},"modified":"2017-09-01T22:00:48","modified_gmt":"2017-09-01T14:00:48","slug":"%e5%8d%97%e5%bc%80%e5%a4%a7%e5%ad%a6adv-energy-mater-%ef%bc%9atio2cntc%e7%ba%b3%e7%b1%b3%e6%a3%92%e7%94%a8%e4%ba%8e%e5%bf%ab%e9%80%9f%e5%82%a8%e9%92%a0%e7%9a%84%e9%92%a0%e7%a6%bb%e5%ad%90%e7%94%b5","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=99578","title":{"rendered":"\u5357\u5f00\u5927\u5b66Adv. Energy Mater.\uff1aTiO2@CNT@C\u7eb3\u7c73\u68d2\u7528\u4e8e\u5feb\u901f\u50a8\u94a0\u7684\u94a0\u79bb\u5b50\u7535\u5bb9\u5668"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u968f\u7740\u4eba\u4eec\u5bf9\u4e8e\u50a8\u80fd\u8bbe\u5907\u9700\u6c42\u7684\u65e5\u76ca\u589e\u5927\uff0c\u5982\u4f55\u5b9e\u73b0\u50a8\u80fd\u8bbe\u5907\u9ad8\u5bb9\u91cf\u548c\u9ad8\u529f\u7387\u6210\u4e3a\u4e86\u7814\u7a76\u8005\u5173\u6ce8\u7684\u95ee\u9898\uff0c\u8fd1\u5e74\u6765\u5f97\u5230\u53d1\u5c55\u7684\u94a0\u79bb\u5b50\u7535\u5bb9\u5668\uff0c\u4e0d\u4ec5\u5177\u6709\u7c7b\u4f3c\u4e8e\u7535\u6c60\u7684\u8f83\u9ad8\u80fd\u91cf\u5bc6\u5ea6\uff0c\u540c\u65f6\u5177\u6709\u7c7b\u4f3c\u4e8e\u7535\u5bb9\u5668\u4e00\u822c\u8f83\u9ad8\u7684\u529f\u7387\u5bc6\u5ea6\u548c\u8f83\u957f\u7684\u5faa\u73af\u5bff\u547d\u7b49\u4e00\u7cfb\u5217\u4f18\u52bf\uff0c\u53d7\u5230\u4e86\u7814\u7a76\u8005\u4eec\u7684\u5173\u6ce8\u3002\u800c\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u8d1f\u6781\u6750\u6599\u4f53\u7cfb\u4e2d\uff0cTiO2<\/sub>\u4f5c\u4e3a\u5178\u578b\u7684\u5d4c\u5165\u578b\u8d1f\u6781\u6750\u6599\uff0c\u5177\u6709\u5e73\u5747\u7535\u538b\u4f4e\u3001\u8d5d\u7535\u5bb9\u7279\u6027\u7b49\u4e00\u7cfb\u5217\u4f18\u52bf\uff0c\u4f46\u5176\u4e5f\u5b58\u5728\u5bfc\u7535\u6027\u80fd\u8f83\u5dee\u7684\u95ee\u9898\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6765\u81ea\u5357\u5f00\u5927\u5b66\u7684\u795d\u8fdc\u6069\uff08\u7b2c\u4e00\u4f5c\u8005\uff09\u3001\u5468\u9707\u6559\u6388\u548c\u9b4f\u8fdb\u5e73\u526f\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u5728Advanced Energy Materials<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cFast Sodium Storage in TiO2<\/sub>@CNT@C Nanorods for High-Performance Na-Ion Capacitors<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u9759\u7535\u7eba\u4e1d\u6cd5\u5236\u5907\u5f97\u5230\u5d4c\u5165\u578b\u8d1f\u6781\u6750\u6599TiO2<\/sub>@CNT@C\u7eb3\u7c73\u68d2\u3002\u901a\u8fc7\u52a8\u529b\u5b66\u8ba1\u7b97\u53ef\u77e5\uff0c\u6750\u6599\u7684\u8d5d\u7535\u5bb9\u6781\u5927\u7a0b\u5ea6\u4e0a\u5f71\u54cd\u4e86\u6750\u6599\u7684\u500d\u7387\u6027\u80fd\u3002\u540c\u65f6\uff0c\u7814\u7a76\u8005\u8fd8\u53d1\u73b0\uff0c\u6750\u6599\u4e2d\u591a\u58c1\u78b3\u7eb3\u7c73\u7ba1\u7684\u52a0\u5165\u80fd\u591f\u8fdb\u4e00\u6b65\u52a0\u5feb\u79bb\u5b50\/\u7535\u5b50\u7684\u4f20\u8f93\u8f6c\u6362\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u5236\u5907\u5f97\u5230\u7684\u9ad8\u6bd4\u8868\u9762\u79ef\u7684\u751f\u7269\u8d28\u78b3\u6750\u6599\u540c\u6837\u62e5\u6709\u80fd\u591f\u63d0\u5347\u5bb9\u91cf\u548c\u7a33\u5b9a\u6027\u3002\u6700\u7ec8\uff0c\u7ec4\u88c5\u5f97\u5230\u7684TiO2<\/sub>@CNT@C\/\/BAC\uff08\u751f\u7269\u8d28\u6d3b\u6027\u78b3\u6750\u6599\uff09\u94a0\u79bb\u5b50\u7535\u5bb9\u5668\u8868\u73b0\u51fa\u826f\u597d\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1 TiO2<\/sub>@C<\/strong>\u4e0e<\/strong>TiO2<\/sub>@CNT@C<\/strong>\u7684\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09TiO2<\/sub>@C\u4e0eTiO2<\/sub>@CNT@C\u7684XRD\u56fe\u8c31<\/p>\n

\uff08b\uff09TiO2<\/sub>@C\u4e0eTiO2<\/sub>@CNT@C\u7684TG\u66f2\u7ebf<\/p>\n

\uff08c\uff09TiO2<\/sub>@C\u4e0eTiO2<\/sub>@CNT@C\u7684\u6c2e\u6c14\u5438\u9644-\u8131\u9644\u66f2\u7ebf<\/p>\n

\uff08d\uff09TiO2<\/sub>@C\u4e0eTiO2<\/sub>@CNT@C\u7684Raman\u56fe\u8c31<\/p>\n

\uff08e\uff09TiO2<\/sub>@CNT@C\u7684Ti 2p\u8f68\u9053\u7684\u9ad8\u5206\u8fa8XPS\u56fe\u8c31<\/p>\n

\u56fe<\/strong>2 TiO2<\/sub>@CNT@C<\/strong>\u4e0e<\/strong>TiO2<\/sub>@C<\/strong>\u7684\u5408\u6210\u793a\u610f\u56fe\u53ca\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\uff0c\uff08b\uff09TiO2<\/sub>@CNT@C\u4e0eTiO2<\/sub>@C\u7684\u5408\u6210\u793a\u610f\u56fe<\/p>\n

\uff08c\uff09\uff0c\uff08d\uff09TiO2<\/sub>@CNT@C\u4e0eTiO2<\/sub>@C\u7684SEM\u56fe\uff0c\u5185\u7f6e\u56fe\u4e3a\u4e24\u79cd\u6750\u6599\u7684TEM\u56fe<\/p>\n

\uff08e\uff09\uff0c\uff08f\uff09TiO2<\/sub>@CNT@C\u4e0eTiO2<\/sub>@C\u7684HRTEM\u56fe<\/p>\n

\uff08g\uff09TiO2<\/sub>@CNT@C\u7684\u9009\u533a\u5143\u7d20\u5206\u6790<\/p>\n

\u56fe<\/strong>3 TiO2<\/sub>@CNT@C<\/strong>\u4e0e<\/strong>TiO2<\/sub>@C<\/strong>\u7684\u534a\u7535\u6c60\u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u626b\u63cf\u901f\u7387\u4e3a0.1 mV\/s-8 mV\/s\u65f6\uff0cTiO2<\/sub>@CNT@C\u7684CV\u66f2\u7ebf<\/p>\n

\uff08b\uff09\u626b\u63cf\u901f\u7387\u4e3a0.1 mV\/s-8 mV\/s\u65f6\uff0cTiO2<\/sub>@CNT@C\u7684\u5cf0\u7535\u6d41\u503c<\/p>\n

\uff08c\uff09\u5f53\u7535\u6d41\u5bc6\u5ea6\u4e3a0.05 A\/g\u65f6\uff0cTiO2<\/sub>@CNT@C\u57280.01 V-2.5 V\u7535\u538b\u533a\u95f4\u5185\u7684\u6052\u6d41\u5145\u653e\u7535\u66f2\u7ebf<\/p>\n

\uff08d\uff09\u5f53\u7535\u6d41\u5bc6\u5ea6\u4e3a0.5 A\/g\u65f6\uff0cTiO2<\/sub>@CNT@C\u4e0eTiO2<\/sub>@C\u7684\u5faa\u73af\u6027\u80fd\u66f2\u7ebf<\/p>\n

\uff08e\uff09TiO2<\/sub>@CNT@C\u4e0eTiO2<\/sub>@C\u7684\u500d\u7387\u6027\u80fd\u66f2\u7ebf<\/p>\n

\uff08f\uff09\u5f53\u626b\u63cf\u901f\u7387\u4e3a1 mV\/s\u65f6\uff0cTiO2<\/sub>@CNT@C\u7684\u7535\u5bb9\u6027\uff08\u7ea2\u8272\uff09\u548c\u6269\u6563\uff08\u7070\u8272\uff09\u7684\u5bb9\u91cf\u8d21\u732e\u767e\u5206\u6bd4<\/p>\n

\uff08g\uff09\u5f53\u7535\u6d41\u5bc6\u5ea6\u4e3a1 A\/g\u65f6\uff0cTiO2<\/sub>@CNT@C\u4e0eTiO2<\/sub>@C\u7684\u957f\u5faa\u73af\u6027\u80fd\u66f2\u7ebf\u4e0eTiO2<\/sub>@CNT@C\u7684\u5e93\u4f26\u6548\u7387\u66f2\u7ebf<\/p>\n

\u56fe<\/strong>4 TiO2<\/sub>@CNT@C\/\/BAC<\/strong>\u7684\u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5728\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\uff0c\u5168\u7535\u6c60\u7684CV\u66f2\u7ebf<\/p>\n

\uff08b\uff09\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u5168\u7535\u6c60\u57281.0-4.0 V\u7535\u538b\u533a\u95f4\u5185\u7684\u5145\u653e\u7535\u66f2\u7ebf\u56fe<\/p>\n

\u56fe5 TiO2<\/sub>@CNT@C\/\/BAC\u7684\u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81\u3001\u5bf9\u6bd4\u4e0e\u5e94\u7528<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09TiO2<\/sub>@CNT@C\/\/BAC\u4e0eTiO2<\/sub>@C\/\/BAC\u7684Ragone\u56fe\uff0c\u5185\u7f6e\u56fe\u4e3aTiO2<\/sub>@CNT@C\/\/BAC\u9a71\u52a8\u8ff7\u4f60\u98ce\u6247\u6548\u679c\u56fe<\/p>\n

\uff08b\uff09TiO2<\/sub>@CNT@C\/\/BAC\u4e0e\u5176\u4ed6\u73b0\u6709\u50a8\u80fd\u8bbe\u5907\u7684\u6027\u80fd\u5bf9\u6bd4<\/p>\n

\uff08c\uff09\u7535\u6d41\u5bc6\u5ea6\u4e3a1 A\/g\u65f6\uff0cTiO2<\/sub>@CNT@C\/\/BAC\u7684\u957f\u5faa\u73af\u6027\u80fd<\/p>\n

\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n

\u672c\u6587\u4e00\u65b9\u9762\uff0c\u5229\u7528\u9759\u7535\u7eba\u4e1d\u6cd5\u5236\u5907\u5f97\u5230\u4e86\u5d4c\u5165\u578bTiO2<\/sub>@CNT@C\u7eb3\u7c73\u68d2\u4f5c\u4e3a\u7535\u5bb9\u5668\u7684\u8d1f\u6781\u6750\u6599\uff0c\u53e6\u4e00\u65b9\u9762\uff0c\u5236\u5907\u5f97\u5230\u5177\u6709\u5927\u6bd4\u8868\u9762\u79ef\u7684\u751f\u7269\u8d28\u6d3b\u6027\u70ad\u6750\u6599\u4f5c\u4e3a\u7535\u5bb9\u5668\u7684\u6b63\u6781\u6750\u6599\u3002\u5728\u8d1f\u6781\u6750\u6599\u4e2d\uff0c\u7531\u4e8e\u591a\u58c1\u78b3\u7eb3\u7c73\u7ba1\u548c\u7eb3\u7c73TiO2<\/sub>\u9897\u7c92\u7684\u5b58\u5728\uff0cTiO2<\/sub>@CNT@C\u8868\u73b0\u51fa\u5305\u62ec\u500d\u7387\u6027\u80fd\u597d\u3001\u5faa\u73af\u7a33\u5b9a\u6027\u597d\u3001\u534a\u7535\u6c60\u5bb9\u91cf\u9ad8\u7b49\u826f\u597d\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u4e3a\u5176\u7535\u5bb9\u5668\u4e2d\u7684\u6210\u529f\u5e94\u7528\u6253\u4e0b\u4e86\u575a\u5b9e\u7684\u57fa\u7840\u3002\u6700\u7ec8\u5236\u5907\u5f97\u5230\u7684TiO2<\/sub>@CNT@C\/\/BAC\u6df7\u5408\u7535\u5bb9\u5668\u5177\u6709\u5f88\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\uff0881.2 Wh\/kg\uff09\u548c\u529f\u7387\u5bc6\u5ea6\uff0812400 W\/kg\uff09\u3002\u57281.0 V-4.0 V\u7535\u538b\u533a\u95f4\u5185\uff0c\u94a0\u79bb\u5b50\u7535\u5bb9\u5668\u57281 A\/g\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u5faa\u73af5000\u5708\u540e\u4ecd\u670985.3%\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\uff0c\u4e0e\u5176\u4ed6\u50a8\u80fd\u5668\u4ef6\u76f8\u6bd4\u6709\u660e\u663e\u7684\u4f18\u52bf\u3002\u672c\u6587\u4e2d\u5236\u5907\u6240\u5f97\u6750\u6599\u7684\u51fa\u8272\u6027\u80fd\uff0c\u4e3a\u7814\u7a76\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u548c\u9ad8\u529f\u7387\u5bc6\u5ea6\u7684\u94a0\u79bb\u5b50\u7535\u5bb9\u5668\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u9014\u5f84\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Fast Sodium Storage in TiO2<\/sub>@CNT@C Nanorods for High-Performance Na-Ion Capacitors<\/a>\uff082017\uff0cAdvanced Energy Materials\uff0cDOI\uff1a10.1002\/aenm.201701222\uff09<\/p>\n

\u3010\u56e2\u961f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

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\u5728\u4e0a\u8ff0\u7814\u7a76\u4e2d\uff0c\u56e2\u961f\u53d1\u8868SCI\u6458\u5f55\u8bba\u6587220\u591a\u7bc7\uff0c\u5176\u4e2d\u5728Prog. Mater. Sci.,<\/strong> J. Am. Chem. Soc., Adv. Mater., Angew. Chem. Int. Ed.<\/strong>\u548c<\/strong>Adv. Energy Mater.<\/strong>\u7b49<\/strong>\u5f71\u54cd\u56e0\u5b5010.0\u4ee5\u4e0a\u6742\u5fd7\u4e0a\u53d1\u8868\u8bba\u658722<\/strong>\u7bc7\u3002\u8bba\u6587\u88ab\u56fd\u5185\u5916\u540c\u884c\u4ed6\u5f15\u7ea610000\u6b21\uff0c15\u7bc7\u8bba\u6587\u5165\u9009ESI\u8fd1\u5341\u5e74\u9ad8\u88ab\u5f15\u8bba\u6587\u30022014\u5e74\u83b7\u5f97\u5929\u6d25\u5e02\u81ea\u7136\u79d1\u5b66\u4e8c\u7b49\u5956\u3002<\/p>\n

\u56e2\u961f\u8fd1\u5e74\u6765\u5728\u5bcc\u6c2e\u591a\u5b54\u78b3\u6750\u6599\u5728\u8d85\u7ea7\u7535\u5bb9\u5668\u548c\u9502\u79bb\u5b50\u6df7\u5408\u7535\u5bb9\u5668\u7684\u7814\u7a76\u53d6\u5f97\u4e86\u7cfb\u5217\u7814\u7a76\u6210\u679c\u3002\u5177\u4f53\u5982\u4e0b\uff1a<\/p>\n

    \n
  1. Mei Yang, Yiren Zhong, Jie Bao, Xianlong Zhou, Jinping Wei, Zhen Zhou,<\/u> Achieving battery-level energy density by constructing aqueous carbonaceous supercapacitors with hierarchical porous N-rich carbon materials, Mater. Chem. A<\/em><\/strong> 2015, 3, 11387-11394.<\/li>\n
  2. Mei Yang, Zhen Zhou, Recent Breakthroughs in Supercapacitors Boosted by Nitrogen-Rich Porous Carbon Materials, Sci.<\/em><\/strong> 2017, 4(8), 1600408.<\/li>\n
  3. Mei Yang, Yiren Zhong, Jingjing Ren, Xianlong Zhou, Jinping Wei, Zhen Zhou, Fabrication of High-Power Li-Ion Hybrid Supercapacitors by Enhancing Exterior Surface Charge Storage, Energy Mater.<\/em><\/strong> 2015, 5(17), 1500550 (VIP, featuring the inside front cover).<\/li>\n
  4. Haichen Gu, Yuan-En Zhu, Jiqian Yang, Jinping Wei, Zhen Zhou, Nanomaterials and technologies for Lithium-Ion Hybrid Supercapacitors, ChemNanoMat<\/em><\/strong> 2016, 2, 578-587.<\/li>\n<\/ol>\n

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