{"id":98692,"date":"2017-08-31T06:30:45","date_gmt":"2017-08-30T22:30:45","guid":{"rendered":"\/\/m.iemloyee.com\/?p=98692"},"modified":"2017-08-27T14:08:54","modified_gmt":"2017-08-27T06:08:54","slug":"jacs-omar-m-yaghi-%e4%b8%8d%e5%90%8c%e6%b9%bf%e5%ba%a6%e4%b8%8b%e6%b0%a8%e5%9f%ba%e5%8c%96mofs%e6%8d%95%e6%8d%89co2%e7%9a%84%e6%9c%ba%e7%90%86%e6%8e%a2%e7%a9%b6","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=98692","title":{"rendered":"Omar M. Yaghi \u6559\u6388 JACS\uff1a\u4e0d\u540c\u6e7f\u5ea6\u4e0b\u6c28\u57fa\u5316MOFs\u6355\u6349CO2\u7684\u673a\u7406\u63a2\u7a76"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n

MOFs\u5177\u6709\u7ed3\u6784\u53ef\u8c03\u63a7\u6027\u597d\u4e14\u6613\u4e8e\u5728\u5b54\u58c1\u4e0a\u5f15\u5165\u5b98\u80fd\u56e2\u7684\u4f18\u70b9\u3002\u8fd9\u4f7f\u5176\u6210\u4e3a\u53ef\u9009\u62e9\u6027\u5927\u91cf\u5438\u6536CO2<\/sub>\u7684\u70ed\u95e8\u6750\u6599\u4e4b\u4e00\u3002\u76ee\u524d\uff0c\u53ef\u6709\u6548\u5438\u9644CO2<\/sub>\u7684MOFs\u7684\u5b54\u7ecf\u8fc7\u70f7\u57fa\u80fa\u5b98\u80fd\u56e2\u5316(R1<\/sub>NHR2<\/sub>\u6216RNH2<\/sub>)\u3002\u8fd9\u4e9b\u70f7\u57fa\u80fa\u57fa\u56e2\u53ef\u4e0eCO2<\/sub>\u53d1\u751f\u53cd\u5e94\u5f62\u6210C-N\u5171\u4ef7\u952e\u4ea7\u751f\u6781\u9ad8\u7684\u4f4e\u538b\u5438\u6536(<100Torr)\u548c\u9009\u62e9\u6027\uff1b\u4e4b\u524d\uff0c\u6c28\u57fa\u7532\u9178\u94f5\u662f\u6355\u83b7CO2<\/sub>\u540e\u4ea7\u751f\u7684\u552f\u4e00\u4ea7\u7269\uff0c\u8be5\u5de5\u4f5c\u53d1\u73b0\u6c28\u57fa\u7532\u9178\u4ea6\u662f\u4e00\u79cd\u4ea7\u7269\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/span><\/p>\n

\u8fd1\u65e5\uff0c\u4e16\u754c\u8457\u540d\u5316\u5b66\u5bb6\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821\u6559\u6388Omar M. Yaghi<\/strong> (\u901a\u8baf\u4f5c\u8005)\u2014\u2014MOFs\u548cCOFs<\/strong>\u53d1\u5c55\u5e94\u7528\u7684\u5960\u57fa\u4eba<\/strong>\u4e4b\u4e00\uff0c\u5728JACS<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cThe Chemistry of CO2<\/sub> Capture in an Amine-Functionalized Metal\u2212Organic Framework under Dry and Humid Conditions<\/strong>\u201d\u7684\u5de5\u4f5c\u3002\u8be5\u7814\u7a76\u6709\u52a9\u4e8e\u63ed\u793a\u5728\u4e0d\u540c\u5b9e\u9645\u6761\u4ef6\u4e0bMOFs\u5bf9CO2<\/sub>\u5438\u9644\u673a\u7406\u548c\u6750\u6599\u8bbe\u8ba1\u548c\u5e94\u7528\u3002<\/p>\n

\n \"\"\u3010\u6ce8\u3011C\uff1a\u7070\u8272\uff0cO\uff1a\u7ea2\u8272\uff0cN\uff1a\u7eff\u8272\uff0cMg\uff1a\u84dd\u8272\u3002\uff08\u4e0b\u540c\uff09<\/p>\n

\n \u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n

\u56fe\u4e00. IRMOF-74-III-(CH2<\/sub>NH2<\/sub>)2<\/sub>\u7684CO2\u5438\u9644\u8131\u9644\u7b49\u6e29\u7ebf<\/strong><\/p>\n

\"\"
\n \u5b9e\u5fc3\u5750\u6807\u70b9<\/strong>\uff1a\u5438\u9644\u7b49\u6e29\u7ebf\uff0c\u7a7a\u5fc3\u5750\u6807\u70b9<\/strong>\uff1a\u8131\u9644\u7b49\u6e29\u7ebf\uff1b\u7ea2\u8272<\/strong>\uff1a\u6d3b\u5316\u7684IRMOF-74-III-(CH2<\/sub>NH2<\/sub>)2<\/sub>\u7b2c\u4e00\u6b21\u5438\u8131\u9644\u5faa\u73af\u7b49\u6e29\u7ebf\uff0c\u9ed1\u8272<\/strong>\uff1a\u672a\u6d3b\u5316\u7684IRMOF-74-III-(CH2<\/sub>NH2<\/sub>)2<\/sub>\u4e00\u6b21\u5faa\u73af\u4e4b\u540e\u7684\u5438\u8131\u9644\u7b49\u6e29\u7ebf\uff0c\u6a59\u8272<\/strong>\uff1a\u5ba4\u6e29\u4e0b\u6d3b\u531612h\u540e\uff0cIRMOF-74-III-(CH2<\/sub>NH2)2\u7b2c\u4e8c\u6b21\u5438\u8131\u9644\u5faa\u73af\u7b49\u6e29\u7ebf\uff0c\u84dd\u8272<\/strong>\uff1a120\u2103\u4e0b\u6d3b\u53162h\u540e\uff0cIRMOF-74-III-(CH2<\/sub>NH2<\/sub>)2<\/sub>\u7b2c\u4e8c\u6b21\u5438\u8131\u9644\u5faa\u73af\u7b49\u6e29\u7ebf\uff1b\u5185\u7f6e\u5c0f\u56fe\uff1a\u4f4e\u538b\u4e0b\u4e0d\u540c\u5438\u8131\u9644\u7b49\u6e29\u7ebf\u7684\u653e\u5927\u56fe\u3002<\/p>\n

\u56fe\u4e8c. \u4e0d\u540c\u6761\u4ef6\u4e0bIRMOF-74-III-(CH2<\/sub>NH2<\/sub>)2<\/sub>\u768413<\/sup>C\/15<\/sup>N-CP-MAS NMR<\/strong><\/p>\n

\"\"
\n a.<\/strong> IRMOF-74-III-(CH2<\/sub>NH2<\/sub>)2<\/sub>\u768413<\/sup>C-CP-MAS NMR\uff1b<\/p>\n

b.<\/strong> \u66b4\u9732\u5728675 Torr\u7684CO2<\/sub>\u4e0b24h(\u7ea2\u8272)\u548c\u771f\u7a7a\u8131\u6c1424h(\u7070\u8272)\u540e\u7684IRMOF-74-III-(CH2<\/sub>NH2<\/sub>)2<\/sub> 13<\/sup>C-CP-MAS NMR\uff1b<\/p>\n

c.<\/strong> \u66b4\u9732\u5728\u76f8\u5bf9\u6e7f\u5ea695%\u7684N2\u6c1b\u56f4\u4e0b24h\u540e\uff0c\u5728675 Torr\u7684CO2\u4e0b\u66b4\u973224h(\u84dd\u8272)\u548c\u771f\u7a7a\u8131\u6c1424h(\u7070\u8272)\u540e\u7684IRMOF-74-III-(CH2<\/sub>NH2<\/sub>)2<\/sub> 13<\/sup>C-CP-MAS NMR\uff1b<\/p>\n

d.<\/strong> \u589e\u52a050%15<\/sup>N\u7684IRMOF-74-III-(CH2<\/sub>NH2<\/sub>)2<\/sub>\u768415<\/sup>N-CP-MAS NMR\uff1b<\/p>\n

e.<\/strong> \u66b4\u9732\u5728675 Torr\u7684CO2\u4e0b24h(\u7ea2\u8272)\u548c\u771f\u7a7a\u8131\u6c1424h(\u7070\u8272)\u540e\u7684IRMOF-74-III-(CH2<\/sub>NH2<\/sub>)2<\/sub> 15<\/sup>N -CP-MAS NMR\uff1b<\/p>\n

f.<\/strong> \u66b4\u9732\u5728\u76f8\u5bf9\u6e7f\u5ea695%\u7684N2<\/sub>\u6c1b\u56f4\u4e0b24h\u540e\uff0c\u5728675 Torr\u7684CO2\u4e0b\u66b4\u973224h(\u84dd\u8272)\u548c\u771f\u7a7a\u8131\u6c1424h(\u7070\u8272)\u540e\u7684IRMOF-74-III-(CH2<\/sub>NH2<\/sub>)2<\/sub> 15<\/sup>N -CP-MAS NMR\u3002<\/p>\n

\u56fe\u4e09. IRMOF-74-III-(CH2<\/sub>NH2<\/sub>)2<\/sub>\u7684\u4fef\u89c6\u7ed3\u6784\u6a21\u578b\u53ca\u5438\u9644CO2<\/sub>\u540e\u6c28\u57fa\u7684\u53d8\u5316<\/strong><\/p>\n

\"\"
\n \u5de6\u00a0\u00a0\u00a0 \u4fa7<\/strong>\uff1a \u5b54\u5185\u7684\u6c28\u57fa\u5206\u5e03\u65b9\u5f0f\uff1b<\/p>\n

\u53f3\u4e0a\u4fa7<\/strong>\uff1a\u76f8\u5bf9\u6e7f\u5ea695%\u65f6\uff0c\u5438\u9644CO2<\/sub>\u524d\u540e\u6c28\u57fa\u7684\u53d8\u5316\uff1b<\/p>\n

\u53f3\u4e0b\u4fa7<\/strong>\uff1a\u76f8\u5bf9\u6e7f\u5ea60%\u65f6\uff0c\u5438\u9644CO2<\/sub>\u524d\u540e\u6c28\u57fa\u7684\u53d8\u5316\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/span><\/p>\n

\u8be5\u5de5\u4f5c\u4ecb\u7ecd\u4e86\u4e00\u79cd\u65b0\u7684\u53cc\u6c28\u57faMOF\u4f53\u7cfb\u2014IRMOF-74-III-(CH2<\/sub>NH2<\/sub>)2<\/sub>\u5e76\u9610\u660e\u4e86\u5728\u4e0d\u540c\u6e7f\u5ea6\u6761\u4ef6\u4e0b\u5176\u4e0eCO2<\/sub>\u76f8\u4e92\u4f5c\u7528\u7684\u5316\u5b66\u673a\u5236\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5<\/strong>\uff1aThe Chemistry of CO2<\/sub> Capture in an Amine-Functionalized Metal\u2212Organic Framework under Dry and Humid Conditions<\/a>\uff08J. Am. Chem. Soc., 2017 DOI: 10.1021\/jacs.7b06382\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u7eb3\u7c73\u7ec4Mr_PSP\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a><\/strong><\/span>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 MOFs\u5177\u6709\u7ed3\u6784\u53ef\u8c03\u63a7\u6027\u597d\u4e14\u6613\u4e8e\u5728\u5b54\u58c1\u4e0a\u5f15\u5165\u5b98\u80fd\u56e2\u7684\u4f18\u70b9\u3002\u8fd9\u4f7f\u5176\u6210\u4e3a\u53ef\u9009\u62e9\u6027\u5927\u91cf\u5438\u6536CO2\u7684\u70ed\u95e8\u6750\u6599\u4e4b\u4e00\u3002\u76ee\u524d\uff0c\u53ef\u6709\u6548\u5438\u9644CO2\u7684MOFs\u7684\u5b54\u7ecf\u8fc7\u70f7\u57fa…<\/p>\n","protected":false},"author":3267,"featured_media":98700,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[54,245],"class_list":["post-98692","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-making","tag-mof"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/98692"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/3267"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=98692"}],"version-history":[{"count":6,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/98692\/revisions"}],"predecessor-version":[{"id":98714,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/98692\/revisions\/98714"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/98700"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=98692"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=98692"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=98692"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}