{"id":98545,"date":"2017-08-31T06:30:21","date_gmt":"2017-08-30T22:30:21","guid":{"rendered":"\/\/m.iemloyee.com\/?p=98545"},"modified":"2017-08-29T18:44:39","modified_gmt":"2017-08-29T10:44:39","slug":"%e6%b8%85%e5%8d%8e%e5%a4%a7%e5%ad%a6angew-chem-int-ed%ef%bc%9a%e5%90%88%e7%90%86%e8%b0%83%e8%8a%82%e5%ba%94%e5%8f%98%e6%8e%a7%e5%88%b6%e9%92%8c%e5%82%ac%e5%8c%96%e5%89%82%e9%80%89%e6%8b%a9%e6%80%a7","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=98545","title":{"rendered":"\u6e05\u534e\u5927\u5b66Angew. Chem. Int. Ed\uff1a\u5408\u7406\u8c03\u8282\u5e94\u53d8\u63a7\u5236\u948c\u50ac\u5316\u5242\u9009\u62e9\u6027\u7528\u4e8e4-\u785d\u57fa\u82ef\u4e59\u70ef\u52a0\u6c22"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u968f\u7740\u5316\u5b66\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u8282\u80fd\u6280\u672f\u7684\u53d1\u5c55\u8c03\u8282\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u9009\u62e9\u6027\u662f\u975e\u5e38\u53ef\u53bb\u7684\u3002\u901a\u5e38\uff0c\u5e26\u4e00\u4e2a\u5b98\u80fd\u56e2\u7684\u5206\u5b50\u80fd\u591f\u91c7\u7528\u4e00\u79cd\u91d1\u5c5e\u50ac\u5316\u5242\u8f6c\u5316\u4e3a\u5408\u9002\u7684\u4ea7\u7269\u3002\u4f46\u662f\u5f53\u5206\u5b50\u4e2d\u8fd8\u6709\u5176\u4ed6\u5b98\u80fd\u56e2\u5b58\u5728\u9009\u62e9\u6027\u63a7\u5236\u4e00\u4e2a\u7279\u6b8a\u5b98\u80fd\u56e2\u662f\u5f88\u6709\u6311\u6218\u7684\u3002\u56e0\u6b64\u5728\u63d0\u9ad8\u91d1\u5c5e\u50ac\u5316\u5242\u9009\u62e9\u6027\u7684\u6709\u6548\u7b56\u7565\u4e0a\u8fd8\u6709\u5f88\u5927\u6587\u7ae0\u53ef\u505a\u3002 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Regulation<\/strong>\u201d\u3002\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u8c03\u8282\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u6676\u683c\u5e94\u53d8\u6765\u6709\u6548\u63a7\u5236\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u9009\u62e9\u6027\u3002\u4e00\u5b9a\u91cf\u7684Co\u539f\u5b50\u63ba\u5165\u5230Ru\u50ac\u5316\u5242\u4e2d\u6765\u8feb\u4f7fRu\u4ea7\u751f\u5e94\u53d8\u3002\u7814\u7a76\u4eba\u5458\u53d1\u73b0\u5f53Ru\u5b58\u57283%\u7684\u6676\u683c\u5e94\u53d8\u65f6\uff0c\u5c55\u73b0\u4e86\u6781\u5176\u9ad8\u7684\u5bf94-\u785d\u57fa\u82ef\u4e59\u70ef\u7684\u52a0\u6c22\u9009\u62e9\u6027\uff0c\u76f8\u6bd4\u4e8e\u7eafRu\uff0c\u4ece66%\u63d0\u9ad8\u523099%\u3002\u7406\u8bba\u7814\u7a76\u8bc1\u5b9e\u6700\u4f18\u7684\u4fa7\u9762\u6676\u683c\u5e94\u53d8\u4fc3\u8fdb\u785d\u57fa\u52a0\u6c22\u4f46\u662f\u6291\u5236\u4e59\u70ef\u57fa\u7684\u52a0\u6c22\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe1 Co-Ru\u7eb3\u7c73\u7c92\u5b50\u7684\u7ed3\u6784\u793a\u610f\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-98546\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/08\/11-11.jpg\" alt=\"\" width=\"600\" height=\"600\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/08\/11-11.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/08\/11-11-150x150.jpg 150w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/08\/11-11-300x300.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a)\u00a0Co-Ru\u7eb3\u7c73\u7c92\u5b50\u7684TEM\u56fe\uff1b<\/p>\n<p>b) Co-Ru\u7eb3\u7c73\u7c92\u5b50\u7684STEM\u56fe\uff1b<\/p>\n<p>c) Co-Ru\u7eb3\u7c73\u7c92\u5b50\u7684EDS\u5143\u7d20\u5206\u5e03\u56fe\uff1b<\/p>\n<p>d) Co-Ru\u7eb3\u7c73\u7c92\u5b50\u7684\u539f\u5b50\u5206\u8fa8HAADF STEM\u56fe\uff1b<\/p>\n<p>e) \u51e0\u4f55\u76f8\u4f4d\u5206\u6790\u5f97\u5230\u7684e<sub>xx<\/sub>\u5e94\u53d8\u5206\u91cf\uff1b<\/p>\n<p><strong>\u56fe2 Co-Ru\u7eb3\u7c73\u7c92\u5b50\u7684XANES\u5149\u8c31<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-98547\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/08\/22-5.jpg\" alt=\"\" width=\"600\" height=\"523\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/08\/22-5.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/08\/22-5-300x262.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a) Ru K-edge\uff1b \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0<\/p>\n<p>b) Co K-edge\uff1b<\/p>\n<p>EXAFS\u5149\u8c31\uff1ac) Ru K-edge\uff1b d) Co K-edge.<\/p>\n<p><strong>\u56fe3 \u6027\u80fd\u6d4b\u8bd5<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-98903\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/08\/33-6.jpg\" alt=\"\" width=\"600\" height=\"1242\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/08\/33-6.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/08\/33-6-145x300.jpg 145w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/08\/33-6-495x1024.jpg 495w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a) 4-\u785d\u57fa\u82ef\u4e59\u70ef\u52a0\u6c22\u7684\u53cd\u6620\u7f51\u7edc\uff1b<\/p>\n<p>b)\u7528\u4e0d\u540c\u5e94\u53d8\u7684Co-Ru\u7eb3\u7c73\u7c92\u5b50\u50ac\u5316\u5242\u7684\u9009\u62e9\u6027\uff1b<\/p>\n<p>c) Co<sub>23<\/sub>-Ru<sub>0.77<\/sub>\u50ac\u5316\u5242\u52a0\u6c22\u5faa\u73af\u6d4b\u8bd5\uff1b<\/p>\n<p><strong>\u56fe4 \u53cd\u5e94\u8def\u7ebf\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-98723\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/08\/4444.jpg\" alt=\"\" width=\"600\" height=\"810\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/08\/4444.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/08\/4444-222x300.jpg 222w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a) Ru(0001)\u9762\u5bf9C<sub>2<\/sub>H<sub>4<\/sub>\u52a0\u6c22\u7684\u53cd\u5e94\u9014\u5f84\uff1b<\/p>\n<p>b) PhNO<sub>2<\/sub>\u5230PhNH<sub>2<\/sub>\u7684\u76f8\u5bf9\u80fd\u91cf\u5206\u5e03\u56fe\uff1b<\/p>\n<p><strong>\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n<p>\u7814\u7a76\u4eba\u5458\u8bc1\u5b9e\u901a\u8fc7\u5408\u7406\u7684\u8c03\u8282\u91d1\u5c5e\u6676\u683c\u5e94\u53d8\uff0c\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u9009\u62e9\u6027\u80fd\u591f\u5f97\u5230\u6709\u6548\u63a7\u5236\u3002HRTEM\u548cXAFS\u7814\u7a76\u8bc1\u660e\u5c06Co\u539f\u5b50\u63ba\u5165Ru\u50ac\u5316\u5242\u4e2d\u80fd\u591f\u538b\u7f29Ru\u6676\u683c\u5e94\u53d8\u3002\u7814\u7a76\u4eba\u5458\u53d1\u73b0\u57283%\u7684\u538b\u7f29\u4e0bRu\u50ac\u5316\u5242\u5bf94-\u785d\u57fa\u82ef\u4e59\u70ef\u7684\u9009\u62e9\u6027\u52a0\u6c22\u4ece66%\u63d0\u9ad8\u5230\u4e8699%\uff0c\u8fd9\u4e0e\u7406\u8bba\u8ba1\u7b97\u7ed3\u679c\u4e00\u81f4\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201706645\/full\" target=\"_blank\" rel=\"noopener\">Rational Control of the Selectivity of a Ruthenium Catalyst for Hydrogenation of 4-Nitrostyrene by Strain Regulation.<\/a> (Angewandte Chemmie International Edition, 2017, DOI:\u00a010.1002\/anie.201706645)<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u524d\u7ebfZ. Chen\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p><strong>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong><a href=\"http:\/\/www.ceshigu.com\/\"><strong>\u6d4b\u8bd5\u8c37<\/strong><\/a><strong>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u968f\u7740\u5316\u5b66\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u8282\u80fd\u6280\u672f\u7684\u53d1\u5c55\u8c03\u8282\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u9009\u62e9\u6027\u662f\u975e\u5e38\u53ef\u53bb\u7684\u3002\u901a\u5e38\uff0c\u5e26\u4e00\u4e2a\u5b98\u80fd\u56e2\u7684\u5206\u5b50\u80fd\u591f\u91c7\u7528\u4e00\u79cd\u91d1\u5c5e\u50ac\u5316\u5242\u8f6c\u5316\u4e3a\u5408\u9002\u7684\u4ea7\u7269\u3002\u4f46\u662f\u5f53\u5206\u5b50\u4e2d\u8fd8\u6709\u5176&#8230;<\/p>\n","protected":false},"author":3029,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-98545","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/98545"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/3029"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=98545"}],"version-history":[{"count":11,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/98545\/revisions"}],"predecessor-version":[{"id":99163,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/98545\/revisions\/99163"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=98545"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=98545"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=98545"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}