{"id":98155,"date":"2017-08-28T06:30:03","date_gmt":"2017-08-27T22:30:03","guid":{"rendered":"\/\/m.iemloyee.com\/?p=98155"},"modified":"2017-08-27T17:16:04","modified_gmt":"2017-08-27T09:16:04","slug":"science-bulletin%e4%b9%94%e9%94%a6%e4%b8%bd%e6%95%99%e6%8e%88%e8%af%be%e9%a2%98%e7%bb%84%e9%87%91%e5%b1%9e%e7%a9%ba%e6%b0%94%e7%94%b5%e6%b1%a0%e6%9c%80%e6%96%b0%e8%bf%9b%e5%b1%95-%e7%89%b9%e6%ae%8a","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=98155","title":{"rendered":"Sci. Bull.\u4e54\u9526\u4e3d\u6559\u6388\u8bfe\u9898\u7ec4\u91d1\u5c5e\u7a7a\u6c14\u7535\u6c60\u6700\u65b0\u8fdb\u5c55: \u7279\u6b8a\u5f62\u8c8c\u7684\u4e09\u7ef4\u86e4\u5f62\u53cc\u529f\u80fd\u9634\u6781\u50ac\u5316\u5242\u5728\u9ad8\u6027\u80fd\u950c\u7a7a\u7535\u6c60\u4e2d\u7684\u5e94\u7528"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u968f\u7740\u4eba\u4eec\u5bf9\u80fd\u6e90\u9700\u6c42\u7684\u6025\u5267\u589e\u957f\u5bfc\u81f4\u4e86\u5316\u77f3\u71c3\u6599\u8fc5\u901f\u6d88\u8017\uff0c\u4ece\u800c\u5f15\u53d1\u4e86\u73af\u5883\u95ee\u9898\u7684\u7206\u53d1\u3002\u7814\u7a76\u4e0e\u53d1\u5c55\u6e05\u6d01\u548c\u53ef\u6301\u7eed\u80fd\u6e90\u5b58\u50a8\u4e0e\u8f6c\u6362\u7cfb\u7edf\u6210\u4e3a\u4e86\u5f53\u4eca\u4e0d\u53ef\u907f\u514d\u7684\u8bfe\u9898\u3002\u76ee\u524d\uff0c\u5728\u4e0d\u540c\u80fd\u91cf\u5b58\u50a8\u548c\u8f6c\u6362\u7c7b\u578b\u4e2d\uff0c\u53ef\u5145\u7535\u950c\u7a7a\u7535\u6c60\u7531\u4e8e\u6210\u672c\u4f4e\u3001\u73af\u5883\u53cb\u597d\u3001\u5b89\u5168\u6027\u80fd\u9ad8\u3001\u6bd4\u80fd\u91cf\u5bc6\u5ea6\u9ad8\u7b49\u4f18\u52bf\u5f15\u8d77\u4e86\u4eba\u4eec\u7684\u5e7f\u6cdb\u5173\u6ce8\uff0c\u5728\u672a\u6765\u80fd\u6e90\u5e94\u7528\u9886\u57df\u8d77\u7740\u4e0d\u53ef\u7f3a\u5c11\u7684\u4f5c\u7528\u3002\u7136\u800c\u5bf9\u4e8e\u53ef\u5145\u7535\u950c\u7a7a\u7535\u6c60\u800c\u8a00\uff0c\u6700\u5927\u7684\u96be\u9898\u662f\u5f00\u53d1\u9ad8\u6548\u5ec9\u4ef7\u7684\u975e\u8d35\u91d1\u5c5e\u53cc\u529f\u80fd\u50ac\u5316\u5242\uff0c\u4ee5\u63d0\u9ad8\u6c27\u6c14\u5728\u6c27\u8fd8\u539f\u4ee5\u53ca\u6c27\u6790\u51fa\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u7f13\u6162\u7684\u52a8\u529b\u5b66\uff0c\u4ece\u800c\u8fdb\u4e00\u6b65\u63d0\u9ad8\u7535\u6c60\u7684\u5145\u653e\u7535\u6548\u7387\uff0c\u51cf\u5c11\u80fd\u91cf\u635f\u8017\u3002\u78b3\u8f7d\u91d1\u5c5e\u6c27\u5316\u7269\u590d\u5408\u6750\u6599\u7531\u4e8e\u5177\u6709\u826f\u597d\u7684\u6c27\u8fd8\u539f\u6216\u6c27\u6790\u51fa\u53cd\u5e94\u6d3b\u6027\u88ab\u4eba\u4eec\u5e7f\u6cdb\u7814\u7a76\u3002\u5176\u4e2dMnOX<\/sub>\u7531\u4e8e\u5177\u6709\u4e30\u5bcc\u7684\u6c27\u5316\u6001\u4ee5\u53ca\u72ec\u7279\u7684\u5316\u5b66\u7ec4\u6210\u4e0e\u6676\u578b\u7ed3\u6784\u6210\u4e3a\u516c\u8ba4\u7684\u6c27\u8fd8\u539f\u50ac\u5316\u5242\u3002\u6b64\u5916\uff0c\u4f5c\u4e3a\u8fc7\u6e21\u91d1\u5c5e\u7684Ni\u3001Co\u4e0eMnOX<\/sub>\u7684\u590d\u5408\u6750\u6599\u5df2\u7ecf\u88ab\u5e7f\u6cdb\u62a5\u9053\u4e3a\u9ad8\u6027\u80fd\u53cc\u529f\u80fd\u50ac\u5316\u5242\u3002\u800c\u78b3\u8f7d\u8fc7\u6e21\u91d1\u5c5eFe\u4e0eMnOX<\/sub>\u7684\u590d\u5408\u6750\u6599\u5374\u5f88\u5c11\u6709\u4eba\u5173\u6ce8\u3002\u56e0\u6b64\u5982\u4f55\u5236\u5907\u4f5c\u4e3a\u9ad8\u6d3b\u6027\u4e0e\u9ad8\u7a33\u5b9a\u6027\u7684\u78b3\u8f7d\u94c1\u9530\u6c27\u5316\u7269\u53cc\u529f\u80fd\u50ac\u5316\u5242\u4f9d\u7136\u5b58\u5728\u6311\u6218\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e1c\u534e\u5927\u5b66\u73af\u5883\u5b66\u9662\u4e54\u9526\u4e3d\u6559\u6388<\/strong>\u8bfe\u9898\u7ec4\u5728Science Bulletin<\/strong>\u4e0a\u53d1\u8868\u9898\u4e3a\u201cA novel composite (FMC) to serve as a durable 3D-clam-shaped bifunctional cathode catalyst for both primary and rechargeable zinc-air batteries<\/strong>.\u201d\u7684\u6587\u7ae0\uff0c\u7814\u7a76\u901a\u8fc7\u4e24\u6b65\u6c34\u70ed\u5408\u6210\u53ca\u9ad8\u6e29\u7119\u70e7\u6cd5\u5206\u522b\u8bbe\u8ba1\u3001\u5408\u6210\u4e86\u94c1-\u9530-\u78b3\u57fa\uff08FMC\uff09\u7cfb\u5217\u50ac\u5316\u5242\u3002\u8be5\u50ac\u5316\u5242\u5448\u73b0\u51fa\u72ec\u7279\u7684\u5f62\u8c8c\u2014\u2014\u4e09\u7ef4\u86e4\u5f62\uff0c\u5177\u6709\u8f83\u5927\u7684\u6bd4\u8868\u9762\u79ef\u3002\u901a\u8fc7\u6539\u53d8\u4e0d\u540c\u7684\u7119\u70e7\u65f6\u95f4\u5236\u5907\u51fa\u4e0d\u540c\u5f62\u8c8c\u548c\u6d3b\u6027\u7684FMC-x\u50ac\u5316\u5242\uff0c\u5e76\u5229\u7528\u7ebf\u6027\u4f0f\u5b89\u6cd5\u626b\u63cf\u3001\u6e10\u53d8\u7535\u6d41\u53d1\u7535\u3001\u957f\u65f6\u95f4\u6052\u6d41\u653e\u7535\u4ee5\u53ca\u6052\u6d41\u5145\u653e\u7535\u7b49\u65b9\u6cd5\u5bf9\u50ac\u5316\u5242\u6d3b\u6027\u548c\u950c\u7a7a\u4e00\u6b21\u4ee5\u53ca\u4e8c\u6b21\u7535\u6c60\u6027\u80fd\u8fdb\u884c\u6d4b\u8bd5\uff0c\u91c7\u7528\u626b\u63cf\u7535\u955c\uff08SEM\uff09\u3001\u900f\u5c04\u7535\u955c\uff08TEM\uff09\u3001X-\u5c04\u7ebf\u884d\u5c04\uff08XRD\uff09\u3001\u7269\u7406\u5438\u8131\u9644\u6bd4\u8868\u9762\u79ef\uff08BET\uff09\u7b49\u7269\u7406\u5149\u8c31\u8868\u5f81\u65b9\u6cd5\u5bf9\u50ac\u5316\u5242\u7684\u5fae\u89c2\u5f62\u8c8c\u7ed3\u6784\u3001\u50ac\u5316\u5242\u7684\u8868\u9762\u7ec4\u6210\u6210\u5206\u53ca\u50ac\u5316\u5242\u7684\u6bd4\u8868\u9762\u79ef\u8fdb\u884c\u8868\u5f81\u3002\u540c\u65f6\uff0c\u5176\u4e2dFMC-3\u7684\u50ac\u5316\u6d3b\u6027\u4ee5\u53ca\u53cc\u529f\u80fd\u6027\u80fd\u660e\u663e\u4f18\u4e8e\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u3001\u540c\u7c7b\u578b\u7684\u5176\u4ed6\u50ac\u5316\u5242\u4ee5\u53ca\u50ac\u5316\u5242\u5355\u4f53\u3002\u5f00\u8def\u7535\u538b(OCV)\u8fbe\u52301.48V\uff0c\u529f\u7387\u5bc6\u5ea6\u8fbe\u5230349 mW cm-2<\/sup>\uff0c\u8fdc\u4f18\u4e8e20% Pt\/C\u50ac\u5316\u5242\u7684118 mW cm-2<\/sup>\uff0c\u540c\u65f6\u83b7\u5f97\u6bd4\u5bb9\u91cf\u5bc6\u5ea6780 mAh g-1<\/sup>\u3002\u6b64\u5916\uff0c\u5728\u591a\u79cd\u5145\u653e\u7535\u6761\u4ef6\u4e0b\u4ea6\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u5145\u653e\u7535\u7a33\u5b9a\u6027\uff0c\u5e76\u4e14\u7ed3\u5408\u7269\u7406\u8868\u5f81\u6280\u672f\u5206\u6790\u50ac\u5316\u5242\u7535\u5316\u5b66\u6d4b\u8bd5\u524d\u540e\u5f62\u8c8c\u7684\u6539\u53d8\uff0c\u901a\u8fc7\u5236\u5907\u5176\u5b83\u5355\u4f53\u50ac\u5316\u5242\u4ee5\u53ca\u6539\u53d8\u70ed\u5904\u7406\u6761\u4ef6\uff0c\u5206\u6790\u4e86\u4e09\u5143\u50ac\u5316\u5242\u7684\u5f62\u6210\u5386\u7a0b\u53ca\u50ac\u5316\u673a\u5236\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1. \u50ac\u5316\u5242\u5236\u5907\u8fc7\u7a0b\u53ca\u5176\u5728\u950c\u7a7a\u7535\u6c60\u4e2d\u7684\u5e94\u7528\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09<\/strong>\u50ac\u5316\u5242\u7684\u5408\u6210\u5de5\u7a0b\uff1b \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0<\/p>\n

\uff08b\uff09<\/strong>\u50ac\u5316\u5242\u5728\u950c\u7a7a\u7535\u6c60\u4e2d\u5e94\u7528<\/p>\n

\u56fe2. \u50ac\u5316\u5242\u7684SEM\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a-c\uff09<\/strong>MnO2<\/sub>\u50ac\u5316\u5242\u7684SEM\u56fe\uff1b \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0<\/p>\n

\uff08d-f\uff09<\/strong>FMC-3\u7684SEM\u56fe<\/p>\n

\u56fe3. \u50ac\u5316\u5242\u7684TEM\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a-c\uff09<\/strong>FMC-3\u7684TEM\u56fe\uff1b \u00a0 \u00a0<\/p>\n

\uff08d\uff09<\/strong>FMC-3\u7684HRTEM\u56fe\u53caFFT\u56fe<\/p>\n

\u56fe4. \u50ac\u5316\u5242\u7684XRD\u53caEDS\u7684\u5206\u6790<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a-b\uff09<\/strong>\u50ac\u5316\u5242\u7684XRD\u56fe\uff1b \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0\u00a0<\/p>\n

\uff08c\uff09<\/strong>FMC-3\u7684EDS\u56fe\uff1b \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0\u00a0<\/p>\n

\uff08d\uff09<\/strong>FMC-3\u50ac\u5316\u5242\u7684\u5143\u7d20\u6bd4\u4f8b\u56fe<\/p>\n

\u56fe5. \u50ac\u5316\u5242\u7684\u6c27\u8fd8\u539f\u4ee5\u53ca\u6c27\u6790\u51fa\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a-b\uff09<\/strong>\u4e0d\u540c\u50ac\u5316\u5242\u7684\u7ebf\u6027\u626b\u63cf\u56fe\uff1b<\/p>\n

\uff08c\uff09<\/strong>FMC-3\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u6d4b\u8bd5\u56fe\uff1b<\/p>\n

\uff08d\uff09<\/strong>FMC-3\u50ac\u5316\u5242\u5728\u4e0d\u540c\u8f6c\u901f\u4e0b\u7684\u7ebf\u6027\u626b\u63cf\u56fe\uff0c\u63d2\u56fe\u4e3a\u7535\u5b50\u8f6c\u79fb\u56fe<\/p>\n

\u56fe6. \u50ac\u5316\u5242\u5728\u4e00\u6b21\u950c\u7a7a\u7535\u6c60\u4e2d\u7684\u5e94\u7528\u53ca\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09<\/strong>\u4e00\u6b21\u950c\u7a7a\u7535\u6c60\u793a\u610f\u56fe\uff1b \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0<\/p>\n

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\uff08c\uff09<\/strong>FMC-3\u50ac\u5316\u5242\u6781\u5316\u66f2\u7ebf\u4e0e\u529f\u7387\u5bc6\u5ea6\u7a33\u5b9a\u6027\u56fe\uff1b \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0<\/p>\n

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\"\"<\/p>\n

\uff08a\uff09<\/strong>\u53ef\u5145\u5f0f\u950c\u7a7a\u7535\u6c60\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff09<\/strong>\u4e0d\u540c\u50ac\u5316\u5242\u7684\u5145\u653e\u7535\u6781\u5316\u66f2\u7ebf\u56fe;<\/p>\n

\uff08c\uff09<\/strong>\u4e0d\u540c\u50ac\u5316\u5242\u7684\u5145\u653e\u7535\u56fe\uff0c\u5faa\u73af\u6761\u4ef6\u4e3a\u7535\u6d41\u5bc6\u5ea630mAcm-2<\/sup>\uff0c\u5145\u653e\u7535\u65f6\u95f41\u5c0f\u65f6; FMC-3\u50ac\u5316\u5242\u7684\u5145\u653e\u7535\u56fe\uff0c<\/p>\n

\uff08d\uff09<\/strong>\u5faa\u73af\u6761\u4ef6\u4e3a\u7535\u6d41\u5bc6\u5ea620mAcm-2<\/sup>\uff0c\u5145\u653e\u7535\u65f6\u95f410\u5206\u949f;<\/p>\n

\uff08e\uff09<\/strong>\u5faa\u73af\u6761\u4ef6\u4e3a\u7535\u6d41\u5bc6\u5ea6100mAcm-2<\/sup>\uff0c\u5145\u653e\u7535\u65f6\u95f44\u5c0f\u65f6;<\/p>\n

\uff08f\uff09<\/strong>\u5faa\u73af\u6761\u4ef6\u4e3a\u7535\u6d41\u5bc6\u5ea660mAcm-2<\/sup>\uff0c\u5145\u75351\u5c0f\u65f6\uff1b\u7535\u6d41\u5bc6\u5ea615mAcm-2<\/sup>\uff0c\u653e\u75354\u5c0f\u65f6<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

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\u539f\u6587\u94fe\u63a5<\/strong>\uff1aA novel composite (FMC) to serve as a durable 3D-clam-shaped bifunctional cathode catalyst for both primary and rechargeable zinc-air batteries.<\/a>\uff08Science Bulletin, 2017, DOI: https:\/\/doi.org\/10.1016\/j.scib.2017.08.006\uff09\u00a0<\/p>\n

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\u672c\u6587\u7531Science Bulletin\u7f16\u8f91\u90e8\u4f9b\u7a3f\uff0c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u7ec4Jane915126\u6574\u7406\u7f16\u8f91\u3002\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065952\u201d\u3002<\/p>\n

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