{"id":96789,"date":"2017-08-21T06:30:30","date_gmt":"2017-08-20T22:30:30","guid":{"rendered":"\/\/m.iemloyee.com\/?p=96789"},"modified":"2017-08-21T10:17:41","modified_gmt":"2017-08-21T02:17:41","slug":"%e6%ad%a6%e6%b1%89%e7%90%86%e5%b7%a5%e9%ba%a6%e7%ab%8b%e5%bc%banano-energy%ef%bc%9a%e5%9f%ba%e4%ba%8e%e4%b8%89%e7%bb%b4%e9%92%92%e6%b0%a7%e5%8c%96%e7%89%a9%e6%b0%b4%e5%87%9d%e8%83%b6%e7%9a%84%e9%ab%98","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=96789","title":{"rendered":"\u6b66\u6c49\u7406\u5de5\u9ea6\u7acb\u5f3aNano Energy\uff1a\u57fa\u4e8e\u4e09\u7ef4\u9492\u6c27\u5316\u7269\u6c34\u51dd\u80f6\u7684\u9ad8\u8d28\u91cf\u8d1f\u8f7d\u7684\u9ad8\u500d\u7387\u50a8\u9502\u6750\u6599"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u9502\u79bb\u5b50\u7535\u6c60\uff08LIBs\uff09\u5728\u80fd\u6e90\u5b58\u50a8\u4e2d\u5360\u6709\u91cd\u8981\u5730\u4f4d\uff0c\u5176\u6bd4\u5bb9\u91cf\u3001\u5145\u653e\u7535\u901f\u7387\u548c\u5faa\u73af\u5bff\u547d\u4e9f\u9700\u8fdb\u4e00\u6b65\u4f18\u5316\u3002\u9492\u6c27\u5316\u7269\u5177\u6709\u9ad8\u7406\u8bba\u5bb9\u91cf\u548c\u4e30\u5bcc\u7684\u6765\u6e90\uff0c\u88ab\u8ba4\u4e3a\u662f\u4e00\u79cd\u5f88\u6709\u6f5c\u529b\u7684LIBs\u7535\u6781\u6750\u6599\uff0c\u7136\u800c\u4f4e\u7535\u5bfc\u7387\u548c\u7f13\u6162\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u9650\u5236\u4e86\u5176\u5e7f\u6cdb\u7684\u5e94\u7528\u3002\u6839\u636e\u6269\u6563\u52a8\u529b\u5b66\u6761\u4ef6\uff0c\u5229\u7528\u7eb3\u7c73\u5e26\u6216\u7eb3\u7c73\u7247\u8d85\u8584\u7684\u51e0\u4f55\u7279\u6027\u51cf\u5c0f\u79bb\u5b50\u6269\u6563\u957f\u5ea6\u80fd\u6709\u6548\u63d0\u5347\u9502\u79bb\u5b50\u5728\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u7684\u6269\u6563\u901f\u7387\u3002\u4f46\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\uff0c\u4e00\u65b9\u9762\u666e\u901a\u8d85\u8584\u5c42\u72b6\u7eb3\u7c73\u6750\u6599\u7684\u81ea\u56e2\u805a\u53ca\u81ea\u5806\u53e0\u4f1a\u9020\u6210\u7535\u6c60\u7684\u5bb9\u91cf\u635f\u5931\uff0c\u5e76\u9650\u5236\u7535\u6c60\u5feb\u901f\u5145\u653e\u7535\u6027\u80fd\u7684\u63d0\u5347\uff1b\u53e6\u4e00\u65b9\u9762\uff0c\u5728\u7535\u6781\u6750\u6599\u7684\u8d28\u91cf\u8d1f\u8f7d\u5f88\u9ad8\u65f6\uff0c\u4f34\u968f\u4ee5\u4e0b\u96be\u9898\uff1a\uff081\uff09\u79bb\u5b50\u7684\u8f93\u8fd0\u53ca\u7535\u5b50\u7684\u4f20\u5bfc\u8def\u5f84\u589e\u957f\uff1b\uff082\uff09\u7ec6\u5fae\u7684\u5f62\u8c8c\u6539\u53d8\u53ef\u80fd\u4f1a\u9020\u6210\u6750\u6599\u6574\u4f53\u7ed3\u6784\u7684\u7834\u574f\uff1b\uff083\uff09\u7535\u6781\u6750\u6599\u5728\u6d82\u8986\u7684\u8fc7\u7a0b\u4e2d\u6613\u4ece\u91d1\u5c5e\u7b94\u7247\uff08\u96c6\u6d41\u4f53\uff09\u5265\u79bb\u3002\u56e0\u6b64\uff0c\u5b9e\u73b0\u9ad8\u8d28\u91cf\u8d1f\u8f7d\u4e0b\u7684\u9ad8\u6027\u80fd\u7535\u6781\u6750\u6599\u5145\u6ee1\u6311\u6218\uff0c\u5f15\u8d77\u5e7f\u6cdb\u79d1\u7814\u5de5\u4f5c\u7684\u5173\u6ce8\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6b66\u6c49\u7406\u5de5\u5927\u5b66\u9ea6\u7acb\u5f3a\u6559\u6388\u548c\u9b4f\u6e6b\u9f99\u535a\u58eb\uff08\u5171\u540c\u901a\u8baf\uff09<\/strong>\u4ee5\u201cNanoribbons and Nanoscrolls Intertwined Three-Dimensional Vanadium Oxide Hydrogels for High-Rate Lithium Storage at High Mass Loading Level.\u201d\u4e3a\u9898Nano Energy\u4e0a\u53d1\u8868\u6587\u7ae0\u62a5\u9053\u4e86\u4e00\u79cd\u65b0\u578bH2<\/sub>V3<\/sub>O8<\/sub>\u4e09\u7ef4\u6c34\u51dd\u80f6\u7ed3\u6784\u590d\u5408\u6750\u6599\u3002\u8be5\u6c34\u51dd\u80f6\u7531\u8d85\u8584\u7eb3\u7c73\u5e26\u548c\u81ea\u5377\u66f2\u7eb3\u7c73\u5377\u76f8\u4e92\u4ea4\u8054\u7ec4\u6210\u3002\u5f53\u7528\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u65f6\uff0c\u7535\u8377\u50a8\u5b58\u4e2d\u7535\u5bb9\u6027\u8d21\u732e\u5927\u5e45\u63d0\u9ad8\uff0c\u8868\u660e\u6c34\u51dd\u80f6\u7ed3\u6784\u5bf9Li+<\/sup>\u7684\u6269\u6563\u52a8\u529b\u5b66\u5177\u6709\u5927\u5e45\u63d0\u5347\u4f5c\u7528\uff0c\u4ece\u800c\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u8fdb\u4e00\u6b65\u57fa\u4e8e\u6c34\u51dd\u80f6\u7684\u51e0\u4f55\u7279\u6027\uff0c\u4f5c\u8005\u5f15\u5165\u4e86\u78b3\u7eb3\u7c73\u7ba1\uff08CNTs\uff09\u7ec4\u88c5\u67d4\u6027\u8584\u819c\uff0c\u5b9e\u73b0\u4e86\u5728\u9ad8\u8d28\u91cf\u8d1f\u8f7d\u4e0b\uff0813 mg cm-2<\/sup>\uff09\u7684\u4f18\u5f02\u50a8\u9502\u6027\u80fd\u3002<\/p>\n

\u3010\u56fe\u6587\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u56fe\u4e00 \u00a0H2<\/sub>V3<\/sub>O8<\/sub>\u6c34\u51dd\u80f6\u53ca\u7eb3\u7c73\u7ebf\u7684\u5408\u6210\u673a\u7406\u56fe\u53ca\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a\uff09H2<\/sub>V3<\/sub>O8<\/sub>\u6c34\u51dd\u80f6\u548c\u7eb3\u7c73\u7ebf\u7684\u5408\u6210\u673a\u7406\u56fe\uff1b<\/p>\n

b,c\uff09\u7eb3\u7c73\u7ebf\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

d,e\uff09\u6c34\u51dd\u80f6\u7684SEM\u56fe\u50cf\u3002<\/p>\n

\u56fe\u4e8c H2<\/sub>V3<\/sub>O8<\/sub>\u6c34\u51dd\u80f6\u53ca\u7eb3\u7c73\u7ebf\u7684XRD, XPS, N2<\/sub>\u7b49\u6e29\u5438\u8131\u9644\u66f2\u7ebf<\/strong><\/p>\n

\"\"<\/p>\n

a\uff09\u6c34\u51dd\u80f6\u548c\u7eb3\u7c73\u7ebf\u7684XRD\u56fe\u8c31\uff1b<\/p>\n

b\uff09\u6c34\u51dd\u80f6\u548c\u7eb3\u7c73\u7ebfV\u76842p\u8f68\u9053XPS\u5206\u6790\uff1b<\/p>\n

c\uff09\u6c34\u51dd\u80f6\u548c\u7eb3\u7c73\u7ebf\u7684N2<\/sub>\u7b49\u6e29\u5438\u8131\u9644\u66f2\u7ebf\u3002<\/p>\n

\u56fe\u4e09 H2<\/sub>V3<\/sub>O8<\/sub>\u6c34\u51dd\u80f6\u7684TEM\uff0c\u6676\u4f53\u7ed3\u6784\u5206\u6790\uff0c\u6c34\u51dd\u80f6\u7684\u7ed3\u6784\u5f62\u6210\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

a\uff09\u6c34\u51dd\u80f6\u7684TEM\u56fe\u8c31\uff1b<\/p>\n

b,c\uff09\u7eb3\u7c73\u5e26\u7684HRTEM\u548cSAED\u56fe\u8c31\uff1b<\/p>\n

d\uff09\u7eb3\u7c73\u5377\u7684HRTEM\u56fe\u8c31\uff1b<\/p>\n

e\uff09\u7eb3\u7c73\u5e26\u7684AFM\u56fe\u50cf\uff1b<\/p>\n

f\uff09\u6c34\u51dd\u80f6\u7684\u7ed3\u6784\u5f62\u6210\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe\u56db H2<\/sub>V3<\/sub>O8<\/sub>\u6c34\u51dd\u80f6\u548c\u7eb3\u7c73\u7ebf\u7684\u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a\uff090.1 mV s-1<\/sup>\u626b\u901f\u4e0b\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

b\uff090.1 A g-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

c\uff09\u500d\u7387\u6027\u80fd\u66f2\u7ebf\uff1b<\/p>\n

d\uff091.0 A g-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5faa\u73af\u6027\u80fd\u66f2\u7ebf\uff1b<\/p>\n

\u56fe\u4e94 \u67d4\u6027H2<\/sub>V3<\/sub>O8<\/sub>\u6c34\u51dd\u80f6\/CNTs\u8584\u819c\u7684\u5236\u5907\u793a\u610f\u56fe\u548c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a\uff09\u67d4\u6027\u6c34\u51dd\u80f6\/CNTs\u8584\u819c\u7684\u5236\u5907\u793a\u610f\u56fe\uff1b<\/p>\n

b\uff09\u6c34\u51dd\u80f6\/CNTs\u590d\u5408\u6c34\u51dd\u80f6\u7684SEM\u56fe<\/p>\n

c,d\uff09\u6c34\u51dd\u80f6\/CNTs\u8584\u819c\u6a2a\u622a\u9762\u7684SEM\u56fe\uff1b<\/p>\n

e\uff09\u6c34\u51dd\u80f6\/CNTs\u8584\u819c\u7684\u500d\u7387\u6027\u80fd\uff1b<\/p>\n

f\uff09\u6c34\u51dd\u80f6\/CNTs\u8584\u819c\u5728\u4e0d\u540c\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

g\uff09\u6c34\u51dd\u80f6\/CNTs\u8584\u819c\u57284.0 A g-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5faa\u73af\u6027\u80fd\u66f2\u7ebf\uff1b<\/p>\n

h\uff09\u6c34\u51dd\u80f6\/CNTs\u8584\u819c\u7684\u9762\u79ef\u6bd4\u5bb9\u91cfvs.<\/em>\u9762\u79ef\u7535\u6d41\u5bc6\u5ea6\u66f2\u7ebf<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u8be5\u7814\u7a76\u5229\u7528\u666e\u9002\u7684\u6db2\u76f8\u5265\u79bb\u6cd5\uff08\u5305\u62ecLi+<\/sup>, Na+<\/sup>, K+<\/sup>, Mg2+<\/sup>, Mn2+<\/sup>, Cu2+<\/sup> \u548c Fe3+<\/sup>\u5747\u53ef\u7528\u4e8e\u9492\u6c27\u5316\u7269\u6c34\u51dd\u80f6\u7684\u5236\u5907\uff09\u9996\u6b21\u7684\u5236\u5907\u4e86\u7531\u7eb3\u7c73\u5e26\u548c\u7eb3\u7c73\u5377\u76f8\u4e92\u4ea4\u8054\u5f62\u6210\u7684\u9492\u6c27\u5316\u7269\u6c34\u51dd\u80f6\u3002\u5f53\u7528\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u65f6\uff0c\u6d4b\u8bd5\u7ed3\u679c\u8868\u660e\u5bf9Li+<\/sup>\u7684\u6269\u6563\u52a8\u529b\u5b66\u5177\u6709\u5927\u5e45\u63d0\u5347\u4f5c\u7528\uff0c\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u7ed3\u5408\u5176\u72ec\u7279\u7684\u4e09\u7ef4\u7ed3\u6784\u7279\u6027\uff0c\u8fdb\u4e00\u6b65\u4e0eCNTs\u590d\u5408\u5236\u5907\u4e86\u65e0\u7c98\u7ed3\u5242\u7684\u67d4\u6027\u8584\u819c\uff0c\u5927\u5e45\u63d0\u5347\u4e86\u6750\u6599\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u5373\u4f7f\u5728\u9ad8\u8d1f\u8f7d\u4e0b\uff0c\u8be5\u8584\u819c\u4ecd\u5177\u5907\u6709\u4f18\u5f02\u7684\u50a8\u9502\u6027\u80fd\uff1a\u5f53\u8d1f\u8f7d\u91cf\u4e3a13 mg cm\u22122<\/sup>\u65f6\uff0c\u5176\u9762\u79ef\u6bd4\u5bb9\u91cf\u9ad8\u8fbe2.70 mAh cm\u22122<\/sup>\uff08\u7535\u6d41\u5bc6\u5ea6\u4e3a0.91 mA cm\u22122<\/sup>\uff09\uff0c\u540c\u65f6\u517c\u5177\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\uff0818.2 mA cm\u22122<\/sup>\u7684\u9762\u79ef\u7535\u6d41\u5bc6\u5ea6\u4e0b\u9762\u79ef\u5bb9\u91cf\u4e3a1.16 mAh cm\u22122<\/sup>\uff09\u3002<\/p>\n

\u8fd9\u4e00\u5de5\u4f5c\u4e2d\u7ec4\u88c5\u590d\u5408\u6c34\u51dd\u80f6\u7684\u65b9\u6cd5\u666e\u9002\u6027\u9ad8\uff0c\u6709\u671b\u62d3\u5c55\u81f3\u5176\u5b83\u8d85\u8584\u6750\u6599\u7684\u5408\u6210\u6784\u7b51\u3002\u6b64\u5916\uff0c\u672c\u5de5\u4f5c\u5b9e\u73b0\u4e86\u9492\u6c27\u5316\u7269\u7535\u6781\u6750\u6599\u5728\u9ad8\u8d28\u91cf\u8d1f\u8f7d\u4e0b\u7684\u4f18\u5f02\u7535\u5316\u5b66\u6027\u80fd\uff0c\u4e3a\u5b9e\u9645\u5e94\u7528\u63d0\u4f9b\u4e86\u53ef\u80fd\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Nanoribbons and Nanoscrolls Intertwined Three-Dimensional Vanadium Oxide Hydrogels for High-Rate Lithium Storage at High Mass Loading Level<\/a>.( Nano Energy,2017,DOI:http:\/\/dx.doi.org\/10.1016\/j.nanoen.2017.08.011)<\/p>\n

\u3010\u76f8\u5173\u4f18\u8d28\u6587\u732e\u63a8\u8350\u3011<\/strong><\/p>\n

    \n
  1. Track batteries degrading in real time<\/a>. Nature 2017 546,469.<\/li>\n
  2. Porous One-Dimensional Nanomaterials: Design, Fabrication and Applications in Electrochemical Energy Storage”, Advanced Materials.<\/a>, 2017, 1602300<\/li>\n
  3. Layer-by-Layer Na3<\/sub>V2<\/sub>(PO4<\/sub>)3<\/sub> Embedded In Reduced Graphene Oxide as Superior Rate and Ultralong-Life Sodium-Ion Battery Cathode.<\/a>, Advanced Energy Materials, 2016, 1600389<\/li>\n
  4. Novel Polygonal Vanadium Oxide Nanoscrolls as Stable Cathode for Lithium Storage, Advanced Functional Materials<\/a>. 2015, 25, 1773\u20131779.<\/li>\n
  5. Nanowire templated semihollow bicontinuous graphene scrolls: designed construction, mechanism, and enhanced energy storage performance.<\/a>[J].\u00a0Journal of the American Chemical Society,\u00a0135(48), 18176-18182.<\/li>\n<\/ol>\n

    \u3010\u56e2\u961f\u7b80\u4ecb\u3011<\/strong><\/p>\n

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    \u9ea6\u7acb\u5f3a\u6559\u6388\u8bfe\u9898\u7ec4\u94fe\u63a5:http:\/\/mai.group.whut.edu.cn<\/strong><\/p>\n

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