{"id":96529,"date":"2017-08-16T14:00:08","date_gmt":"2017-08-16T06:00:08","guid":{"rendered":"\/\/m.iemloyee.com\/?p=96529"},"modified":"2017-08-16T14:42:58","modified_gmt":"2017-08-16T06:42:58","slug":"%e4%b8%ad%e7%a7%91%e9%99%a2%e4%b8%8a%e6%b5%b7%e6%9c%89%e6%9c%ba%e6%89%80%e8%83%a1%e9%87%91%e6%b3%a2%e8%af%be%e9%a2%98%e7%bb%84%ef%bc%9a%e5%9c%a8%e6%b8%a9%e5%92%8c%e6%9d%a1%e4%bb%b6%e4%b8%8b%e5%88%b6","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=96529","title":{"rendered":"\u4e2d\u79d1\u9662\u4e0a\u6d77\u6709\u673a\u6240\u80e1\u91d1\u6ce2\u8bfe\u9898\u7ec4\uff1a\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u5236\u5907\u56db\u6c1f\u4e59\u70ef\u5e76\u7528\u4e8e\u6709\u673a\u5408\u6210"},"content":{"rendered":"<p><strong><b>\u3010<\/b><\/strong><strong><b>\u6210\u679c\u7b80\u4ecb<\/b><\/strong><strong><b>\u3011<\/b><\/strong><\/p>\n<p>\u00a0 \u00a0 \u00a0 \u00a0 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\u00a0 \u00a0 \u00a0 \u6700\u8fd1\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u4e0a\u6d77\u6709\u673a\u5316\u5b66\u7814\u7a76\u6240\u6709\u673a\u6c1f\u5316\u5b66\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u80e1\u91d1\u6ce2\u8bfe\u9898\u7ec4\u6210\u529f\u5b9e\u73b0\u4e86\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u5feb\u901f\u5c0f\u91cf\u5236\u5907\u56db\u6c1f\u4e59\u70ef\uff0c\u5e76\u7528\u4e8e\u6709\u673a\u5408\u6210\u4e2d\u3002\u4ed6\u4eec\u4ee5\u5b9e\u9a8c\u5ba4\u5e38\u89c1\u6613\u5f97\u7684\u4e09\u6c1f\u7532\u57fa\u4e09\u7532\u57fa\u7845\u70f7\uff08Me<sub>3<\/sub>SiCF<sub>3<\/sub>\uff09\u4e3a\u539f\u6599\uff08\u4e00\u822c\u91c7\u75282.5-3.0 mmol\u91cf\uff09\uff0c\u4ee5\u7898\u5316\u94a0\u4e3a\u50ac\u5316\u5242\uff085 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decoding=\"async\" class=\"aligncenter size-full wp-image-96530\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/08\/1-37.jpg\" alt=\"\" width=\"600\" height=\"210\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/08\/1-37.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/08\/1-37-300x105.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u5b9e\u9a8c\u5ba4\u6761\u4ef6\u4e0b\u539f\u4f4d\u751f\u6210\u56db\u6c1f\u4e59\u70ef\u4ee5\u53ca\u56db\u6c1f\u4e59\u70ef\u53c2\u4e0e\u7684\u6c1f\u70f7\u57fa\u5316\u53cd\u5e94<\/p>\n<p><strong><b>\u56fe2 <\/b><\/strong><strong><b>\u524d\u671f\u7814\u7a76\u4e0e\u672c\u7814\u7a76\u7684\u5dee\u522b<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-96531\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/08\/2-37.jpg\" alt=\"\" width=\"600\" height=\"277\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/08\/2-37.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/08\/2-37-300x139.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u901a\u8fc7\u4e8c\u6c1f\u5361\u5bbe\u548cTFE\u4e0eTMSCF<sub>3<\/sub>\u8fdb\u884c\u6c1f\u70f7\u57fa\u5316<\/p>\n<p><strong><b>\u3010\u7814\u7a76\u5185\u5bb9\u3011<\/b><\/strong><\/p>\n<p>\u00a0 \u00a0 \u00a0 \u00a0 \u5728\u6210\u529f\u5b9e\u73b0\u50ac\u5316\u4ea7\u751f\u56db\u6c1f\u4e59\u70ef\u7684\u57fa\u7840\u4e0a\uff0c\u4ed6\u4eec\u5229\u7528\u4e92\u901a\u7684\u53cc\u53cd\u5e94\u5668\uff0c\u628a\u9884\u5148\u5236\u5f97\u7684\u56db\u6c1f\u4e59\u70ef\u6210\u529f\u5e94\u7528\u4e8e\u6709\u673a\u542b\u6c1f\u5206\u5b50\u7684\u5408\u6210\u4e2d\u3002\u4e00\u65b9\u9762\uff0c\u4ed6\u4eec\u5229\u7528\u56db\u6c1f\u4e59\u70ef\u4e0e\u6c1f\u5316\u94ef\u3001\u6c2f\u5316\u4e9a\u94dc\u53ca\u914d\u4f531,10-\u83f2\u5570\u5549\uff08phen\uff09\u53cd\u5e94\u5236\u5f97\u4e94\u6c1f\u4e59\u57fa\u94dc\u7edc\u5408\u7269CF<sub>3<\/sub>CF<sub>2<\/sub>Cu(phen)\uff0c\u540e\u8005\u518d\u4e0e\u82b3\u57fa\u6216\u8005\u6742\u82b3\u57fa\u7898\u5316\u7269\u53cd\u5e94\u5236\u5f97\u5404\u79cd\u4e94\u6c1f\u4e59\u57fa\u53d6\u4ee3\u7684\u82b3\u70c3\u6216\u6742\u82b3\u70c3\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u7528\u82ef\u915a\u94a0\u7b49\u6c27\u4eb2\u6838\u8bd5\u5242\u4ee3\u66ff\u6c1f\u5316\u94ef\uff0c\u5728\u6c2f\u5316\u4e9a\u94dc\u548c\u914d\u4f531,10-\u83f2\u5570\u5549\u5b58\u5728\u4e0b\u5bf9\u56db\u6c1f\u4e59\u70ef\u53d1\u751f\u6c27-\u94dc\u5316\u53cd\u5e94\u751f\u62102-\u82b3\u6c27\u57fa-1,1,2,2-\u56db\u6c1f\u4e59\u57fa\u94dc\u7edc\u5408\u7269ArOCF<sub>2<\/sub>CF<sub>2<\/sub>Cu(phen)\uff0c\u540e\u8005\u4e0e\u82b3\u57fa\u7898\u5316\u7269\u5076\u8054\u5f97\u5230\u4ee5\u56db\u6c1f\u4e59-1,2-\u53c9\u57fa\u8054\u63a5\u7684\u82b3\u57fa\u919a\u7c7b\u5316\u5408\u7269\u3002\u53e6\u5916\uff0c\u4ed6\u4eec\u8fd8\u628a\u5236\u5f97\u7684\u56db\u6c1f\u4e59\u70ef\u5e94\u7528\u4e8e\u5bf9\u5404\u7c7b\u6c27-\u3001\u786b-\u3001\u6c2e-\u4eb2\u6838\u8bd5\u5242\u7684\u9ad8\u65481,1,2,2-\u56db\u6c1f\u4e59\u57fa\u5316\u53cd\u5e94\u4e2d\u3002<\/p>\n<p>\u00a0 \u00a0 \u00a0 \u00a0 \u7814\u7a76\u5de5\u4f5c\u5728\u7ebf\u53d1\u8868\u540e\uff0c7\u670824\u65e5\u51fa\u7248\u7684\u7f8e\u56fd\u5316\u5b66\u4f1a\u5316\u5b66\u4e0e\u5de5\u7a0b\u65b0\u95fb\uff08C&amp;E News\uff09\u5468\u520a\u5bf9\u8be5\u7814\u7a76\u5de5\u4f5c\u8fdb\u884c\u4e86\u62a5\u9053\u3002\u8be5\u62a5\u9053\u8ba4\u4e3a\u4e0a\u6d77\u6709\u673a\u6240\u201c\u53d1\u5c55\u4e86\u4e00\u79cd\u5feb\u901f\u5236\u5907\u56db\u6c1f\u4e59\u70ef\u7684\u7a81\u7834\u6027\u65b9\u6cd5\u201d\uff0c\u8be5\u6280\u672f\u662f\u201c\u628a\u56db\u6c1f\u4e59\u70ef\u5b89\u5168\u5e94\u7528\u4e8e\u6709\u673a\u5408\u6210\u7684\u4e00\u79cd\u4fbf\u6377\u65b9\u6cd5\u201d\u3002\u62a5\u9053\u8ba4\u4e3a\u5229\u7528\u6613\u5f97\u7684Me<sub>3<\/sub>SiCF<sub>3<\/sub>\uff08\u7ecf\u7531\u56db\u6c1f\u4e59\u70ef\uff09\u6765\u5f00\u5c55\u4e94\u6c1f\u4e59\u57fa\u5316\u548c\u56db\u6c1f\u4e59\u57fa\u5316\u53cd\u5e94\u662f\u201c\u65b0\u7248\u7684\u6c1f\u70f7\u57fa\u5316\u53cd\u5e94\u201d\u3002\u62a5\u9053\u6700\u540e\u8fd8\u63f4\u5f15\u4f5c\u8005\u7684\u9884\u671f\uff0c\u8ba4\u4e3a\u8be5\u7814\u7a76\u6210\u679c\u5c06\u4f1a\u52a0\u901f\u56db\u6c1f\u4e59\u70ef\u5316\u5b66\u7684\u53d1\u5c55\u3002<\/p>\n<p>\u00a0 \u00a0 \u00a0 \u00a0\u8be5\u7814\u7a76\u5de5\u4f5c\u5f97\u5230\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u59d4\u3001\u79d1\u6280\u90e8\u3001\u4e2d\u79d1\u9662\u548c\u4e0a\u6d77\u5e02\u79d1\u59d4\u7684\u8d44\u52a9\u3002<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1a<a href=\"http:\/\/www.cas.cn\/syky\/201708\/t20170811_4611060.shtml\" target=\"_blank\" rel=\"noopener\">http:\/\/www.cas.cn\/syky\/201708\/t20170811_4611060.shtml<\/a><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201705734\/full\" target=\"_blank\" rel=\"noopener\">TMSCF<sub>3<\/sub>\u00a0as a Convenient Source of CF<sub>2<\/sub>=CF<sub>2<\/sub>\u00a0for Pentafluoroethylation, (Aryloxy)tetrafluoroethylation, and Tetrafluoroethylation<\/a>\u00a0(Angew. Chem. Int. Ed., 2017, DOI:10.1002\/anie.201705734)<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u77f3\u5c0f\u6885\u7f16\u8f91\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" rel=\"noopener\">\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\">\u6d4b\u8bd5\u8c37<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u6210\u679c\u7b80\u4ecb\u3011 \u00a0 \u00a0 \u00a0 \u00a0 \u56db\u6c1f\u4e59\u70ef\uff08F2C=CF2\uff09\u662f\u4e00\u7c7b\u5316\u5b66\u5de5\u4e1a\u4e2d\u5927\u91cf\u4f7f\u7528\u7684\u6c14\u4f53\u539f\u6599\uff0c\u4e3b\u8981\u7528\u4e8e\u5408\u6210\u542b\u6c1f\u805a\u5408\u7269\u548c\u5404\u7c7b\u542b\u6c1f\u7cbe\u7ec6\u5316\u5b66\u54c1\u3002\u5de5\u4e1a\u4e0a\u4e00\u822c\u91c7\u7528\u9ad8\u6e29\uff0855&#8230;<\/p>\n","protected":false},"author":2832,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-96529","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/96529"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2832"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=96529"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/96529\/revisions"}],"predecessor-version":[{"id":96579,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/96529\/revisions\/96579"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=96529"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=96529"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=96529"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}