{"id":96123,"date":"2017-08-17T14:00:44","date_gmt":"2017-08-17T06:00:44","guid":{"rendered":"\/\/m.iemloyee.com\/?p=96123"},"modified":"2017-08-14T17:26:57","modified_gmt":"2017-08-14T09:26:57","slug":"adv-mater-%ef%bc%9a%e8%87%aa%e7%ba%a0%e9%94%99%e7%ad%96%e7%95%a5%e5%ae%9e%e7%8e%b0%e7%b2%be%e5%87%86%e3%80%81%e5%a4%a7%e8%a7%84%e6%a8%a1%e3%80%81%e5%b9%b3%e8%a1%8c%e7%9a%84%e5%ae%8f%e8%a7%82%e8%b6%85","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=96123","title":{"rendered":"Adv. Mater.\uff1a\u81ea\u7ea0\u9519\u7b56\u7565\u5b9e\u73b0\u7cbe\u51c6\u3001\u5927\u89c4\u6a21\u3001\u5e73\u884c\u7684\u5b8f\u89c2\u8d85\u5206\u5b50\u7ec4\u88c5"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p><strong>\u5b8f\u89c2\u8d85\u5206\u5b50\u7ec4\u88c5\uff08Macroscopic supramolecular assembly, MSA\uff09<\/strong>\u662f\u8d85\u5206\u5b50\u5316\u5b66\u9886\u57df\u7684\u65b0\u5174\u524d\u6cbf\u7814\u7a76\u65b9\u5411\uff0c\u5df2\u9010\u6e10\u53d1\u5c55\u6210\u4e3a\u4e00\u79cd\u76f4\u63a5\u4ece\u7ec6\u80de\u5c3a\u5ea6\u6784\u7b51\u57fa\u5143\u5236\u5907\u4f53\u76f8\u8d85\u5206\u5b50\u6750\u6599\u7684\u65b0\u65b9\u6cd5\u3002\u4e0e\u4f20\u7edf\u7684\u4ece\u5206\u5b50\u5c42\u6b21\u6784\u7b51\u57fa\u5143\u5236\u5907\u81ea\u7ec4\u88c5\u6750\u6599\u7684\u65b9\u6cd5\u76f8\u6bd4\uff0cMSA\u53ef\u901a\u8fc7\u8c03\u8282\u6784\u7b51\u57fa\u5143\u7684\u5c3a\u5bf8\u548c\u6750\u8d28\u6765\u7075\u6d3b\u8c03\u63a7\u4f53\u76f8\u6750\u6599\u7684\u6027\u80fd\u3002\u7531\u4e8eMSA\u4e2d\u8d85\u5206\u5b50\u76f8\u4e92\u4f5c\u7528\u662f\u77ed\u7a0b\u76f8\u4e92\u4f5c\u7528\uff0c\u96be\u4ee5\u8c03\u6574\u6784\u7b51\u57fa\u5143\u4e4b\u95f4\u7684\u5339\u914d\u7a0b\u5ea6\uff0c\u81ea\u7ec4\u88c5\u8fc7\u7a0b\u5bf9\u4e8e\u4f4e\u5339\u914d\u5ea6\u7684\u9519\u4f4d\u73b0\u8c61\u5e76\u4e0d\u654f\u611f\uff0c\u4ece\u800c\u5bfc\u81f4\u5728\u9762\u5411\u4f53\u76f8\u6750\u6599\u5236\u5907\u7684\u5e94\u7528\u65f6MSA\u7684\u4f4e\u7cbe\u786e\u5ea6\u95ee\u9898\u3002\u8fd9\u4e9b\u9519\u4f4d\u95ee\u9898\uff0c\u5728\u6ca1\u6709\u4eba\u4e3a\u5e72\u9884\u7684\u60c5\u51b5\u4e0b\uff0c\u4f1a\u968f\u7740\u7ec4\u88c5\u6b65\u9aa4\u548c\u6784\u7b51\u57fa\u5143\u6570\u76ee\u7684\u589e\u5927\u800c\u88ab\u9010\u6e10\u653e\u5927\u3002\u5c3d\u7ba1\u4e00\u4e9b\u6784\u7b51\u57fa\u5143\u5404\u5411\u5f02\u6027\u4fee\u9970\u7684\u9884\u9632\u6027\u7b56\u7565\u53ef\u5728\u4e00\u5b9a\u7a0b\u5ea6\u4e0a\u63d0\u9ad8\u6709\u5e8f\u7a0b\u5ea6\uff0c\u4f46\u9519\u4f4d\u73b0\u8c61\u4f9d\u7136\u96be\u4ee5\u6d88\u9664\u3002\u56e0\u800c\uff0c\u53d1\u5c55\u5177\u6709\u666e\u9002\u6027\u7684\u7ec4\u88c5\u540e\u81ea\u7ea0\u9519\u7b56\u7565\u4ee5\u5b9e\u73b0\u7cbe\u51c6\u7ec4\u88c5\uff0c\u5bf9\u4e8e\u81ea\u7ec4\u88c5\u65b9\u6cd5\u5236\u5907\u6709\u5e8f\u7ed3\u6784\u529f\u80fd\u6750\u6599\u800c\u8a00\uff0c\u662f\u975e\u5e38\u91cd\u8981\u7684\uff0c\u4e5f\u5145\u6ee1\u6311\u6218\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u5317\u4eac\u5316\u5de5\u5927\u5b66\u77f3\u5cf0\u6559\u6388\u548c\u6210\u68a6\u5a07\u526f\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u3001\u897f\u5357\u4ea4\u901a\u5927\u5b66\u5d14\u6811\u52cb\u6559\u6388\u3001\u5fb7\u56fd\u4e9a\u741b\u5de5\u4e1a\u5927\u5b66Alexander\u3000Kuehne\u535a\u58eb\u7b49\u4eba<\/strong>\u5728<strong>Adv. Mater.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a<strong>\u201cSelf-Correction Strategy for Precise, Massive, and Parallel Macroscopic Supramolecular Assembly\u201d<\/strong>\u7684\u6587\u7ae0\u3002\u6587\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u62a5\u9053\u4e86\u57fa\u4e8e\u52a8\u6001\u7ec4\u88c5\/\u89e3\u7ec4\u88c5\u7684\u81ea\u7ea0\u9519\u7b56\u7565\uff0c\u5229\u7528\u89e3\u7ec4\u88c5\u6761\u4ef6\u4e0b\u6eb6\u6db2\u7684\u6269\u6563\u52a8\u529b\u5b66\u63a7\u5236\uff0c\u9009\u62e9\u6027\u5730\u5c06\u9519\u4f4d\u7ec4\u88c5\u4f53\u89e3\u7ec4\u88c5\uff0c\u540c\u65f6\u7cbe\u51c6\u7ec4\u88c5\u4f53\u4e0d\u53d7\u5f71\u54cd\uff0c\u901a\u8fc78\u6b21\u89e3\u7ec4\u88c5\/\u518d\u7ec4\u88c5\u7684\u5faa\u73af\u3001\u8fed\u4ee3\u8fc7\u7a0b\uff0c\u5b9e\u73b0\u4e86100\u5bf9\u6784\u7b51\u57fa\u5143\u7684\u5e73\u884c\u3001\u5927\u89c4\u6a21\u3001\u7cbe\u51c6\u5b8f\u89c2\u8d85\u5206\u5b50\u7ec4\u88c5\u3002\u8fd9\u4e00\u81ea\u7ea0\u9519\u7b56\u7565\u7684\u5173\u952e\u5728\u4e8e\uff1a\uff081\uff09\u6709\u6548\u7504\u522b\u975e\u7cbe\u51c6\u548c\u7cbe\u51c6\u7ec4\u88c5\u7ed3\u6784\uff0c\u5e76\u5c06\u975e\u7cbe\u51c6\u7ed3\u6784\u9009\u62e9\u6027\u89e3\u7ec4\u88c5\uff1b\uff082\uff09\u6240\u5f15\u5165\u7684\u8d85\u5206\u5b50\u76f8\u4e92\u4f5c\u7528\u80fd\u591f\u5b9e\u73b0\u591a\u6b21\u91cd\u590d\u7684\u89e3\u7ec4\u88c5\/\u518d\u7ec4\u88c5\uff0c\u4ece\u800c\u80fd\u8ba9\u89e3\u5f00\u7684\u6784\u7b51\u57fa\u5143\u901a\u8fc7\u591a\u6b21\u518d\u7ec4\u88c5\u7684\u673a\u4f1a\u5b9e\u73b0\u7cbe\u51c6\u7ec4\u88c5\u3002\u4ed6\u4eec\u4ee5\u5e26\u6709\u76f8\u53cd\u7535\u8377\u7684\u6c34\u51dd\u80f6\u4e3a\u6a21\u578b\u4f53\u7cfb\uff0c\u5728\u7eaf\u6c34\u4e2d\u5b9e\u73b0\u6c34\u51dd\u80f6\u7684\u7ec4\u88c5\uff0c\u5728\u9ad8\u6d53\u5ea6\u6c2f\u5316\u94a0\u6eb6\u6db2\u4e2d\u5b9e\u73b0\u5176\u89e3\u7ec4\u88c5\uff0c\u7531\u4e8e\u89e3\u7ec4\u88c5\u8fc7\u7a0b\u53d7\u5230\u6c2f\u5316\u94a0\u6eb6\u6db2\u7684\u6269\u6563\u52a8\u529b\u5b66\u63a7\u5236\uff0c\u89e3\u7ec4\u88c5\u6240\u9700\u8981\u7684\u65f6\u95f4\u968f\u7740\u7ec4\u88c5\u4f53\u7684\u5339\u914d\u7a0b\u5ea6\u589e\u52a0\u800c\u5ef6\u957f\uff0c\u5373\u89e3\u7ec4\u88c5\u52a8\u529b\u5b66\u662f\u81ea\u52a8\u7b5b\u9009\u975e\u7cbe\u51c6\u548c\u7cbe\u51c6\u7ed3\u6784\u7684\u91cd\u8981\u6761\u4ef6\uff1a\u5728\u4e00\u5b9a\u89e3\u7ec4\u88c5\u65f6\u95f4\u4e0b\uff0840 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loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-96134\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/08\/1-34.jpg\" alt=\"\" width=\"500\" height=\"427\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/08\/1-34.jpg 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/08\/1-34-300x256.jpg 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" 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\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/08\/2-35-295x300.jpg 295w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/strong> a\uff09\u4ece\u80fd\u91cf\u9762\u7684\u89d2\u5ea6\u7406\u89e3MSA\u7ec4\u88c5\u4f53\u5b58\u5728\u591a\u79cd\u70ed\u529b\u5b66\u53ef\u80fd\u7684\u7a33\u6001\uff1b<\/p>\n<p>b\uff09\u5728NaCl\u6c34\u6eb6\u6db2\u4e2d\u6d4b\u5f97\u7684PEI\u6c34\u51dd\u80f6\u4e0ePAA\u6c34\u51dd\u80f6\u95f4\u76f8\u4e92\u4f5c\u7528\u529b\u7684\u539f\u4f4d\u3001\u5b9e\u65f6\u53d8\u5316\uff1b<\/p>\n<p>c\uff09\u5c06\u7cbe\u51c6\u5339\u914d\u7684\u4e8c\u805a\u4f53\u7ec4\u88c5\u4f53\u6d78\u6ce1\u4e8e\u88ab\u4e9a\u7532\u57fa\u84dd\u67d3\u8272\u7684NaCl\u6c34\u6eb6\u6db2\u4e2d\uff0c\u6d78\u6ce1\u4e0d\u540c\u65f6\u95f4\u540e\u53d6\u51fa\uff0c\u4eba\u4e3a\u5206\u5f00\uff0c\u89c2\u5bdf\u7ec4\u88c5\u754c\u9762\u7684\u67d3\u6599\u6269\u6563\u73b0\u8c61\uff1b<\/p>\n<p>d\uff09\u968f\u7740\u5728NaCl\u6eb6\u6db2\u4e2d\u6d78\u6ce1\u65f6\u95f4\u7684\u589e\u52a0\uff0c100\u5bf9\u968f\u673a\u9707\u8361\u5f97\u5230\u7684\u4e8c\u805a\u4f53\u4e2d\u53d1\u751f\u89e3\u7ec4\u88c5\u7684\u5bf9\u6570\u7edf\u8ba1\uff1b<\/p>\n<p>e\uff09\u5f53\u4e8c\u805a\u4f53\u4ea4\u66ff\u6d78\u6ce1\u4e8e\u7eaf\u6c34\u548cNaCl\u6c34\u6eb6\u6db2\u4e2d\u65f6\uff0cPEI\u6c34\u51dd\u80f6\u4e0ePAA\u6c34\u51dd\u80f6\u95f4\u76f8\u4e92\u4f5c\u7528\u529b\u7684\u539f\u4f4d\u3001\u5b9e\u65f6\u53d8\u5316\uff1a\u8868\u660ePEI\u6c34\u51dd\u80f6\u4e0ePAA\u6c34\u51dd\u80f6\u5728\u6c2f\u5316\u94a0\u4e2d\u89e3\u7ec4\u88c5\u4e0e\u6c34\u4e2d\u518d\u7ec4\u88c5\u8fc7\u7a0b\u5177\u6709\u826f\u597d\u7684\u53ef\u91cd\u590d\u6027\u3002<\/p>\n<p><strong>\u56fe3\uff1a\u7a0b\u5e8f\u5316\u81ea\u7ea0\u9519\u7b56\u7565\u3002<\/strong><\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-96136\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/08\/3-29.jpg\" alt=\"\" width=\"500\" height=\"526\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/08\/3-29.jpg 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/08\/3-29-285x300.jpg 285w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/strong><\/p>\n<p>a\uff09\uff08\u8ba1\u7b97\u673a\uff09while\u5faa\u73af\u8bed\u53e5\u7684\u6d41\u7a0b\u793a\u610f\u56fe\uff1b<\/p>\n<p>b\uff09\u5c06100\u5bf9PEI\u6c34\u51dd\u80f6\u548cPAA\u6c34\u51dd\u80f6\u5728\u53bb\u79bb\u5b50\u6c34\u4e2d\u968f\u673a\u632f\u83615\u5206\u949f\u540e\u7ec4\u88c5\uff0c\u5404\u7ec4\u88c5\u4f53\u7684\u5339\u914d\u7a0b\u5ea6\u968f\u673a\uff1b<\/p>\n<p>c\uff09\u5728NaCl\uff081 M\uff09\u4e2d\u89e3\u7ec4\u88c5\u540e\uff0c\u53ea\u6709\u5339\u914d\u5ea6\u8f83\u9ad8\u7684\u4e8c\u805a\u4f53\u4fdd\u7559\u4e86\u4e0b\u6765\uff08\u4ee5\u7eff\u8272\u683c\u5b50\u663e\u793a\uff09\uff0c\u800c\u5176\u4ed6\u5339\u914d\u7a0b\u5ea6\u4f4e\u7684\u4e8c\u805a\u4f53\u89e3\u7ec4\u88c5\u6210\u4e3a\u5355\u72ec\u7684\u6784\u7b51\u57fa\u5143\uff08\u7070\u8272\u683c\u5b50\uff0c\u672a\u663e\u793a\uff09\uff1b<\/p>\n<p>d-j\uff09\u6bcf\u4e2a\u6c34(5min)\/\u6c2f\u5316\u94a0(40min)\u5904\u7406\u5faa\u73af\u540e\uff0c\u7edf\u8ba1NaCl\u6c34\u6eb6\u6db2\u4e2d\u4fdd\u7559\u4e0b\u6765\u7684\u4e8c\u805a\u4f53\u6570\u76ee\u3002\u8fdb\u5ea6\u6761\u8868\u793a\u5b8c\u7f8e\u7ec4\u88c5\u7684\u4e8c\u805a\u4f53\u7684\u767e\u5206\u6bd4\uff1a\u53d1\u73b0\u901a\u8fc78\u6b21\u8fed\u4ee3\u53ef\u4ee5\u5b9e\u73b0100\u4e2a\u4e8c\u805a\u4f53100%\u7cbe\u51c6\u7ec4\u88c5\u3002<\/p>\n<p><strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n<p>\u5728\u672c\u6587\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u63d0\u51fa\u4e86\u4e00\u79cd\u57fa\u4e8e\u52a8\u6001\u7ec4\u88c5\u7cfb\u7edf\u7684\u81ea\u7ea0\u9519\u7b56\u7565\uff0c\u8bc1\u660e\u4e86\u7cbe\u51c6\u3001\u5927\u89c4\u6a21\u3001\u5e73\u884c\u5b8f\u89c2\u8d85\u5206\u5b50\u7ec4\u88c5\uff08MSA\uff09\u7684\u53ef\u884c\u6027\uff0c\u6709\u6548\u89e3\u51b3\u4e86MSA\u8fc7\u7a0b\u7ed3\u6784\u7cbe\u5ea6\u4f4e\u3001\u6709\u5e8f\u6027\u5dee\u7684\u95ee\u9898\u3002\u7814\u7a76\u4eba\u5458\u4ee5\u5e26\u6709\u76f8\u53cd\u7535\u8377\u7684\u6c34\u51dd\u80f6\u4e3a\u6a21\u578b\u7cfb\u7edf\uff0c\u5efa\u7acb\u4e86\u4e00\u4e2a\u7eaf\u7cb9\u7531\u6269\u6563\u52a8\u529b\u5b66\u63a7\u5236\u7684\u89e3\u7ec4\u88c5\u673a\u5236\uff0c\u4f7f\u5f97\u8be5\u4f53\u7cfb\u80fd\u591f\u81ea\u52a8\u8bc6\u522b\u5e76\u7ea0\u6b63\u975e\u7cbe\u51c6\u7ec4\u88c5\u7ed3\u6784\uff1a\u901a\u8fc7\u5c06\u4f53\u7cfb\u53cd\u590d\u3001\u4ea4\u66ff\u6d78\u6ce1\u4e8eNaCl\u6eb6\u6db2\u548c\u7eaf\u6c34\u4e2d\u4e00\u5b9a\u65f6\u95f4\u5b9e\u73b0\u975e\u7cbe\u51c6\u7ed3\u6784\u7684\u89e3\u7ec4\u88c5\u548c\u518d\u7ec4\u88c5\uff0c\u5386\u7ecf8\u6b21\u5faa\u73af\u3001\u8fed\u4ee3\u540e\u5b9e\u73b0\u4e86100\u4e2a\u4e8c\u805a\u4f53\u7684100%\u7cbe\u51c6\u7ec4\u88c5\u3002\u8fd9\u4e00\u81ea\u7ea0\u9519\u7b56\u7565\u89e3\u51b3\u4e86MSA\u4e2d\u666e\u904d\u5b58\u5728\u7684\u5bf9\u7ec4\u88c5\u8fc7\u7a0b\u4e2d\u51fa\u9519\u4e0d\u654f\u611f\u7684\u95ee\u9898\uff0c\u4fc3\u8fdb\u4e86MSA\u5728\u6750\u6599\u5236\u5907\u65b9\u9762\u7684\u5e7f\u6cdb\u5e94\u7528\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/adma.201702444\/full\" target=\"_blank\" rel=\"noopener\">Self-Correction Strategy for Precise, Massive, and Parallel\u3000Macroscopic Supramolecular Assembly<\/a><\/strong>\uff08<em>Adv.Mater.<\/em>,<strong>2017<\/strong>,DOI: 10.1002\/adma.201702444\uff09<\/p>\n<p><strong>\u3010\u7814\u7a76\u56e2\u961f\u4ecb\u7ecd\u3011<\/strong><\/p>\n<p><strong>\u5317\u4eac\u5316\u5de5\u5927\u5b66\u8d85\u5206\u5b50\u6750\u6599\u56e2\u961f\u7531\u77f3\u5cf0\u6559\u6388\u7ec4\u5efa<\/strong>\uff0c<strong>\u957f\u671f\u81f4\u529b\u4e8e\u5b8f\u89c2\u8d85\u5206\u5b50\u7ec4\u88c5\u53ca\u5176\u5e94\u7528\u65b9\u9762\u7684\u7814\u7a76<\/strong>\u3002\u4e0d\u540c\u4e8e\u4f20\u7edf\u5206\u5b50\u6216\u7eb3\u7c73\u5c3a\u5ea6\u6784\u7b51\u57fa\u5143\u7684\u8d85\u5206\u5b50\u7ec4\u88c5\uff0c\u5b8f\u89c2\u8d85\u5206\u5b50\u7ec4\u88c5\u4e2d\u7684\u6784\u7b51\u57fa\u5143\u5c3a\u5bf8\u901a\u5e38\u572810\u5fae\u7c73\u4ee5\u4e0a\uff0c\u7ec4\u88c5\u8fc7\u7a0b\u6d89\u53ca\u4fee\u9970\u6709\u5927\u91cf\u8d85\u5206\u5b50\u5b98\u80fd\u56e2\u7684\u754c\u9762-\u754c\u9762\u95f4\u76f8\u4e92\u4f5c\u7528\uff0c\u7ec4\u88c5\u884c\u4e3a\u548c\u7ec4\u88c5\u673a\u7406\u66f4\u52a0\u590d\u6742\u3002\u5728\u6784\u7b51\u57fa\u5143\u6750\u6599\u65b9\u9762\uff0c\u81ea2011\u5e74\u4ee5\u6765\uff0c\u56fd\u5185\u5916\u5b8f\u89c2\u8d85\u5206\u5b50\u7ec4\u88c5\u7684\u7814\u7a76\u4e3b\u8981\u9650\u4e8e\u6c34\u51dd\u80f6\u4f5c\u4e3a\u6784\u7b51\u57fa\u5143\u7684\u4f53\u7cfb\uff0c\u62a5\u9053\u4e86\u4e3b\u5ba2\u4f53\u8bc6\u522b\u3001\u6c22\u952e\u3001\u914d\u4f4d\u952e\u3001\u9759\u7535\u3001DNA\u6742\u5316\u7b49\u8d85\u5206\u5b50\u76f8\u4e92\u4f5c\u7528\u5bfc\u81f4\u7684\u5b8f\u89c2\u7ec4\u88c5\u884c\u4e3a\u3002\u4e3a\u89e3\u51b3\u521a\u6027\u6750\u6599\u6784\u7b51\u57fa\u5143\u96be\u4ee5\u5b9e\u73b0\u5b8f\u89c2\u7ec4\u88c5\u7684\u95ee\u9898\uff0c\u8be5\u56e2\u961f\u63d0\u51fa\u4e86\u201c\u67d4\u6027\u95f4\u9694\u5c42(flexible spacing coating)\u201d\u7684\u6982\u5ff5(Adv. Mater. 2014, 26, 3009)\uff0c\u5373\u5728\u6784\u7b51\u57fa\u5143\u8868\u9762\u5f15\u5165\u5177\u6709\u9ad8\u5ea6\u6d41\u52a8\u7279\u6027\u7684\u6d82\u5c42\uff0c\u4ee5\u4fc3\u8fdb\u8868\u9762\u8d85\u5206\u5b50\u5b98\u80fd\u56e2\u95f4\u7684\u591a\u91cd\u76f8\u4e92\u4f5c\u7528(multivalency)\uff0c\u4ece\u800c\u63d0\u9ad8\u6784\u7b51\u57fa\u5143\u4e4b\u95f4\u7684\u7ed3\u5408\u5f3a\u5ea6\uff0c\u5b9e\u73b0\u5b8f\u89c2\u7ec4\u88c5\u3002\u8fd9\u4e00\u6982\u5ff5\u6253\u7834\u4e86\u5b8f\u89c2\u8d85\u5206\u5b50\u7ec4\u88c5\u7684\u6750\u6599\u9650\u5236\uff0c\u4e3a\u5b8f\u89c2\u8d85\u5206\u5b50\u7ec4\u88c5\u4e2d\u6784\u7b51\u57fa\u5143\u7684\u8bbe\u8ba1\u539f\u5219\u63d0\u4f9b\u4e86\u601d\u8def\u3002\u5728\u7ec4\u88c5\u65b9\u6cd5\u65b9\u9762\uff0c\u7531\u4e8e\u6784\u7b51\u57fa\u5143\u5c3a\u5bf8\u8f83\u5927\uff0c\u5206\u5b50\u70ed\u8fd0\u52a8\u65e0\u6cd5\u9a71\u4f7f\u5176\u81ea\u53d1\u8fd0\u52a8\u548c\u6709\u6548\u78b0\u649e\uff0c\u5927\u591a\u6570\u62a5\u9053\u4e2d\u4f9d\u8d56\u5916\u529b\u9707\u8361\u4f7f\u6784\u7b51\u57fa\u5143\u78b0\u649e\uff0c\u4e3a\u6b64\uff0c\u8be5\u56e2\u961f\u53d1\u5c55\u4e86\u4e00\u7cfb\u5217\u81ea\u9a71\u52a8\u65b9\u6cd5\uff0c\u5e76\u5c06\u6784\u7b51\u57fa\u5143\u7684\u81ea\u53d1\u8fd0\u52a8\u4e0e\u5b8f\u89c2\u7ec4\u88c5\u8fc7\u7a0b\u6709\u673a\u7ed3\u5408\u8d77\u6765\uff0c\u5b9e\u73b0\u4e86\u5b8f\u89c2\u81ea\u7ec4\u88c5(Angew. Chem. Int. Ed. 2015, 54, 8952)\u3002\u5728\u76f8\u5173\u8868\u5f81\u624b\u6bb5\u65b9\u9762\uff0c\u8be5\u56e2\u961f\u8003\u8651\u5b8f\u89c2\u7ec4\u88c5\u4e2d\u5904\u4e8e\u6db2\u4f53\u73af\u5883\u548c\u9707\u8361\u7684\u771f\u5b9e\u60c5\u51b5\uff0c\u53d1\u5c55\u4e86\u539f\u4f4d\u3001\u5b9e\u65f6\u76d1\u6d4b\u6784\u7b51\u57fa\u5143\u4e4b\u95f4\u76f8\u4e92\u4f5c\u7528\u529b\u7684\u65b9\u6cd5\u3002\u5728\u5e94\u7528\u524d\u666f\u63a2\u7d22\u65b9\u9762\uff0c\u8be5\u56e2\u961f\u5229\u7528\u8d85\u5206\u5b50\u7ec4\u88c5\u5b9e\u9a8c\u6761\u4ef6\u6e29\u548c\u3001\u81ea\u4e0b\u800c\u4e0a\u6784\u7b51\u3001\u751f\u7269\u76f8\u5bb9\u6027\u4f53\u7cfb\u4e30\u5bcc\u7b49\u7279\u70b9\uff0c\u53d1\u5c55\u4e86\u4e00\u79cd\u5177\u6709\u5316\u5b66\u7ec4\u5206\u548c\u6750\u6599\u5728\u4e09\u7ef4\u7a7a\u95f4\u53ef\u63a7\u7684\u6709\u5e8f\u7ed3\u6784\u5236\u5907\u65b0\u65b9\u6cd5(Adv. Funct. Mater. 2015, 25, 6851)\uff0c\u4ee5\u9762\u5411\u7ec4\u7ec7\u5de5\u7a0b\u652f\u67b6\u5236\u5907\u65b9\u9762\u7684\u5e94\u7528\uff1b\u5229\u7528\u81ea\u7ec4\u88c5\u65b9\u6cd5\u5e73\u884c\u3001\u5927\u89c4\u6a21\u3001\u4f4e\u6210\u672c\u5236\u5907\u7684\u4f18\u52bf\uff0c\u63d0\u51fa\u4e86\u5b8f\u89c2\u8d85\u5206\u5b50\u7ec4\u88c5\u5728\u751f\u7269\u82af\u7247\u5236\u5907\u65b9\u9762\u7684\u5e94\u7528\u3002<\/p>\n<p><strong>\u3010\u76f8\u5173\u6587\u732e\u63a8\u8350\u3011<\/strong><\/p>\n<p>[1] M. J. Cheng, F. Shi, J. S. Li, Z. F. Lin, C. Jiang, M. Xiao, L. Q. Zhang, W. T. Yang, T. Nishi,<em> Adv. Mater.<\/em> <strong>2014<\/strong>, 26, 3009. <\/p>\n<p>[2] M. J. Cheng, Y. Wang, L. L. Yu, H. J. Su, W. D. Han, Z. F. Lin, J. S. Li, H. J. Hao, C. Tong, X. L. Li, F. Shi,<em> Adv. Funct. Mater.<\/em> <strong>2015<\/strong>, 25, 6851. <\/p>\n<p>[3] M. Xiao, Y. M. Xian, F. Shi, <em>Angew. Chem. Int. Ed.<\/em> <strong>2015<\/strong>, 54, 8952.<\/p>\n<p>[4] M. J. Cheng, G. N. Ju, Y. W. Zhang, M. M. Song, Y. J. Zhang, F. Shi, <em>Small<\/em> <strong>2014<\/strong>, 10, 3907. <\/p>\n<p>[5] M. J. Cheng, Q. Liu, Y. M. Xian, F. Shi,<em> ACS. Appl. Mater. Interfaces<\/em> <strong>2014<\/strong>, 6, 7572.<\/p>\n<p>[6] M. J. Cheng, H. T. Gao, Y. J. Zhang, W. Tremel, J. F. Chen, F. Shi, W. Knoll,<em> Langmuir<\/em><strong> 2011<\/strong>, 27, 6559.<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u9ad8\u5206\u5b50\u6750\u6599\u7ec4arrinal_Ding\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" rel=\"noopener\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\">\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u5b8f\u89c2\u8d85\u5206\u5b50\u7ec4\u88c5\uff08Macroscopic supramolecular assembly, MSA\uff09\u662f\u8d85\u5206\u5b50\u5316\u5b66\u9886\u57df\u7684\u65b0\u5174\u524d\u6cbf\u7814\u7a76\u65b9\u5411\uff0c\u5df2\u9010\u6e10\u53d1\u5c55\u6210\u4e3a\u4e00&#8230;<\/p>\n","protected":false},"author":1057,"featured_media":96128,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[42],"class_list":["post-96123","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-gaofenzi"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/96123"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/1057"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=96123"}],"version-history":[{"count":11,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/96123\/revisions"}],"predecessor-version":[{"id":96451,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/96123\/revisions\/96451"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/96128"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=96123"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=96123"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=96123"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}