{"id":95805,"date":"2017-08-12T06:30:06","date_gmt":"2017-08-11T22:30:06","guid":{"rendered":"\/\/m.iemloyee.com\/?p=95805"},"modified":"2017-08-11T16:44:51","modified_gmt":"2017-08-11T08:44:51","slug":"%e3%80%90%e6%8a%95%e7%a8%bf%e5%be%85%e5%ae%9a%e3%80%91%e6%b5%8e%e5%8d%97%e5%a4%a7%e5%ad%a6%ef%bc%9anano-energy%ef%bc%9a%e9%ab%98%e8%83%bd%e9%87%8f%e5%af%86%e5%ba%a6%e6%9f%94%e6%80%a7ppymno2%e9%9d%9e","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=95805","title":{"rendered":"\u6d4e\u5357\u5927\u5b66Nano Energy\uff1a\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u67d4\u6027PPy\/MnO2\u975e\u5bf9\u79f0\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u7ec4\u88c5\u8bbe\u8ba1"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u968f\u7740\u4fbf\u643a\u5f0f\u7535\u5b50\u8bbe\u5907\u9700\u6c42\u7684\u5feb\u901f\u589e\u957f\uff0c\u67d4\u6027\u3001\u8f7b\u8d28\u7684\u8d85\u7ea7\u7535\u5bb9\u5668\u662f\u4e00\u79cd\u65b0\u578b\u7684\u50a8\u80fd\u5668\u4ef6\uff0c\u4ee5\u5176\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\u548c\u5b89\u5168\u6027\u53d7\u5230\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u4f5c\u4e3a\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u91cd\u8981\u7ec4\u6210\u90e8\u5206\uff0c\u7535\u6781\u6750\u6599\u51b3\u5b9a\u7740\u5668\u4ef6\u7684\u6574\u4f53\u6027\u80fd\u3002\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u3001\u5bfc\u7535\u805a\u5408\u7269\u7b49\u8d5d\u7535\u5bb9\u6750\u6599\u8d44\u6e90\u4e30\u5bcc\u3001\u7eff\u8272\u73af\u4fdd\u3001\u7535\u5316\u5b66\u6027\u80fd\u4f18\u8d8a\uff0c\u5176\u4e2d\u4e8c\u6c27\u5316\u9530\u7535\u6781\u6750\u6599\u7531\u4e8e\u5bfc\u7535\u6027\u80fd\u4f4e\u3001\u4f7f\u5176\u5728\u7535\u5316\u5b66\u53cd\u5e94\u4e2d\u4e0d\u80fd\u8fdb\u884c\u9ad8\u6548\u7684\u81ea\u7531\u7535\u5b50\u548c\u79bb\u5b50\u7684\u8f93\u8fd0\u3002\u4e3a\u4e86\u589e\u52a0\u6750\u6599\u7684\u5bfc\u7535\u6027\u548c\u6d3b\u6027\u9762\u79ef\uff0c\u63d0\u9ad8\u6750\u6599\u7684\u7a33\u5b9a\u6027\uff0c\u8fdb\u884c\u7535\u6781\u6750\u6599\u5f62\u8c8c\u7684\u548c\u7ed3\u6784\u7684\u8c03\u63a7\u662f\u81f3\u5173\u91cd\u8981\u7684\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u6d4e\u5357\u5927\u5b66\u5f90\u9521\u91d1\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u4e0e\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u7fdf\u5929\u4f51\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u5408\u4f5c\u5728Nano Energy\u5728\u7ebf\u53d1\u8868\u9898\u4e3a\u201cFlexible and High Energy Density Asymmetrical Supercapacitors based on Core\/Shell Conducting PolymerNanowires\/ Manganese Dioxide Nanoflakescore\/shell\u201d\u7684\u6587\u7ae0\uff0c\u62a5\u9053\u4e86\u4e00\u79cd\u4f4e\u6e29\uff0c\u7b80\u5355\uff0c\u73af\u4fdd\u7684\u65b9\u6cd5\u5408\u6210PPy\u7eb3\u7c73\u7ebf\u4e3a\u5bfc\u7535\u9aa8\u67b6\u548c\u6781\u8584\u7684MnO2<\/sub>\u7eb3\u7c73\u7247\u4e3a\u58f3\u7684\u7eb3\u7c73\u7ed3\u6784\u3002\u8fd9\u79cd\u6838\u58f3\u7ed3\u6784\u9ad8\u6548\u7684\u589e\u52a0\u4e86MnO2<\/sub>\u7684\u6d3b\u6027\u9762\u79ef\u548c\u5bfc\u7535\u6027\uff0c\u4e5f\u63d0\u9ad8\u4e86PPy\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u8fdb\u800c\u7f29\u77ed\u4e86\u79bb\u5b50\u7684\u4f20\u8f93\u8ddd\u79bb\u3002PPy@MnO2<\/sub>\u6838\u58f3\u7ed3\u6784\u5177\u6709\u9ad8\u7684\u6bd4\u7535\u5bb9(276 F g\u22121 <\/sup>\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a2 A g\u22121<\/sup>\u65f6)\u548c\u6781\u9ad8\u7535\u5bb9\u4fdd\u6301\u738772.5%(200 F g\u22121<\/sup>\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a20 A g\u22121<\/sup>). \u5e76\u8fdb\u4e00\u6b65\u4ee5PPy@MnO2<\/sub>\u6838\u58f3\u7ed3\u6784\u4e3a\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u6b63\u6781\u6750\u6599\uff0c\u4ee5\u8d85\u7ea7\u7535\u5bb9\u6d3b\u6027\u70ad(AC)\u4e3a\u8d1f\u6781\u6750\u6599\u7ec4\u88c5\u6210\u8d85\u67d4\u6027\u975e\u5bf9\u79f0\u7535\u5bb9\u5668\u3002\u5f97\u5230\u7684\u8d85\u7ea7\u7535\u5bb9\u5668\u62e5\u6709\u6770\u51fa\u7684\u7a33\u5b9a\u6027(\u57283 A g\u22121<\/sup>\u65f6\u5faa\u73af6000\u6b21\u4fdd\u6301\u521d\u59cb\u7535\u5bb9\u503c\u768490.3%)\uff0c\u673a\u68b0\u67d4\u97e7\u6027\uff0c\u5bbd\u7684\u7535\u538b\u7a97\u53e3(1.8-2.0 V)\u548c\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6(25.8 W h kg\u22121<\/sup>\u5728\u529f\u7387\u5bc6\u5ea6\u4e3a901.7 W kg\u22121<\/sup>)\u3002\u8fd9\u79cd\u7b56\u7565\u91c7\u7528\u7b80\u5355\u7684\u65b9\u6cd5\u5236\u5907\u4f4e\u6210\u672c\u7684\u7535\u6781\u6750\u6599\uff0c\u5c06\u4fc3\u8fdb\u67d4\u6027\u50a8\u80fd\u88c5\u7f6e\u7684\u5feb\u901f\u53d1\u5c55\u3002<\/p>\n

\u3010<\/strong>\u56fe\u6587\u5bfc\u8bfb<\/strong>\u3011<\/strong><\/p>\n

\u56fe1\uff1aMnO2<\/sub>\u7eb3\u7c73\u7247\uff0cPPy\u7eb3\u7c73\u7ebf\u548cPPy@MnO2<\/sub>\u6838\u58f3\u7ed3\u6784\u7684\u5408\u6210\u793a\u610f\u56fe\uff0c\u5f62\u8c8c\u8868\u5f81\u548c\u7ed3\u6784\u3001\u6210\u5206\u5206\u6790<\/p>\n

\"\"<\/p>\n

(a)PPy\u7eb3\u7c73\u7ebf@MnO2<\/sub>\u7eb3\u7c73\u7247\u6838\/\u58f3\u7eb3\u7c73\u7ed3\u6784\u5408\u6210\u793a\u610f\u56fe\u3002<\/p>\n

(b, c)\u548c(d, e) MnO2<\/sub>\u7eb3\u7c73\u7247\u7684\u9ad8\u4f4e\u500dSEM\u56fe\u548cPPy\u7eb3\u7c73\u7ebfSEM\u56fe\u3002<\/p>\n

(f, g)PPy\u7eb3\u7c73\u7ebf@MnO2<\/sub>\u7eb3\u7c73\u7247SEM\u56fe\u3002<\/p>\n

(h, i) PPy@MnO2<\/sub>\u6838\/\u58f3\u7eb3\u7c73\u7ed3\u6784\u7684EDS\u5143\u7d20\u5206\u5e03\u56fe\u3002<\/p>\n

(j)PPy\u7eb3\u7c73\u7ebf@MnO2<\/sub>\u7eb3\u7c73\u7247\u7684XRD\u56fe\u8c31\u3002<\/p>\n

\u56fe2\uff1aPPy@MnO2<\/sub>\u6838\u58f3\u7ed3\u6784\u7684\u7535\u5316\u5b66\u7535\u5bb9\u6027\u80fd\u8868\u5f81\u53ca\u5206\u6790<\/p>\n

\"\"<\/p>\n

(a)MnO2<\/sub>\u3001PPy\u3001ACFC\u548cPPy@MnO2<\/sub>\u6838\/\u58f3\u7eb3\u7c73\u7ed3\u6784\u572830 mV s-1<\/sup>\u4e0b\u7684CV \u66f2\u7ebf\u5bf9\u6bd4\u56fe\u3002<\/p>\n

(b)MnO2<\/sub>\u3001PPy\u3001ACFC\u548cPPy@MnO2<\/sub>\u6838\/\u58f3\u7eb3\u7c73\u7ed3\u6784\u57283A g-1<\/sup>\u4e0b\u7684GCD\u66f2\u7ebf\u56fe\u3002<\/p>\n

(c)\u4e09\u79cd\u4e0d\u540c\u7535\u6781\u6750\u6599\u7684\u500d\u7387\u6027\u80fd\u56fe\u3002<\/p>\n

(d) PPy\u7eb3\u7c73\u7ebf@MnO2<\/sub>\u7eb3\u7c73\u7247\u7535\u6781\u6750\u6599\u5728\u4e0d\u540c\u626b\u901f\u4e0b\u7684CV\u56fe\u3002<\/p>\n

(e)PPy\u7eb3\u7c73\u7ebf@MnO2<\/sub>\u7eb3\u7c73\u7247\u7535\u6781\u6750\u6599\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u6052\u6d41\u5145\u653e\u7535\u56fe<\/p>\n

(f)\u57283 A g -1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0bPPy\u7eb3\u7c73\u7ebf\u548cPPy\u7eb3\u7c73\u7ebf@MnO2<\/sub>\u7eb3\u7c73\u7247\u7535\u6781\u7684\u5faa\u73af\u5bff\u547d\u56fe\u53ca\u7535\u6781\u5728\u5faa\u73af\u524d\u540e\u989c\u8272\u7684\u53d8\u5316\u3002<\/p>\n

\u56fe3\uff1a\u975e\u5bf9\u79f0\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u7ec4\u88c5\u793a\u610f\u56fe\u3001\u5de5\u4f5c\u7535\u538b\u548c\u67d4\u97e7\u6027\u7684\u6d4b\u8bd5<\/p>\n

\"\"<\/p>\n

(a)\u975e\u5bf9\u79f0\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u7ec4\u88c5\u793a\u610f\u56fe\u3002<\/p>\n

(b) \u975e\u5bf9\u79f0\u67d4\u6027\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u67d4\u97e7\u6027\u6570\u5b57\u56fe\u50cf\u3002<\/p>\n

(c)PPy@MnO2<\/sub>\u6838\/\u58f3\u7eb3\u7c73\u7ed3\u6784\u4e0eAC\u7535\u6781\u5728\u626b\u63cf\u901f\u7387\u4e3a30 mV s\u22121<\/sup>\u7684CV\u66f2\u7ebf\u3002<\/p>\n

(d)PPy\u7eb3\u7c73\u7ebf@MnO2<\/sub>\u7eb3\u7c73\u7247\u975e\u5bf9\u79f0\u67d4\u6027\u8d85\u7ea7\u7535\u5bb9\u5668\u5728\u626b\u63cf\u901f\u7387\u4e3a30 mV s\u22121<\/sup>\u4e0b\u7684CV\u66f2\u7ebf\u3002<\/p>\n

\u56fe4\uff1aPPy\u7eb3\u7c73\u7ebf@MnO2<\/sub>\u7eb3\u7c73\u7247\u975e\u5bf9\u79f0\u67d4\u6027\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u7535\u5316\u5b66\u7535\u5bb9\u6027\u80fd\u8868\u5f81\u53ca\u5206\u6790<\/p>\n

\"\"<\/p>\n

(a) PPy\u7eb3\u7c73\u7ebf@MnO2<\/sub>\u7eb3\u7c73\u7247\u975e\u5bf9\u79f0\u67d4\u6027\u8d85\u7ea7\u7535\u5bb9\u5668\u5728\u4e0d\u540c\u626b\u901f\u4e0b\u7684CV\u56fe\u3002<\/p>\n

(b)PPy\u7eb3\u7c73\u7ebf@MnO2<\/sub>\u7eb3\u7c73\u7247\u975e\u5bf9\u79f0\u67d4\u6027\u8d85\u7ea7\u7535\u5bb9\u5668\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u6052\u6d41\u5145\u653e\u7535\u56fe\u3002<\/p>\n

(c)\u975e\u5bf9\u79f0\u67d4\u6027\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u6d4b\u8bd5\u3002<\/p>\n

(d)\u975e\u5bf9\u79f0\u67d4\u6027\u8d85\u7ea7\u7535\u5bb9\u5668\u4e0e\u5df2\u62a5\u9053\u7684\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u5bf9\u6bd4Ragone plot\u56fe\u3002<\/p>\n

(e)\u975e\u5bf9\u79f0\u67d4\u6027\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u673a\u68b0\u67d4\u97e7\u6027\u7814\u7a76\u3002<\/p>\n

(f)\u4e00\u7247\u548c\u4e24\u7247\u975e\u5bf9\u79f0\u67d4\u6027\u8d85\u7ea7\u7535\u5bb9\u5668\u4e32\u8054\u6052\u6d41\u5145\u5206\u7535\u56fe\u53ca\u7b80\u5355\u5e94\u7528\u3002<\/p>\n

\u3010<\/strong>\u603b<\/strong>\u7ed3\u4e0e\u5c55\u671b<\/strong>\u3011<\/strong><\/p>\n

\u8be5\u79cdPPy@MnO2<\/sub>\u6838\u58f3\u7ed3\u6784\uff0c\u901a\u8fc7\u534f\u8c03\u5145\u5206\u5229\u7528MnO2<\/sub>\u5728\u4e2d\u6027\u7535\u89e3\u6db2\u4e2d\u7684\u9ad8\u7a33\u5b9a\u6027\u548c\u805a\u5408\u7269PPy\u7684\u4f18\u826f\u5bfc\u7535\u6027\uff0c\u6784\u5efa\u4e86\u5feb\u901f\u3001\u4e30\u5bcc\u3001\u9ad8\u6548\u7684\u7535\u5b50\u548c\u79bb\u5b50\u8f93\u8fd0\u8def\u5f84\uff0c\u6709\u6548\u7684\u89e3\u51b3\u4e86PPy\u5728\u4e2d\u6027\u7535\u89e3\u6db2\u4e0b\u7684\u4e0d\u7a33\u5b9a\u6027\u3002\u7ec4\u88c5\u7684\u67d4\u6027\u8d85\u7ea7\u7535\u5bb9\u5668\u62e5\u6709\u6770\u51fa\u7684\u7a33\u5b9a\u6027\uff0c\u673a\u68b0\u67d4\u97e7\u6027\uff0c\u5bbd\u7684\u7535\u538b\u7a97\u53e3\u548c\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u8be5\u65b9\u6cd5\u53ef\u4ee5\u9002\u7528\u4e8e\u5927\u89c4\u6a21\u5236\u5907\u73af\u5883\u53cb\u597d\u578b\u7684\u805a\u5421\u54af\u6742\u5316\u590d\u5408\u6750\u6599\uff0c\u5f88\u5bb9\u6613\u63a8\u5e7f\u5230\u5236\u5907\u5176\u4ed6\u7684\u9ad8\u6027\u80fd\u50a8\u80fd\u7eb3\u7c73\u7535\u6781\u6750\u6599\u3002<\/p>\n

\u3010<\/strong>\u53c2<\/strong>\u8003\u6587\u732e<\/strong>\u3011<\/strong><\/p>\n

\u6587\u7ae0\u94fe\u63a5\uff1aFlexible and high energy density asymmetrical supercapacitors based on\u00a0<\/a>core\/shell conducting polymer nanowires\/manganese dioxide nanoflakes<\/a> (Nano Energy 2017 DOI:\u00a0http:\/\/dx.doi.org\/10.1016\/j.nanoen.2017.03.045<\/a>)<\/p>\n

\u672c\u6587\u7531\u6d4e\u5357\u5927\u5b66\u5f90\u9521\u91d1\u6559\u6388\u6295\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u5927\u57ce\u5c0f\u7231\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1a<\/strong>xiaofire-18<\/strong>\uff0c\u5434\u73ab\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

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