{"id":93803,"date":"2017-08-01T06:30:05","date_gmt":"2017-07-31T22:30:05","guid":{"rendered":"\/\/m.iemloyee.com\/?p=93803"},"modified":"2017-07-30T11:45:20","modified_gmt":"2017-07-30T03:45:20","slug":"%e9%a6%99%e6%b8%af%e7%a7%91%e6%8a%80%e5%a4%a7%e5%ad%a6macromolecules%ef%bc%9a%e5%ba%94%e7%94%a8aie%e8%8d%a7%e5%85%89%e6%8e%a2%e9%92%88%e9%ab%98%e5%af%b9%e6%af%94%e5%ba%a6%e8%a7%82%e6%b5%8b%e5%92%8c","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=93803","title":{"rendered":"\u5510\u672c\u5fe0\u9662\u58ebMacromolecules\uff1a\u5e94\u7528AIE\u8367\u5149\u63a2\u9488\u9ad8\u5bf9\u6bd4\u5ea6\u89c2\u6d4b\u548c\u533a\u5206\u805a\u5408\u7269\u5171\u6df7\u7269\u5fae\u76f8\u5206\u79bb\u5f62\u8c8c"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

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\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

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\"\"<\/p>\n

(A) \u57fa\u4e8e\u201c\u5206\u5b50\u5185\u8fd0\u52a8\u53d7\u9650\uff08RIM\uff09\u201d\u673a\u5236\u7684AIE\u6750\u6599\u53ef\u80fd\u901a\u8fc7\u5728\u4e24\u76f8\u4e2d\u7684\u4e0d\u540c\u53d1\u5149\u5f3a\u5ea6\u6765\u89c2\u5bdf\u548c\u533a\u5206\u7531\u4e0d\u540c\u521a\u6027\u7ec4\u5206\u7ec4\u6210\u7684\u805a\u5408\u7269\u5171\u6df7\u4f53\u7cfb\u7684\u76f8\u5206\u79bb\u5f62\u8c8c\uff1b<\/p>\n

(B) \u5177\u6709\u201c\u626d\u66f2\u7684\u5206\u5b50\u5185\u7535\u8377\u8f6c\u79fb\uff08TICT\uff09\u201d\u7279\u6027\u7684AIE\u6750\u6599\u53ef\u80fd\u901a\u8fc7\u5728\u4e24\u76f8\u4e2d\u7684\u4e0d\u540c\u53d1\u5149\u989c\u8272\u6765\u89c2\u5bdf\u548c\u533a\u5206\u7531\u4e0d\u540c\u6781\u6027\u7ec4\u5206\u7ec4\u6210\u7684\u805a\u5408\u7269\u5171\u6df7\u4f53\u7cfb\u7684\u76f8\u5206\u79bb\u5f62\u8c8c\u3002<\/p>\n

\u56fe2 \u5b9e\u9a8c\u6d41\u7a0b\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

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\u56fe3 \u63ba\u6742TPE\u7684\u805a\u5408\u7269\u5355\u7ec4\u5206\u53ca\u5171\u6df7\u8584\u819c\u7684\u8367\u5149\u663e\u5fae\u955c\u56fe\u50cf<\/strong><\/p>\n

\"\"<\/p>\n

\uff08A-C\uff09 \u660e\u573a\u56fe\u50cf\uff1b<\/p>\n

\uff08A1-C1\uff09\u8367\u5149\u56fe\u50cf\uff1b<\/p>\n

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\n \u6bd4\u4f8b\u5c3a\uff1a200\u03bcm\u3002<\/p>\n

\u56fe4 SEM\u56fe\u50cf\u4e0e\u5149\u5b66\u663e\u5fae\u955c\u660e\u573a\u53ca\u8367\u5149\u56fe\u50cf\u5bf9\u6bd4<\/strong><\/p>\n

\"\"<\/p>\n

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\u56fe5 1.0 wt\uff05TPE\u63ba\u6742\u7684\u4e0d\u540cPB\u8d28\u91cf\u5206\u6570\u4e0d\u540c\u7684PS\/PB\u5171\u6df7\u7269\u8584\u819c\u7684\u8367\u5149\u56fe\u50cf<\/strong><\/p>\n

\"\"<\/p>\n

\n \u6bd4\u4f8b\u5c3a\uff1a200\u03bcm\uff08\u4e3b\u56fe\uff09\u548c20\u03bcm\uff08\u63d2\u56fe\uff09\u3002<\/p>\n

\u56fe6 AIE+TICT\u5206\u5b50\u5728\u4e0d\u540c\u6781\u6027\u73af\u5883\u4e2d\u7684\u53d1\u5149\u60c5\u51b5<\/strong><\/p>\n

\"\"<\/p>\n

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\n \u63d2\u56fe\uff1a\u4f7f\u7528\u624b\u6301\u5f0f\u7d2b\u5916\u706f\u5728365nm\u7d2b\u5916\u7ebf\u7167\u5c04\u4e0b\u62cd\u6444\u7684TPABMO\u63ba\u6742\u7684\u805a\u5408\u7269\u8584\u819c\u7167\u7247\u3002<\/p>\n

\u56fe7 \u63ba\u6742TPABMO\u7684\u805a\u5408\u7269\u5355\u7ec4\u5206\u53ca\u5171\u6df7\u8584\u819c\u7684\u8367\u5149\u663e\u5fae\u955c\u56fe\u50cf<\/strong><\/p>\n

\"\"<\/p>\n

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\"\"<\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1aHigh-Contrast Visualization and Di\ufb00erentiation of Microphase Separation in Polymer Blends by Fluorescent AIE Probes<\/a><\/strong>\uff08Macromolecules \uff0c2017\uff0cDOI: 10.1021\/acs.macromol.7b00973\uff09<\/p>\n

\u56e2\u961f\u4ecb\u7ecd\uff1a<\/strong>\u53ef\u53c2\u89c1\u5510\u672c\u5fe0\u6559\u6388\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u8bfe\u9898\u7ec4\u7f51\u7ad9\uff1ahttp:\/\/webhost1.ust.hk\/~tangbz\/<\/a><\/p>\n

\u8bfe\u9898\u7ec4\u6700\u8fd1\u5408\u5f71\u5982\u4e0b\uff1a<\/p>\n

\"\"<\/p>\n

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\n 2001\u5e74,\u5510\u672c\u5fe0\u9662\u58eb\u56e2\u961f\u5728\u4e16\u754c\u4e0a\u6700\u5148\u63d0\u51fa\u805a\u96c6\u8bf1\u5bfc\u53d1\u5149\uff08AIE\uff09\u6982\u5ff5\uff0c\u8fc4\u4eca\u5df2\u5f00\u53d1\u51fa\u4e86\u4f17\u591a\u5177\u6709AIE\u6027\u8d28\u7684\u5148\u8fdb\u53d1\u5149\u6750\u6599\u3002\u8fd9\u9879\u53d1\u73b0\u4ece\u6839\u672c\u4e0a\u89e3\u51b3\u4e86\u4f20\u7edf\u7684\u53d1\u5149\u6750\u6599\u5728\u805a\u96c6\u6001\u6216\u56fa\u6001\u4e0b\u53d1\u5149\u5f88\u5f31\u751a\u81f3\u4e0d\u53d1\u5149\u8fd9\u4e00\u957f\u671f\u9650\u5236\u53d1\u5149\u6750\u6599\u53d1\u5c55\u7684\u68d8\u624b\u95ee\u9898\u3002AIE\u6548\u5e94\u7684\u53d1\u73b0\u4e3a\u79d1\u5b66\u5bb6\u4eec\u6df1\u5165\u7814\u7a76\u805a\u96c6\u6001\u4e0b\u53d1\u5149\u5316\u5408\u7269\u7684\u53d1\u5149\u6027\u8d28\u63d0\u4f9b\u4e86\u5e73\u53f0\uff0c\u4f7f\u5f97\u6280\u672f\u4eba\u5458\u53ef\u4ee5\u7075\u6d3b\u5730\u5229\u7528\u53d1\u5149\u5316\u5408\u7269\u7684\u805a\u96c6\u8fc7\u7a0b\uff0c\u800c\u4e0d\u7528\u518d\u88ab\u52a8\u5730\u89c4\u907f\u805a\u96c6\u4f53\u7684\u51fa\u73b0\u3002\u81ea\u53d1\u73b0\u4ee5\u6765\uff0cAIE\u8fd9\u4e00\u7531\u4e2d\u56fd\u79d1\u5b66\u5bb6\u5f00\u521b\u548c\u5f15\u5bfc\u7684\u65b0\u9886\u57df\u6b63\u5438\u5f15\u7740\u6765\u81ea\u5168\u7403\u7684\u7814\u7a76\u5174\u8da3\uff0c\u5efa\u7acb\u8d77\u4e86\u5f88\u9ad8\u7684\u5b66\u672f\u5f71\u54cd\u529b\u3002\u4ee5\u201cAggregation-Induced Emission\u201d\u4e3a\u5173\u952e\u8bcd\u4eceWeb of Science\u6570\u636e\u5e93\u4e2d\u83b7\u53d6\u7684\u6570\u636e\u8868\u660e\uff1a\u4ece2001\u5e74\u81f3\u4eca\uff0c\u5510\u672c\u5fe0\u6559\u6388\u8bfe\u9898\u7ec4\u6240\u53d1\u8868\u7684\u5173\u4e8eAIE\u7684\u7814\u7a76\u8bba\u6587\u53ca\u7efc\u8ff0\u7684\u5f15\u7528\u60c5\u51b5\u5355\u7bc7\u5f15\u7528>1,000\u6b21\uff0c\u4e00\u5e74\u5185\u5f15\u7528>300\u6b21\u3002\u591a\u79cd\u5177\u6709\u4e0d\u540c\u529f\u80fd\u7684AIE\u8367\u5149\u63a2\u9488\u5df2\u88ab\u6210\u529f\u5f00\u53d1\u5e76\u5e94\u7528\u4e8e\u751f\u7269\u3001\u5316\u5b66\u7b49\u591a\u9886\u57df\u5f53\u4e2d\u3002\u5173\u4e8e\u805a\u96c6\u8bf1\u5bfc\u53d1\u5149\u6750\u6599\u7684\u4ecb\u7ecd\u53ef\u4ee5\u53c2\u89c1\u7efc\u8ff0Chem. Rev., 2015, 115 (21), 11718\u201311940.<\/p>\n

\"\"<\/p>\n

\u805a\u96c6\u8bf1\u5bfc\u53d1\u5149\u73b0\u8c61\u4e0e\u4f20\u7edf\u805a\u96c6\u8367\u5149\u731d\u706d\u73b0\u8c61\u7684\u5bf9\u6bd4<\/strong><\/p>\n

\"\"<\/p>\n

AIE\u6750\u6599\u5728\u591a\u9886\u57df\u7684\u5e94\u7528<\/strong><\/p>\n

\uff082\uff09\u76f8\u5173\u4f18\u8d28\u6587\u732e\u63a8\u8350\u00a0<\/strong><\/p>\n

1) Roose, J.; Leung, A. C. S.; Wang, J.; Peng, Q.; Sung, H. H. Y.; Williams, I. D.; Tang, B. Z. A Colour-Tunable Chiral AIEgen: Reversible Coordination, Enantiomer Discrimination and Morphology Visualization. Chem. Sci. 2016, 7, 61066114.
\n 2) Li, J. W.; Li, Y.; Chan, C. Y. K.; Kwok, R. T. K.; Li, H. K.; Zrazhevskiy, P.; Gao, X. H.; Sun, J. Z.; Qin, A. J.; Tang, B. Z. An Aggregation-Induced-Emission Platform for Direct Visualization of Interfacial Dynamic Self-Assembly. Angew. Chem. Int. Ed. 2014, 53, 1351813522.
\n 3) Wang, Z. K.; Nie, J. Y.; Qin, W.; Hu, Q. L.; Tang, B. Z. Gelation Process Visualized by Aggregation-Induced Emission Fluorogens. Nat. Commun. 2016, 7, 12033.
\n 4) Guan, W. J.; Wang, S.; Lu, C.; Tang, B. Fluorescence Microscopy as an Alternative to Electron Microscopy for Microscale Dispersion Evaluation of Organic-Inorganic Composites. Nat. Commun. 2016, 7, 11811.<\/p>\n

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