{"id":93569,"date":"2017-07-30T14:00:50","date_gmt":"2017-07-30T06:00:50","guid":{"rendered":"\/\/m.iemloyee.com\/?p=93569"},"modified":"2017-08-01T00:00:05","modified_gmt":"2017-07-31T16:00:05","slug":"%e5%8e%a6%e9%97%a8%e5%a4%a7%e5%ad%a6%ef%bc%9a%e5%8d%95%e5%88%86%e6%95%a3%e7%a8%80%e5%9c%9f-%e8%bf%87%e6%b8%a1%e9%87%91%e5%b1%9e%e5%9b%a2%e7%b0%87%e7%9a%84%e7%a3%81%e6%80%a7%e7%a0%94%e7%a9%b6%e5%8f%96","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=93569","title":{"rendered":"\u53a6\u95e8\u5927\u5b66\uff1a\u5355\u5206\u6563\u7a00\u571f-\u8fc7\u6e21\u91d1\u5c5e\u56e2\u7c07\u7684\u78c1\u6027\u7814\u7a76\u53d6\u5f97\u65b0\u8fdb\u5c55"},"content":{"rendered":"<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u53a6\u95e8\u5927\u5b66\u5b54\u7965\u5efa\u6559\u6388\u548c\u9f99\u814a\u751f\u6559\u6388\u5728\u5355\u5206\u6563\u7a00\u571f-\u8fc7\u6e21\u91d1\u5c5e\u56e2\u7c07\u7684\u5236\u5907\u4e0e\u78c1\u6027\u7814\u7a76\u53d6\u5f97\u65b0\u8fdb\u5c55\uff0c\u76f8\u5173\u6210\u679c\u4ee5\u201cNew Insight into Magnetic Interaction in Monodisperse Gd<sub>12<\/sub>Fe<sub>14<\/sub>\u00a0Metal Cluster\u201d\u4e3a\u9898\u5728\u7ebf\u53d1\u8868\u5728<em><i>Angew. Chem. Int. Ed.(<\/i><\/em>2017.DOI: 10.1002\/anie.201705697)\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe1\u00a0\u91d1\u5c5e\u7c07\u82af\u7684\u68d2\u7403\u89c6\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-93575\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/1-22.png\" alt=\"\" width=\"600\" height=\"570\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/1-22.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/1-22-300x285.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u914d\u4f53\u6c22\u539f\u5b50\u88ab\u7701\u7565<\/p>\n<p><strong>\u56fe2\u00a0\u62df\u5408\u66f2\u7ebf\u5206\u6790<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-93576\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/2-23.png\" alt=\"\" width=\"517\" height=\"687\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/2-23.png 517w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/2-23-226x300.png 226w\" sizes=\"(max-width: 517px) 100vw, 517px\" \/><\/p>\n<p>\uff08a\uff091\uff08\u25cb\uff09\u548c1a@SiO<sub>2<\/sub>\uff08\u25a1\uff09\u7684\u03c7M T\u4e0eT\u7684\u5b9e\u9a8c\u56fe\uff0c\u03c7M T\u5bf9T\u7684\u62df\u5408\u66f2\u7ebf\uff08\u5b9e\u7ebf\uff09\u4e3a1\uff08\u7ea2\u8272\uff09\u548c1a@SiO<sub>2<\/sub>\uff08\u84dd\u8272\uff09<\/p>\n<p>\uff08b\uff09\u8349\u56fe1\uff0c\u4e0d\u542bFe-Fe\u8fde\u63a5<\/p>\n<p><strong>\u3010\u7814\u7a76\u5185\u5bb9\u3011<\/strong><\/p>\n<p>\u7406\u89e3\u590d\u6742\u56e2\u7c07\u4f53\u7cfb\u4e2d\u7684\u78c1\u4ea4\u6362\u4f5c\u7528\u5bf9\u6307\u5bfc\u56e2\u7c07\u78c1\u6027\u6750\u6599\u7684\u8bbe\u8ba1\u4e0e\u5408\u6210\u81f3\u5173\u91cd\u8981\uff0c\u800c\u76ee\u524d\u5355\u5206\u6563\u56e2\u7c07\u7684\u78c1\u4ea4\u6362\u4f5c\u7528\u7684\u5b9e\u9a8c\u4e0e\u7406\u8bba\u7814\u7a76\u975e\u5e38\u5c11\u3002\u8be5\u8bfe\u9898\u7ec4\u5236\u5907\u4e86\u76ee\u524d\u62a5\u9053\u7684\u6700\u9ad8\u6838\u7a00\u571f-\u94c1\u6c27\u56e2\u7c07Gd<sub>12<\/sub>Fe<sub>14<\/sub>\uff0c\u5e76\u5229\u7528\u53cd\u76f8\u5fae\u4e73\u6cd5\u6210\u529f\u5236\u5907\u4e86\u5355\u5206\u6563\u56e2\u7c07Gd<sub>12<\/sub>Fe<sub>14<\/sub>@SiO<sub>2<\/sub>\u7684\u6838\u58f3\u7ed3\u6784\u3002\u5b9e\u9a8c\u4e0e\u7406\u8bba\u7814\u7a76\u8868\u660e\uff0cSiO<sub>2<\/sub>\u5c42\u7684\u5305\u8986\u4e0d\u4f46\u6709\u6548\u6d88\u9664\u4e86\u56e2\u7c07\u95f4\u7684\u78c1\u76f8\u4e92\u4f5c\u7528\uff0c\u800c\u4e14\u589e\u52a0\u4e86\u5916\u56f4Fe<sup>3+<\/sup>\u79bb\u5b50\u7684\u78c1\u96f6\u573a\u5206\u88c2\u503c,\u540c\u65f6\u964d\u4f4e\u4e86\u6574\u4e2a\u56e2\u7c07\u5206\u5b50\u7684\u78c1\u5404\u9879\u5f02\u6027\u3002\u8be5\u7814\u7a76\u4e3a\u4eba\u4eec\u7406\u89e3\u5355\u5206\u6563\u91d1\u5c5e\u56e2\u7c07\u5206\u5b50\u7684\u78c1\u4ea4\u6362\u4f5c\u7528\u63d0\u4f9b\u4e86\u65b0\u7684\u8ba4\u8bc6\u3002<\/p>\n<p>\u8be5\u5de5\u4f5c\u7531\u535a\u58eb\u751f\u90d1\u79c0\u82f1\uff08\u7b2c\u4e00\u4f5c\u8005\uff09\u3001\u5f20\u8f89\u3001\u5218\u670b\u6615\u3001\u675c\u660e\u6d69\u3001\u97e9\u82f1\u59ff\u3001\u5371\u8363\u4f73\u7b49\u5171\u540c\u5b8c\u6210\u3002\u6d59\u6c5f\u5de5\u4e1a\u5927\u5b66\u5e84\u6842\u6797\u535a\u58eb\u5bf9\u56e2\u7c07\u7684\u78c1\u6027\u8fdb\u884c\u4e86\u7406\u8bba\u8ba1\u7b97\uff0c\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u56fd\u5bb6\u8109\u51b2\u5f3a\u78c1\u573a\u79d1\u5b66\u4e2d\u5fc3\u7684\u738b\u632f\u5174\u526f\u6559\u6388\u548c\u6b27\u9633\u949f\u6587\u6559\u6388\u8fdb\u884c\u4e86\u9ad8\u573aESR\u6d4b\u8bd5\u4e0e\u89e3\u91ca\u5de5\u4f5c\u3002EXAFS\u5728\u4e0a\u6d77\u5149\u6e90\u540c\u6b65\u8f90\u5c04\u4e2d\u5fc3\u5b8c\u6210\uff0c\u7531\u53f8\u9510\u6559\u6388\u548c\u9093\u5fb7\u4f1a\u6559\u6388\u63d0\u4f9b\u5e2e\u52a9\u3002\u8be5\u7814\u7a76\u5de5\u4f5c\u5f97\u5230\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u59d4\uff0821422106, 21371144, 21431005, 21390391)\u3001\u79d1\u6280\u90e8\uff082014CB845601)\u7b49\u76f8\u5173\u9879\u76ee\u7684\u8d44\u52a9\u3002<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1a<a href=\"http:\/\/chem.xmu.edu.cn\/show.asp?id=2236\" target=\"_blank\" rel=\"noopener noreferrer\">http:\/\/chem.xmu.edu.cn\/show.asp?id=2236<\/a><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a <a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201705697\/full\" target=\"_blank\" rel=\"noopener noreferrer\">New Insight into Magnetic Interaction in Monodisperse Gd<sub>12<\/sub>Fe<sub>14<\/sub>\u00a0Metal Cluster<\/a>\uff08Angew. Chem. Int. Ed.,2017,DOI\uff1a10.1002\/anie.201705697 \u00a0\uff09<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8Allen\u7f16\u8f91\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" rel=\"noopener noreferrer\">\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener noreferrer\">\u6d4b\u8bd5\u8c37<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u6210\u679c\u7b80\u4ecb\u3011 \u53a6\u95e8\u5927\u5b66\u5b54\u7965\u5efa\u6559\u6388\u548c\u9f99\u814a\u751f\u6559\u6388\u5728\u5355\u5206\u6563\u7a00\u571f-\u8fc7\u6e21\u91d1\u5c5e\u56e2\u7c07\u7684\u5236\u5907\u4e0e\u78c1\u6027\u7814\u7a76\u53d6\u5f97\u65b0\u8fdb\u5c55\uff0c\u76f8\u5173\u6210\u679c\u4ee5\u201cNew Insight into Magnetic&#8230;<\/p>\n","protected":false},"author":349,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-93569","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/93569"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/349"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=93569"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/93569\/revisions"}],"predecessor-version":[{"id":93591,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/93569\/revisions\/93591"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=93569"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=93569"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=93569"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}