{"id":93136,"date":"2017-07-27T06:30:52","date_gmt":"2017-07-26T22:30:52","guid":{"rendered":"\/\/m.iemloyee.com\/?p=93136"},"modified":"2017-07-26T15:54:44","modified_gmt":"2017-07-26T07:54:44","slug":"%e5%8e%a6%e5%a4%a7%e7%89%a9%e7%90%86%e7%b3%bb%e8%ae%a1%e7%ae%97%e5%87%9d%e8%81%9a%e6%80%81%e7%89%a9%e7%90%86%e7%a0%94%e7%a9%b6%e7%bb%84%ef%bc%9a%e7%94%b5%e8%bf%98%e5%8e%9f%e5%90%88%e6%88%90%e6%b0%a8","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=93136","title":{"rendered":"\u53a6\u5927\u7269\u7406\u7cfb\u8ba1\u7b97\u51dd\u805a\u6001\u7269\u7406\u7814\u7a76\u7ec4\uff1a\u7535\u8fd8\u539f\u5408\u6210\u6c28\u7406\u8bba\u7814\u7a76\u53d6\u5f97\u91cd\u8981\u8fdb\u5c55"},"content":{"rendered":"

\u3010<\/b><\/strong>\u6210\u679c\u7b80\u4ecb<\/b><\/strong>\u3011<\/b><\/strong><\/p>\n

\u53a6\u95e8\u5927\u5b66\u7269\u7406\u79d1\u5b66\u4e0e\u6280\u672f\u5b66\u9662\u8ba1\u7b97\u51dd\u805a\u6001\u7269\u7406\u7814\u7a76\u7ec4\u5434\u987a\u60c5\u6559\u6388\u3001\u66f9\u6615\u777f\u52a9\u7406\u6559\u6388\u4e0e\u534e\u5357\u7406\u5de5\u738b\u6d77\u8f89\u6559\u6388\u8bfe\u9898\u7ec4\u5728\u7535\u50ac\u5316\u5408\u6210\u6c28\u7814\u7a76\u53d6\u5f97\u91cd\u8981\u8fdb\u5c55\uff0c\u76f8\u5173\u6210\u679c\u4ee5\u201cAmmonia electrosynthesis with high selectivity under ambient conditions via a Li+<\/sup>\u00a0incorporation strategy\u201d\u4e3a\u9898\u53d1\u8868\u5728Journal of the American Chemical Society\u4e0a\u3002<\/p>\n

\u3010<\/b><\/strong>\u56fe\u6587\u5bfc\u8bfb<\/b><\/strong>\u3011<\/b><\/strong><\/p>\n

\u56fe<\/b><\/strong>1 <\/b><\/strong>\u793a\u610f\u56fe\u53ca\u8868\u5f81\u7ed3\u679c<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09PEBCD\u7684\u4e24\u6b65\u5408\u6210\u8def\u7ebf\u56fe\u793a\uff1aI\uff09\u6eb6\u6db2\u805a\u5408\uff0cII\uff09\u70ed\u5904\u7406\u3002<\/p>\n

\uff08b\uff09SEM\u56fe\u50cf\u3002<\/p>\n

\uff08c\uff09\u5143\u7d20\u6620\u5c04\u548cEDS\u3002<\/p>\n

\uff08d\uff09XPS\u56fe\u8c31\u3002<\/p>\n

\uff08e\uff09PEBCD\u7684FTIR\u56fe\u8c31\u3002<\/p>\n

\u56fe2 PEBCD<\/b><\/strong>\/<\/b><\/strong>C\u7684NRR\u884c\u4e3a<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09NRR\u53cd\u5e94\u6c60\u793a\u610f\u56fe\u3002<\/p>\n

\uff08b\uff0925\u2103\u4e0b\u5404\u79cd\u7535\u4f4d\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u3002<\/p>\n

\uff08c\uff0925\u2103\u4e0b\u5404\u79cd\u7535\u4f4d\u7684NH3<\/sub>\u4ea7\u7387\u3002<\/p>\n

\uff08d\uff09\u5faa\u73af\u7a33\u5b9a\u6027\u7ed3\u679c\u3002<\/p>\n

\u3010\u7814\u7a76\u5185\u5bb9\u3011<\/b><\/strong><\/p>\n

\u6c28\u662f\u5316\u80a5\u5de5\u4e1a\u548c\u6709\u673a\u5316\u5de5\u7684\u4e3b\u8981\u539f\u6599\uff0c\u56fa\u6c2e\u4ea7\u6c28\u5728\u751f\u7269\u3001\u5316\u5b66\u548c\u73af\u5883\u7b49\u5b66\u79d1\u4e2d\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u5de5\u4e1a\u4e0a\u901a\u5e38\u7531\u6c22\u6c14\u548c\u6c2e\u6c14\u53cd\u5e94\u5408\u6210\u6c28\uff0c\u8be5\u53cd\u5e94\u53ea\u80fd\u5728\u9ad8\u6e29\u9ad8\u538b\u548c\u50ac\u5316\u5242\u6761\u4ef6\u4e0b\u8fdb\u884c\uff0c\u5176\u56fa\u6c2e\u4ea7\u6c28\u7684\u6548\u7387\u4f4e\u4e14\u6781\u4e0d\u73af\u4fdd\u3002\u901a\u8fc7\u7cfb\u7edf\u7684\u7814\u7a76\uff0c\u738b\u6d77\u8f89\u6559\u6388\u8bfe\u9898\u7ec4\u53d1\u73b0\u5c06\u00a0Li+<\/sup>\u5d4c\u5165\u690d\u5165\u7684poly(N-ethyl-benzene-1,2,4,5-tetracarboxylic diimide)(PEBCD)\u5206\u5b50\u5728\u7535\u50ac\u5316\u6c2e\u6c14\u8fd8\u539f\u5408\u6210\u6c28\uff08NRR\uff09\u7684\u8fc7\u7a0b\u4e2d\u5177\u6709\u6781\u9ad8\u7684\u9009\u62e9\u6027\uff0c\u4e14\u53cd\u5e94\u53ef\u5728\u5e38\u6e29\u5e38\u538b\u4e0b\u8fdb\u884c\u3002\u5434\u987a\u60c5\u6559\u6388\u548c\u66f9\u6615\u777f\u52a9\u7406\u6559\u6388\u901a\u8fc7\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u7814\u7a76\u4e86\u50ac\u5316\u5242\u6d3b\u6027\u4f4d\u7684\u7ed3\u6784\u7279\u5f81\u548c\u53ef\u80fd\u7684\u50ac\u5316\u673a\u7406\uff0c\u8ba8\u8bba\u5206\u6790\u4e86\u50ac\u5316\u53cd\u5e94\u8def\u5f84\u3002\u7814\u7a76\u53d1\u73b0\uff0cLi+<\/sup>\u4e0ePEBCD\u4e0a\u7684O-Li+<\/sup>]\u00b7N2<\/sub>-Hx\u201d\u4e2d\u95f4\u4f53\uff0c\u8fd9\u4e00\u5206\u5b50\u7ea7\u522b\u7684\u6a21\u578b\u4e3a\u4f18\u5316NRR\u53cd\u5e94\u63d0\u4f9b\u4e86\u6307\u5bfc\u5e76\u4e3a\u7535\u50ac\u5316\u6c2e\u6c14\u8fd8\u539f\u6210\u6c28\u9ad8\u6548\u9ad8\u9009\u62e9\u6027\u975e\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002<\/p>\n

\u8be5\u5de5\u4f5c\u7684\u7406\u8bba\u90e8\u5206\u5f97\u5230\u4e86\u56fd\u5bb6\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u9879\u76ee\u7684\u8d44\u52a9\u3002<\/p>\n

\u539f\u6587\u94fe\u63a5\uff1ahttp:\/\/cpst.xmu.edu.cn\/pmee\/node\/950<\/a><\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aAmmonia electrosynthesis with high selectivity under ambient conditions via a Li+<\/sup>\u00a0incorporation strategy<\/a>\u00a0(J. Am. Chem. Soc., 2017, DOI: 10.1021\/jacs.7b04393)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u77f3\u5c0f\u6885\u7f16\u8f91\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u6210\u679c\u7b80\u4ecb\u3011 \u53a6\u95e8\u5927\u5b66\u7269\u7406\u79d1\u5b66\u4e0e\u6280\u672f\u5b66\u9662\u8ba1\u7b97\u51dd\u805a\u6001\u7269\u7406\u7814\u7a76\u7ec4\u5434\u987a\u60c5\u6559\u6388\u3001\u66f9\u6615\u777f\u52a9\u7406\u6559\u6388\u4e0e\u534e\u5357\u7406\u5de5\u738b\u6d77\u8f89\u6559\u6388\u8bfe\u9898\u7ec4\u5728\u7535\u50ac\u5316\u5408\u6210\u6c28\u7814\u7a76\u53d6\u5f97\u91cd\u8981\u8fdb\u5c55\uff0c\u76f8\u5173\u6210\u679c\u4ee5\u201cAm…<\/p>\n","protected":false},"author":2832,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-93136","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/93136"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2832"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=93136"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/93136\/revisions"}],"predecessor-version":[{"id":93363,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/93136\/revisions\/93363"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=93136"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=93136"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=93136"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}