{"id":92835,"date":"2017-07-23T02:21:30","date_gmt":"2017-07-22T18:21:30","guid":{"rendered":"\/\/m.iemloyee.com\/?p=92835"},"modified":"2017-07-23T12:12:38","modified_gmt":"2017-07-23T04:12:38","slug":"%e5%8d%97%e4%ba%ac%e8%88%aa%e7%a9%ba%e8%88%aa%e5%a4%a9%e5%a4%a7%e5%ad%a6mater-today%e7%bb%bc%e8%bf%b0%ef%bc%9a%e6%8e%a2%e7%a9%b6%e9%87%91%e5%b1%9e%e6%9c%89%e6%9c%ba%e6%a1%86%e6%9e%b6%ef%bc%88mofs","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=92835","title":{"rendered":"\u5357\u4eac\u822a\u7a7a\u822a\u5929\u5927\u5b66Mater. Today\u7efc\u8ff0\uff1a\u63a2\u7a76\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOFs\uff09\u6750\u6599\u5728\u80fd\u91cf\u5b58\u50a8\u9886\u57df\u4e2d\u7684\u5e94\u7528"},"content":{"rendered":"<p><span style=\"color: #ff0000\"><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n<p>\u4f20\u7edf\u5316\u77f3\u80fd\u6e90\u7684\u6709\u9650\u50a8\u91cf\u6240\u5f15\u53d1\u7684\u80fd\u6e90\u5371\u673a\u7ec8\u5c06\u5236\u7ea6\u4eba\u7c7b\u793e\u4f1a\u7684\u53ef\u6301\u7eed\u53d1\u5c55\u4ee5\u53ca\u5a01\u80c1\u4eba\u7c7b\u7684\u751f\u5b58\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u65b0\u5174\u66ff\u4ee3\u80fd\u6e90\u5df2\u7ecf\u6210\u4e3a\u5f53\u4eca\u4e00\u4e2a\u8feb\u5728\u7709\u776b\u7684\u4efb\u52a1\u3002\u7535\u5316\u5b66\u80fd\u6e90\u50a8\u5b58\u5668\u4ef6\u4f5c\u4e3a\u5229\u7528\u65b0\u80fd\u6e90\u7684\u91cd\u8981\u4e00\u73af\u76ee\u524d\u88ab\u53d7\u79d1\u7814\u754c\u4ee5\u53ca\u5de5\u4e1a\u754c\u7684\u5173\u6ce8\u3002<\/p>\n<p>\u5728\u7535\u5316\u5b66\u80fd\u6e90\u50a8\u5b58\u7cfb\u7edf\u4e2d\uff0c\u4e8c\u6b21\u7535\u6c60\uff08\u5373\u53ef\u5145\u7535\u7535\u6c60\uff09\u548c\u8d85\u7ea7\u7535\u5bb9\u5668\u662f\u6700\u91cd\u8981\u7684\u4e24\u7c7b\u5668\u4ef6\u3002\u9502\u79bb\u5b50\u7535\u6c60\u5177\u6709\u80fd\u91cf\u5bc6\u5ea6\u9ad8\u3001\u8d28\u91cf\u5c0f\u7b49\u4f18\u52bf\uff0c\u5df2\u7ecf\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u4fbf\u643a\u5f0f\u7535\u5b50\u8bbe\u5907\u3001\u7535\u52a8\u6c7d\u8f66\u3001\u5206\u5e03\u5f0f\u50a8\u80fd\u7b49\u3002\u6b64\u5916\uff0c\u94a0\u56e0\u5176\u5728\u5730\u7403\u4e0a\u50a8\u91cf\u8f83\u9502\u4e30\u5bcc\uff08\u5982\u6d77\u6c34\u4e2d\uff09\uff0c\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u7814\u53d1\u8fd1\u4e9b\u5e74\u9010\u6e10\u5174\u8d77\u3002\u8d85\u7ea7\u7535\u5bb9\u5668\u5219\u4ee5\u5176\u9ad8\u529f\u7387\u5bc6\u5ea6\u3001\u957f\u5bff\u547d\u3001\u4f4e\u6210\u672c\uff0c\u76ee\u524d\u5df2\u7ecf\u5f97\u5230\u5e7f\u6cdb\u5173\u6ce8\u5e76\u4e14\u88ab\u5e94\u7528\u4e8e\u822a\u7a7a\u7cfb\u7edf\u548c\u7535\u52a8\u4ea4\u901a\u5de5\u5177\u3002<\/p>\n<p>\u9002\u7528\u4e8e\u4e8c\u6b21\u7535\u6c60\u548c\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u7535\u6781\u6750\u6599\u5e94\u5177\u6709\u9ad8\u6bd4\u8868\u9762\u79ef\u3001\u9ad8\u5bfc\u7535\u6027\u548c\u9002\u5b9c\u7684\u5b54\u5bb9\u548c\u5b54\u5f84\u3002\u91d1\u5c5e\u6709\u673a\u6846\u67b6(MOFs)\u662f\u4e00\u7c7b\u7531\u6709\u673a\u914d\u4f53\u548c\u91d1\u5c5e\u79bb\u5b50\u6216\u56e2\u7c07\u901a\u8fc7\u914d\u4f4d\u952e\u81ea\u7ec4\u88c5\u5f62\u6210\u7684\u5177\u6709\u5206\u5b50\u5185\u5b54\u9699\u7684\u6709\u673a-\u65e0\u673a\u6742\u5316\u6750\u6599\u91d1\u5c5e\u914d\u5408\u7269\uff0c\u5176\u7ed3\u6784\u5177\u6709\u957f\u7a0b\u6709\u5e8f\u6027\u3002\u7531\u4e8e\u5176\u53ef\u8c03\u63a7\u7684\u5b54\u5c3a\u5bf8\u3001\u5927\u91cf\u7684\u5b54\u9053\u7ed3\u6784\u3001\u9ad8\u6bd4\u8868\u9762\u79ef\u548c\u4e30\u5bcc\u7684\u8868\u9762\u5b98\u80fd\u56e2\u7b49\u7279\u70b9\u8fd1\u5e74\u6765\u53d7\u5230\u4e86\u6750\u6599\u5de5\u4f5c\u8005\u7684\u9752\u7750\u3002MOFs\u53ef\u6ee1\u8db3\u4e8c\u6b21\u7535\u6c60\u548c\u8d85\u7ea7\u7535\u5bb9\u5668\u7535\u6781\u6750\u6599\u7684\u9700\u6c42\uff0c\u662f\u4e0b\u4e00\u4ee3\u5177\u6709\u53d1\u5c55\u6f5c\u529b\u7684\u7535\u6781\u6750\u6599\u3002<\/p>\n<p>2017\u5e746\u67088\u65e5\uff0c<em>Materials Today<\/em>\u671f\u520a\u5728\u7ebf\u53d1\u8868\u4e86\u7531<strong><span style=\"color: #0000ff\">\u5357\u4eac\u822a\u7a7a\u822a\u5929\u5927\u5b66<\/span>\u7aa6\u8f89<\/strong>\u6559\u6388\u3001<strong><span style=\"color: #000000\">\u5f20\u6821\u521a<\/span><\/strong>\u6559\u6388(\u5171\u540c\u901a\u8baf)\u53ca\u5f90\u6842\u94f6\u535a\u58eb(\u7b2c\u4e00\u4f5c\u8005)\u7b49\u64b0\u5199\u7684\u7efc\u8ff0\u8bba\u6587\u201cExploring metal organic frameworks for energy storage in batteries and supercapacitors\u201d\u3002\u6587\u7ae0\u4ecb\u7ecd\u4e86MOFs\u5728\u9502\u79bb\u5b50\u7535\u6c60\u3001\u94a0\u79bb\u5b50\u7535\u6c60\u3001\u9502\u786b\u7535\u6c60\u3001\u9502\u7852\u7535\u6c60\u3001\u9502\u6c27\u7535\u6c60\u4ee5\u53ca\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u5e94\u7528\u3002\u8bba\u6587\u7efc\u8ff0\u4e86MOFs\u7684\u7ed3\u6784\u3001\u6bd4\u8868\u9762\u79ef\u3001\u529f\u80fd\u6709\u673a\u94fe\u3001\u91d1\u5c5e\u4e2d\u5fc3\u539f\u5b50\u4e0e\u5668\u4ef6\u7535\u5316\u5b66\u6027\u80fd\u4e4b\u95f4\u7684\u5173\u7cfb\uff0c\u5e76\u8fdb\u4e00\u6b65\u5c55\u671b\u4e86\u901a\u8fc7\u8c03\u63a7MOFs\u7ed3\u6784\u4e0e\u5f62\u8c8c\u7b49\u6765\u63d0\u9ad8\u5668\u4ef6\u7684\u80fd\u91cf\u5bc6\u5ea6\u3001\u529f\u7387\u5bc6\u5ea6\u3001\u5faa\u73af\u7a33\u5b9a\u6027\u7b49\u6027\u80fd\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-92836 \" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/1-45.jpg\" alt=\"\" width=\"591\" height=\"580\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/1-45.jpg 694w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/1-45-300x294.jpg 300w\" sizes=\"(max-width: 591px) 100vw, 591px\" \/><\/p>\n<p style=\"text-align: center\"><strong>\uff08\u7efc\u8ff0\u603b\u89c8\u56fe\uff09<\/strong><\/p>\n<p><span style=\"color: #ff0000\"><strong>\u3010\u56fe\u6587\u4fe1\u606f\u3011<\/strong><\/span><\/p>\n<p><strong>\uff08\u672c\u6587\u56fe\u7247\u6765\u81ea\u6587\u540e\u7684\u6587\u732e\uff09<\/strong><\/p>\n<p><strong>\u4e00\u3001\u7535\u6c60\u7535\u6781\u6750\u6599<\/strong><\/p>\n<p>\u8be5\u90e8\u5206\u4e3b\u8981\u63a2\u8ba8\u4e86MOFs\u4ee5\u53ca\u5176\u884d\u751f\u7269\u5728\u9502\u79bb\u5b50\u7535\u6c60\u3001\u94a0\u79bb\u5b50\u7535\u6c60\u3001\u9502\u6c27\u7535\u6c60\u3001\u9502\u786b\u7535\u6c60\u4ee5\u53ca\u9502\u7852\u7535\u6c60\u4e2d\u7684\u5e94\u7528\u3002<\/p>\n<p><strong>1-1 <\/strong><strong>\u9502<\/strong><strong>\/<\/strong><strong>\u94a0\u79bb\u5b50\u7535\u6c60<\/strong><\/p>\n<p>\u81ea2007\u5e74\u6cd5\u56fdJ-M. Tarascon\u8bfe\u9898\u7ec4\u9996\u6b21\u62a5\u9053\u4e86MOFs\u53ef\u7528\u4f5c\u4e8c\u6b21\u7535\u6c60\u7684\u7535\u6781\u6750\u6599\u4ee5\u6765\uff0c\u4eba\u4eec\u5bf9\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u6750\u6599\u5728\u7535\u6c60\u9886\u57df\u4e2d\u7684\u5e94\u7528\u5c55\u5f00\u4e86\u5927\u91cf\u7684\u7814\u7a76\u5de5\u4f5c\u3002\u672c\u8282\u4e3b\u8981\u4ecb\u7ecd\u4e86MOFs\u4f5c\u4e3a\u7535\u6781\u6750\u6599\u5728\u9502\u79bb\u5b50\u548c\u94a0\u79bb\u5b50\u7535\u6c60\u4e2d\u5e94\u7528\u5e76\u7740\u91cd\u4ecb\u7ecd\u4e86\u666e\u9c81\u58eb\u84dd\u53ca\u7c7b\u666e\u9c81\u58eb\u84dd\u5316\u5408\u7269\u3002\u8fd9\u4e9b\u5316\u5408\u7269\u56e0\u5176\u4e09\u7ef4\u591a\u5b54\u7ed3\u6784\uff0c\u5927\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u53ef\u4ee5\u53ef\u9006\u5730\u8131\/\u5d4c\u78b1\u91d1\u5c5e\u79bb\u5b50\u800c\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u53ef\u5145\u7535\u7535\u6c60\u7684\u6b63\u6781\u6750\u6599\u3002<\/p>\n<p>\u672c\u8bfe\u9898\u7ec4\u9996\u6b21\u62a5\u9053\u4e86\u7c7b\u666e\u9c81\u58eb\u84dd\u5316\u5408\u7269\u94b4\u6c30\u9178\u94b4\u548c\u94b4\u6c30\u9178\u9530\u4f5c\u4e3a\u8d1f\u6781\u6750\u6599\u5728\u9502\u79bb\u5b50\u548c\u94a0\u79bb\u5b50\u4e8c\u6b21\u7535\u6c60\uff08\u975e\u6c34\u7535\u89e3\u6db2\uff09\u4e2d\u7684\u5e94\u7528(<em>J. Mater. Chem. A<\/em>, 2014, 2, 5852)\u3002\u6b64\u5916\u8fd8\u4ecb\u7ecd\u4e86\u67d4\u6027\u81ea\u652f\u6491\u7535\u6781(<em>J. Mater. Chem. A<\/em>, 2015, 3, 16590)\u3001\u5229\u7528\u5177\u6709\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u5206\u5b50\u8868\u9762\u4fee\u9970\u63d0\u9ad8\u6750\u6599\u7684\u7535\u5316\u5b66\u53cd\u5e94\u52a8\u529b\u5b66(<em>ACS Appl. Mater. Interfaces<\/em> <strong>2017<\/strong>, 9, 20306-20312)\u7b49\u76f8\u5173\u65b9\u9762\u7684\u5de5\u4f5c\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-92837 \" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/2-41.jpg\" alt=\"\" width=\"598\" height=\"470\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/2-41.jpg 693w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/2-41-300x236.jpg 300w\" sizes=\"(max-width: 598px) 100vw, 598px\" \/><\/p>\n<p>\u56fe1. K<sub>4<\/sub>Na<sub>2<\/sub>[Fe(C<sub>2<\/sub>O<sub>4<\/sub>)<sub>2<\/sub>]<sub>3<\/sub><strong><sup>.<\/sup><\/strong>2H<sub>2<\/sub>O\u7684\u6676\u4f53\u7ed3\u6784\u793a\u610f\u56fe\uff1a(a)\u94c1\u539f\u5b50\u9644\u8fd1\u7684\u914d\u4f4d\u7ed3\u6784\u793a\u610f\u56fe\u3002(b)\u4e09\u7ef4\u8349\u9178\u94c1\u9aa8\u67b6\u793a\u610f\u56fe\u3002(c)\u94a0\u79bb\u5b50\u5728K<sub>4<\/sub>Na<sub>2<\/sub>[Fe(C<sub>2<\/sub>O<sub>4<\/sub>)<sub>2<\/sub>]<sub>3<\/sub><strong><sup>.<\/sup><\/strong>2H<sub>2<\/sub>O\u4e2d\u7684\u8131\/\u5d4c\u901a\u9053\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n<p><strong>1-2 <\/strong><strong>\u9502\u6c27\u7535\u6c60<\/strong><\/p>\n<p>\u9502\u6c27\u7535\u6c60\u5177\u6709\u6781\u9ad8\u7684\u7406\u8bba\u6bd4\u80fd\u91cf\u5bc6\u5ea6\uff0c\u53ef\u4ee5\u6ee1\u8db3\u672a\u6765\u957f\u7eed\u822a\u91cc\u7a0b\u7535\u52a8\u6c7d\u8f66\u7684\u9700\u6c42\u3002\u56e0\u6b64\u8fd9\u79cd\u7535\u6c60\u6709\u671b\u6210\u4e3a\u65b0\u4e00\u4ee3\u5546\u7528\u7535\u6c60\u3002\u7136\u800c\uff0c\u7531\u4e8e\u9502\u6c27\u7535\u6c60\u4ea7\u7269\u8fc7\u6c27\u5316\u9502\uff08Li<sub>2<\/sub>O<sub>2<\/sub>\uff09\u8f83\u5dee\u7684\u5bfc\u7535\u6027\u548c\u6eb6\u89e3\u6027\uff0c\u5bfc\u81f4\u7535\u6c60\u9634\u6781\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u7f13\u6162\u3001\u7535\u6c60\u8fc7\u7535\u52bf\u8f83\u5927\u3001\u5faa\u73af\u5bff\u547d\u77ed\u3002\u56e0\u6b64\uff0c\u8bbe\u8ba1\u548c\u7814\u7a76\u5177\u6709\u9ad8\u50ac\u5316\u6d3b\u6027\u3001\u7279\u6b8a\u7ed3\u6784\u7684\u9634\u6781\u50ac\u5316\u5242\u4ee5\u6539\u5584\u9502\u6c27\u7535\u6c60\u7684\u5145\u653e\u7535\u53cd\u5e94\u7684\u4f20\u8f93\u52a8\u529b\u5b66\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002<\/p>\n<p>\u7531\u4e8eMOFs\u4ee5\u53caMOFs\u884d\u751f\u7269\u5177\u6709\u5927\u6bd4\u8868\u9762\u79ef\uff0c\u6d3b\u6027\u91d1\u5c5e\u4f4d\u70b9\u548c\u7ed3\u6784\u53ef\u8c03\u7684\u7279\u70b9\uff0c\u5b83\u4eec\u53ef\u4ee5\u4f5c\u4e3a\u50ac\u5316\u5242\u6750\u6599\u5e94\u7528\u5728\u9502\u6c27\u7535\u6c60\u4f53\u7cfb\u3002\u672c\u7ae0\u8282\u6982\u8ff0\u4e86MOFs\u884d\u751f\u7269\uff08\u5305\u62ec\u91d1\u5c5e\u6c27\u5316\u7269\u3001\u78b3\u6750\u6599\u3001\u91d1\u5c5e\u6c27\u5316\u7269\/\u78b3\u6750\u6599\u590d\u5408\u6750\u6599\u4ee5\u53ca\u786b\u5316\u7269\u7b49\uff09\u5728\u9502\u6c27\u7535\u6c60\u4e2d\u50ac\u5316\u6027\u80fd\u7684\u524d\u6cbf\u7814\u7a76\u3002MOFs\u4ee5\u53caMOFs\u884d\u751f\u7269\u5728\u9502\u6c27\u7535\u6c60\u4e2d\u4e0d\u4ec5\u53ef\u4ee5\u4f5c\u4e3a\u9634\u6781\u50ac\u5316\u5242\u6750\u6599\uff0c\u800c\u4e14\u8fd8\u53ef\u4e0e\u5176\u4ed6\u6750\u6599\u7ed3\u5408\u5236\u5907\u7a7a\u6c14\u7535\u6781\u7684\u9009\u62e9\u6027\u900f\u6c14\u819c\u4ee5\u63d0\u9ad8\u9502\u6c27\u7535\u6c60\u7684\u80fd\u91cf\u8f6c\u5316\u6548\u7387\u3001\u589e\u5927\u521d\u59cb\u653e\u7535\u5bb9\u91cf\u3001\u6539\u5584\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n<p><strong>1-3 <\/strong><strong>\u9502\u786b\u7535\u6c60<\/strong><\/p>\n<p>\u9502\u786b\u7535\u6c60\u56e0\u5176\u5177\u6709\u9ad8\u7684\u7406\u8bba\u6bd4\u5bb9\u91cf(1675 mAh\/g)\u53ca\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea6(2600 Wh\/kg)\uff0c\u6210\u4e3a\u4e0b\u4e00\u4ee3\u6700\u5177\u53d1\u5c55\u6f5c\u529b\u7684\u65b0\u578b\u9ad8\u80fd\u5316\u5b66\u7535\u6e90\u4f53\u7cfb\u4e4b\u4e00\u3002\u4f46\u662f\uff0c\u6b63\u6781\u6750\u6599\u786b\u7684\u5bfc\u7535\u6027\u4f4e\u4ee5\u53ca\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u4ea7\u751f\u7684\u4e2d\u95f4\u4ea7\u7269\u591a\u786b\u5316\u9502\u6613\u6eb6\u4e8e\u6709\u673a\u7535\u89e3\u6db2\uff0c\u5bfc\u81f4\u5176\u4f4e\u7684\u7535\u5316\u5b66\u5229\u7528\u7387\u548c\u5dee\u7684\u5faa\u73af\u6027\u80fd\uff0c\u4e25\u91cd\u5236\u7ea6\u4e86\u9502\u786b\u7535\u6c60\u7684\u5b9e\u9645\u5e94\u7528\u3002\u672c\u8bfe\u9898\u7ec4\u9996\u6b21\u62a5\u9053\u5229\u7528MOF-5\u78b3\u5316\u884d\u751f\u7684\u591a\u5b54\u78b3\u6750\u6599\u4f5c\u4e3a\u786b\u7684\u57fa\u8d28\u6750\u6599(<em>J. Mater. Chem. A<\/em>, <strong>2013<\/strong>, 1, 4490-4496)\uff0c\u901a\u8fc7\u6784\u7b51\u786b-\u591a\u5b54\u78b3\u590d\u5408\u6750\u6599\u5b9e\u73b0\u4f53\u76f8\u5185\u5feb\u901f\u7535\u5b50\u4f20\u8f93, \u6709\u6548\u964d\u4f4e\u4e86\u786b\u6b63\u6781\u7684\u4f4e\u5bfc\u7535\u6027\u7684\u5f71\u54cd, \u63d0\u9ad8\u7535\u6781\u7684\u6d3b\u6027\u7269\u8d28\u7535\u5316\u5b66\u5229\u7528\u7387\uff1b\u540c\u65f6\uff0c\u591a\u5b54\u78b3\u6750\u6599\u7eb3\u7c73\u5b54\u9053\u7684\u5f3a\u6bdb\u7ec6\u7ba1\u4f5c\u7528\u529b\u53ef\u951a\u5b9a\u6d3b\u6027\u7269\u8d28\u786b\u4ee5\u53ca\u4e2d\u95f4\u4ea7\u7269\uff0c\u51cf\u5c11\u6d3b\u6027\u7269\u8d28\u7684\u635f\u5931\u548c\u6291\u5236\u591a\u786b\u5316\u9502\u7684\u6eb6\u89e3\u3002<\/p>\n<p>\u6b64\u5916\uff0c\u672c\u8282\u8fd8\u4ecb\u7ecd\u4e86\u672c\u8bfe\u9898\u7ec4\u5728\u9502\u786b\u7535\u6c60\u4e2d\u7684\u4e8c\u6c27\u5316\u949b\u9694\u5c42(<em>Nano Res.<\/em>,<strong> 2015<\/strong>, 8, 3066)\u3001\u5bfc\u7535\u529f\u80fd\u7c98\u7ed3\u5242(<em>Nano Energy, <\/em><strong>2017<\/strong><em>, <\/em>31, 568-574)\u4ee5\u53ca\u77f3\u58a8\u70ef\u5806\u579b\u6548\u5e94(<em>Chem. Eng. J.<\/em>, <strong>2017<\/strong>, 322, 454-462)\u7684\u7b2c\u4e00\u6027\u539f\u7406\u7814\u7a76\u5de5\u4f5c\uff0c\u603b\u7ed3\u5e76\u7b80\u8981\u5730\u63d0\u51fa\u4e86MOFs\u4e2d\u5fc3\u539f\u5b50\u5bf9\u591a\u786b\u5316\u9502\u548c\u591a\u786b\u5316\u7852\u7684\u5316\u5b66\u5438\u9644\u673a\u5236\uff08\u56fe2\uff09\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-92838 \" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/3-30.jpg\" alt=\"\" width=\"579\" height=\"367\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/3-30.jpg 694w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/3-30-300x190.jpg 300w\" sizes=\"(max-width: 579px) 100vw, 579px\" \/><\/p>\n<p>\u56fe2. MOFs\u4e0eLi<sub>2<\/sub>S<sub>4<\/sub>\uff08\u4e00\u79cd\u591a\u786b\u5316\u9502\uff09\u5316\u5b66\u4f5c\u7528\u6210\u952e\u65b9\u5f0f\u793a\u610f\u56fe\u3002<\/p>\n<p><strong>1-4 <\/strong><strong>\u9502\u7852\u7535\u6c60<\/strong><\/p>\n<p>\u9502\u7852\u7535\u6c60\u56e0\u5176\u5177\u6709\u9ad8\u7684\u4f53\u79ef\u6bd4\u5bb9\u91cf(3253 mAh cm<sup>-3<\/sup>)\u53ca\u8d28\u91cf\u6bd4\u5bb9\u91cf(678 mAh g<sup>-1<\/sup>)\uff0c\u4e5f\u6210\u4e3a\u5177\u6709\u53d1\u5c55\u6f5c\u529b\u7684\u65b0\u578b\u9ad8\u80fd\u7535\u6c60\u4e4b\u4e00\u3002\u56fe3\u6240\u793a\u4e3a\u9502\u7852\u7535\u6c60\u7684\u5de5\u4f5c\u539f\u7406\u793a\u610f\u56fe\u3002\u540c\u9502\u786b\u7535\u6c60\u4e00\u6837\uff0c\u9502\u7852\u7535\u6c60\u540c\u6837\u6709\u7740\u5bff\u547d\u77ed\u3001\u6548\u7387\u4f4e\u7684\u7f3a\u70b9\u3002\u672c\u7ae0\u8282\u4e3b\u8981\u4ecb\u7ecd\u4e86\u7531MOFs\u884d\u751f\u51fa\u7684\u78b3\u6750\u6599\u4ee5\u53ca\u63ba\u6c2e\u78b3\u6750\u6599\u4f5c\u4e3a\u7852\u7684\u57fa\u5e95\u6750\u6599\u7684\u76f8\u5173\u5de5\u4f5c\uff08\u5229\u7528\u78b3\u6750\u6599\u7684\u5bfc\u7535\u6027\u548c\u5b54\u9053\u5bf9\u591a\u7852\u5316\u7269\u7684\u7269\u7406\u5438\u9644\u6765\u6539\u5584\u7535\u6c60\u6027\u80fd\uff09\u3002\u540c\u65f6\u63d0\u51faMOFs\u5728\u9502\u7852\u7535\u6c60\u6b63\u6781\u4e2d\u5177\u6709\u7c7b\u4f3c\u4e8e\u56fe2\u6240\u793a\u7684\u5316\u5b66\u5438\u9644\u4f5c\u7528\u673a\u5236\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-92839 \" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/4-23.jpg\" alt=\"\" width=\"598\" height=\"520\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/4-23.jpg 866w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/4-23-300x261.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/4-23-768x667.jpg 768w\" sizes=\"(max-width: 598px) 100vw, 598px\" \/><\/p>\n<p>\u56fe3. \u9502\u7852\u7535\u6c60\u5145\u653e\u7535\u8fc7\u7a0b\u793a\u610f\u56fe\u3002<\/p>\n<p><strong>\u4e8c\u3001\u8d85\u7ea7\u7535\u5bb9\u5668<\/strong><\/p>\n<p>\u8be5\u90e8\u5206\u63a2\u8ba8\u4e86MOFs\u4ee5\u53ca\u5176\u884d\u751f\u7269\u4f5c\u4e3a\u7535\u6781\u6750\u6599\u5728\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u5e94\u7528\u3002MOFs\u53ca\u6c27\u5316\u7269\u3001\u786b\u5316\u7269\u3001\u78b3\u6750\u6599\u7b49MOF\u884d\u751f\u7269\u90fd\u662f\u5177\u6709\u5e94\u7528\u6f5c\u529b\u7684\u7535\u5bb9\u5668\u7535\u6781\u6750\u6599\u3002<\/p>\n<p><strong>2-1 MOFs<\/strong><\/p>\n<p>\u8d85\u7ea7\u7535\u5bb9\u5668\u4e3b\u8981\u5206\u4e3a\u53cc\u7535\u5c42\u7535\u5bb9\u5668\u548c\u8d5d\u7535\u5bb9\u5668\u3002MOFs\u5177\u6709\u8f83\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\u3001\u72ec\u7279\u7684\u5b54\u9053\u7ed3\u6784\u4ee5\u53ca\u4e30\u5bcc\u7684\u7535\u5316\u5b66\u6d3b\u6027\u4f4d\u70b9\uff0c\u662f\u4e00\u7c7b\u4f18\u5f02\u7684\u8d5d\u7535\u5bb9\u7535\u6781\u6750\u6599\u3002\u4f46\u662f\uff0c\u5927\u90e8\u5206MOFs\u7684\u8f83\u5dee\u7684\u5bfc\u7535\u6027\u4f7f\u5176\u4e0d\u9002\u5408\u7528\u4f5c\u7535\u6781\u6750\u6599\u3002\u7136\u800c\u901a\u8fc7\u7145\u70e7\u5c06\u6709\u673a\u914d\u4f53\u79fb\u9664\u6216\u8f6c\u5316\u6210\u78b3\uff0c\u53ef\u5c06\u4f4e\u6d3b\u6027\u7684MOFs\u8f6c\u53d8\u4e3a\u9ad8\u6d3b\u6027\u7684\u91d1\u5c5e\u5316\u5408\u7269\u6216\u91d1\u5c5e-\u78b3\u590d\u5408\u7269\u3002<\/p>\n<p>\u672c\u7ae0\u8282\u6982\u8ff0\u4e86\u6700\u8fd1MOFs\u7535\u6781\u6750\u6599\u7684\u4fee\u9970\u65b9\u6cd5\u4ee5\u53caMOFs\u4f5c\u4e3a\u8d85\u7ea7\u7535\u5bb9\u5668\u9694\u819c\u7684\u5e94\u7528\u3002<\/p>\n<p><strong>2-2 MOFs<\/strong><strong>\u884d\u751f\u7684\u91d1\u5c5e\u6c27\u5316\u7269<\/strong><strong>\/<\/strong><strong>\u786b\u5316\u7269<\/strong><\/p>\n<p>\u91d1\u5c5e\u6c27\u5316\u7269\/\u786b\u5316\u7269\u56e0\u5176\u9ad8\u7406\u8bba\u6bd4\u7535\u5bb9\u88ab\u4f5c\u4e3a\u8d5d\u7535\u5bb9\u7535\u6781\u6750\u6599\u5e7f\u6cdb\u5e94\u7528\u3002MOFs\u4e2d\u7684\u91d1\u5c5e\u79bb\u5b50\u6216\u56e2\u7c07\u662f\u5f62\u6210\u884d\u751f\u7269\u4e2d\u91d1\u5c5e\u7684\u6765\u6e90\uff1b\u540c\u65f6\uff0cMOFs\u4e2d\u6709\u673a\u914d\u4f53\u53ef\u5728\u7a7a\u6c14\u4e2d\u79fb\u9664\uff0c\u4ece\u800c\u83b7\u5f97\u591a\u5b54\u91d1\u5c5e\u6c27\u5316\u7269\/\u786b\u5316\u7269\uff1b\u6216\u662f\u5728\u60f0\u6027\u6c14\u4f53\u4e2d\u7145\u70e7\u4f7f\u6709\u673a\u914d\u4f53\u5f62\u6210\u78b3\uff0c\u8fdb\u800c\u5f62\u6210\u591a\u5b54\u7684\u91d1\u5c5e\u6c27\u5316\u7269\/\u786b\u5316\u7269-\u78b3\u590d\u5408\u6750\u6599\u3002\u672c\u8282\u6982\u8ff0\u4e86\u901a\u8fc7\u9009\u62e9\u4e0d\u540c\u7684MOFs\u505a\u524d\u9a71\u4f53\u4ee5\u5f97\u5230\u5404\u79cd\u6027\u80fd\u4f18\u5f02\u7684\u91d1\u5c5e\u6c27\u5316\u7269\/\u786b\u5316\u7269\u590d\u5408\u6750\u6599\u7684\u65b9\u6cd5\u4ee5\u53ca\u4ed6\u4eec\u5728\u8d85\u7ea7\u7535\u5bb9\u5668\u4e2d\u7684\u5e94\u7528\u3002<\/p>\n<p><strong>2-3 MOFs<\/strong><strong>\u884d\u751f\u7684\u78b3\u6750\u6599<\/strong><\/p>\n<p>\u78b3\u6750\u6599\u56e0\u5177\u6709\u53ef\u5851\u6027\u5f3a\u3001\u7535\u5bfc\u7387\u9ad8\u3001\u5316\u5b66\u6027\u80fd\u7a33\u5b9a\u3001\u6765\u6e90\u4e30\u5bcc\u3001\u4ef7\u683c\u4f4e\u5ec9\u7b49\u4f18\u70b9\u800c\u88ab\u4f5c\u4e3a\u5e7f\u6cdb\u7814\u7a76\u7684\u8d85\u7ea7\u7535\u5bb9\u5668\u7535\u6781\u6750\u6599\u3002\u78b3\u6750\u6599\u7684\u50a8\u8377\u673a\u7406\u662f\u57fa\u4e8e\u53cc\u7535\u5c42\uff08\u5177\u4f53\u5185\u5bb9\u53ef\u53c2\u89c1\u6750\u6599\u4eba\u7f51\u4e0a\u7684\u4e00\u7bc7\u5b66\u672f\u5e72\u8d27\u6587\u7ae0\uff1a<a href=\"\/\/m.iemloyee.com\/wp-admin\/post.php?post=84150&amp;action=edit\">\/\/m.iemloyee.com\/wp-admin\/post.php?post=84150&amp;action=edit<\/a>\uff09\u3002\u589e\u5927\u6bd4\u8868\u9762\uff0c\u4f18\u5316\u5b54\u7ed3\u6784\uff0c\u6539\u5584\u8868\u9762\u6027\u80fd\uff0c\u63d0\u9ad8\u7535\u5bfc\u7387\u7b49\u90fd\u662f\u63d0\u5347\u8d85\u7ea7\u7535\u5bb9\u5668\u50a8\u80fd\u80fd\u529b\u7684\u6709\u6548\u63aa\u65bd\u3002<\/p>\n<p>\u672c\u90e8\u5206\u4ecb\u7ecd\u4e86\u4f7f\u7528\u4e0d\u540c\u7684MOFs\u4f5c\u4e3a\u524d\u9a71\u4f53\uff0c\u901a\u8fc7\u78b3\u5316\u3001\u79fb\u9664\u91d1\u5c5e\u6210\u5206\uff0c\u5236\u5907\u5404\u79cd\u5177\u6709\u4f18\u826f\u7535\u5316\u5b66\u6027\u80fd\u7684\u78b3\u6750\u6599\u3002\u5982\u56fe4\u6240\u793a\u4fbf\u662f\u4e00\u79cd\u5229\u7528\u4e24\u79cd\u4e0d\u540cMOFs\uff08ZIF-8\u548cZIF-67\uff09\u5236\u5907\u5177\u6709\u6838\u58f3\u7ed3\u6784\u7684\u591a\u5b54\u78b3\u7535\u6781\u7684\u65b9\u6cd5\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-92840 \" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/5-17.jpg\" alt=\"\" width=\"594\" height=\"361\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/5-17.jpg 831w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/5-17-300x182.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/5-17-768x467.jpg 768w\" sizes=\"(max-width: 594px) 100vw, 594px\" \/><\/p>\n<p>\u56fe4. (a) ZIF-8\u548c\u6c2e\u63ba\u6742\u7684\u78b3\u5236\u5907\u793a\u610f\u56fe\u3002(b) ZIF-67\u548c\u77f3\u58a8\u5316\u7684\u78b3\u5236\u5907\u793a\u610f\u56fe\u3002(c) ZIF-8@ ZIF-67\u548c\u6c2e\u63ba\u6742\u7684\u975e\u6676\u578b\u78b3@\u77f3\u58a8\u5316\u78b3\u5236\u5907\u793a\u610f\u56fe\u3002<\/p>\n<p><span style=\"color: #ff0000\"><strong>\u3010\u603b\u7ed3\u4e0e\u5c55\u671b\u3011<\/strong><\/span><\/p>\n<p>MOFs\u53ca\u5176\u884d\u751f\u7269\u5177\u6709\u7ed3\u6784\u53ef\u8c03\u3001\u5b54\u9699\u4e30\u5bcc\u3001\u5b54\u5f84\u53ef\u8c03\u3001\u6bd4\u8868\u9762\u79ef\u9ad8\u4ee5\u53ca\u5b58\u5728\u529f\u80fd\u91d1\u5c5e\u4e2d\u5fc3\u7b49\u7279\u70b9\uff0c\u5728\u7535\u6c60\u548c\u8d85\u7ea7\u7535\u5bb9\u5668\u5df2\u7136\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u6027\u80fd\u3002<\/p>\n<p>\u7136\u800c\u73b0\u9636\u6bb5\u4ecd\u8fd8\u6709\u5f88\u591a\u6311\u6218\u9700\u8981\u89e3\u51b3\uff0c\u5177\u4f53\u800c\u8a00\uff1a<\/p>\n<p>\u7b2c\u4e00\uff0cMOFs\u5728\u6f6e\u6e7f\u7a7a\u6c14\u4e2d\u7684\u7a33\u5b9a\u6027\u9700\u8981\u8fdb\u4e00\u6b65\u63d0\u9ad8\u4ee5\u53ca\u5176\u5728\u9502\/\u94a0\/\u94be\u79bb\u5b50\u7535\u6c60\u7684\u50a8\u80fd\u673a\u5236\u6709\u5f85\u4e8e\u8fdb\u4e00\u6b65\u9610\u660e\uff1b<\/p>\n<p>\u7b2c\u4e8c\uff0cMOFs\u4ee5\u53ca\u5176\u884d\u751f\u7684\u6c27\u5316\u7269\u3001\u786b\u5316\u7269\u7684\u5bfc\u7535\u6027\u9700\u8981\u8fdb\u4e00\u6b65\u63d0\u9ad8\u4ee5\u63d0\u5347\u5668\u4ef6\u6027\u80fd\uff1b<\/p>\n<p>\u7b2c\u4e09\uff0c\u65b0\u5f00\u53d1\u7684MOFs\u91d1\u5c5e\u4e2d\u5fc3\u4e0e\u591a\u786b\u5316\u9502\u6216\u591a\u786b\u5316\u7852\u4e4b\u95f4\u7684\u5316\u5b66\u5438\u9644\u6709\u5f85\u8fdb\u4e00\u6b65\u7cfb\u7edf\u7684\u7406\u8bba\u7814\u7a76\uff0c\u4ece\u800c\u4e3a\u8fdb\u4e00\u6b65\u63d0\u5347\u9502\u786b\/\u9502\u7852\u7535\u6c60\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u63d0\u4f9b\u7535\u6781\u8bbe\u8ba1\u601d\u8def\u3002<\/p>\n<p><span style=\"color: #ff0000\"><strong>\u3010\u6587\u732e\u94fe\u63a5\u3011<\/strong><\/span><\/p>\n<p>Xu et al., <a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S1369702116302929\">Exploring metal organic frameworks for energy storage in batteries and supercapacitors <\/a>(<em>Mater. Today<\/em>, <strong>2017<\/strong>, 20, 191-209)<\/p>\n<p><span style=\"color: #ff0000\"><strong>\u3010\u8bfe\u9898\u7ec4\u7b80\u4ecb\u3011<\/strong><\/span><\/p>\n<p>\u5f20\u6821\u521a\u6559\u6388\u8bfe\u9898\u7ec4\u4f9d\u6258\u4e8e\u5357\u4eac\u822a\u7a7a\u822a\u5929\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u6280\u672f\u5b66\u9662\uff0c\u5728\u529f\u80fd\u6750\u6599\u7684\u8bbe\u8ba1\u5236\u5907\u3001\u7535\u5316\u5b66\u50a8\u8377\u673a\u7406\u7814\u7a76\u3001\u65b0\u578b\u50a8\u80fd\u5668\u4ef6\u7684\u8bbe\u8ba1\u548c\u6784\u5efa\u7b49\u9886\u57df\u53d6\u5f97\u4e86\u4e00\u7cfb\u5217\u7814\u7a76\u6210\u679c\u3002\u8bfe\u9898\u7ec4\u76ee\u524d\u5df2\u5728<em>Nat. Commun., Adv. Mater.<\/em><em>\uff0c<\/em><em>Mater. Today, Nano Lett.<\/em><em>\uff0c<\/em><em>Adv. Funct. Mater.<\/em><em>\uff0c<\/em><em>Adv. Energy Mater., Energy Environ. Sci., Nano Energy, Chem. Mater., Chem. Sci.<\/em>\u7b49\u56fd\u9645\u9ad8\u6c34\u5e73\u6743\u5a01\u6742\u5fd7\u4e0a\u53d1\u8868\u903e\u767e\u7bc7\u5b66\u672f\u8bba\u6587\uff0c\u5e76\u591a\u6b21\u83b7\u5f97\u6559\u80b2\u90e8\u81ea\u7136\u79d1\u5b66\u5956\u3001\u6c5f\u82cf\u7701\u79d1\u5b66\u6280\u672f\u5956\u7b49\u8363\u8a89\u3002<\/p>\n<p>\u8bfe\u9898\u7ec4\u7f51\u7ad9: http:\/\/energy.nuaa.edu.cn\/zhanggroup\/<\/p>\n<p>\u672c\u5bfc\u8bfb\u7531\u8bba\u6587\u7b2c\u4e00\u4f5c\u8005\u5f90\u6842\u94f6\u64b0\u7a3f\uff0c\u6750\u6599\u4eba\u7279\u9080\u7f16\u8f91\u5218\u7530\u5b87\u7f16\u8f91\u5e76\u53d1\u8868\u3002\u672c\u5bfc\u8bfb\u7684\u64b0\u5199\u5f97\u5230\u4e86\u5357\u4eac\u822a\u7a7a\u822a\u5929\u5927\u5b66\u5f20\u6821\u521a\u6559\u6388\u8bfe\u9898\u7ec4\u8042\u5e73\u7684\u5927\u529b\u652f\u6301\uff0c\u5728\u6b64\u8868\u793a\u611f\u8c22\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u4f20\u7edf\u5316\u77f3\u80fd\u6e90\u7684\u6709\u9650\u50a8\u91cf\u6240\u5f15\u53d1\u7684\u80fd\u6e90\u5371\u673a\u7ec8\u5c06\u5236\u7ea6\u4eba\u7c7b\u793e\u4f1a\u7684\u53ef\u6301\u7eed\u53d1\u5c55\u4ee5\u53ca\u5a01\u80c1\u4eba\u7c7b\u7684\u751f\u5b58\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u65b0\u5174\u66ff\u4ee3\u80fd\u6e90\u5df2\u7ecf\u6210\u4e3a\u5f53\u4eca\u4e00\u4e2a\u8feb\u5728\u7709\u776b\u7684\u4efb\u52a1\u3002\u7535\u5316\u5b66\u80fd\u6e90&#8230;<\/p>\n","protected":false},"author":2791,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-92835","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/92835"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2791"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=92835"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/92835\/revisions"}],"predecessor-version":[{"id":92861,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/92835\/revisions\/92861"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=92835"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=92835"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=92835"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}