{"id":92168,"date":"2017-07-20T06:30:36","date_gmt":"2017-07-19T22:30:36","guid":{"rendered":"\/\/m.iemloyee.com\/?p=92168"},"modified":"2017-07-19T18:41:22","modified_gmt":"2017-07-19T10:41:22","slug":"nature-energy%ef%bc%9a%e6%96%b0%e5%9e%8b%e9%ab%98%e7%a8%b3%e5%ae%9a%e6%80%a7pt-pd-au%e7%94%b5%e5%82%ac%e5%8c%96%e5%89%82%e5%a2%9e%e5%bc%baorr%e5%82%ac%e5%8c%96%e6%b4%bb%e6%80%a7","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=92168","title":{"rendered":"Nature Energy\uff1a\u65b0\u578b\u9ad8\u7a33\u5b9a\u6027Pt\u2013Pd\u2013Au\u7535\u50ac\u5316\u5242\u589e\u5f3aORR\u50ac\u5316\u6d3b\u6027"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u5bf9\u4e8e\u6c27\u8fd8\u539f\u53cd\u5e94(ORR)\u800c\u8a00\uff0c\u9ad8\u6d3b\u6027\u4f4ePt\u542b\u91cf\u7684\u7eb3\u7c73\u6838\u58f3\u7ed3\u6784\u50ac\u5316\u5242\u6709\u671b\u4f5c\u4e3a\u9634\u6781\u5728\u71c3\u6599\u7535\u6c60\u4e2d\u5e7f\u6cdb\u5e94\u7528\u3002\u7136\u800c\uff0c\u5728\u8be5\u7c7b\u50ac\u5316\u5242\u8868\u9762\u548c\u754c\u9762\u7ed3\u6784\u4e0a\uff0c\u7ecf\u5e38\u4f1a\u51fa\u73b0\u7ed3\u6784\u9000\u5316\u548c\u8010\u4e45\u6027\u5dee\u7684\u95ee\u9898\uff0c\u6240\u4ee5\u5982\u4f55\u901a\u8fc7\u5408\u7406\u7684\u7ed3\u6784\u8bbe\u8ba1\u548c\u6210\u5206\u8c03\u63a7\u6765\u89e3\u51b3\u8fd9\u4e00\u95ee\u9898\u4f9d\u7136\u662fORR\u7814\u7a76\u7684\u70ed\u70b9\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n

\u5317\u4eac\u65f6\u95f47\u670810\u65e5\uff0c\u5929\u6d25\u7406\u5de5\u5927\u5b66\u4e01\u8f76<\/strong>\u6559\u6388<\/strong>\u3001\u7f57\u4fca\u6559\u6388<\/strong>\u548c\u5317\u4eac\u8ba1\u7b97\u79d1\u5b66\u7814\u7a76\u4e2d\u5fc3<\/strong>\u7684\u5218\u5229\u6c11\u52a9\u7406\u6559\u6388<\/strong> (\u5171\u540c\u901a\u8baf\u4f5c\u8005)\u5728Nature Energy<\/strong>\u4e0a\u5728\u7ebf\u53d1\u8868\u4e86\u4e00\u7bc7\u9898\u4e3a \u201cSurface evolution of a Pt-Pd-Au electrocatalyst for stable oxygen reduction<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u5728\u7eb3\u7c73\u591a\u5b54Au\u4e0a\u5305\u8986\u4e00\u5c42\u4e9a\u7eb3\u7c73\u7ea7Pt-Pd\u58f3\u5c42\uff0c\u5236\u5907\u4e86\u4e00\u79cd\u65b0\u578b\u7eb3\u7c73\u591a\u5b54\u7535\u50ac\u5316\u5242\uff0c\u8be5\u50ac\u5316\u5242\u57280.9V\u4e0b\u7684ORR\u521d\u59cb\u8d28\u91cf\u6d3b\u6027\u53ef\u8fbe1.140 A \uff0c\u662f\u76ee\u524d\u5546\u7528Pt\/C\u50ac\u5316\u5242\u76844~12\u500d\u3002\u7ecf\u8fc730,000\u4e2a\u5faa\u73af\u540e\uff0cNPG-Pd-Pt\u7684\u8868\u9762\u7ed3\u6784\u8fbe\u5230\u7a33\u5b9a\uff0cORR Pt\u8d28\u91cf\u6d3b\u6027\u589e\u52a0\u5230\u4e861.471 A \uff0c\u4e4b\u540e\u5373\u4f7f\u572870,000\u4e2a\u5faa\u73af\u5468\u671f\u4ee5\u4e0a\u4e5f\u57fa\u672c\u4e0d\u53d8\u3002\u5229\u7528\u50cf\u5dee\u6821\u6b63\u626b\u63cf\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\uff08STEM\uff09\u548c\u539f\u5b50\u7ea7\u5206\u8fa8\u80fd\u8c31\uff08AR-EDS\uff09\u7b49\u5206\u6790\u624b\u6bb5\uff0c\u7814\u7a76\u4eba\u5458\u5f97\u51fa\u4e86\u8d77\u59cb\u6d3b\u6027\u7684\u53d8\u5316\u662f\u58f3\u5c42\u6392\u5e03\u8f6c\u53d8\u7684\u7ed3\u679c\uff0c\u5373\u58f3\u5c42\u4ece\u6700\u521d\u7684Pt-Pd\u53cc\u91d1\u5c5e\u5c42\u8f6c\u53d8\u4e3a\u53cc\u5c42\u7ed3\u6784\uff0c\u5176\u4e2d\u8868\u5c42\u4e3a\u5bcc\u542b\u94c2\u7684\u4e09\u91d1\u5c5e\u76f8\uff0c\u6700\u540e\u9010\u6e10\u8f6c\u53d8\u4e3a\u5747\u4e00\u6d3b\u6027\u800c\u53c8\u7a33\u5b9a\u7684Pt-Pd-Au\u5408\u91d1\u8868\u9762\u3002\u901a\u8fc7\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u5f97\u77e5\uff0c\u5728ORR\u4e2d\uff0c\u8be5\u5408\u91d1\u80fd\u591f\u964d\u4f4e\u5438\u9644OH\u4e2d\u95f4\u7269\u6700\u7ec8\u5f62\u6210\u6c34\u81ea\u7531\u80fd\u53d8\u5316\u3002\u4e0e\u65b0\u5236\u7684Pt\/C\u76f8\u6bd4\uff0c\u6b64\u7c7bPt-Pd-Au ORR\u7535\u50ac\u5316\u5242\u7684\u8d28\u91cf\u6d3b\u6027\u662f\u517615\u500d\u4e4b\u9ad8\uff0c\u7ecf\u8fc7\u540e\u7eed\u5faa\u73af\u8bc1\u660e\u8be5\u50ac\u5316\u5242\u7a33\u5b9a\u6027\u975e\u5e38\u51fa\u4f17\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb<\/strong>\u3011<\/p>\n

\u56fe<\/strong>1\u00a0 NPG-Pd-Pt<\/strong>\u7535\u50ac\u5316\u5242<\/strong>\u7684\u8868\u9762\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a. \u7535\u50ac\u5316\u5242\u7684\u4f4e\u500d\u9ad8\u89d2\u5ea6\u73af\u5f62\u6697\u573a (HAADF)\u50cf\uff1b<\/p>\n

b. \u7535\u50ac\u5316\u5242\u8868\u9762\u533a\u57df\u9ad8\u5206\u8fa8\u7387HAADF\u50cf\uff0c\u5176\u4e2d\u767d\u8272\u7684\u865a\u7ebf\u8868\u793a\u7684\u662f\u6838\u548c\u58f3\u4e4b\u95f4\u5927\u81f4\u7684\u754c\u9762\u533a\u57df\uff1b<\/p>\n

c. \u7535\u50ac\u5316\u5242\u8868\u9762\u533a\u57df\u7684\u9ad8\u5206\u8fa8\u7387HAADF\u50cf\uff1b<\/p>\n

d-f. \u56fec\u7684EDS\u8868\u5f81\u7ed3\u679c\uff1aAu\uff0cPd\u548cPt\u7684\u5143\u7d20\u5206\u5e03\u56fe\uff1b<\/p>\n

g. \u56fed-f\u7684\u6574\u5408\u8986\u76d6\u56fe\u50cf\u3002<\/p>\n

\u56fe<\/strong>2 NPG-Pd-Pt<\/strong>\u7535\u50ac\u5316\u5242\u8868\u9762\u7684<\/strong>AR-EDS<\/strong>\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a. NPG-Pd-Pt\u8868\u9762\u533a\u57df\u7684\u9ad8\u5206\u8fa8HAADF\u56fe\u50cf\uff1b<\/p>\n

b-d. \u56fea\u6240\u5bf9\u5e94\u7684AR-EDS\u8868\u5f81\u7ed3\u679c\uff0c\u5373Au\uff0cPd\u548cPt\u7684\u5143\u7d20\u5206\u5e03\u56fe\u3002\u5176\u5927\u5c0f\u4e0ea\u56fe\u7684\u4e00\u6837\uff0ca-d\u56fe\u4e2d\u7684\u6570\u636e\u662f\u6807\u51c6\u5dee\u8303\u56f4\u5185\u7684\u6676\u9762\u95f4\u8ddd\uff1b<\/p>\n

e-i. \u5206\u522b\u4e3aa-d\u7684\u5feb\u901f\u5085\u91cc\u53f6\u53d8\u6362(FFT)\u6a21\u578b\u3002i\u56fe\u662fb-d\u56fe\u7684\u8986\u76d6\u56fe\uff0c\u5176\u8868\u9762\u672b\u7aef\u4e0eAu\u7684(111)\u6676\u9762\u4e00\u6837\u3002a-d\u56fe\u7ecf\u8fc7\u4e86\u7ef4\u7eb3\u6ee4\u6ce2\u5668\u7684\u6ee4\u6ce2(\u8be6\u89c1\u56fe3)\uff1b\u5728HAADF\u56fe\u50cf\u4e2d\uff0c\u7ef4\u7eb3\u6ee4\u6ce2\u5668\u88ab\u5e7f\u6cdb\u7528\u4e8e\u53bb\u9664\u566a\u97f3\u3002\u901a\u8fc7g\u548ch\u56feFFT\u6a21\u578b\u7684\u5bf9\u6bd4\uff0c\u5176\u5dee\u522b\u66f4\u5bb9\u6613\u88ab\u89c2\u5bdf\u5230(\u8be6\u89c1\u56fe3)\u3002<\/p>\n

\u56fe<\/strong>3\u00a0<\/strong>\u7535\u50ac\u5316\u5242\u7684\u7535\u5316\u5b66\u6027\u80fd\u7684\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a. NPG-Pd-Pt\uff0cNPG-Pd\u548c\u5546\u7528Pt\/C\u7684CV\u66f2\u7ebf\u3002\u6d4b\u8bd5\u6761\u4ef6\uff1a25\u2103Ar\u9971\u548c\u76840.1 M HClO4<\/sub>\uff0c\u626b\u63cf\u901f\u7387\u4e3a50 mV\/s\u3002\u2217OH\uff0cj\u548cE\u8868\u660e\u7f9f\u57fa\u5206\u522b\u5438\u9644\u5728\u6676\u4f53\u8868\u9762\u4e0a\u65f6\u7684\u7535\u6d41\u6d53\u5ea6\u548c\u7535\u52bf\uff1b<\/p>\n

b. NPG-Pd-Pt\uff0cNPG-Pd\u548c\u5546\u7528Pt\/C\u7684\u6b63\u5411ORR\u6781\u5316\u66f2\u7ebf\u3002\u20180.846V\u2019\u548c\u20180.892V\u2019\u5206\u522b\u662fPt\/C\u548cNPG-Pd\u66f2\u7ebf\u7684\u534a\u6ce2\u7535\u4f4d\u503c\uff0c\u4e24\u8005\u5dee\u503c\u4e3a\u201846mV\u2019\uff1b<\/p>\n

c-d. NPG-Pd-Pt \u6837\u54c1\u7684CV\u66f2\u7ebf(c)\u548c\u6b63\u5411ORR\u6781\u5316\u66f2\u7ebf(d)\u3002d\u4e2d\u63d2\u56fe\u662f\u865a\u7ebf\u6846\u5185\u66f2\u7ebf\u6bb5\u7684\u653e\u5927\u56fe\u3002b\u56fe\u4e2d\u7684\u7bad\u5934\u548cd\u56fe\u4e2d\u7684\u63d2\u56fe\u8868\u793a\u5bf9\u5e94\u66f2\u7ebf\u4e2d\u534a\u6ce2\u7535\u4f4d\u7684\u4f4d\u7f6e\uff1b<\/p>\n

e-f. \u5728\u7a33\u5b9a\u6027\u6d4b\u8bd5\u7684\u4e0d\u540c\u9636\u6bb5\u4e2d\uff0c0.9Vvs. RHE\u6761\u4ef6\u4e0b\uff0cNPG-Pd-Pt\u548cPt\/C\u7684ORR\u6bd4\u6d3b\u6027\u548c\u8d28\u91cf\u6d3b\u6027\u6761\u5f62\u56fe\uff0c\u548c\u5206\u522b\u8868\u793aORR\u6bd4\u6d3b\u6027\u548c\u8d28\u91cf\u6d3b\u6027\u7535\u6d41\u5bc6\u5ea6\u3002<\/p>\n

\u56fe<\/strong>4 NPG-Pd-Pt10\uff0c000<\/sub>\u548cNPG-Pd-Pt30\uff0c000<\/sub><\/strong>\u7535\u50ac\u5316\u5242\u8868\u9762\u7684\u5143\u7d20\u5206\u5e03\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

a,f. NPG-Pd-Pt10\uff0c000<\/sub>\u548cNPG-Pd-Pt30\uff0c000<\/sub>\u8868\u9762\u533a\u57df\u7684\u9ad8\u5206\u8fa8\u7387HAADF\u50cf\uff1b<\/p>\n

b-d. \u56fea\u5bf9\u5e94\u7684AR-EDS\u8868\u5f81\u7ed3\u679c\uff1aAu\uff0cPd\u548cPt\u7684\u5143\u7d20\u5206\u5e03\u56fe\uff1b<\/p>\n

e. b-d\u7684\u8986\u76d6\u56fe\uff0c\u5176\u8868\u9762\u672b\u7aef\u4e0eAu\u7684(100)\u6676\u9762\u662f\u76f8\u540c\u7684;<\/p>\n

g-i. \u56fef\u5bf9\u5e94\u7684AR-EDS\u8868\u5f81\u7ed3\u679c\uff1aAu\uff0cPd\u548cPt\u7684\u5143\u7d20\u5206\u5e03\u56fe\uff1b<\/p>\n

a-d\u548cf-i\u662f\u6807\u51c6\u5dee\u8303\u56f4\u5185\u7684\u6676\u9762\u95f4\u8ddd\u503c\u3002<\/p>\n

\u56fe<\/strong>5 Pt-Pd-Au<\/strong>\u548c<\/strong>Pt<\/strong>\u7684<\/strong>(111)<\/strong>\u8868\u9762\u6709\u5438\u9644\u6027\u80fd\u7684\u7ed3\u6784\u4ee5\u53ca<\/strong>ORR<\/strong>\u4e0d\u540c\u53cd\u5e94\u9636\u6bb5\u7684\u81ea\u7531\u80fd\u5256\u9762\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

a-b. \u5728Pt-Pd-Au(a\u56fe)\u548cPt(b\u56fe)\u6a21\u578b\u4e0a\uff0c\u4e2d\u95f4\u7269\u79cd\u5438\u9644\u6784\u578b\u7684\u9876\u89c6\u56fe(\u4ece\u5de6\u5f80\u53f3\u4f9d\u6b21\u4e3a\uff1a\u2217OOH\uff0c\u2217O \u548c \u2217OH)\u3002\u84dd\uff0c\u7c89\uff0c\u9ec4\uff0c\u7ea2\uff0c\u767d\u7403\u5206\u522b\u4ee3\u8868Pt\uff0cPd\uff0cAu\uff0cO\u548cH\u5143\u7d20\u3002\u5728a\u56fe\u548cb\u56fe\u4e2d\u865a\u7ebf\u533a\u57df\u662f\u7528\u4e8e\u8ba1\u7b97\u7684\u8d85\u6676\u80de\uff1b<\/p>\n

c\uff0e Pt(\u9ed1\u7ebf)\u548cPt-Pd-Au(\u7ea2\u7ebf)\u8868\u793a ORR\u4e0d\u540c\u53cd\u5e94\u9636\u6bb5\u7684\u81ea\u7531\u80fd\u5256\u9762\u56fe\uff0c\u5b9e\u7ebf\u548c\u865a\u7ebf\u5206\u522b\u5bf9\u5e94\u4e8eU=0V\u548cU=0.9V\u3002\u5728ORR\u53cd\u5e94\u4e2d\uff0cU\u662f\u5916\u52a0\u7535\u4f4d\uff0c0.9Vvs. RHE\u662f\u5b9e\u9a8c\u4e2d\u7528\u7684\u7535\u4f4d(\u56fe3e\uff0cf)\u3002<\/p>\n

\u3010\u5c0f\u7ed3<\/strong>\u3011<\/p>\n

\u5728\u6b64\u9879\u7814\u7a76\u5de5\u4f5c\u4e2d\uff0c\u8d77\u521d\u8bbe\u8ba1\u7684Pt-on-Pd\u53cc\u5c42\u8868\u9762\u7ed3\u6784\u4e3b\u8981\u662f\u53cc\u91d1\u5c5ePt-Pd\u5408\u91d1\u76f8\uff0c\u901a\u8fc7\u7535\u4f4d\u5faa\u73af\u8868\u9762\u7ed3\u6784\u8f6c\u53d8\u6210\u4e86\u66f4\u7a33\u5b9a\u7684Pt-Pd-Au\u5408\u91d1\u76f8\uff0c\u4ece\u800c\u63d0\u9ad8\u4e86ORR\u7684Pt\u8d28\u91cf\u6d3b\u6027\uff0c\u6bd4\u5546\u7528Pt\/C\u589e\u52a0\u4e86\u6570\u500d\uff0c\u4e14\u7535\u4f4d\u626b\u63cf70,000\u5468\u671f\u80fd\u4fdd\u6301\u51e0\u8fd1\u5b8c\u7f8e\u7684\u6d3b\u6027\uff0c\u7a33\u5b9a\u6027\u80fd\u4f18\u5f02\u3002\u5728\u672c\u6587\u4e2d\uff0c\u7ed3\u5408\u7b2c\u4e00\u6027\u539f\u7406\u6a21\u62df\u7ed3\u679c\uff0c\u7814\u7a76\u4eba\u5458\u5f97\u51fa\u4ee5\u4e0b\u7ed3\u8bba\uff0c\u6700\u7ec8\u5f97\u5230\u7684Pt-Pd-Au\u7684\u8868\u9762\u539f\u5b50\u7ec4\u6210\u964d\u4f4e\u4e86\u5728\u50ac\u5316\u5242\u8868\u9762\u4e0a\u5438\u9644*OH\u81ea\u7531\u57fa\u8f6c\u53d8\u4e3a\u6c34\u7684\u81ea\u7531\u80fd\u53d8\u5316\uff0c\u4ece\u800c\u63d0\u9ad8\u4e86\u8be5\u7c7b\u50ac\u5316\u5242\u7684ORR\u50ac\u5316\u6d3b\u6027\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5<\/strong>\uff1aSurface evolution of a Pt\u2013Pd\u2013Au electrocatalyst for stable oxygen reduction<\/a>\uff08Nat.Energy\uff0c2017\uff0cDOI\uff1a10.1038\/nenergy.2017.111\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5218\u9526\u9526\u7f16\u8bd1\uff0c\u8d75\u98de\u9f99\u5ba1\u6838\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>.<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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