{"id":91165,"date":"2017-07-15T14:00:16","date_gmt":"2017-07-15T06:00:16","guid":{"rendered":"\/\/m.iemloyee.com\/?p=91165"},"modified":"2017-07-15T17:34:49","modified_gmt":"2017-07-15T09:34:49","slug":"%e4%b8%8a%e6%b5%b7%e6%9c%89%e6%9c%ba%e6%89%80%ef%bc%9a%e5%85%ad%e4%bb%b7%e7%a1%ab%e6%b0%9f%e4%ba%a4%e6%8d%a2%e5%8f%8d%e5%ba%94%e7%a0%94%e7%a9%b6%e4%b8%ad%e5%8f%96%e5%be%97%e8%bf%9b%e5%b1%95","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=91165","title":{"rendered":"\u4e0a\u6d77\u6709\u673a\u6240\uff1a\u516d\u4ef7\u786b\u6c1f\u4ea4\u6362\u53cd\u5e94\u7814\u7a76\u4e2d\u53d6\u5f97\u8fdb\u5c55"},"content":{"rendered":"<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u6700\u8fd1\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u4e0a\u6d77\u6709\u673a\u5316\u5b66\u7814\u7a76\u6240\u6709\u673a\u6c1f\u5316\u5b66\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u7814\u7a76\u5458\u8463\u4f73\u5bb6\u4e0eScripps\u7814\u7a76\u6240\u6559\u6388Sharpless\u548c\u535a\u58eb\u5434\u9e4f\u5408\u4f5c\uff0c\u5728\u516d\u4ef7\u786b\u6c1f\u4ea4\u6362\u53cd\u5e94\u7814\u7a76\u65b9\u9762\u53d6\u5f97\u4e86\u65b0\u7684\u7a81\u7834\uff1a\u4ed6\u4eec\u53d1\u73b0\u4e86\u4e00\u7c7b\u9634\u79bb\u5b50\u6c1f\u76d0[HF2-]\uff08Bifluoride anion\uff09\uff0c\u53ef\u4ee5\u4f5c\u4e3a\u66f4\u52a0\u9ad8\u6548\u7684\u50ac\u5316\u5242\u4fc3\u8fdbSuFEx\u53cd\u5e94\uff0c\u5408\u6210\u805a\u786b\u9178\u916f\u6216\u805a\u78fa\u9178\u916f\u7c7b\u9ad8\u5206\u5b50\u6750\u6599\u3002\u8be5\u6210\u679c\u6700\u8fd1\u4ee5Bifluoride-catalysed sulfur(VI) fluoride exchange reaction for the synthesis of polysulfates and polysulfonates\u4e3a\u9898\u53d1\u8868\u4e8eNat.Chem.\u4e0a\u3002\u8be5\u7814\u7a76\u5de5\u4f5c\u5f97\u5230\u4e0a\u6d77\u6709\u673a\u6240\u767e\u4eba\u8ba1\u5212\u3001\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u59d4\u3001\u4e2d\u79d1\u9662\u6218\u7565\u6027\u5148\u5bfc\u79d1\u6280\u4e13\u9879\uff08B\u7c7b\uff09\u3001\u4e2d\u79d1\u9662\u6709\u673a\u6c1f\u5316\u5b66\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u4ee5\u53ca\u4e0a\u6d77\u5e02\u79d1\u59d4\u7684\u652f\u6301\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>1<\/strong><strong>\u516d\u4ef7\u786b\u6c1f\u4ea4\u6362\u53cd\u5e94\uff08<\/strong><strong>SuFEx<\/strong><strong>\uff09<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-91167 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/1-29.jpg\" alt=\"\" width=\"600\" height=\"184\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/1-29.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/1-29-300x92.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2<\/strong><strong>\u901a\u8fc7<\/strong><strong>Bifluoride <\/strong><strong>\u50ac\u5316\u7684<\/strong><strong>SuFEx<\/strong><strong>\u53cd\u5e94\u5408\u6210\u7684\u805a\u786b\u9178\u916f\u3001\u805a\u78fa\u9178\u916f<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-91181 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/3-7.png\" alt=\"\" width=\"600\" height=\"256\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/3-7.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/3-7-300x128.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u3010\u7814\u7a76\u5185\u5bb9\u3011<\/strong><\/p>\n<p>\u9ad8\u4ef7\u4e3b\u65cf\u6c1f\u5316\u7269\u5177\u6709\u5f88\u9ad8\u7684\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u4f46\u5176\u5728\u7279\u5b9a\u6761\u4ef6\u4e0b\u7684\u6d3b\u5316\u53c8\u80fd\u5b9e\u73b0\u6781\u5176\u9ad8\u6548\u7684\u5316\u5b66\u952e\u8f6c\u5316\u548c\u94fe\u63a5\uff0c\u8fd9\u79cd\u7279\u6b8a\u7684\u7a33\u5b9a\u6027\u4e0e\u53cd\u5e94\u6027\u7684\u7ed3\u5408\uff0c\u51b3\u5b9a\u4e86\u8be5\u7c7b\u5316\u5408\u7269\u5728\u6709\u673a\u5408\u6210\u5316\u5b66\u3001\u6750\u6599\u5316\u5b66\u3001\u5316\u5b66\u751f\u7269\u5b66\u548c\u836f\u7269\u5316\u5b66\u4e2d\u5c06\u6709\u7740\u72ec\u7279\u7684\u6f5c\u5728\u5e94\u7528\u3002\u516d\u4ef7\u786b\u6c1f\u4ea4\u6362\u53cd\u5e94Sulfur(VI)Fluoride Exchange(SuFEx)\u7684\u6210\u529f\u6b63\u662f\u5229\u7528\u4e86\u516d\u4ef7\u786b\u6c1f\u952e\u7684\u8fd9\u79cd\u7279\u6b8a\u53cd\u5e94\u6d3b\u6027\u3002\u81ea\u4ece2014\u5e74\uff0cSharpless\u6559\u6388(Angew. Chem. Int. Ed. 2014, 9430) \u9996\u6b21\u63d0\u51fa\u5e76\u6210\u529f\u5b9e\u73b0\u516d\u4ef7\u786b\u6c1f\u4ea4\u6362\u53cd\u5e94\u4ee5\u6765\uff0c\u8be5\u7c7b\u53cd\u5e94\u5df2\u5728\u6709\u673a\u5408\u6210\u5316\u5b66\u3001\u6750\u6599\u5316\u5b66\u3001\u836f\u7269\u5316\u5b66\u3001\u5316\u5b66\u751f\u7269\u5b66\u7279\u522b\u662f\u86cb\u767d\u8d28\u5206\u5b50\u9009\u62e9\u6027\u6807\u8bb0\u548c\u4fee\u9970\u7b49\u65b9\u9762\u53d7\u5230\u5e7f\u6cdb\u5173\u6ce8\u5e76\u5c55\u793a\u4e86\u5f88\u597d\u7684\u5e94\u7528\u524d\u666f\uff0c\u88ab\u79f0\u4e3a\u65b0\u4e00\u4ee3\u70b9\u51fb\u5316\u5b66\uff0c\u6210\u4e3a\u5f53\u524d\u6c1f\u5316\u5b66\u7814\u7a76\u7684\u65b0\u70ed\u70b9\u3002<\/p>\n<p>\u4e0e\u805a\u78b3\u9178\u916f\u548c\u805a\u916f\u7c7b\u6750\u6599\u76f8\u6bd4\uff0c\u76f8\u5e94\u7684\u805a\u786b\u9178\u916f\u548c\u805a\u78fa\u9178\u916f\u7c7b\u6750\u6599\u5177\u6709\u66f4\u9ad8\u7684\u5316\u5b66\u7a33\u5b9a\u6027\uff08Sulfate Vs Carbonate\uff0cSulfonate Vs Ester\uff09\u548c\u4f18\u5f02\u7684\u529b\u5b66\u6027\u80fd\uff0c\u5176\u7279\u6b8a\u7684\u97e7\u6027\u548c\u6297\u51b2\u51fb\u6027\u4f7f\u5f97\u8fd9\u7c7b\u65b0\u578b\u70ed\u5851\u6027\u6750\u6599\u5f88\u6709\u53ef\u80fd\u5728\u6c7d\u8f66\u5236\u9020\u3001\u822a\u7a7a\u822a\u5929\u3001\u7535\u5b50\u8bbe\u5907\u3001\u5efa\u7b51\u548c\u5305\u88c5\u6750\u6599\u7b49\u9886\u57df\u53d6\u5f97\u5e94\u7528\u3002\u4f46\u662f\uff0c\u7531\u4e8e\u4f20\u7edf\u5408\u6210\u65b9\u6cd5\u548c\u5de5\u827a\u7684\u9650\u5236\uff0c\u65e0\u6cd5\u5927\u91cf\u83b7\u5f97\u6b64\u7c7b\u805a\u5408\u7269\uff0c\u56e0\u6b64\uff0c\u5230\u76ee\u524d\u4e3a\u6b62\uff0c\u805a\u786b\u9178\u916f\u548c\u805a\u78fa\u9178\u916f\u7c7b\u6750\u6599\u4ecd\u7136\u672a\u80fd\u5b9e\u73b0\u89c4\u6a21\u5316\u751f\u4ea7\u548c\u5546\u4e1a\u5e94\u7528\u3002<\/p>\n<p>\u5b9e\u9a8c\u53d1\u73b0\uff0c\u65b0\u7684\u9634\u79bb\u5b50\u76d0\u50ac\u5316\u5242\u76f8\u6bd4\u65e9\u671f\u53d1\u73b0\u7684\u8d85\u5f3a\u78b1\u7c7b\u50ac\u5316\u5242\u6d3b\u6027\u6709\u6570\u91cf\u7ea7\u63d0\u5347\uff0c\u4f7f\u7528\u4e07\u5206\u4e4b\u4e94\u7684\u50ac\u5316\u5242\u5373\u53ef\u5b9e\u73b0\u9ad8\u6548\u50ac\u5316SuFEx\u53cd\u5e94\uff0c\u800c\u4e14\u53cd\u5e94\u4f53\u7cfb\u6761\u4ef6\u6e29\u548c\uff0c\u5e95\u7269\u9002\u5e94\u5e7f\uff0c\u80fd\u591f\u65b9\u4fbf\u5730\u5b9e\u73b0\u7cfb\u5217\u82b3\u57fa\u805a\u786b\u9178\u916f\u548c\u805a\u78fa\u9178\u916f\u7c7b\u805a\u5408\u7269\u7684\u5408\u6210\uff0c\u4ea7\u7269\u5177\u6709\u7406\u60f3\u7684\u805a\u5408\u5ea6\u4ee5\u53ca\u4f18\u79c0\u7684\u5206\u5b50\u91cf\u5206\u5e03\u3002\u8fd9\u4e00\u65b0\u50ac\u5316\u4f53\u7cfb\u7684\u53d1\u73b0\u4e3a\u901a\u8fc7SuFEx\u53cd\u5e94\u5b9e\u73b0\u82b3\u57fa\u805a\u786b\u9178\u916f\u3001\u805a\u78fa\u9178\u916f\u7c7b\u9ad8\u5206\u5b50\u6750\u6599\u7684\u5de5\u4e1a\u653e\u5927\u4e43\u81f3\u672a\u6765\u7684\u5e94\u7528\u5960\u5b9a\u4e86\u57fa\u7840\u3002\u8be5\u5de5\u4f5c\u53d1\u8868\u540e\uff0c\u7b2c\u4e00\u65f6\u95f4\u88abChemical &amp; Engineering News \uff08C&amp;EN\uff0c2017\uff0cJune 26\uff09\u5173\u6ce8\uff0c\u5e76\u5728News of the Week\u680f\u76ee\u4e2d\u8bc4\u8bba\uff0c\u8ba4\u4e3a\u8be5\u65b9\u6cd5\u62d3\u5c55\u4e86SuFEx\u5e95\u7269\u7684\u9002\u7528\u8303\u56f4\uff0c\u8ba9\u6750\u6599\u5316\u5b66\u5bb6\u80fd\u591f\u66f4\u52a0\u65b9\u4fbf\u5730\u5f97\u5230\u8be5\u7c7b\u578b\u7684\u805a\u5408\u7269\uff0c\u5bf9\u8fd9\u4e9b\u65b0\u805a\u5408\u7269\u6027\u80fd\u7684\u63a2\u7d22\u4e5f\u53ef\u4ee5\u66f4\u52a0\u5145\u5206\u5730\u5f00\u5c55\u3002\u8be5\u5de5\u4f5c\u7531Scripps\u7814\u7a76\u6240\u4e0e\u4e2d\u79d1\u9662\u4e0a\u6d77\u6709\u673a\u6240\u5408\u4f5c\u5b8c\u6210\uff0c\u4e5f\u662fSharpless\u4f5c\u4e3a\u7279\u8058\u6559\u6388\u52a0\u5165\u4e2d\u79d1\u9662\u6709\u673a\u6c1f\u5316\u5b66\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u540e\u5408\u4f5c\u53d1\u8868\u7684\u7b2c\u4e00\u7bc7\u8bba\u6587\u3002\u8463\u4f73\u5bb6\u662f\u8be5\u5de5\u4f5c\u7684\u5171\u540c\u901a\u8baf\u4f5c\u8005\u3002<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1a<a href=\"http:\/\/www.cas.cn\/syky\/201707\/t20170710_4608050.shtml\" target=\"_blank\" rel=\"noopener noreferrer\">http:\/\/www.cas.cn\/syky\/201707\/t20170710_4608050.shtml<\/a>\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/www.nature.com\/nchem\/journal\/vaop\/ncurrent\/full\/nchem.2796.html\" target=\"_blank\" rel=\"noopener noreferrer\">Bifluoride-catalysed sulfur(VI) fluoride exchange reaction for the synthesis of polysulfates and polysulfonates<\/a>\uff08Nat.Chem.\uff0c2017\uff0cDOI\uff1a10.1038\/nchem.2796\uff09<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u738b\u51b0\u7f16\u8f91\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" rel=\"noopener noreferrer\">\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener noreferrer\">\u6d4b\u8bd5\u8c37<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u6210\u679c\u7b80\u4ecb\u3011 \u6700\u8fd1\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u4e0a\u6d77\u6709\u673a\u5316\u5b66\u7814\u7a76\u6240\u6709\u673a\u6c1f\u5316\u5b66\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u7814\u7a76\u5458\u8463\u4f73\u5bb6\u4e0eScripps\u7814\u7a76\u6240\u6559\u6388Sharpless\u548c\u535a\u58eb\u5434\u9e4f\u5408\u4f5c\uff0c\u5728\u516d\u4ef7\u786b\u6c1f\u4ea4\u6362\u53cd\u5e94\u7814&#8230;<\/p>\n","protected":false},"author":53,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[116],"class_list":["post-91165","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-catalyst"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/91165"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/53"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=91165"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/91165\/revisions"}],"predecessor-version":[{"id":91183,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/91165\/revisions\/91183"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=91165"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=91165"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=91165"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}