{"id":9113,"date":"2016-04-24T17:00:43","date_gmt":"2016-04-24T09:00:43","guid":{"rendered":"\/\/m.iemloyee.com\/?p=9113"},"modified":"2016-04-24T22:42:38","modified_gmt":"2016-04-24T14:42:38","slug":"%e5%90%88%e6%88%90%e6%89%8b%e6%80%a7%e5%88%86%e5%ad%90%e7%9a%84%e6%a0%b9%e6%9c%ac%e9%80%94%e5%be%84","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=9113","title":{"rendered":"\u5408\u6210\u624b\u6027\u5206\u5b50\u7684\u6839\u672c\u9014\u5f84"},"content":{"rendered":"

Paolo Melchiorre\u6559\u6388\u6240\u5e26\u9886\u7684\u7814\u7a76\u56e2\u961f\uff0c\u5728\u897f\u73ed\u7259\u52a0\u6cf0\u7f57\u5c3c\u4e9a\u5316\u5b66\u7814\u7a76\u6240\uff08ICIQ\uff09\u63a2\u7a76\u51fa\u4e00\u79cd\u9009\u62e9\u6027\u5408\u6210\u624b\u6027\u5206\u5b50\u7684\u65b0\u65b9\u6cd5\u3002\u8be5\u65b0\u65b9\u6cd5\u662f\u5c06\u5bf9\u6620\u9009\u62e9\u6027\u4e9a\u80fa\u79bb\u5b50\u5316\u5b66\u8fc7\u7a0b\u4e0e\u5149\u81f4\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u5242\u7ed3\u5408\u5728\u4e00\u8d77\uff0c\u5728\u975e\u5e38\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\u53d1\u751f\u53cd\u5e94\uff0c\u5f97\u5230\u5177\u6709\u6781\u9ad8\u5bf9\u6620\u9009\u62e9\u6027\u7684\u56db\u5143\u78b3\u7acb\u6784\u4e2d\u5fc3\u3002\u8fd9\u4e00\u7814\u7a76\u7ed3\u679c\u88ab\u520a\u767b\u5728Nature\u6742\u5fd7\u4e0a\u3002<\/p>\n

\u624b\u6027\u5206\u5b50\u6307\u7684\u662f\uff0c\u4e00\u4e2a\u78b3\u539f\u5b50\u901a\u8fc7\u56db\u6839\u5171\u4ef7\u952e\u4e0e\u56db\u4e2a\u53d6\u4ee3\u57fa\u76f8\u8fde\uff0c\u5f53\u8fd9\u56db\u4e2a\u53d6\u4ee3\u57fa\u90fd\u4ee5\u78b3\u4e3a\u4e2d\u5fc3\u65f6\u88ab\u79f0\u4f5c\u56db\u5143\u7acb\u6784\u4e2d\u5fc3\u3002\u5982\u679c\u4e00\u4e2a\u5206\u5b50\u662f\u624b\u6027\u7684\uff0c\u90a3\u4e48\u8fd9\u4e2a\u5206\u5b50\u5c31\u5b58\u5728\u4e24\u79cd\u53ef\u80fd\u7684\u5bfe\u6620\u6784\u578b\uff08\u8fd9\u4e24\u79cd\u6784\u578b\u7a0b\u955c\u9762\u5bf9\u79f0\uff0c\u6c38\u8fdc\u4e0d\u53ef\u80fd\u91cd\u53e0\uff09\u3002\u624b\u6027\u5206\u5b50\u6709\u591a\u79cd\u5e94\u7528\uff0c\u5c24\u5176\u662f\u5728\u751f\u7269\u5316\u5b66\u9886\u57df\uff0c\u56e0\u4e3a\u624b\u6027\u5206\u5b50\u5bf9\u4e8e\u751f\u547d\u7684\u8d77\u6e90\u975e\u5e38\u91cd\u8981\u3002<\/p>\n

Melchiorre\u6559\u6388\u7684\u56e2\u961f\u5728\u624b\u6027\u5206\u5b50\u7684\u5408\u6210\u4e0a\u53d6\u5f97\u7a81\u7834\u6027\u8fdb\u5c55\uff0c\u4ed6\u4eec\u628a\u7531\u53ef\u89c1\u5149\u6fc0\u53d1\u7684\u50ac\u5316\u5242\u4e0e\u624b\u6027\u6709\u673a\u50ac\u5316\u5242\u76f8\u7ed3\u5408\uff0c\u4ece\u800c\u5b9e\u73b0\u4e86\u9009\u62e9\u6027\u5408\u6210\u6240\u9700\u5206\u5b50\u3002<\/p>\n

Melchiorre\u6559\u6388\u8bf4\uff0c\u201c\u8be5\u65b9\u6cd5\u6210\u529f\u7684\u5173\u952e\u5c31\u662f\u624b\u6027\u6709\u673a\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\uff0c\u56e0\u4e3a\u5b83\u53ef\u4ee5\u7acb\u4f53\u9009\u62e9\u6027\u5730\u963b\u6b62\u7531\u5149\u5316\u5b66\u9a71\u52a8\u7684\u78b3\u4e2d\u5fc3\u81ea\u7531\u57fa\u7684\u751f\u6210\u3002\u624b\u6027\u6709\u673a\u50ac\u5316\u5242\u5728\u672a\u6765\u6709\u53ef\u80fd\u5bf9\u7acb\u4f53\u9009\u62e9\u6027\u5408\u6210\u56db\u5143\u7acb\u6784\u4e2d\u5fc3\u8d77\u5230\u4fc3\u8fdb\u4f5c\u7528\uff0c\u8fd9\u662f\u7528\u4f20\u7edf\u65b9\u6cd5\u65e0\u6cd5\u5b9e\u73b0\u7684\u3002\u6211\u4eec\u73b0\u5728\u6b63\u5728\u52aa\u529b\u63a2\u7a76\u8fd9\u4e9b\u53ef\u80fd\u6027\u3002\u201d<\/p>\n

\u4e00\u822c\u60c5\u51b5\u4e0b\uff0c\u624b\u6027\u5206\u5b50\u7684\u5408\u6210\u9700\u8981\u6709\u673a\u91d1\u5c5e\u5316\u5408\u7269\u5e76\u4e25\u683c\u63a7\u5236\u53cd\u5e94\u6761\u4ef6\u3002\u76f8\u6bd4\u8f83\u800c\u8a00\uff0cICIQ\u63d0\u51fa\u7684\u63a2\u7a76\u7ed3\u679c\uff0c\u53cd\u5e94\u6761\u4ef6\u66f4\u4e3a\u6e29\u548c\uff0c\u6709\u671b\u6210\u4e3a\u624b\u6027\u5206\u5b50\u5408\u6210\u7684\u65b0\u65b9\u6cd5\u3002<\/p>\n

\"Figure<\/p>\n

\u56fe1. \u5408\u6210\u56db\u5143\u7acb\u6784\u4e2d\u5fc3\u7684\u5171\u8f6d\u52a0\u6210\u6280\u672f<\/strong>
\na. \u901a\u8fc7\u7ecf\u5178\u6781\u5316\u65b9\u6cd5\uff0c\u5efa\u7acb\u91d1\u5c5e\u50ac\u5316\u7684\u6709\u673a\u91d1\u5c5e\u8bd5\u5242\u7684\u5bf9\u6620\u9009\u62e9\u6027\u5171\u8f6d\u52a0\u6210
\nb. \u4e3a\u53cc\u91cd\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u548c\u4e9a\u80fa\u79bb\u5b50\u50ac\u5316\u5242\u4f5c\u7528\u4e0b\u7684\u539f\u5b50\u56e2\u5171\u8f6d\u52a0\u6210\uff08RCAs\uff09\u53cd\u5e94\u8bbe\u8ba1\u65b9\u6848\uff1b\u7070\u8272\u5708\u4e2d\u8868\u793a\u624b\u6027\u6709\u673a\u50ac\u5316\u5242\u652f\u67b6\uff1b
\nc. \u5b9e\u73b0\u5728\u4e9a\u80fa\u79bb\u5b50\u50ac\u5316\u4e0b\uff0c\u539f\u5b50\u56e2(\u2022R2)\u8fdb\u884c\u5171\u8f6d\u52a0\u6210\u53cd\u5e94\u662f\u4e00\u9879\u6311\u6218\uff1b
\nd. \u901a\u8fc7\u7535\u5b50\u63a5\u529b\u65b9\u6cd5\u8fdb\u884c\u5206\u5b50\u5185\u53cd\u5e94\uff0c\u5feb\u901f\u53bb\u9664\u5bff\u547d\u77ed\u6682\u7684\u03b1-iminyl\u81ea\u7531\u57fa\u6b63\u79bb\u5b50\uff0c\u800c\u4e92\u53d8\u5f02\u6784\u5316\u7684\u4f5c\u7528\u662f\u9632\u6b62\u7535\u5b50\u7684\u53cd\u5411\u4f20\u8f93\uff08BET\uff09\u3002
\n\u5176\u4e2d\uff0cSET\u4ee3\u8868\u4f46\u7535\u5b50\u4f20\u8f93\uff1bPC\u4ee3\u8868\u5149\u4fc3\u50ac\u5316\u5242\uff1bPCred\u4ee3\u8868\u5149\u4fc3\u50ac\u5316\u5242\u7684\u7b80\u5316\u5f62\u5f0f\u3002\u84dd\u8272\u692d\u5706\u8868\u793a\u7535\u5b50\u5bcc\u79ef\uff0c\u6709\u8fd8\u539f\u6027\uff1b\u7ea2\u8272\u692d\u5706\u4ee3\u8868\u7a33\u5b9a\u7684\u6c27\u5316\u6027\u90e8\u5206\u3002<\/p>\n

\"Figure<\/p>\n

\u56fe2 \u62df\u8bae\u673a\u7406\u548c\u673a\u7406\u7814\u7a76<\/strong>
\na. \u4e9a\u80fa\u79bb\u5b50\u548c\u5149\u81f4\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u5faa\u73af\u7684\u534f\u540c\u4f5c\u7528\uff0c\u4f7f\u5f97\u5bf9\u6620\u9009\u62e9\u6027\u539f\u5b50\u56e2\u5171\u8f6d\u52a0\u6210\u53cd\u5e94\uff08RCA\uff09\u5728\u03b1,\u03b2-\u4e0d\u9971\u548c\u7fb0\u57fa\u5316\u5408\u7269\u4e0a\u5f97\u4ee5\u5b9e\u73b01a\u3002
\n\u81ea\u7531\u57fa\u901a\u8fc7\u4e0e\u4e9a\u80fa\u79bb\u5b50\u53d1\u751f\u52a0\u6210\u53cd\u5e94A-1\uff0c\u7535\u5b50\u4f20\u9012\u673a\u5236\u5feb\u901f\u5730\u964d\u4f4e\u4e86\u4e0d\u7a33\u5b9a\u7684\u81ea\u7531\u57fa\u6b63\u79bb\u5b50\u7684\u6570\u91cfB-1\uff0c\u5e76\u751f\u6210\u4e00\u4e2acarbazoliumyl\u81ea\u7531\u57fa\u6b63\u79bb\u5b50C-1\uff0c\u8fd9\u4e00\u8fc7\u7a0b\u88ab\u7531\u4e8c\u7ea7\u70ef\u80fa\u5411\u76f8\u5e94\u7684\u4e9a\u80fa\u4e92\u53d8\u5f02\u6784\u5316\u65f6\u4ea7\u751f\u7684\u53cd\u5411\u7535\u5b50\u4f20\u8f93\u6240\u963b\u6b62D-1\u3002\u5728D-1\u8fc7\u7a0b\u51cf\u5c11carbazoliumyl\u81ea\u7531\u57fa\u6b63\u79bb\u5b50\u53ef\u4ee5\u5b9e\u73b0\u5149\u50ac\u5316\u5242\u7684\u518d\u751f\uff0c\u540c\u65f6\u7531\u4e8e\u4e9a\u80faE-1\u7684\u6c34\u89e3\u4f5c\u7528\uff0c\u6c28\u57fa\u50ac\u5316\u52424\u88ab\u91ca\u653e\u3002
\nb. \u4f7f\u7528X\u5c04\u7ebf\u89c2\u5bdf\u5494\u5511\u57fa\u4e9a\u80fa\u79bb\u5b50A-1\u7684\u6676\u4f53\u7ed3\u6784\uff1a\u5494\u5511\u6c2e\u5230\u73af\u5df1\u70efsp2 \u03b1-\u78b3\u952e\u4e2d\u70b9\u7684\u8ddd\u79bb\u88ab\u6807\u6ce8\u51fa\u6765\u3002
\nc. \u73af\u5408\u4f5c\u7528\u8bd5\u9a8c\u8868\u660e\uff0c\u5f53\u4f7f\u7528\u5494\u5511\u57fa\u50ac\u5316\u52424e\u65f6\uff0c\u03b1-iminyl\u81ea\u7531\u57fa\u4e2d\u95f4\u4ea7\u7269B-1\u4e0d\u4f1a\u51fa\u73b0\u3002<\/p>\n

\"Figure<\/p>\n

\u56fe3 \u5e95\u7269\u8303\u56f4\uff1a\u901a\u8fc7\u53cc\u50ac\u5316\u5242\u2014\u2014\u5149\u50ac\u5316\u5242\u548c\u6709\u673a\u50ac\u5316\u5242\u7684\u534f\u540c\u4f5c\u7528\u6765\u5bf9\u6620\u9009\u62e9\u6027\u5730\u6355\u83b7\u82ef\u5e76\u4e8c\u8302\u884d\u751f\u81ea\u7531\u57fa\u3002<\/strong>
\n\u73af\u72b6\u03b1,\u03b2-\u4e0d\u9971\u548c\u7fb0\u57fa\u5316\u5408\u72691\u548c\u82ef\u5e76\u4e8c\u6076\u8302\u70f7\u53d6\u4ee3\u57fa2\u80fd\u591f\u53c2\u4e0e\u6709\u673a\u50ac\u5316\u5242\u4e0d\u5bf9\u79f0\u81ea\u7531\u57fa\u5171\u8f6d\u52a0\u6210\uff08RCA\uff09\u6765\u5408\u6210\u56db\u5143\u7acb\u6784\u4e2d\u5fc3\uff08\u59823\u6240\u793a\uff09\u30023a \u2013 3k\u5c55\u793a\u4e86\u5b64\u7acb\u4ea7\u7269\u7684\u4ea7\u91cf\u548c\u5bf9\u6620\u4f53\u8fc7\u91cf\u3002\u901a\u8fc72\u548cHAT\u673a\u5236\uff0cTBADT-\u4e2d\u95f4\u4ea7\u7269\u7684\u5149\u81f4\u6c27\u5316\u8fd8\u539f\u5faa\u73af\u751f\u6210\u4ee5\u78b3\u4e3a\u4e2d\u5fc3\u7684\u57fa\u56e2\u7684\u7ec6\u8282\u88ab\u5c55\u793a\u5728\u56fe2a\u4e2d\u3002\u65b9\u6846\u4e2d\u5708\u51fa\u7684\u662f\u5494\u5511\u57fa\u6709\u673a\u50ac\u5316\u52424e\u3002TBS\uff1a\u53d4\u4e01\u57fa\u4e8c\u7532\u57fa\u6c2f\u7845\u70f7\uff1bTBABF4\uff1a\u56db\u4e01\u57fa\u6c1f\u787c\u9178\u94f5\uff1bd.r.\uff1a\u975e\u5bfe\u6620\u7684\u6bd4\u4f8b\u3002<\/p>\n

\"Figure<\/p>\n

\u56fe4 \u5e95\u7269\u8303\u56f4\uff1a\u901a\u8fc7\u53cc\u50ac\u5316\u5242\u2014\u2014\u5149\u50ac\u5316\u5242\u548c\u6709\u673a\u50ac\u5316\u5242\u7684\u534f\u540c\u4f5c\u7528\u6765\u5bf9\u6620\u9009\u62e9\u6027\u5730\u6355\u83b7\u03b1-\u6c28\u57fa\u81ea\u7531\u57fa\u3002<\/strong>
\na. \u5149\u5316\u5b66\u6709\u673a\u50ac\u5316\u5242\u81ea\u7531\u57fa\u5171\u8f6d\u52a0\u6210\u53cd\u5e94\u4fc3\u4f7f\u56db\u5143\u7acb\u6784\u4e2d\u5fc3\u7684\u751f\u6210\u3002
\nb. \u73af\u72b6\u03b1,\u03b2-\u4e0d\u9971\u548c\u7fb0\u57fa\u5316\u5408\u72691\u548c\u53d4\u80fa6\u80fd\u591f\u53c2\u52a0\u8be5\u53cd\u5e94\u30027a \u2013 7k\u5c55\u793a\u4e86\u72ec\u7acb\u4ea7\u7269\u7684\u4ea7\u91cf\u548c\u5bf9\u6620\u4f53\u8fc7\u91cf\u3002\u901a\u8fc7SET\u673a\u5236\uff0c\u94f1\u4e2d\u95f4\u4ea7\u7269\u7684\u5149\u81f4\u6c27\u5316\u8fd8\u539f\u5faa\u73af\u4ea7\u751f\u4ee5\u78b3\u4e3a\u4e2d\u5fc3\u7684\u57fa\u56e2\u7684\u7ec6\u8282\u88ab\u5c55\u793a\u5728\u56fe2a\u4e2d\u3002\u65b9\u6846\u4e2d\u5708\u51fa\u7684\u662f\u94f1\u5149\u81f4\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u52428\u7684\u7ed3\u6784\u3002
\nc. \u4f7f\u7528\u82ef\u7532\u916e\u5149\u50ac\u5316\u52429\u8fdb\u884c\u7684\u7eaf\u6709\u673a\u50ac\u5316\u5242\u5bf9\u6620\u9009\u62e9\u6027\u81ea\u7531\u57fa\u5171\u8f6d\u52a0\u6210\u53cd\u5e94\u3002<\/p>\n

\u611f\u8c22\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5f20\u6587\u535a\u63d0\u4f9b\u7d20\u6750\u3002<\/p>\n

\u6587\u732e\u4e0b\u8f7d\u94fe\u63a5\uff1aAsymmetric catalytic formation of quaternary carbons by iminium ion trapping of radicals<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

Paolo Melchiorre\u6559\u6388\u6240\u5e26\u9886\u7684\u7814\u7a76\u56e2\u961f\uff0c\u5728\u897f\u73ed\u7259\u52a0\u6cf0\u7f57\u5c3c\u4e9a\u5316\u5b66\u7814\u7a76\u6240\uff08ICIQ\uff09\u63a2\u7a76\u51fa\u4e00\u79cd\u9009\u62e9\u6027\u5408\u6210\u624b\u6027\u5206\u5b50\u7684\u65b0\u65b9\u6cd5\u3002\u8be5\u65b0\u65b9\u6cd5\u662f\u5c06\u5bf9\u6620\u9009\u62e9\u6027\u4e9a\u80fa\u79bb…<\/p>\n","protected":false},"author":67,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[42],"class_list":["post-9113","post","type-post","status-publish","format-standard","hentry","category-keji","tag-gaofenzi"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/9113"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/67"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=9113"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/9113\/revisions"}],"predecessor-version":[{"id":9610,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/9113\/revisions\/9610"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=9113"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=9113"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=9113"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}