{"id":90177,"date":"2017-07-09T14:00:22","date_gmt":"2017-07-09T06:00:22","guid":{"rendered":"\/\/m.iemloyee.com\/?p=90177"},"modified":"2017-07-07T13:28:36","modified_gmt":"2017-07-07T05:28:36","slug":"%e4%b8%ad%e5%9b%bd%e7%a7%91%e5%ad%a6%e9%99%a2%e5%a4%a7%e5%ad%a6%e9%bb%84%e8%be%89afm%ef%bc%9a-pedotpss%e8%be%85%e5%8a%a9%e5%89%a5%e7%a6%bb%e5%92%8c%e5%8a%9f%e8%83%bd%e5%8c%962d%e7%ba%b3%e7%b1%b3","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=90177","title":{"rendered":"\u4e2d\u56fd\u79d1\u5b66\u9662\u5927\u5b66\u9ec4\u8f89AFM\uff1a PEDOT:PSS\u8f85\u52a9\u5265\u79bb\u548c\u529f\u80fd\u53162D\u7eb3\u7c73\u7247\u7528\u4e8e\u9ad8\u6027\u80fd\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u4ece2004\u5e74\uff0c\u77f3\u58a8\u70ef\u4f5c\u4e3a\u4e00\u79cd\u6709\u8da3\u7684\u4e8c\u7ef4\u7eb3\u7c73\u6750\u6599\u7531\u4e8e\u5176\u4f18\u5f02\u7684\u673a\u68b0\u6027\u80fd\u3001\u7535\u6027\u80fd\u3001\u5149\u6027\u80fd\u3001\u70ed\u6027\u80fd\u800c\u5f15\u8d77\u8bb8\u591a\u5173\u6ce8\uff0c\u6700\u8fd1\uff0c\u4e00\u79cd\u77f3\u58a8\u70ef\u7684\u7c7b\u4f3c\u7269\u2014\u4e8c\u7ef4\u7ed3\u6784\u7684\u8fc7\u6e21\u91d1\u5c5e\u53cc\u786b\u5c5e\u5316\u5408\u7269\uff08TMD\u7eb3\u7c73\u7247\uff09\u5728\u7535\u5b50\u9886\u57df\u7684\u5e94\u7528\u663e\u793a\u51fa\u5de8\u5927\u7684\u6f5c\u529b\uff0c\u6bd4\u5982MoS2<\/sub>\u548cWS2<\/sub>\u3002\u8457\u540d\u7684\u805a\u4e59\u6491\u4e8c\u6c27\u567b\u5429\uff1a\u805a\u82ef\u4e59\u70ef\u78fa\u9178\uff08PEDOT:PSS\uff09\u5e7f\u6cdb\u7528\u4e8e\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u7684\u7a7a\u7a74\u63d0\u53d6\u5c42(HEL)\uff0c\u5176\u6709\u8bb8\u591a\u7f3a\u70b9\u6bd4\u5982\u5438\u6c34\u6027\u548c\u9178\u6027\u4f1a\u5bfc\u81f4\u7a33\u5b9a\u6027\u964d\u4f4e\u3002\u6700\u8fd1\uff0c\u7814\u7a76\u4eba\u5458\u4eec\u7528TMD\u7eb3\u7c73\u7247\u66ff\u4ee3PEDOT:PSS\u4f5c\u4e3a\u6709\u57fa\u592a\u9633\u80fd\u7535\u6c60\u7a7a\u7a74\u63d0\u53d6\u5c42\u7684\u65b0\u9009\u62e9\u3002\u57fa\u4e8e\u539f\u59cb\u5f62\u72b6\u7684TMD\u7eb3\u7c73\u7247\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u7684\u529f\u7387\u8f6c\u6362\u6548\u7387(PCE)\u901a\u5e38\u4e0d\u80fd\u8d85\u8d8a\u57fa\u4e8e\u4f20\u7edf\u754c\u9762\u6ce8\u5165\u6750\u6599\u7684\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\uff0c\u53ef\u80fd\u662f\u7531\u4e8e2H\u76f8\u52301T\u76f8\u7684\u76f8\u8f6c\u53d8\u4e0eTMD\u7eb3\u7c73\u7247\u7684\u529f\u51fd\u4e0d\u5339\u914d\u3002\u4e3a\u4e86\u89e3\u51b3\u6b64\u95ee\u9898\uff0c\u5bf9TMD\u7eb3\u7c73\u7247\u8fdb\u884c\u9884\u5904\u7406\uff0c\u6bd4\u5982\u8fc7\u6c27\u5316\u6c22\u6c27\u5316\u3001UV-O3<\/sub>\u5904\u7406\u3001\u52a0\u5165\u63ba\u6742\u5242\u7b49\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u6700\u8fd1\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u5927\u5b66\u9ec4\u8f89\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u5728Advanced Functional Materials<\/strong>\u00a0\u4e0a\u4ee5\u201cPEDOT:PSS-Assisted Exfoliation and Functionalization of 2D Nanosheets for High-Performance Organic Solar Cells<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u6587\u7ae0\uff0c\u6587\u7ae0\u4ecb\u7ecd\u4e86\u4e00\u79cd\u5728PEDOT:PSS\u6eb6\u6db2\u4e2d\u9ad8\u6548\u5265\u79bb\u5757\u4f53\u8fc7\u6e21\u91d1\u5c5e\u53cc\u786b\u5c5e\u5316\u5408\u7269\u548c\u77f3\u58a8\u70ef\u7684\u6e29\u548c\u53ef\u6269\u5c55\u65b9\u6cd5\uff0c\u7528\u4e8e\u5236\u5907\u5355\u5c42\u6216\u5c11\u5c42\u7eb3\u7c73\u7247\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00<\/strong> \u5265\u79bb\u5149\u5b66\u7167\u7247\u548c\u5149\u8c31\u5206\u6790<\/strong><\/p>\n

\"\"<\/p>\n

a) P-MoS2<\/sub>\u5728\u4e0d\u540c\u8d85\u58f0\u65f6\u95f4\u4e0b\u7684\u60ac\u6d6e\u6db2\u5149\u5b66\u7167\u7247\uff1b<\/p>\n

b) \u5728\u7a00\u91ca\u540eP-MoS2<\/sub>\u5206\u6563\u6db2\u7684\u4e01\u8fbe\u5c14\u6548\u5e94\u73b0\u8c61\uff1b<\/p>\n

c) P-MoS2<\/sub>\u7eb3\u7c73\u7247\u5728\u6c34\u4e2d\u4e0d\u540c\u8d85\u58f0\u65f6\u95f4\u4e0b\u5265\u79bb\u7684UV-vis\u5438\u6536\u5149\u8c31\uff1b<\/p>\n

d) PEDOT:PSS\u7a00\u91ca\u540e\uff0cP-MoS2<\/sub>\uff0cP-WS2<\/sub>\u548cP-\u77f3\u58a8\u70ef\u6eb6\u6db2\u7684PL\u5149\u8c31\u3002<\/p>\n

\u56fe\u4e8c<\/strong> \u4e0d\u540c\u5265\u79bb\u6837\u54c1\u7684\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a,b,e) \u00a0P-MoS2<\/sub>\uff0cP-WS2<\/sub>\u548cP-\u77f3\u58a8\u70ef\u7eb3\u7c73\u7247\u7684TEM\u56fe\uff0c\u5185\u90e8\u4e3a\u5bf9\u5e94SAED\u56fe\uff1b<\/p>\n

c,d) \u00a0P-MoS2<\/sub>\uff0cP-WS2<\/sub>\u7eb3\u7c73\u7247\u7684HRTEM\u56fe\uff1b<\/p>\n

f,g,h) \u00a0P-MoS2<\/sub>\uff0cP-WS2<\/sub>\u548cP-\u77f3\u58a8\u70ef\u7eb3\u7c73\u7247\u7684AFM\u56fe\u3002<\/p>\n

\u56fe\u4e09<\/strong> \u4e0d\u540c\u5265\u79bb\u6837\u54c1\u7684\u62c9\u66fc\u56fe\u8c31\u548c<\/strong>XRD<\/strong>\u56fe\u8c31<\/strong><\/p>\n

\"\"<\/p>\n

a,b,c) \u00a0P-MoS2<\/sub>\uff0cP-WS2<\/sub>\u548cP-\u77f3\u58a8\u70ef\u7eb3\u7c73\u7247\u53ca\u5bf9\u5e94\u5757\u4f53\u6676\u4f53\u7684\u62c9\u66fc\u56fe\u8c31\uff1b<\/p>\n

d,e,f) \u00a0P-MoS2<\/sub>\uff0cP-WS2<\/sub>\u548cP-\u77f3\u58a8\u70ef\u7eb3\u7c73\u7247\u53ca\u5bf9\u5e94\u5757\u4f53\u6676\u4f53\u7684XRD\u56fe\u3002<\/p>\n

\u56fe\u56db<\/strong> \u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u5668\u4ef6\u7ed3\u6784\u53ca\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a) \u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u5668\u4ef6\u7ed3\u6784\uff1b<\/p>\n

b,c) PEDOT:PSS\u548cPEDOT:PSS\/ WS2<\/sub>\u8584\u819c\u7684AFM\u5c42\u6790\u56fe\u50cf\uff0c\u57fa\u5e95\u662fITO\/\u73bb\u7483\uff1b<\/p>\n

d) C\u56fe\u5e73\u9762\u7684\u653e\u5927\u56fe\uff1b<\/p>\n

e) PEDOT:PSS\u548cPEDOT:PSS\/ WS2<\/sub>\u6837\u54c1\u7684\u900f\u5c04\u5149\u8c31\uff1b<\/p>\n

f) \u57fa\u4e8eP3HT:PC61<\/sub>BM \u548c PTB7-Th:PC71<\/sub>BM\u6d3b\u6027\u6750\u6599\u7684J-V\u66f2\u7ebf\uff1b<\/p>\n

g) \u57fa\u4e8e\u4e0d\u540c\u7a7a\u7a74\u63d0\u53d6\u5c42P3HT:PC61<\/sub>BM \u548c PTB7-Th:PC71<\/sub>BM\u7684EQE\u66f2\u7ebf\u3002<\/p>\n

\u56fe\u4e94<\/strong> \u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u5668\u4ef6\u7684\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a) ITO\u548cAu\u7535\u6781\u4e4b\u95f4\u4ec5\u542b\u7a7a\u7a74\u7684\u4e0d\u540c\u7a7a\u7a74\u63d0\u53d6\u5c42\u5668\u4ef6\u5728\u65e0\u5149\u6761\u4ef6\u4e0b\u6d4b\u8bd5\u5f97\u5230\u7684\u5178\u578bJ-V\u66f2\u7ebf\uff1b<\/p>\n

b) \u57fa\u4e8eP3HT:PC61<\/sub>BM \u548c PTB7-Th:PC71<\/sub>BM\u6d3b\u6027\u5c42\u7684\u4e0d\u540c\u7a7a\u7a74\u63d0\u53d6\u5c42\u5668\u4ef6\u7684J-V\u7279\u6027\uff1b<\/p>\n

c) PEDOT:PSS\u548cPEDOT:PSS\/ WS2<\/sub>\u6837\u54c1\u7684\u62c9\u66fc\u5149\u8c31\uff1b<\/p>\n

d) \u57fa\u4e8eP3HT:PC61<\/sub>BM \u6d3b\u6027\u5c42\u4e0d\u540c\u7a7a\u7a74\u63d0\u53d6\u5c42\u5668\u4ef6\u7684\u7a33\u5b9a\u6027\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u8005\u4eec\u901a\u8fc7\u5728PEDOT:PSS\u6eb6\u6db2\u4e2d\u5265\u79bb\u5757\u4f53\u4e8c\u7ef4\u6750\u6599\u6210\u529f\u5730\u5236\u5907\u51fa\u4e86\u5355\u5c42\u6216\u5c11\u5c42\u77f3\u58a8\u70ef\/ TMD\u7eb3\u7c73\u7247\uff0c\u4e00\u6b65\u6cd5\u5236\u5907\u6df7\u5408\u58a8\u6c34\u53ef\u4ee5\u4f5c\u4e3a\u9ad8\u6548\u7684\u7a7a\u7a74\u63d0\u53d6\u5c42\u4ee5\u63d0\u9ad8\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u529f\u7387\u8f6c\u6362\u6548\u7387\u548c\u7a33\u5b9a\u6027\u3002\u7ed3\u679c\u8868\u660e\uff0c\u6539\u5584TMD\u7eb3\u7c73\u7247\u7684\u7535\u5bfc\u7387\u53ef\u80fd\u63d0\u9ad8\u754c\u9762\u5c42\u4e4b\u95f4\u7684\u7535\u8377\u4f20\u8f93\u3002\u8fd9\u9879\u5de5\u4f5c\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u9896\u7684\u65b9\u6cd5\u5236\u5907\u5355\u5c42\u6216\u5c11\u5c42\u77f3\u58a8\u70ef\/ TMD\uff0c\u5e76\u4e3aTMD\/\u5171\u8f6d\u805a\u5408\u7269\u7eb3\u7c73\u590d\u5408\u6750\u6599\u7684\u5e94\u7528\u63d0\u4f9b\u4e86\u65b9\u6cd5\u3002<\/p>\n

\u539f\u6587\u94fe\u63a5<\/strong>\uff1aPEDOT:PSS-Assisted Exfoliation and Functionalization of 2D Nanosheets for High-Performance Organic Solar Cells<\/a>. (Adv. Funct. Mater., 2017, DOI: 10.1002\/adfm.201701622)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u7ec4Jane915126\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065952\u201d\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c<\/strong>\u4e0a\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u4ece2004\u5e74\uff0c\u77f3\u58a8\u70ef\u4f5c\u4e3a\u4e00\u79cd\u6709\u8da3\u7684\u4e8c\u7ef4\u7eb3\u7c73\u6750\u6599\u7531\u4e8e\u5176\u4f18\u5f02\u7684\u673a\u68b0\u6027\u80fd\u3001\u7535\u6027\u80fd\u3001\u5149\u6027\u80fd\u3001\u70ed\u6027\u80fd\u800c\u5f15\u8d77\u8bb8\u591a\u5173\u6ce8\uff0c\u6700\u8fd1\uff0c\u4e00\u79cd\u77f3\u58a8\u70ef\u7684\u7c7b\u4f3c\u7269\u2014\u4e8c\u7ef4\u7ed3\u6784\u7684\u8fc7\u6e21\u91d1\u5c5e…<\/p>\n","protected":false},"author":369,"featured_media":90179,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[78],"class_list":["post-90177","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-photovoltaic"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/90177"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/369"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=90177"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/90177\/revisions"}],"predecessor-version":[{"id":90387,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/90177\/revisions\/90387"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/90179"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=90177"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=90177"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=90177"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}