{"id":89454,"date":"2017-07-02T06:30:04","date_gmt":"2017-07-01T22:30:04","guid":{"rendered":"\/\/m.iemloyee.com\/?p=89454"},"modified":"2017-07-02T00:10:31","modified_gmt":"2017-07-01T16:10:31","slug":"%e4%b8%ad%e7%a7%91%e9%99%a2%e7%a6%8f%e5%bb%ba%e7%89%a9%e6%9e%84%e6%89%80%e5%ad%99%e5%ba%86%e7%a6%8f%e5%9b%a2%e9%98%9f%ef%bc%9a%e9%98%b4%e7%a6%bb%e5%ad%90%e8%af%86%e5%88%ab%e8%af%b1%e5%af%bc%e9%85%8d","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=89454","title":{"rendered":"\u4e2d\u79d1\u9662\u798f\u5efa\u7269\u6784\u6240\u5b59\u5e86\u798f\u56e2\u961f\uff1a\u9634\u79bb\u5b50\u8bc6\u522b\u8bf1\u5bfc\u914d\u4f4d\u81ea\u7ec4\u88c5\u7814\u7a76\u83b7\u8fdb\u5c55"},"content":{"rendered":"<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u4e2d\u56fd\u79d1\u5b66\u9662\u798f\u5efa\u7269\u8d28\u7ed3\u6784\u7814\u7a76\u6240\u7ed3\u6784\u5316\u5b66\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u7814\u7a76\u5458\u5b59\u5e86\u798f\u53ca\u5176\u56e2\u961f\u5728\u5177\u6709\u591a\u79cd\u9634\u79bb\u5b50\u54cd\u5e94\u6027\u952e\u5408\u7684\u81ea\u9002\u6027\u914d\u4f4d\u81ea\u7ec4\u88c5\u7814\u7a76\u9886\u57df\u53d6\u5f97\u7a81\u7834\u3002\u7814\u7a76\u53d1\u73b0\uff1a\u534a\u521a\u6027\u53cc\u82ef\u5e76\u54aa\u5511\u6865\u8fde\u914d\u4f53\uff08<strong><b>1<\/b><\/strong>\uff09\u4e0e\u5177\u6709\u5e73\u9762\u56db\u65b9\u914d\u4f4d\u6784\u578b\u7684\u94af\u79bb\u5b50\u5728\u4e0d\u540c\u9634\u79bb\u5b50\u5b58\u5728\u6761\u4ef6\u4e0b\u53ef\u4ee5\u81ea\u7ec4\u88c5\u5f97\u52305\u79cd\u4e0d\u540c\u5c3a\u5bf8\u7684Pd<sub>n<\/sub>L<sub>2n<\/sub>\u00a0(n = 3, 4, 5, 6, 7)\u578b\u7684\u91d1\u5c5e\u6709\u673a\u5927\u73af\u53d7\u4f53\uff0c\u5e76\u901a\u8fc7NMR\u3001ESI-MS\u3001X\u5c04\u7ebf\u884d\u5c04\u7b49\u624b\u6bb5\u5bf9\u5176\u8fdb\u884c\u4e86\u7ed3\u6784\u786e\u8ba4\u3002\u6676\u4f53\u7ed3\u6784\u89e3\u6790\u8bc1\u660e\uff0c\u5927\u73af\u5185\u8868\u9762\u7684\u54aa\u5511\u6c22\u539f\u5b50\u4e0e\u9634\u79bb\u5b50\u5f62\u6210\u591a\u91cd\u6c22\u952e\u4f5c\u7528\uff0c\u5e76\u5bf9\u6700\u7ec8\u7684\u81ea\u7ec4\u88c5\u7ed3\u6784\u8d77\u4e86\u6a21\u677f\u4f5c\u7528\u3002\u540c\u65f6\uff0c\u591a\u7ea7\u4e32\u8054\u9634\u79bb\u5b50\u6ef4\u5b9a\u5b9e\u9a8c\u603b\u7ed3\u4e86\u57fa\u4e8e\u9634\u79bb\u5b50\u6784\u578b\u548c\u5c3a\u5bf8\u7684\u8bf1\u5bfc\u5339\u914d\u539f\u7406\u7684\u5404\u4e2a\u591a\u5143\u73af\u53d7\u4f53\u4e4b\u95f4\u76f8\u4e92\u8f6c\u5316\u89c4\u5f8b\uff0c\u5e76\u63ed\u793a\u4e86\u5728NO<sub>3<\/sub><sup>&#8211;<\/sup>\u8bf1\u5bfc\u4e03\u5143\u73af\u8f6c\u5316\u4e09\u5143\u73af\u7684\u8fc7\u7a0b\u4e2d\u5b58\u5728\u516d\u3001\u4e94\u3001\u56db\u5143\u73af\u4e2d\u95f4\u4f53\u7684\u5b58\u5728\u3002\u57fa\u4e8e\u4ee5\u4e0a\u53d1\u73b0\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86\u9634\u79bb\u5b50\u5ba2\u4f53\u548c\u91d1\u5c5e\u6709\u673a\u5927\u73af\u4e4b\u95f4\u7684\u6c22\u952e\u4f5c\u7528\u63a8\u52a8\u7684\u8bf1\u5bfc\u5339\u914d\u81ea\u9002\u5e94\u8f6c\u5316\u673a\u7406\u3002\u8be5\u5de5\u4f5c\u4e3a\u65b0\u578b\u9634\u79bb\u5b50\u53d7\u4f53\u7684\u7ed3\u6784\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u4e00\u6761\u65b0\u601d\u8def\u3002\u4e0a\u8ff0\u7814\u7a76\u5de5\u4f5c\u4ee5\u9898\u4e3a\u201c<strong>A self-assembled Pd<sub>2<\/sub>L<sub>4<\/sub>cage that selectively encapsulates nitrate<\/strong>\u201d\u53d1\u8868\u4e8e<em><i><strong>Nature Communications<\/strong>\u4e0a\u3002<\/i><\/em><\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe1 \u6676\u4f53\u7ed3\u6784\u900f\u89c6\u56fe\u53ca\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\u793a\u610f\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-89486\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/02.gif\" alt=\"\" width=\"600\" height=\"358\" \/><\/p>\n<p>\uff08A\uff09\u5177\u6709\u4e00\u4e2a\u5305\u5c01\u7684NO<sub>3<\/sub><sup>&#8211;<\/sup> \u9634\u79bb\u5b50\u76842a\u7684\u6676\u4f53\u7ed3\u6784\u900f\u89c6\u56fe<\/p>\n<p>\uff08B\uff09\u5728NO<sub>3<\/sub><sup>&#8211;<\/sup>\u548c\u82ef\u5e76\u54aa\u5511\u914d\u4f53\u4e4b\u95f4\u53d1\u73b0\u7684\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\uff08\u7528\u7eff\u8272\u865a\u7ebf\u7a81\u51fa\u663e\u793a\uff09<\/p>\n<p><strong>\u56fe2\u00a0 \u590d\u5408\u7269(NO<sub>3<\/sub>\u22822)\u00b7(BF<sub>4<\/sub>)<sub>3<\/sub>\u7684ESI-Q-TOF\u8d28\u8c31\u5206\u6790<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-89487\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/07\/01.gif\" alt=\"\" width=\"600\" height=\"385\" \/><\/p>\n<p>\u5176\u663e\u793a\u51fa\u5bf9\u5e94\u4e8e[(NO<sub>3<\/sub>\u22822)\u00b7(BF<sub>4<\/sub>)<sub>3\u2212n<\/sub>]<sup><sub>n+<\/sub><\/sup>, (n = 1\u20133)\u7684m\/z\u5206\u522b\u4e3a2202.5594,1057.7774,676.1837\u5904\u89c2\u5bdf\u5230\u7684\u7a81\u51fa\u5cf0<\/p>\n<p><strong>\u3010\u7814\u7a76\u5185\u5bb9\u3011<\/strong><\/p>\n<p>\u9634\u79bb\u5b50\u5316\u5b66\u5728\u98df\u54c1\u3001\u533b\u836f\u3001\u73af\u5883\u7b49\u9886\u57df\u53d1\u6325\u7740\u5341\u5206\u5173\u952e\u7684\u4f5c\u7528\u3002\u5bf9\u7279\u5b9a\u9634\u79bb\u5b50\u5177\u6709\u9009\u62e9\u6027\u8bc6\u522b\u548c\u4f20\u611f\u4f5c\u7528\u7684\u4eba\u5de5\u53d7\u4f53\u7684\u8bbe\u8ba1\u5408\u6210\u4e00\u76f4\u662f\u8d85\u5206\u5b50\u5316\u5b66\u7684\u91cd\u8981\u7814\u7a76\u5185\u5bb9\u3002\u6b64\u524d\uff0c\u6587\u732e\u4e2d\u5df2\u7ecf\u62a5\u9053\u4e86\u5927\u91cf\u7684\u7eaf\u6709\u673a\u6216\u6709\u673a-\u65e0\u673a\u6742\u5316\u7684\u5927\u73af\u6216\u8005\u7b3c\u72b6\u9634\u79bb\u5b50\u53d7\u4f53\u5206\u5b50\u3002\u7136\u800c\uff0c\u524d\u4eba\u7684\u5de5\u4f5c\u5f80\u5f80\u662f\u5229\u7528\u521a\u6027\u6a21\u5757\u6765\u6784\u7b51\u5177\u6709\u56fa\u5b9a\u5c3a\u5bf8\u548c\u6784\u578b\u7684\u8d85\u5206\u5b50\u53d7\u4f53\uff0c\u4ee5\u5b9e\u73b0\u5bf9\u7279\u5b9a\u9634\u79bb\u5b50\u7684\u4e13\u4e00\u9009\u62e9\u6027\u3002\u8fd9\u4f7f\u5f97\u591a\u6570\u9634\u79bb\u5b50\u53d7\u4f53\u7ed3\u6784\u5355\u4e00\u4e14\u6ca1\u6709\u666e\u9002\u6027\u3002\u56e0\u6b64\uff0c\u8bbe\u8ba1\u5177\u6709\u591a\u79cd\u9634\u79bb\u5b50\u8bc6\u522b\u884c\u4e3a\u3001\u4e14\u5177\u6709\u8bf1\u5bfc\u5339\u914d\u81ea\u9002\u5e94\u578b\u7684\u8d85\u5206\u5b50\u53d7\u4f53\u5177\u6709\u91cd\u8981\u7684\u79d1\u5b66\u610f\u4e49\u3002<\/p>\n<p>\u6b64\u524d\uff0c\u8be5\u8bfe\u9898\u7ec4\u8fd8\u62a5\u9053\u4e86\u5177\u6709\u7279\u5f02\u6027\u785d\u9178\u6839\u8bc6\u522b\u529f\u80fd\u7684\u5206\u5b50\u5bb9\u5668\u578b\u8d85\u5206\u5b50\u53d7\u4f53\u8bbe\u8ba1\u4e0e\u5408\u6210\u5de5\u4f5c\uff0c\u5e76\u88ab\u9009\u4e3a\u6742\u5fd7\u7684\u5185\u5c01\u9762\u52a0\u4ee5\u4ecb\u7ecd\uff08<em><i>Chem. Commun.<\/i><\/em>\u00a02015,51, 16767.DOI:10.1039\/c5cc07306e\uff09\u3002<\/p>\n<p>\u8be5\u7814\u7a76\u83b7\u5f97\u4e2d\u79d1\u9662\u6218\u7565\u6027\u5148\u5bfc\u79d1\u6280\u4e13\u9879\uff08B\u7c7b\uff09\u3001\u56fd\u5bb6\u57fa\u91d1\u59d4\u201c\u65e0\u673a-\u6709\u673a\u6742\u5316\u529f\u80fd\u6750\u6599\u201d\u521b\u65b0\u7fa4\u4f53\u3001\u4e2d\u7ec4\u90e8\u201c\u9752\u5e74\u5343\u4eba\u8ba1\u5212\u201d\u9879\u76ee\u3001\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9762\u4e0a\u53ca\u9752\u5e74\u9879\u76ee\u3001\u798f\u5efa\u7701\u201c\u6770\u51fa\u9752\u5e74\u201d\u57fa\u91d1\u7b49\u7684\u8d44\u52a9\u3002<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1a<a href=\"http:\/\/www.cas.cn\/syky\/201706\/t20170628_4606744.shtml\" target=\"_blank\" rel=\"noopener noreferrer\">http:\/\/www.cas.cn\/syky\/201706\/t20170628_4606744.shtml<\/a><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/pubs.rsc.org\/en\/Content\/ArticleLanding\/CC\/2015\/C5CC07306E\" target=\"_blank\" rel=\"noopener noreferrer\">A self-assembled Pd<sub>2<\/sub>L<sub>4<\/sub>cage that selectively encapsulates nitrate<\/a>\u00a0(Nat.Commun.,2017,DOI:10.1038\/ncomms15898)<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8Allen\u7f16\u8f91\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" rel=\"noopener noreferrer\">\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener noreferrer\">\u6d4b\u8bd5\u8c37<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u6210\u679c\u7b80\u4ecb\u3011 \u4e2d\u56fd\u79d1\u5b66\u9662\u798f\u5efa\u7269\u8d28\u7ed3\u6784\u7814\u7a76\u6240\u7ed3\u6784\u5316\u5b66\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u7814\u7a76\u5458\u5b59\u5e86\u798f\u53ca\u5176\u56e2\u961f\u5728\u5177\u6709\u591a\u79cd\u9634\u79bb\u5b50\u54cd\u5e94\u6027\u952e\u5408\u7684\u81ea\u9002\u6027\u914d\u4f4d\u81ea\u7ec4\u88c5\u7814\u7a76\u9886\u57df\u53d6\u5f97\u7a81\u7834\u3002\u7814\u7a76\u53d1\u73b0\uff1a\u534a\u521a&#8230;<\/p>\n","protected":false},"author":349,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-89454","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/89454"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/349"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=89454"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/89454\/revisions"}],"predecessor-version":[{"id":89545,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/89454\/revisions\/89545"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=89454"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=89454"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=89454"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}