{"id":89341,"date":"2017-07-03T06:30:05","date_gmt":"2017-07-02T22:30:05","guid":{"rendered":"\/\/m.iemloyee.com\/?p=89341"},"modified":"2017-07-03T10:44:57","modified_gmt":"2017-07-03T02:44:57","slug":"%e9%99%88%e6%98%a5%e6%88%90angew-chem-int-ed%ef%bc%9a%e5%9f%ba%e4%ba%8e%e8%8a%b3%e9%a6%99%e6%97%8f%e9%85%b0%e4%ba%9a%e8%83%ba%e7%9a%84%e7%83%ad%e6%bf%80%e5%bb%b6%e8%bf%9f%e8%8d%a7%e5%85%89%e6%9d%90","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=89341","title":{"rendered":"\u9648\u4f20\u5cf0&\u738b\u9e70Angew. Chem. Int. Ed\uff1a\u57fa\u4e8e\u82b3\u9999\u65cf\u9170\u4e9a\u80fa\u7684\u70ed\u6fc0\u5ef6\u8fdf\u8367\u5149\u6750\u6599\uff0c\u53ef\u5e94\u7528\u4e8e\u9ad8\u6548\u6709\u673a\u53d1\u5149\u4e8c\u6781\u7ba1"},"content":{"rendered":"
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Chem. Int. Ed<\/strong>\u53d1\u8868\u4e86\u9898\u4e3a\u201cAromatic-Imide-Based Thermally Activated Delayed Fluorescence Materials for Highly Efficient Organic Light-Emitting Diodes\u201d<\/strong>\u7684\u6587\u7ae0\uff0c\u7814\u53d1\u4e86\u4e00\u79cd\u57fa\u4e8e\u82b3\u9999\u65cf\u9170\u4e9a\u80fa\u7684\u70ed\u6fc0\u5ef6\u8fdf\u8367\u5149\u6750\u6599\u5e94\u7528\u4e8e\u9ad8\u6548\u6709\u673a\u53d1\u5149\u4e8c\u6781\u7ba1\uff0c\u82b3\u9999\u65cf\u9170\u4e9a\u80fa\u5177\u6709\u4f18\u5f02\u7684\u5149\u7535\u6027\u80fd\u548c\u5f88\u5f3a\u7684\u5438\u7535\u80fd\u529b\uff0c\u8be5\u8bfe\u9898\u7ec4\u901a\u8fc7\u8fdb\u4e00\u6b65\u4f18\u5316\u8bbe\u8ba1\u5177\u6709\u4f9b\u4f53-\u53d7\u4f53-\u4f9b\u4f53\u7ed3\u6784\u7684\u65b0\u578b\u548c\u6709\u6548\u7684TADF\u5206\u5b50\u7ed3\u6784\uff0c\u83b7\u5f97\u7684\u82b3\u65cf\u9170\u4e9a\u80fa\u663e\u793a\u51fa\u9ad8\u7684PLQY\uff0c\u5b83\u4eec\u7684\u77ac\u6001PL\u5149\u8c31\u5177\u6709\u660e\u663e\u7684\u6e29\u5ea6\u4f9d\u8d56\u6027\u5ef6\u8fdf\u6027\u80fd\uff0c\u63ba\u6742AI-Cz\u548cAl-TBCz\u7684OLED\u7684\u6027\u80fd\u7a81\u51fa\uff0cEQE\u5206\u522b\u9ad8\u8fbe23.2\uff05\u548c21.1\uff05\u3002<\/p>\n \u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n \u56fe<\/strong>1<\/strong>\uff1a<\/strong>\u82b3\u9999\u9170\u4e9a\u80fa<\/strong>AI-Cz<\/strong>\u548c<\/strong>AI-TBCz<\/strong>\u7684\u5316\u5b66\u7ed3\u6784<\/strong><\/p>\n AI-Cz\u548cAI-TBCz\u7684HOMO\u4e3b\u8981\u4f4d\u4e8e\u5494\u5511\u57fa\u90e8\u5206\uff0c\u56e0\u4e3a\u5b83\u4eec\u5177\u6709\u5f3a\u7684\u7ed9\u7535\u80fd\u529b\uff0c\u5e76\u4e14LUMO\u7531\u4e8e\u5176\u5f3a\u5438\u7535\u5b50\u6027\u8d28\u800c\u4f4d\u4e8e\u82b3\u65cf\u9170\u4e9a\u80fa\u90e8\u5206\u4e0a;\u8fd9\u79cd\u6e05\u6670\u7684\u7a7a\u95f4\u7535\u5b50\u5206\u79bb\u53ef\u4ee5\u6709\u6548\u5730\u7834\u574f\u7535\u8377\u8f6c\u79fb\u6fc0\u53d1\u6001\u7684\u7535\u5b50\u8dc3\u8fc1\u3002<\/p>\n \u56fe<\/strong>2<\/strong>\uff1a<\/strong>AI-Cz<\/strong>\u53ca\u5176\u4e8c\u805a\u4f53\u7684\u6676\u4f53\u7ed3\u6784<\/strong><\/p>\n 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\u5728\u5176\u8367\u5149\u5149\u8c31\u4e2d\u4e5f\u89c2\u5bdf\u5230\u5728\u7ea6455nm\u548c465nm\u5904\u7684AI-Cz\u548cAI-TBCz\u7684\u77ed\u5cf0\u503c\u6ce2\u957f\uff0c\u8fd9\u53ef\u80fd\u5f52\u56e0\u4e8e\u663e\u793a\u626d\u66f2\u7684\u5206\u5b50\u5185\u7535\u8377\u8f6c\u79fb\u7684\u5206\u5b50\u7684\u5c40\u90e8\u6fc0\u53d1\u6001\u3002 \u6b64\u5916\uff0c\u53d1\u73b0AI-Cz\u548cAI-TBCz\u7684\u78f7\u5149\u5e26\u4f4d\u4e8e498\u548c505nm\uff0c\u5176\u76f8\u5e94\u7684T1\u80fd\u7ea7\u5206\u522b\u4e3a2.49\u548c2.46eV\u3002<\/p>\n \u56fe<\/strong>5<\/strong>\uff1a<\/strong>\u77ac\u6001<\/strong>PL<\/strong>\u5149\u8c31\u56fe<\/strong><\/p>\n \u56fe5\u662f5\u00b11wt\uff05AI-Cz\uff1amCBP\u819c\u548c5\u00b11wt\uff05AI-TBCz\uff1amCBP\u819c\u5728300K\u4e0b\u7684\u77ac\u6001PL\u7279\u6027\uff1b\u63d2\u56fe\u4e3a5\u00b11wt\uff05AI-Cz\uff1amCBP\u8584\u819c\u7684\u77ac\u6001PL\u5149\u8c31\u7684\u6e29\u5ea6\u4f9d\u8d56\u6027\u3002<\/p>\n \u56fe<\/strong>6<\/strong>\uff1a<\/strong>\u57fa\u4e8e<\/strong>AI-Cz<\/strong>\u548c<\/strong>AI-TBCz<\/strong>\u4f5c\u4e3a\u53d1\u5c04\u4f53\u7684<\/strong>OLED<\/strong>\u7684\u53d1\u5149\u6027\u80fd\u56fe<\/strong><\/p>\n a)\u7535\u6d41\u5bc6\u5ea6-\u7535\u538b-\u4eae\u5ea6\u7279\u6027\u56fe\uff1b<\/p>\n b) EQE\u4eae\u5ea6\u7279\u6027\uff1b\u63d2\u56fe\u4e3a\u5668\u4ef6\u572810 V\u65f6\u7684EL\u5149\u8c31\u3002<\/p>\n \u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n \u8be5\u56e2\u961f\u5408\u6210\u4e86\u4e00\u79cd\u57fa\u4e8e\u82b3\u9999\u65cf\u9170\u4e9a\u80fa\u7684\u70ed\u6fc0\u5ef6\u8fdf\u8367\u5149\u6750\u6599\u5e94\u7528\u4e8e\u9ad8\u6548\u6709\u673a\u53d1\u5149\u4e8c\u6781\u7ba1\uff0c\u8be5\u6750\u6599\u5177\u6709\u5c0f\u7684\u0394EST\u503c\u4ee5\u53ca\u77ac\u6001PL\u5149\u8c31\u8bc1\u660e\u4e86\u5b83\u4eec\u4f18\u5f02\u7684TADF\u6027\u8d28\u3002\u63ba\u6742\u540e\u7684AI-Cz\u548cAl-TBCz\u7684OLED\u7684\u6027\u80fd\u7a81\u51fa\uff0cEQE\u5206\u522b\u9ad8\u8fbe23.2\uff05\u548c21.1\uff05\u3002<\/p>\n \u6587\u732e\u94fe\u63a5\uff1a<\/strong>Aromatic-Imide-Based Thermally Activated Delayed Fluorescence Materials for Highly Efficient Organic Light-Emitting Diodes<\/a>\uff08Angew. Chem. Int. Ed, 2017, DOI: 10.1002\/anie.201704435\uff09<\/p>\n \u672c\u6587\u7531\u6750\u6599\u4eba\u7535\u5b50\u7535\u5de5\u5b66\u672f\u7ec4\u6768\u8d85\u6574\u7406\u7f16\u8f91\u3002<\/p>\n \u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002\u5982\u679c\u4f60\u5bf9\u7535\u5b50\u6750\u6599\u611f\u5174\u8da3\uff0c\u613f\u610f\u4e0e\u7535\u5b50\u7535\u5de5\u9886\u57df\u4eba\u624d\u4ea4\u6d41\uff0c\u8bf7\u52a0\u5165\u6750\u6599\u4eba\u7535\u5b50\u7535\u5de5\u6750\u6599\u5b66\u4e60\u5c0f\u7ec4\uff08QQ\u7fa4\uff1a482842474\uff09\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n<\/strong><\/p>\n
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