{"id":87474,"date":"2017-06-24T14:00:58","date_gmt":"2017-06-24T06:00:58","guid":{"rendered":"\/\/m.iemloyee.com\/?p=87474"},"modified":"2017-06-23T15:18:46","modified_gmt":"2017-06-23T07:18:46","slug":"%e4%b8%ad%e7%a7%91%e9%99%a2%e5%a4%a7%e8%bf%9e%e5%8c%96%e7%89%a9%e6%89%80%e5%88%98%e4%b8%ad%e6%b0%91%e3%80%81%e9%ad%8f%e8%bf%8e%e6%97%ad%e5%9b%a2%e9%98%9f%ef%bc%9a%e7%94%b2%e9%86%87%e5%88%b6%e7%83%af","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=87474","title":{"rendered":"\u4e2d\u79d1\u9662\u5927\u8fde\u5316\u7269\u6240\u5218\u4e2d\u6c11\u3001\u9b4f\u8fce\u65ed\u56e2\u961f\uff1a\u7532\u9187\u5236\u70ef\u70c3\u53cd\u5e94\u673a\u7406\u7814\u7a76\u53d6\u5f97\u65b0\u8fdb\u5c55"},"content":{"rendered":"<p><strong><b>\u3010<\/b><\/strong><strong><b>\u6210\u679c\u7b80\u4ecb<\/b><\/strong><strong><b>\u3011<\/b><\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u7532\u9187\u5236\u70ef\u70c3\u56fd\u5bb6\u5de5\u7a0b\u5b9e\u9a8c\u5ba4\u5218\u4e2d\u6c11\u3001\u9b4f\u8fce\u65ed\u56e2\u961f\u5728\u7532\u9187\u5236\u70ef\u70c3\u521d\u59cbC-C\u952e\u751f\u6210\u673a\u7406\u7814\u7a76\u65b9\u9762\u53d6\u5f97\u65b0\u8fdb\u5c55\u3002\u8be5\u7814\u7a76\u5de5\u4f5c\u9898\u4e3a\u201cDirect Mechanism of the First Carbon-Carbon Bond Formation in the Methanol-to-Hydrocarbons Process\u201d\u5f97\u5230\u5ba1\u7a3f\u4eba\u7684\u9ad8\u5ea6\u8bc4\u4ef7\uff0c\u4ee5\u201c\u70ed\u70b9\u6587\u7ae0\u201d\u5f62\u5f0f\u53d1\u8868\u5728Angewandte Chemie International Edition\u4e0a\uff0c\u5e76\u88ab\u63a8\u8350\u4e3a\u5185\u5c01\u9762\u6587\u7ae0\u3002<\/p>\n<p><strong><b>\u3010<\/b><\/strong><strong><b>\u56fe\u6587\u5bfc\u8bfb<\/b><\/strong><strong><b>\u3011<\/b><\/strong><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>1 <\/b><\/strong><strong><b>GC-MS<\/b><\/strong><strong><b>\u8272\u8c31\u56fe<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-87476\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/06\/1-59.jpg\" alt=\"\" width=\"600\" height=\"431\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/06\/1-59.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/06\/1-59-300x216.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>HZSM-5\u50ac\u5316\u5242\u5728300\u2103\u4e0b\u7532\u9187\u91cd\u91cf\u65f6\u901f\uff08WHSV\uff09\u4e3a2.0 h<sup>-1<\/sup>\u7684MTH\u53cd\u5e94\u4e2d\u6d41\u51fa\u7269\u7684GC-MS\u8272\u8c31\u56fe\u3002 \u63d2\u56fe\u7a81\u51fa\u663e\u793a\u5706\u5708\u4e2d\u7684\u7ec6\u8282\u3002<\/p>\n<p><strong><b>\u56fe2 <\/b><\/strong><strong><b>\u8868\u5f81\u7ed3\u679c<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-87477\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/06\/2-55.jpg\" alt=\"\" width=\"600\" height=\"477\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/06\/2-55.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/06\/2-55-300x239.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>\u00a0<\/b><\/strong>HZSM-5\u50ac\u5316\u5242\u5728300\u2103\u65f625-240\u00a0s\u7684<sup>13<\/sup>C-\u7532\u9187\u8f6c\u5316\u7684<sup>13<\/sup>C CP\/MAS NMR\u5149\u8c31\u3002 *\u8868\u793a\u65cb\u8f6c\u8fb9\u5e26\u3002<\/p>\n<p><strong><b>\u3010\u7814\u7a76\u5185\u5bb9\u3011<\/b><\/strong><\/p>\n<p>\u7532\u9187\u5236\u70ef\u70c3\u56fd\u5bb6\u5de5\u7a0b\u5b9e\u9a8c\u5ba4\u4e00\u76f4\u575a\u6301\u5e94\u7528\u7814\u7a76\u4e0e\u57fa\u7840\u7814\u7a76\u5e76\u91cd\uff0c\u4e0d\u4f46\u5728\u7532\u9187\u5236\u70ef\u70c3\uff08MTO\uff09\u8fc7\u7a0b\u5de5\u4e1a\u5316\u65b9\u9762\u53d6\u5f97\u5de8\u5927\u6210\u529f\uff0c\u800c\u4e14\u957f\u671f\u81f4\u529b\u4e8e\u8be5\u5316\u5b66\u8fc7\u7a0b\u4e2d\u7684\u57fa\u7840\u79d1\u5b66\u95ee\u9898\u7814\u7a76\u3002\u867d\u7136MTO\u8fc7\u7a0b\u7a33\u6001\u53cd\u5e94\u9636\u6bb5\u7684\u95f4\u63a5\u673a\u7406\u5df2\u5f62\u6210\u5e7f\u6cdb\u7684\u5171\u8bc6\uff0c\u4f46MTO\u53cd\u5e94\u4e2d\u4eceC<sub>1<\/sub>\u7269\u79cd\u7532\u9187\u6216\u8005\u4e8c\u7532\u919a\u751f\u6210\u7b2c\u4e00\u4e2aC-C\u952e\u7684\u53cd\u5e94\u4e00\u76f4\u662fC<sub>1<\/sub>\u5316\u5b66\u4e2d\u6781\u5177\u6311\u6218\u6027\u548c\u4e89\u8bae\u6027\u7684\u8bfe\u9898\u3002\u7531\u4e8e\u8f6c\u5316\u53d1\u751f\u5728\u53cd\u5e94\u7684\u6700\u521d\u59cb\u9636\u6bb5\uff0c\u96be\u4ee5\u6355\u83b7\u4e2d\u95f4\u7269\u79cd\uff0c\u4e00\u76f4\u4ee5\u6765\u6240\u63d0\u51fa\u7684\u53cd\u5e94\u673a\u7406\u7f3a\u4e4f\u76f4\u63a5\u8bc1\u636e\u3002\u8be5\u9879\u5de5\u4f5c\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u5728\u7ebf\u76d1\u6d4b\u6700\u521d\u59cb\u53cd\u5e94\u9636\u6bb5\uff0c\u63a8\u6d4b\u521d\u59cb\u70ef\u70c3\u6765\u6e90\u4e8e\u50ac\u5316\u5242\u8868\u9762C<sub>1<\/sub>\u5438\u9644\u7269\u79cd\u7684\u76f4\u63a5\u8f6c\u5316\uff1b\u968f\u540e\u901a\u8fc7\u50ac\u5316\u5242\u6db2\u6c2e\u6dec\u51b7\u548c\u56fa\u4f53\u6838\u78c1\u8868\u5f81\uff0c\u786e\u5b9a\u4e86\u50ac\u5316\u5242\u4e0a\u6700\u521d\u59cb\u53cd\u5e94\u9636\u6bb5\u5b58\u5728\u7684\u8868\u9762C<sub>1<\/sub>\u5438\u9644\u7269\u79cd\uff08\u7532\u9187\u548c\u4e8c\u7532\u919a\uff09\u548cC<sub>1<\/sub>\u6d3b\u6027\u7269\u79cd\uff08\u8868\u9762\u7532\u6c27\u57fa\u548c\u4e09\u7532\u57fa\u6c27\u9393\u79bb\u5b50\uff09\uff1b\u8fdb\u4e00\u6b65\u901a\u8fc7\u539f\u4f4d\u56fa\u4f53\u6838\u78c1\u7814\u7a76\uff0c\u5728\u771f\u5b9e\u7532\u9187\u8f6c\u5316\u53cd\u5e94\u6761\u4ef6\u4e0b\uff0c\u6210\u529f\u6355\u6349\u5230\u4e8c\u7532\u919aC-H\u952e\u6d3b\u5316\u540e\u751f\u6210\u7684\u7c7b\u4e9a\u7532\u6c27\u57fa\uff08methyleneoxy analogue\uff09\u7269\u79cd\uff0c\u7531\u6b64\u83b7\u53d6\u4e86C<sub>1<\/sub>\u7269\u79cd\u6d3b\u5316\u751f\u6210\u7b2c\u4e00\u4e2aC-C\u952e\u7684\u76f4\u63a5\u8bc1\u636e\uff1b\u5728\u6b64\u57fa\u7840\u4e0a\u63d0\u51fa\u4e86\u521d\u59cb\u70ef\u70c3\u751f\u6210\u7684\u53cd\u5e94\u8def\u5f84\u2014\u2014\u8868\u9762\u7532\u6c27\u57fa\/\u4e09\u7532\u57fa\u6c27\u9393\u79bb\u5b50\u534f\u52a9\u7532\u9187\/\u4e8c\u7532\u919a\u6d3b\u5316\u8f6c\u5316\u7684\u534f\u540c\u53cd\u5e94\u673a\u7406\u3002\u8fd9\u662f\u9996\u6b21\u5728MTO\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u539f\u4f4d\u89c2\u6d4b\u5230C<sub>1<\/sub>\u7269\u79cd\u7684\u521d\u59cb\u6d3b\u5316\u548c\u8f6c\u5316\uff0c\u8fd9\u4e00\u53d1\u73b0\u5c06\u5173\u8054\u7532\u9187\u521d\u59cb\u8f6c\u5316\u7684\u76f4\u63a5\u673a\u7406\u548c\u9ad8\u6548\u8f6c\u5316\u9636\u6bb5\u7684\u95f4\u63a5\u673a\u7406\uff0c\u5efa\u7acb\u7532\u9187\u8f6c\u5316\u53cd\u5e94\u5b8c\u6574\u7684\u53cd\u5e94\u5386\u7a0b\u3002\u6b64\u524d\u5728MTO\u53cd\u5e94\u7a33\u5b9a\u9636\u6bb5\u70c3\u6c60\uff08Hydrocarbon Pool\uff09\u673a\u7406\u7684\u7814\u7a76\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u66fe\u76f4\u63a5\u6355\u6349\u5230\u6700\u4e3a\u91cd\u8981\u7684\u53cd\u5e94\u4e2d\u95f4\u7269\u79cd\u2014\u2014\u82ef\u57fa\u548c\u73af\u620a\u70ef\u57fa\u78b3\u6b63\u79bb\u5b50\u4e2d\u95f4\u4f53\uff0c\u5e76\u786e\u5b9a\u4e86\u5206\u5b50\u7b5b\u50ac\u5316\u7532\u9187\u5236\u70ef\u70c3\u7684\u50ac\u5316\u5faa\u73af\u9014\u5f84\uff08<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ja209950x\" target=\"_blank\" rel=\"noopener noreferrer\">J. Am. Chem. Soc.\u00a02012\uff0c134\uff082\uff09\uff0c836-839<\/a>\uff1b<a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201303586\/abstract\" target=\"_blank\" rel=\"noopener noreferrer\">Angew. Chem. Int. Ed.\u00a02013\uff0c52(44)\uff0c11564-11568<\/a>\uff09\u3002\u8fd9\u4e9b\u5de5\u4f5c\u4e30\u5bcc\u4e86C<sub>1<\/sub>\u50ac\u5316\u5316\u5b66\u7684\u57fa\u672c\u7406\u8bba\uff0c\u4e5f\u5bf9MTO\u7684\u5de5\u4e1a\u5e94\u7528\u5177\u6709\u91cd\u8981\u7684\u4fc3\u8fdb\u548c\u652f\u6491\u4f5c\u7528\u3002<\/p>\n<p>\u4e0a\u8ff0\u7814\u7a76\u5de5\u4f5c\u5f97\u5230\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u3001\u4e2d\u79d1\u9662\u524d\u6cbf\u79d1\u5b66\u91cd\u70b9\u7814\u7a76\u9879\u76ee\u3001\u80fd\u6e90\u6750\u6599\u5316\u5b66\u534f\u540c\u521b\u65b0\u4e2d\u5fc3\uff08iChEM\uff09\u548c\u4e2d\u79d1\u9662\u9752\u5e74\u521b\u65b0\u4fc3\u8fdb\u4f1a\u7684\u8d44\u52a9\u4e0e\u652f\u6301\u3002<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1a<a href=\"http:\/\/www.cas.cn\/syky\/201706\/t20170616_4605304.shtml\" target=\"_blank\" rel=\"noopener noreferrer\">http:\/\/www.cas.cn\/syky\/201706\/t20170616_4605304.shtml<\/a><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/onlinelibrary.wiley.com\/wol1\/doi\/10.1002\/anie.201703902\/full\" target=\"_blank\" rel=\"noopener noreferrer\">Direct Mechanism of the First Carbon-Carbon Bond Formation in the Methanol-to-Hydrocarbons Process <\/a>(Angew. Chem. Int. Ed.\uff0c2017, DOI: 10.1002\/anie.201703902)<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u77f3\u5c0f\u6885\u7f16\u8f91\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" rel=\"noopener noreferrer\">\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener noreferrer\">\u6d4b\u8bd5\u8c37<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u6210\u679c\u7b80\u4ecb\u3011 \u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u7532\u9187\u5236\u70ef\u70c3\u56fd\u5bb6\u5de5\u7a0b\u5b9e\u9a8c\u5ba4\u5218\u4e2d\u6c11\u3001\u9b4f\u8fce\u65ed\u56e2\u961f\u5728\u7532\u9187\u5236\u70ef\u70c3\u521d\u59cbC-C\u952e\u751f\u6210\u673a\u7406\u7814\u7a76\u65b9\u9762\u53d6\u5f97\u65b0\u8fdb\u5c55\u3002\u8be5\u7814\u7a76\u5de5\u4f5c\u9898\u4e3a\u201cD&#8230;<\/p>\n","protected":false},"author":2832,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-87474","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/87474"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2832"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=87474"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/87474\/revisions"}],"predecessor-version":[{"id":88117,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/87474\/revisions\/88117"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=87474"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=87474"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=87474"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}