{"id":86862,"date":"2017-06-19T14:00:43","date_gmt":"2017-06-19T06:00:43","guid":{"rendered":"\/\/m.iemloyee.com\/?p=86862"},"modified":"2017-06-19T14:19:12","modified_gmt":"2017-06-19T06:19:12","slug":"%e5%8d%97%e5%bc%80%e5%a4%a7%e5%ad%a6%e5%8c%96%e5%ad%a6%e5%ad%a6%e9%99%a2%e4%bd%95%e8%89%af%e5%b9%b4%e6%95%99%e6%8e%88%e8%af%be%e9%a2%98%e7%bb%84%ef%bc%9a%e4%ba%8c%e6%b0%a7%e5%8c%96%e7%a2%b3","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=86862","title":{"rendered":"\u5357\u5f00\u5927\u5b66\u5316\u5b66\u5b66\u9662\u4f55\u826f\u5e74\u6559\u6388\u8bfe\u9898\u7ec4\uff1a\u4e8c\u6c27\u5316\u78b3\u201c\u53d8\u5e9f\u4e3a\u5b9d\u201d\u5728\u5b66\u754c\u9996\u6b21\u5b9e\u73b0\u5206\u7ea7\u53ef\u63a7\u8fd8\u539f"},"content":{"rendered":"<p><strong><b>\u3010<\/b><\/strong><strong><b>\u6210\u679c\u7b80\u4ecb<\/b><\/strong><strong><b>\u3011<\/b><\/strong><\/p>\n<p>\u7eff\u6c34\u9752\u5c71\u5c31\u662f\u91d1\u5c71\u94f6\u5c71\u3002\u6709\u6548\u5229\u7528\u8d44\u6e90\u4fdd\u62a4\u73af\u5883\uff0c\u53d1\u5c55\u7eff\u8272\u5316\u5b66\u6210\u4e3a\u5927\u52bf\u6240\u8d8b\u3002\u4e8c\u6c27\u5316\u78b3\u662f\u6700\u4e3b\u8981\u7684\u6e29\u5ba4\u6c14\u4f53\uff0c\u540c\u65f6\u4e5f\u662f\u50a8\u91cf\u4e30\u5bcc\u3001\u5b89\u5168\u53ef\u9760\u7684\u53ef\u518d\u751f\u8d44\u6e90\uff0c\u901a\u8fc7\u5316\u5b66\u8f6c\u5316\u53ef\u5bf9\u5176\u8fdb\u884c\u8d44\u6e90\u5316\u5229\u7528\uff0c\u5b9e\u73b0\u201c\u53d8\u5e9f\u4e3a\u5b9d\u201d\u3002\u8fd1\u65e5\uff0c\u5316\u5b66\u5b66\u9662\u4f55\u826f\u5e74\u6559\u6388\u8bfe\u9898\u7ec4\u5229\u7528\u4e09\u7532\u94f5\u4e59\u5185\u916f\uff08\u751c\u83dc\u78b1\uff09\u4f5c\u4e3a\u9ad8\u6548\u3001\u53ef\u6301\u7eed\u7684\u6709\u673a\u5c0f\u5206\u5b50\u50ac\u5316\u5242\uff0c\u5728\u80fa\u548c\u4e8c\u82ef\u57fa\u7845\u70f7\u5b58\u5728\u4e0b\u5b9e\u73b0\u4e86\u4e8c\u6c27\u5316\u78b3\u5206\u7ea7\u53ef\u63a7\u5730\u8fd8\u539f\u529f\u80fd\u5316\u53cd\u5e94\uff0c\u8fd9\u662f\u5b66\u754c\u9996\u6b21\u540c\u65f6\u5b9e\u73b0\u4e8c\u6c27\u5316\u78b3\u53ef\u8c03\u76842\u30014\u30016\u7535\u5b50\u8fd8\u539f\u4e0e\u78b3-\u6c2e\u952e\u6784\u7b51\u76f8\u7ed3\u5408\uff0c\u53ef\u7528\u4e8e\u7532\u9170\u80fa\u3001\u7f29\u919b\u80fa\u548c\u7532\u80fa\u7c7b\u5316\u5408\u7269\u7684\u5408\u6210\u548c\u5236\u5907\uff0c\u8fd9\u4e9b\u662f\u5177\u6709\u9ad8\u9644\u52a0\u503c\u7684\u5316\u5de5\u4ea7\u54c1\u548c\u53ef\u751f\u7269\u964d\u89e3\u7684\u529f\u80fd\u6750\u6599\u3002\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201cBetaine Catalysis for Hierarchical Reduction of CO<sub>2<\/sub>\u00a0with Amines and Hydrosilane To Form Formamides, Aminals, and Methylamines\u201d\u53d1\u8868\u4e8eAngewandte\u00a0Chemie\u00a0International Edition\u4e0a\u3002\u3000<\/p>\n<p><strong><b>\u3010<\/b><\/strong><strong><b>\u56fe\u6587\u5bfc\u8bfb<\/b><\/strong><strong><b>\u3011<\/b><\/strong><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>1 <\/b><\/strong><strong><b>\u53cd\u5e94\u5f0f<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-86866\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/06\/\u65e0\u6807\u9898-3.jpg\" alt=\"\" width=\"600\" height=\"191\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/06\/\u65e0\u6807\u9898-3.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/06\/\u65e0\u6807\u9898-3-300x96.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u4e8c\u6c27\u5316\u78b3\u548c\u80fa\u7684\u8fd8\u539f\u529f\u80fd\u5316\uff0c\u53ef\u7528\u4e8e\u7532\u9170\u80fa\uff0c\u80fa\u57fa\u548c\u7532\u80fa<\/p>\n<p><strong><b>\u56fe2 <\/b><\/strong><strong><b>\u793a\u610f\u56fe<\/b><\/strong><strong><b><br \/>\n <\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-86867\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/06\/\u65e0\u6807\u98981.jpg\" alt=\"\" width=\"600\" height=\"527\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/06\/\u65e0\u6807\u98981.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/06\/\u65e0\u6807\u98981-300x264.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u4e8c\u6c27\u5316\u78b3\u548c\u80fa\u7684\u8fd8\u539f\u529f\u80fd\u5316\u53cd\u5e94\u9014\u5f84\u6709\u9009\u62e9\u6027\u5730\u63d0\u4f9b\u7532\u9170\u80fa\uff0c\u7532\u80fa\u548c\u6c28\u57fa\u5316\u5408\u7269<\/p>\n<p><strong><b>\u3010\u7814\u7a76\u5185\u5bb9\u3011<\/b><\/strong><\/p>\n<p>\u76ee\u524d\uff0c\u5168\u7403\u6bcf\u5e74\u5927\u7ea6\u6709180 MT\u7684\u4e8c\u6c27\u5316\u78b3\u7528\u4e8e\u5316\u5de5\u4ea7\u54c1\u7684\u5408\u6210\u3002\u7531\u4e8e\u4e8c\u6c27\u5316\u78b3\u70ed\u529b\u5b66\u4e0a\u7684\u4f4e\u80fd\u6001\uff0c\u80fd\u91cf\u662f\u5176\u8f6c\u5316\u5229\u7528\u7684\u57fa\u7840\uff1b\u53e6\u4e00\u65b9\u9762\uff0c\u4e8c\u6c27\u5316\u78b3\u5206\u5b50\u52a8\u529b\u5b66\u4e0a\u7684\u60f0\u6027\u51b3\u5b9a\u4e86\u6709\u6548\u5c06\u5176\u8f6c\u5316\u5fc5\u9700\u8fdb\u884c\u6d3b\u5316\uff0c\u800c\u6d3b\u5316\u7684\u5173\u952e\u53d6\u51b3\u4e8e\u9ad8\u6548\u50ac\u5316\u5242\u4f53\u7cfb\u3002\u4ee5\u4e8c\u6c27\u5316\u78b3\u5408\u6210\u5c3f\u7d20\u3001\u805a\u78b3\u9178\u916f\u3001\u73af\u72b6\u78b3\u9178\u916f\u3001\u7fa7\u9178\u916f\u7b49\u6709\u7528\u5316\u5b66\u54c1\u662f\u5b98\u80fd\u56e2\u5316\uff08\u529f\u80fd\u5316\uff09\u8fc7\u7a0b\uff0c\u4f46\u662f\u6ca1\u6709\u78b3\u7684\u4ef7\u6001\u53d8\u5316\u548c\u80fd\u91cf\u79ef\u7d2f\uff1b\u53e6\u4e00\u65b9\u9762\uff0c\u5c06\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u4e3a\u4e00\u6c27\u5316\u78b3\u3001\u7532\u9178\u3001\u7532\u9187\u3001\u7532\u919b\u3001\u7532\u70f7\u7b49\u6f5c\u5728\u71c3\u6599\uff0c\u5176\u8fd8\u539f\u529f\u80fd\u5316\u53ef\u4ee5\u66ff\u4ee3\u77f3\u6cb9\u5316\u5de5\u5236\u5907\u4f17\u591a\u7684\u5316\u5de5\u4ea7\u54c1\uff0c\u4f46\u5176\u57fa\u71c3\u6599\uff08\u8fd8\u539f\u4ea7\u7269\uff09\u7684\u5e02\u573a\u7ade\u4e89\u529b\u5219\u662f\u9700\u8981\u89e3\u51b3\u7684\u95ee\u9898\u3002<\/p>\n<p>\u201c\u4e8c\u6c27\u5316\u78b3\u901a\u8fc72\u7535\u5b50\u8fd8\u539f\u30016\u7535\u5b50\u8fd8\u539f\u8fc7\u7a0b\uff0c\u53ef\u4ee5\u5206\u522b\u5f97\u5230\u7532\u9170\u80fa\u3001\u7532\u80fa\u4ea7\u7269\uff1b\u4f46\u662f\uff0c\u5c06\u4e8c\u6c27\u5316\u78b3\u9009\u62e9\u6027\u5730\u901a\u8fc74\u7535\u5b50\u8fd8\u539f\u5236\u5907\u7f29\u919b\u80fa\u4ecd\u662f\u5177\u6709\u6311\u6218\u7684\u8bfe\u9898\uff0c\u540c\u65f6\u505a\u5230\u73af\u5883\u53cb\u597d\u5c31\u66f4\u96be\u4e86\u3002\u201d\u4f55\u826f\u5e74\u4ecb\u7ecd\uff0c\u5b66\u754c\u540c\u884c\u4e2d\uff0cCantat\u8bfe\u9898\u7ec4\u4e8e2015\u5e74\u9996\u6b21\u5b9e\u73b0\u5c06\u4e8c\u6c27\u5316\u78b34\u7535\u5b50\u8fd8\u539f\u81f3\u7532\u919b\u6c34\u5e73\uff0c\u968f\u540e\u4e0e\u80fa\u4f5c\u7528\u5f97\u5230\u7f29\u919b\u80fa\u4ea7\u7269\uff08ACS Catal., 2015, 5, 3983\uff09\u3002\u540c\u5e74\uff0cBontemps\u8bfe\u9898\u7ec4\u5b9e\u73b0\u94c1\u57fa\u7edc\u5408\u7269\u50ac\u5316\u8fd8\u539f\u4e8c\u6c27\u5316\u78b3\u81f3\u53cc\u787c\u6c27\u57fa\u7f29\u7532\u919b\u6216\u7532\u6c27\u57fa\u787c\u70f7\uff0c\u4e00\u9505\u4e24\u6b65\u5b9e\u73b0\u4e86CO<sub>2<\/sub>\u8fd8\u539f\u5230\u7532\u919b\u6c34\u5e73\u5e76\u6784\u7b51\u65b0\u952e\uff08J. Am. Chem. Soc., 2015, 137, 9563\uff09\u3002\u968f\u540e\uff0cLeitner\u8bfe\u9898\u7ec4\u53d1\u5c55\u4e86\u53cc\u7ec4\u4efd\u50ac\u5316\u4f53\u7cfb\uff0c\u5b9e\u73b0\u4e86\u76f4\u63a5\u5408\u6210\u4e8c\u7532\u6c27\u7532\u70f7\uff0c\u8fd9\u662f\u9996\u4f8b\u4e8c\u6c27\u5316\u78b3\u50ac\u5316\u6c22\u5316\u9009\u62e9\u6027\u5730\u8fd8\u539f\u53cd\u5e94\uff0c\u63a7\u5236\u5728\u7532\u919b\u6c34\u5e73\u7684\u62a5\u9053\uff08Angew. Chem. Int. Ed., 2016, 55, 12266\uff09\uff0c\u76ee\u524d\u5bf9\u4e8e\u5c06CO<sub>2<\/sub>\u9009\u62e9\u6027\u5730\u8fd8\u539f\u81f3\u7f29\u919b\u6c34\u5e73\u7684\u62a5\u9053\u5341\u5206\u6709\u9650\u3002<\/p>\n<p>\u4f55\u826f\u5e74\u6559\u6388\u8bfe\u9898\u7ec4\u53d1\u5c55\u4e86\u4e8c\u6c27\u5316\u78b3\u7684\u5206\u7ea7\u53ef\u63a7\u7684\u8fd8\u539f\u7b56\u7565\u3002\u4ed6\u4eec\u91c7\u7528\u56db\u4e01\u57fa\u6c1f\u5316\u80fa\u4f5c\u4e3a\u9ad8\u6d3b\u6027\u6709\u673a\u5c0f\u5206\u5b50\u50ac\u5316\u5242\uff0c\u5b9e\u73b0\u4e86\u80fa\u5b58\u5728\u4e0b\u4e8c\u6c27\u5316\u78b3\u7684\u8fd8\u539f\u529f\u80fd\u5316\uff0c\u5373\u4e8c\u6c27\u5316\u78b3\u76842\u62166\u7535\u5b50\u8fd8\u539f\u5e76\u540c\u65f6\u6784\u7b51\u78b3\u6c2e\u952e\u3002\u901a\u8fc7\u8c03\u8282\u7845\u70f7\u7c7b\u578b\uff0c\u53ef\u4ee5\u9009\u62e9\u6027\u83b7\u5f97\u7532\u9170\u80fa\u6216\u6df1\u5ea6\u8fd8\u539f\u4ea7\u7269\u7532\u80fa\u7c7b\u5316\u5408\u7269\u3002\u5f53\u4f7f\u7528\u4e09\u4e59\u6c27\u57fa\u7845\u70f7\u4f5c\u4e3a\u8fd8\u539f\u5242\u65f6\uff0c\u5728\u5e38\u6e29\u5e38\u538b\u4e0b\u53ef\u4ee5\u4e13\u4e00\u5730\u5f97\u5230\u7532\u9170\u80fa\u4ea7\u7269\uff1b\u800c\u5f53\u4f7f\u7528\u6d3b\u6027\u66f4\u9ad8\u7684\u82ef\u7845\u70f7\u65f6\uff0c50\u2103\u65f6\u4ee5\u9ad8\u8fbe99%\u7684\u6536\u7387\u5236\u5907\u7532\u80fa\u7c7b\u5316\u5408\u7269\u3002\u4ed6\u4eec\u6210\u529f\u5730\u5206\u79bb\u5f97\u5230\u7532\u9170\u5316\u53cd\u5e94\u4e2d\u7684\u5173\u952e\u4e2d\u95f4\u4f53\u7532\u9178\u7845\u916f\uff0c\u57fa\u4e8e\u6b64\u63d0\u51fa\u4e86\u6c1f\u79bb\u5b50\u4fc3\u8fdb\u7684\u4ece\u6c22\u7845\u70f7\u5230\u4e8c\u6c27\u5316\u78b3\/\u7532\u9170\u80fa\u7684\u8d1f\u6c22\u8f6c\u79fb\u673a\u7406\u3002\u8be5\u6210\u679c\u53d1\u8868\u5728Chem. Eur. J. 2016, 22, 16489\u4e0a\uff0c\u5e76\u88ab\u8bc4\u4e3a\u70ed\u70b9\u8bba\u6587\uff0c\u9009\u4f5c\u5c01\u9762\u6587\u7ae0\u3002<\/p>\n<p>\u57fa\u4e8e\u6c1f\u5316\u7269\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\u4ee5\u53ca\u6c27\u5177\u6709\u6c1f\u7c7b\u4f3c\u7684\u4eb2\u7845\u6027\u80fd\uff0c\u4f55\u826f\u5e74\u8bfe\u9898\u7ec4\u8fdb\u4e00\u6b65\u7b5b\u9009\u4e86\u78b3\u9178\u76d0\u3001\u9187\u76d0\u3001\u7fa7\u9178\u76d0\u3001\u6c22\u6c27\u5316\u7269\u7b49\u4e00\u7cfb\u5217\u50ac\u5316\u5242\uff0c\u53d1\u73b0\u7532\u9178\u76d0\u50ac\u5316\u6548\u679c\u6700\u597d\uff0c\u8fd9\u53ef\u80fd\u662f\u56e0\u4e3a\u5176\u5408\u9002\u7684\u4eb2\u7845\u6027\u80fd\uff0c\u76f8\u5173\u6210\u679c\u53d1\u8868\u4e8eGreen Chem., 2017, 19, 1726-1731\u4e0a\u3002\u201c\u8fd9\u662f\u4e00\u4f8b\u65e0\u91d1\u5c5e\u3001\u73af\u5883\u53cb\u597d\u7684\u50ac\u5316\u8fc7\u7a0b\uff0c\u4ee5\u4e8c\u82ef\u57fa\u7845\u70f7\u4e3a\u8fd8\u539f\u5242\u5c06\u4e8c\u6c27\u5316\u78b36\u7535\u5b50\u8fd8\u539f\u80fa\u5316\u81f3\u7532\u9187\u6c34\u5e73\uff0c\u5373\u83b7\u5f97\u80fa\u7684\u7532\u57fa\u5316\u4ea7\u7269\u3002\u4f55\u826f\u5e74\u4ecb\u7ecd\u3002\u201d<\/p>\n<p>\u901a\u8fc7\u63a7\u5236\u5b9e\u9a8c\uff0c\u8bfe\u9898\u7ec4\u53d1\u73b0\uff0c\u4e09\u7532\u94f5\u4e59\u5185\u916f\u53ef\u7528\u4f5c\u9ad8\u6548\u3001\u53ef\u6301\u7eed\u7684\u6709\u673a\u5c0f\u5206\u5b50\u50ac\u5316\u5242\u7528\u4e8e\u80fa\u548c\u4e8c\u82ef\u57fa\u7845\u70f7\u5b58\u5728\u4e0b\u4e8c\u6c27\u5316\u78b3\u7684\u8fd8\u539f\u529f\u80fd\u5316\u53cd\u5e94\uff0c\u5b9e\u73b0\u5206\u7ea7\u53ef\u63a7\u5730\u8fd8\u539f\u4e8c\u6c27\u5316\u78b3\u3002\u5229\u7528\u8fd9\u4e00\u7b56\u7565\uff0c\u901a\u8fc7\u8c03\u8282\u4e8c\u6c27\u5316\u78b3\u7528\u91cf\u548c\u53cd\u5e94\u6e29\u5ea6\uff0c\u53ef\u63a7\u5730\u83b7\u5f97\u4e0d\u540c\u80fd\u91cf\u7ea7\u522b\u7684\u8fd8\u539f\u4ea7\u7269\uff0c\u5982\u7532\u9170\u80fa\u3001\u7f29\u919b\u80fa\u548c\u7532\u80fa\u3002\u5728\u5e38\u538b\u300170\u2103\u53cd\u5e94\uff0c\u4e13\u4e00\u5730\u5f62\u6210\u7532\u80fa\u5316\u5408\u7269\uff1b\u572810\u4e2a\u6807\u51c6\u5927\u6c14\u538b\u300150\u2103\u53cd\u5e94\uff0c\u5219\u83b7\u5f97\u7532\u9170\u5316\u4ea7\u7269\uff1b\u5f53\u964d\u4f4e\u4e8c\u6c27\u5316\u78b3\u7528\u91cf\u4e3a1\u5f53\u91cf\u65f6\uff0c\u9ad8\u9009\u62e9\u6027\u5730\u5f97\u5230\u7f29\u919b\u80fa\u3002<\/p>\n<p>\u8fd9\u4ee3\u8868\u7740\u4e8c\u6c27\u5316\u78b3\u80fd\u88ab\u5206\u7ea7\u53ef\u63a7\u5730\u8fd8\u539f\u5230\u7532\u9178\u3001\u7532\u919b\u548c\u7532\u9187\u6c34\u5e73\u3002\u8fc4\u4eca\u4e3a\u6b62\uff0c\u4e8c\u6c27\u5316\u78b3\u5206\u7ea7\u53ef\u63a7\u8fd8\u539f\u5f97\u5230\u7532\u9170\u80fa\u3001\u7f29\u919b\u80fa\u548c\u7532\u80fa\u7c7b\u5316\u5408\u7269\u5c1a\u672a\u89c1\u62a5\u9053\u3002\u540c\u65f6\u901a\u8fc7\u5173\u952e\u4e2d\u95f4\u4f53\u7f29\u919b\u80fa\u7684\u5206\u79bb\u9274\u5b9a\uff0c\u63d0\u51fa\u4e86\u4e00\u79cd\u65b0\u9896\u7684\u7ecf\u5386\u7f29\u919b\u80fa\u7684\u7532\u57fa\u5316\u53cd\u5e94\u8def\u5f84\u3002\u8fd9\u4e00\u7b56\u7565\u628a\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u548c\u6784\u7b51\u78b3\u6c2e\u952e\u7ed3\u5408\u8d77\u6765\uff0c\u5408\u6210\u4e86\u591a\u79cd\u901a\u5e38\u6765\u81ea\u4e8e\u77f3\u6cb9\u539f\u6599\u7684\u5316\u5b66\u54c1\u548c\u50a8\u80fd\u6750\u6599\uff0c\u6269\u5927\u4e86\u76f4\u63a5\u4ece\u4e8c\u6c27\u5316\u78b3\u83b7\u53d6\u5316\u5408\u7269\u7684\u8303\u56f4\uff0c\u5c06\u4f1a\u5728\u4e00\u5b9a\u7a0b\u5ea6\u4ee3\u66ff\u73b0\u6709\u7684\u77f3\u6cb9\u5316\u5b66\u5de5\u4e1a\uff0c\u5177\u6709\u5de8\u5927\u7684\u53d1\u5c55\u6f5c\u529b\u3002\u8be5\u7814\u7a76\u6210\u679c\u53d1\u8868\u4e8e\u9876\u7ea7\u671f\u520aAngew. Chem. Int. Ed.\uff0cDOI\uff1a10.1002\/anie.201702734\u4e0a\uff0c\u5ba1\u7a3f\u4eba\u5bf9\u8be5\u6210\u679c\u505a\u51fa\u8bc4\u4ef7\uff1a\u5c3d\u7ba1\u4e8c\u6c27\u5316\u78b3\u53c2\u4e0e\u7684\u8fd8\u539f\u8f6c\u5316\u53cd\u5e94\u5df2\u6709\u8bf8\u591a\u62a5\u9053\uff0c\u4f46\u8fd9\u4efd\u5de5\u4f5c\u4ecd\u662f\u975e\u5e38\u503c\u5f97\u5173\u6ce8\u7684\uff0c\u8fd9\u662f\u56e0\u4e3a\u5229\u7528\u8fd9\u4e00\u5206\u7ea7\u8fd8\u539f\u7b56\u7565\uff0c\u53ef\u63a7\u5730\u83b7\u5f97\u4e0d\u540c\u80fd\u91cf\u7ea7\u522b\u7684\u8fd8\u539f\u4ea7\u7269\uff0c\u8fd9\u4ee3\u8868\u7740\u4e8c\u6c27\u5316\u78b3\u80fd\u88ab\u5206\u7ea7\u53ef\u63a7\u5730\u8fd8\u539f\u5230\u7532\u9178\u3001\u7532\u919b\u548c\u7532\u9187\u6c34\u5e73\u3002\u5c24\u5176\u503c\u5f97\u5173\u6ce8\u7684\u662f\uff0c\u8fd9\u4e00\u7b56\u7565\u5b9e\u73b0\u4e86\u4ee5\u5f80\u88ab\u8ba4\u4e3a\u6781\u5177\u6311\u6218\u7684\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u5230\u7532\u919b\u6c34\u5e73\u3002\u603b\u4e4b\uff0c\u4f5c\u8005\u5c55\u793a\u4e86\u4e00\u79cd\u6709\u8da3\u7684\u4e8c\u6c27\u5316\u78b3\u5206\u7ea7\u8fd8\u539f\u7b56\u7565\uff0c\u628a\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u548c\u6784\u7b51\u78b3\u6c2e\u952e\u7ed3\u5408\u8d77\u6765\uff0c\u5408\u6210\u4e86\u591a\u79cd\u901a\u5e38\u6765\u81ea\u4e8e\u77f3\u6cb9\u539f\u6599\u7684\u5316\u5b66\u54c1\u548c\u50a8\u80fd\u6750\u6599\u3002<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1a<a href=\"http:\/\/chem.nankai.edu.cn\/ejymzhylm.aspx?t=4&amp;m=5&amp;n=3172\" target=\"_blank\" rel=\"noopener noreferrer\">http:\/\/chem.nankai.edu.cn\/ejymzhylm.aspx?t=4&amp;m=5&amp;n=3172<\/a><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201702734\/full\" target=\"_blank\" rel=\"noopener noreferrer\">Betaine Catalysis for Hierarchical Reduction of CO<sub>2<\/sub>\u00a0with Amines and Hydrosilane To Form Formamides, Aminals, and Methylamines<\/a>\u00a0(Angew. Chem. Int. Ed., 2017, DOI\uff1a10.1002\/anie.201702734)<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u77f3\u5c0f\u6885\u7f16\u8f91\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" rel=\"noopener noreferrer\">\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener noreferrer\">\u6d4b\u8bd5\u8c37<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u6210\u679c\u7b80\u4ecb\u3011 \u7eff\u6c34\u9752\u5c71\u5c31\u662f\u91d1\u5c71\u94f6\u5c71\u3002\u6709\u6548\u5229\u7528\u8d44\u6e90\u4fdd\u62a4\u73af\u5883\uff0c\u53d1\u5c55\u7eff\u8272\u5316\u5b66\u6210\u4e3a\u5927\u52bf\u6240\u8d8b\u3002\u4e8c\u6c27\u5316\u78b3\u662f\u6700\u4e3b\u8981\u7684\u6e29\u5ba4\u6c14\u4f53\uff0c\u540c\u65f6\u4e5f\u662f\u50a8\u91cf\u4e30\u5bcc\u3001\u5b89\u5168\u53ef\u9760\u7684\u53ef\u518d\u751f\u8d44\u6e90\uff0c\u901a\u8fc7\u5316\u5b66&#8230;<\/p>\n","protected":false},"author":2832,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-86862","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/86862"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2832"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=86862"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/86862\/revisions"}],"predecessor-version":[{"id":87174,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/86862\/revisions\/87174"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=86862"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=86862"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=86862"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}