{"id":86444,"date":"2017-06-18T06:30:01","date_gmt":"2017-06-17T22:30:01","guid":{"rendered":"\/\/m.iemloyee.com\/?p=86444"},"modified":"2017-06-16T20:26:12","modified_gmt":"2017-06-16T12:26:12","slug":"%e5%8e%a6%e9%97%a8%e5%a4%a7%e5%ad%a6%e5%8c%96%e5%ad%a6%e5%8c%96%e5%b7%a5%e5%ad%a6%e9%99%a2%ef%bc%9a10%e7%a2%b3%e9%be%99%e5%88%86%e5%ad%90%e9%aa%a8%e6%9e%b6%e7%9a%84%e6%9e%84%e7%ad%91%e5%8f%96%e5%be%97","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=86444","title":{"rendered":"\u53a6\u95e8\u5927\u5b66\u5316\u5b66\u5316\u5de5\u5b66\u9662\uff1a10\u78b3\u9f99\u5206\u5b50\u9aa8\u67b6\u7684\u6784\u7b51\u53d6\u5f97\u6700\u65b0\u7814\u7a76\u6210\u679c"},"content":{"rendered":"<p><strong><b>\u3010<\/b><\/strong><strong><b>\u6210\u679c\u7b80\u4ecb<\/b><\/strong><strong><b>\u3011<\/b><\/strong><\/p>\n<p>\u53a6\u95e8\u5927\u5b66\u539f\u521b\u7684\u201c\u78b3\u9f99\u5316\u5b66\uff08Carbolong Chemistry\uff09\u201d\u518d\u6b21\u53d6\u5f97\u91cd\u8981\u8fdb\u5c55\uff0c\u5f15\u5165\u8fc7\u6e21\u91d1\u5c5e\u66ff\u4ee3\u6709\u673a\u4e09\u5e76\u4e94\u5143\u73af\u9aa8\u67b6IV\u2019\u7684\u4e2d\u5fc3sp<sup>3<\/sup>\u6742\u5316\u78b3\u539f\u5b50\uff0c\u9996\u6b21\u5408\u6210\u5f97\u5230\u91d1\u5c5e\u5904\u4e8e\u6865\u5934\u4f4d\u7684\u4e09\u5e76\u4e94\u5143\u73af\u5206\u5b50\u9aa8\u67b6\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cSynthesis and Characterization of a Metallacyclic Framework with Three Fused Five-membered Rings\u201d\u4e3a\u9898\u53d1\u8868\u4e8eAngewandte Chemie International Edition\u4e0a\u3002\u8be5\u5de5\u4f5c\u9996\u6b21\u62a5\u9053\u4e8610\u78b3\u9f99\u4e0e\u8fc7\u6e21\u91d1\u5c5e\u87af\u5408\u800c\u6210\u7684\u4e09\u5e76\u4e94\u5143\u73af\u5206\u5b50\u9aa8\u67b6\u3002<\/p>\n<p><strong><b>\u3010<\/b><\/strong><strong><b>\u56fe\u6587\u5bfc\u8bfb<\/b><\/strong><strong><b>\u3011<\/b><\/strong><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>1 \u5177\u6709\u7a20\u5408\u4e94\u5143\u73af\u7684\u591a\u73af\u7edc\u5408\u7269\u7684\u793a\u610f\u56fe<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-86445\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/06\/201706121707277296.jpg\" alt=\"\" width=\"600\" height=\"99\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/06\/201706121707277296.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/06\/201706121707277296-300x50.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>\u56fe2 \u590d\u5408\u72692a\u548ct-bunc\u7684\u53cd\u5e94<\/b><\/strong><strong><b>\u793a\u610f\u56fe<\/b><\/strong><strong><b><br \/>\n <\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-86631\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/06\/\u65e0\u6807\u9898-2.jpg\" alt=\"\" width=\"600\" height=\"294\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/06\/\u65e0\u6807\u9898-2.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/06\/\u65e0\u6807\u9898-2-300x147.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>\u3010\u7814\u7a76\u5185\u5bb9\u3011<\/b><\/strong><\/p>\n<p>\u8fd1\u5e74\uff0c\u8be5\u9662\u7cfb\u5217\u62a5\u9053\u4e86\u4e00\u7c7b\u5168\u65b0\u7684\u82b3\u9999\u4f53\u7cfb\u2014\u2014\u91d1\u5c5e\u6742\u620a\u642d\u7094(Nature Chem., 2013, 5, 698; ACIE, 2015, 54, 7189)\u548c\u91d1\u5c5e\u6742\u620a\u642d\u70ef(Nat. Commun., 2014, 5, 3265)\u3002\u5728\u6b64\u57fa\u7840\u4e0a\uff0c\u4e00\u7cfb\u5217\u91d1\u5c5e\u6865\u4f4d\u591a\u73af\u5206\u5b50\u9aa8\u67b6\u88ab\u62a5\u9053\uff0c\u5305\u62ec\uff1a\u91d1\u5c5e\u6742\u620a\u642d\u70ef\u5e76\u4e09\u5143\u73afII (ACIE, 2015, 54, 3102)\u3001\u91d1\u5c5e\u6742\u620a\u642d\u70ef\u5e76\u56db\u5143\u73afIII (ACIE, 2015, 54, 6181)\u3001\u91d1\u5c5e\u6742\u620a\u642d\u70ef\u5e76\u516d\u5143\u73afV (Sci. Adv. 2016, 2, e1601031)\u7b49\u3002\u8fd9\u662f\u4e00\u7c7b\u5168\u65b0\u5206\u5b50\u9aa8\u67b6\u57fa\u5143\uff0c\u53ef\u5206\u522b\u770b\u6210\u75317\u30018\u30019\u300112\u4e2a\u78b3\u539f\u5b50\u7ec4\u6210\u7684\u7eaf\u78b3\u94fe(Carbolong)\u4e0e\u8fc7\u6e21\u91d1\u5c5e\u7684\u87af\u5408\u7269\u3002\u56e0\u6b64\uff0c\u8be5\u6821\u9010\u6b65\u5efa\u7acb\u4e86\u72ec\u7279\u7684\u201c\u78b3\u9f99\u5316\u5b66\u201d(the chemistry of Carbolong)\u3002\u7136\u800c\uff0c\u78b3\u9f99\u5bb6\u65cf\u7684\u91cd\u8981\u6210\u5458\uff0c\u753110\u4e2a\u7eaf\u78b3\u539f\u5b50\u4e0e\u8fc7\u6e21\u91d1\u5c5e\u87af\u5408\u7684\u4e09\u5e76\u4e94\u5143\u73af\u9aa8\u67b6IV\u5374\u4e00\u76f4\u672a\u89c1\u62a5\u9053\u3002<\/p>\n<p>\u5728\u7ecf\u5178\u6709\u673a\u5316\u5b66\u4e2d\uff0c\u56e0\u4e3a\u4e2d\u5fc3\u78b3\u539f\u5b50\u7684sp<sup>3<\/sup>\u6742\u5316\uff0c\u7531\u5168\u78b3\u539f\u5b50\u7ec4\u6210\u7684\u4e09\u5e76\u4e94\u5143\u73af\u9aa8\u67b6IV\u2019\u662f\u975e\u5e73\u9762\u7684\uff0c\u81f3\u4eca\u4ecd\u672a\u89c1\u62a5\u9053\u3002\u672c\u6587\u62a5\u9053\u5f15\u5165\u8fc7\u6e21\u91d1\u5c5e\u66ff\u4ee3\u6709\u673a\u4e09\u5e76\u4e94\u5143\u73af\u9aa8\u67b6IV\u2019\u7684\u4e2d\u5fc3sp<sup>3<\/sup>\u6742\u5316\u78b3\u539f\u5b50\uff0c\u9996\u6b21\u5408\u6210\u5f97\u5230\u91d1\u5c5e\u5904\u4e8e\u6865\u5934\u4f4d\u7684\u4e09\u5e76\u4e94\u5143\u73af\u5206\u5b50\u9aa8\u67b6\u3002\u753110\u4e2a\u78b3\u539f\u5b50\u7ec4\u6210\u7684\u7eaf\u78b3\u94fe\u4e0e\u8fc7\u6e21\u91d1\u5c5e\u87af\u5408\u7684\u5206\u5b50\u9aa8\u67b6IV\u662f\u78b3\u9f99\u5316\u5b66\u7684\u91cd\u8981\u4e00\u73af\u3002<\/p>\n<p>\u8be5\u5de5\u4f5c\u662f\u5728\u590f\u6d77\u5e73\u6559\u6388\u6307\u5bfc\u4e0b\uff0c\u4e3b\u8981\u7531\u80fd\u6e90\u6750\u6599\u5316\u5b66\u534f\u540c\u521b\u65b0\u4e2d\u5fc3\u51fa\u7ad9\u535a\u58eb\u540e\u6731\u4ece\u9752\uff08\u7b2c\u4e00\u4f5c\u8005\uff09\u5b8c\u6210\u3002\u7406\u8bba\u8ba1\u7b97\u90e8\u5206\u5f97\u5230\u5316\u5b66\u5316\u5de5\u5b66\u9662\u5415\u946b\u6559\u6388\u3001\u6731\u519b\u526f\u6559\u6388\u7684\u5927\u529b\u652f\u6301\u3002\u8be5\u7814\u7a76\u5de5\u4f5c\u5f97\u5230\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u59d4\u7b49\u9879\u76ee\u7684\u652f\u6301\u3002<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1a<a href=\"http:\/\/chem.xmu.edu.cn\/show.asp?id=2197\" target=\"_blank\" rel=\"noopener noreferrer\">http:\/\/chem.xmu.edu.cn\/show.asp?id=2197<\/a><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201704057\/full\" target=\"_blank\" rel=\"noopener noreferrer\">Synthesis and Characterization of a Metallacyclic Framework with Three Fused Five-membered Rings <\/a>(Angew. Chem. Int. Ed.,\u00a02017, DOI:10.1002\/anie.201704057)<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u77f3\u5c0f\u6885\u7f16\u8f91\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" rel=\"noopener noreferrer\">\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener noreferrer\">\u6d4b\u8bd5\u8c37<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u6210\u679c\u7b80\u4ecb\u3011 \u53a6\u95e8\u5927\u5b66\u539f\u521b\u7684\u201c\u78b3\u9f99\u5316\u5b66\uff08Carbolong Chemistry\uff09\u201d\u518d\u6b21\u53d6\u5f97\u91cd\u8981\u8fdb\u5c55\uff0c\u5f15\u5165\u8fc7\u6e21\u91d1\u5c5e\u66ff\u4ee3\u6709\u673a\u4e09\u5e76\u4e94\u5143\u73af\u9aa8\u67b6IV\u2019\u7684\u4e2d\u5fc3sp3\u6742\u5316\u78b3\u539f&#8230;<\/p>\n","protected":false},"author":2832,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-86444","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/86444"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2832"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=86444"}],"version-history":[{"count":6,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/86444\/revisions"}],"predecessor-version":[{"id":86919,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/86444\/revisions\/86919"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=86444"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=86444"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=86444"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}