{"id":86401,"date":"2017-06-15T06:30:30","date_gmt":"2017-06-14T22:30:30","guid":{"rendered":"\/\/m.iemloyee.com\/?p=86401"},"modified":"2017-06-13T10:10:04","modified_gmt":"2017-06-13T02:10:04","slug":"jacs%ef%bc%9a%e9%87%91%e5%b1%9e%e6%9c%89%e6%9c%ba%e9%aa%a8%e6%9e%b6%e5%9f%ba%e7%a2%b3%e7%ba%b3%e7%b1%b3%e7%ae%a1%e7%9a%84%e5%ae%9a%e5%90%91%e5%bd%a2%e6%88%90","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=86401","title":{"rendered":"JACS\uff1a\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u57fa\u78b3\u7eb3\u7c73\u7ba1\u7684\u5b9a\u5411\u5f62\u6210"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u78b3\u7eb3\u7c73\u7ba1\uff08CNT\uff09\u662f\u91cd\u8981\u7684\u540c\u7d20\u5f02\u5f62\u4f53\u78b3\u7eb3\u7c73\u7ba1\uff0c\u5177\u6709\u76f4\u5f84\u8303\u56f4\u4ece1\u5230\u6570\u5341\u7eb3\u7c73\uff0c\u957f\u5ea6\u8303\u56f4\u4ece\u51e0\u5fae\u7c73\u5230\u51e0\u5398\u7c73\u7684\u5706\u67f1\u5f62\u7ed3\u6784\u3002\u5728\u8fc7\u53bb\u7684\u51e0\u5341\u5e74\u4e2d\uff0cCNT\u663e\u793a\u51fa\u5de8\u5927\u7684\u6f5c\u529b\u903b\u8f91\u7535\u8def\uff0c\u6c14\u4f53\u5b58\u50a8\uff0c\u50ac\u5316\u548c\u80fd\u91cf\u5b58\u50a8\uff0c\u56e0\u4e3a\u5b83\u4eec\u5177\u6709\u975e\u51e1\u7684\u7535\u5b50\uff0c\u673a\u68b0\u548c\u7ed3\u6784\u6027\u80fd\u3002\u7136\u800c\uff0cCNT\u5408\u6210\u4e2d\u7684\u6df7\u6c8c\u6869\uff0c\u9ad8\u6210\u672c\u548c\u9ad8\u8017\u80fd\u7684\u95ee\u9898\u4ecd\u6709\u5f85\u89e3\u51b3\u3002\u5728\u8fd9\u91cc\uff0c\u5f00\u53d1\u4e86\u4e00\u79cd\u5bb9\u6613\u7684\uff0c\u4e00\u822c\u7684\u548c\u9ad8\u4ea7\u91cf\u7684\u7b56\u7565\uff0c\u7528\u4e8e\u901a\u8fc7\u4f4e\u6e29\u7684\u70ed\u89e3\u8fc7\u7a0b\u4ece\u91d1\u5c5e-\u6709\u673a\u9aa8\u67b6\uff08MOF\uff09\u5411CNT\u5f62\u6210\u3002\u6240\u9009\u7684MOF\u6676\u4f53\u4f5c\u4e3a\u7eb3\u7c73\u50ac\u5316\u5242\u548c\u78b3\u6e90\u7684\u5355\u4e00\u524d\u4f53\u3002\u5f62\u6210CNT\u7684\u5173\u952e\u662f\u5728\u70ed\u89e3\u8fc7\u7a0b\u4e2d\u83b7\u5f97\u5177\u6709\u9ad8\u6d3b\u6027\u7684\u5c0f\u578b\u7eb3\u7c73\u50ac\u5316\u5242\u3002\u901a\u8fc7\u8c03\u8282\u76f8\u5e94\u7684MOF\uff0c\u8fdb\u4e00\u6b65\u5747\u5300\u5730\u5c06\u6742\u539f\u5b50\u5e76\u5165\u78b3\u7eb3\u7c73\u7ba1\u4e2d\uff0c\u6210\u529f\u5730\u6269\u5c55\u4e86\u8be5\u65b9\u6cd5\u4ee5\u83b7\u5f97\u5404\u79cd\u53d6\u5411\u7684CNT-\u7ec4\u88c5\u7ed3\u6784\u3002\u5177\u4f53\u6765\u8bf4\uff0c\u6c2e\u63ba\u6742\u7684CNT\u7ec4\u88c5\u7684\u4e2d\u7a7a\u7ed3\u6784\u5728\u80fd\u91cf\u8f6c\u6362\u548c\u5b58\u50a8\u4e24\u8005\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u6027\u80fd\u3002\u5728\u5b9e\u9a8c\u5206\u6790\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u6a21\u62df\u7684\u57fa\u7840\u4e0a\uff0c\u4f18\u8d8a\u7684\u6027\u80fd\u5f52\u529f\u4e8e\u7406\u60f3\u90e8\u4ef6\u4e0e\u591a\u7ea7\u7ed3\u6784\u4e4b\u95f4\u7684\u534f\u540c\u6548\u5e94\u3002\u53e6\u5916\uff0c\u78b3\u7eb3\u7c73\u7ba1\u4e2d\u5408\u9002\u7684\u77f3\u58a8N\u63ba\u6742\u548c\u9650\u5236\u91d1\u5c5e\u7eb3\u7c73\u7c92\u5b50\u90fd\u589e\u52a0\u4e86\u8d39\u7c73\u80fd\u7ea7\u9644\u8fd1\u7684\u72b6\u6001\u5bc6\u5ea6\uff0c\u964d\u4f4e\u4e86\u529f\u51fd\u6570\uff0c\u4ece\u800c\u6709\u6548\u5730\u63d0\u9ad8\u4e86\u5176\u6c27\u8fd8\u539f\u6d3b\u6027\u3002\u53ef\u884c\u7684\u5408\u6210\u7b56\u7565\u548c\u63d0\u51fa\u7684\u673a\u5236\u5c06\u523a\u6fc0\u8fb9\u7f18\u5730\u533a\u78b3\u7eb3\u7c73\u7ba1\u7684\u5feb\u901f\u53d1\u5c55\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6b66\u6c49\u7406\u5de5\u5927\u5b66\u9ea6\u7acb\u5f3a\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u53a6\u95e8\u5927\u5b66\u6731\u6893\u5fe0\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u5728JACS<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cOriented Formation of Carbon Nanotubes from Metal-Organic Frameworks<\/strong>\u201d \u7684\u6587\u7ae0\u3002\u8be5\u7814\u7a76\u56e2\u961f\u8bbe\u8ba1\u4e86\u4e00\u79cd\u5bb9\u6613\u548c\u9ad8\u4ea7\u91cf\u7684\u7b56\u7565\uff0c\u7528\u4e8e\u901a\u8fc7\u4f4e\u6e29\u7684\u70ed\u89e3\u8fc7\u7a0b\u4eceMOF\u901a\u5e38\u5bfc\u5411\u5f62\u6210CNT\u3002\u5728\u70ed\u89e3\u8fc7\u7a0b\u4e2d\uff0c\u4ea7\u751f\u7684\u8fd8\u539f\u6c14\u4f53\u9996\u5148\u5c06\u91d1\u5c5e\u79bb\u5b50\/\u7c07\u8f6c\u53d8\u6210\u91d1\u5c5e\u7eb3\u7c73\u50ac\u5316\u5242\uff1b\u7136\u540e\u8fd9\u4e9b\u7eb3\u7c73\u50ac\u5316\u5242\u8fdb\u4e00\u6b65\u50ac\u5316\u6b8b\u4f59\u7684\u6709\u673a\u5355\u5143\u4ee5\u5f62\u6210CNT\u3002\u901a\u5e38\u53ef\u4ee5\u901a\u8fc7MOF\u7684\u8c03\u5236\u6765\u5e94\u7528\u8be5\u7b56\u7565\u6765\u83b7\u5f97\u4e0d\u540c\u5f62\u6001\u4fdd\u5b58\u7684CNT-\u7ec4\u88c5\u7ed3\u6784\u3002\u5236\u5907\u7684\u7ed3\u6784\u5177\u6709\u9ad8\u6bd4\u8868\u9762\u79ef\uff0c\u53d7\u63a7\u63ba\u6742\u5242\uff0c\u5206\u5c42\u5b54\u9699\u548c\u7a33\u5b9a\u7684\u6846\u67b6\uff0c\u56e0\u6b64\u5bfc\u81f4\u9ad8\u6d3b\u6027\uff0c\u5feb\u901f\u7684\u8d28\u91cf\u8fd0\u8f93\u548c\u826f\u597d\u7684\u5e94\u53d8\u8c03\u8282\u3002\u56e0\u6b64\uff0c\u5e94\u7528\u4e8e\u80fd\u91cf\u8f6c\u6362\u548c\u50a8\u5b58\u65f6\uff0c\u4e0e\u5c01\u88c5\u5728N-CNT\u4e2d\u7684\u91d1\u5c5e\u548c\/\u6216\u91d1\u5c5e\u6c27\u5316\u7269\u7eb3\u7c73\u9897\u7c92\u7ec4\u88c5\u7684\u7ed3\u6784\u663e\u793a\u51fa\u4f18\u5f02\u7684\u6027\u80fd\u3002\u8be6\u7ec6\u7684\u5b9e\u9a8c\u5206\u6790\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u6a21\u62df\u8868\u660e\uff0c\u5408\u9002\u7684N\u63ba\u6742\u548c\u6709\u9650\u91d1\u5c5e\u7eb3\u7c73\u7c92\u5b50\u4e4b\u95f4\u7684\u534f\u540c\u6548\u5e94\u8d4b\u4e88\u4e86\u8be5\u7ed3\u6784\u5177\u6709\u51fa\u8272\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u8fdb\u4e00\u6b65\u4e86\u89e3\u4e86\u9650\u5236\u5728N-CNT\u4e2d\u7684\u91d1\u5c5e\u7eb3\u7c73\u7c92\u5b50\u7684\u7ed3\u6784-\u6027\u8d28\u76f8\u5173\u6027\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1 <\/strong>\u6cb8\u77f3\u54aa\u5511\u9178\u916f\u9aa8\u67b6\uff08<\/strong>ZIF-67<\/strong>\uff09\u7684<\/strong>N<\/strong>\u63ba\u6742<\/strong>CNT-<\/strong>\u7ec4\u88c5\u7684\u4e2d\u7a7a\u5341\u4e8c\u9762\u4f53\u7684\u5408\u6210\u548c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09ZIF-67\u7684N-CNTs\u5f62\u6210\u8fc7\u7a0b\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b-d\uff09ZIF-67\uff08b\uff09\u7684SEM\u56fe\u50cf\u548c\u5728435\u2103\u5728\u6c29\u6c14\u4e2d\u4f4e\u6e29\u70ed\u89e30.5h\uff08c\uff09\u548c8h\uff08d\uff09\u540e\u5236\u5907\u7684\u6837\u54c1\uff1b<\/p>\n

\uff08e-j\uff09N-CNT\u7ec4\u88c5\u7684\u4e2d\u7a7a\u5341\u4e8c\u9762\u4f53\u7684SEM\uff0cTEM\u548cHRTEM\u56fe\u50cf\u3002<\/p>\n

\u56fe<\/strong>2 <\/strong>\u5b9a\u5411\u5f62\u6210\u65b9\u6cd5\u7684\u5e7f\u6cdb\u6269\u5c55<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a1\uff09Co\uff0cFe-ZIF\u524d\u4f53\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08a2-a5\uff09Co\uff0cFe-ZIF\u884d\u751f\u7684N-CNT\u7ec4\u88c5\u7684\u5fae\u7403\u7684SEM\uff0cTEM\u548cHRTEM\u56fe\u50cf\uff1b<\/p>\n

\uff08b1\uff09Ni-ZIF\u524d\u4f53\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08b2-b5\uff09Ni-ZIF\u884d\u751f\u7684N-CNT\u7ec4\u88c5\u7684\u5fae\u7403\u7684SEM\uff0cTEM\u548cHRTEM\u56fe\u50cf\uff1b<\/p>\n

\uff08c1\uff09Co-BTC\u524d\u4f53\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08c2-c5\uff09Co-BTC\u884d\u751f\u7684CNT\u7ec4\u88c5\u7684\u5fae\u7247\u7684SEM\uff0cTEM\u548cHRTEM\u56fe\u50cf\uff1b<\/p>\n

\uff08d1\uff09Ni-BTC\u524d\u4f53\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08d2-d5\uff09Ni-BTC\u884d\u751f\u7684CNT\u7ec4\u88c5\u7684\u4e2d\u7a7a\u5fae\u7403\u7684SEM\uff0cTEM\u548cHRTEM\u56fe\u50cf\uff1b<\/p>\n

\uff08e1\uff09Co-MOF\u524d\u4f53\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08e2-e5\uff09Co-MOF\u884d\u751f\u7684CNT-\u7ec4\u88c5\u7684\u7eb3\u7c73\u68d2\u7684SEM\uff0cTEM\u548cHRTEM\u56fe\u50cf\uff1b<\/p>\n

\uff08f1\uff09Co-ZIF-67@Zn-ZIF-8\u524d\u4f53\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08f2-f5\uff09Co-ZIF-67@Zn-ZIF-8\u884d\u751f\u7684N-CNT\u7ec4\u88c5\u7684\u6838-\u58f3\u5341\u4e8c\u9762\u4f53\u7684SEM\uff0cTEM\u548cHRTEM\u56fe\u50cf\u3002<\/p>\n

\u56fe<\/strong>3 <\/strong>\u5c01\u88c5\u5728<\/strong>N-CNT<\/strong>\u4e2d\u7684\u91d1\u5c5e\u7eb3\u7c73\u7c92\u5b50\u7684<\/strong>ORR<\/strong>\u7535\u50ac\u5316\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5728O2<\/sub>\u9971\u548c\u76840.1MKOH\u4e2d\u7684N-CNTs-435\uff0cN-CNTs-550\uff0cN-CNTs-650\uff0cN-CNTs-750\u548cPt\/C\u7684LSV\u66f2\u7ebf\uff0c\u626b\u63cf\u901f\u7387\u4e3a5mVs-1<\/sup>\u548c1600rpm\uff1b<\/p>\n

\uff08b\uff09N-CNTs-650\u5728O2<\/sub>\u9971\u548c\u76840.1MKOH\u4e2d\u7684\u626b\u63cf\u901f\u7387\u4e3a5mVs-1<\/sup>\u548c\u4e0d\u540c\u65cb\u8f6c\u901f\u7387\u7684LSV\u66f2\u7ebf\uff1b<\/p>\n

\uff08c\uff09\u4e0d\u540c\u7535\u4f4d\u7684N-CNTs-650\u7684K-L\u56fe\uff1b<\/p>\n

\uff08d\uff09\u4f7f\u7528N-CNTs-650\u5728\u9971\u548c\u76840.1MKOH\u4e2d\u4ee51600rpm\u8bb0\u5f55\u7684RRDE\u4f0f\u5b89\u56fe\uff1b<\/p>\n

\uff08e\uff09\u57fa\u4e8eRRDE\u6570\u636e\u7684\u5404\u79cd\u7535\u4f4d\u7684N-CNTs-650\u7684\u8fc7\u6c27\u5316\u7269\u4ea7\u7387\u548c\u7535\u5b50\u6570\uff1b<\/p>\n

\uff08f\uff09N-CNTs-650\u548cPt\/C\u57281600rpm\u4e0b\u5728O2<\/sub>\u9971\u548c\u76840.1M KOH\u548c0.7V\u76f8\u5bf9\u4e8eRHE\u4e0b\u7684\u8ba1\u65f6\u7535\u6d41\uff08\u5f53\u524d\u65f6\u95f4\uff09\u54cd\u5e94\u3002<\/p>\n

\u56fe<\/strong>4<\/strong> N-CNTs<\/strong>\u6837\u54c1\u7684\u7279\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09N-CNTs-435\uff0cN-CNT-550\uff0cN-CNTs-650\u548cN-CNT-750\u4e2dC\uff0cN\u548cH\u7684\u76f8\u5bf9\u542b\u91cf\uff1b<\/p>\n

\uff08b\uff09N-CNTs-435\uff0cN-CNTs-550\uff0cN-CNTs-650\u548cN-CNT-750\u7684\u9ad8\u5206\u8fa8\u7387N1s<\/sub>XPS\u5149\u8c31\uff1b<\/p>\n

\uff08c\uff09\u5421\u5576N\uff0c\u5421\u54afN\u548c\u77f3\u58a8N\u7684\u76f8\u5e94\u542b\u91cf\uff1b<\/p>\n

\uff08d\uff09Co\u7eb3\u7c73\u9897\u7c92\u548cN-CNTs-650\u7684\u9ad8\u5206\u8fa8\u7387Co2p3\/2<\/sub>XPS\u5149\u8c31\uff1b<\/p>\n

\uff08e\uff09\u4f7f\u7528HeI\uff0821.2eV\uff09\u8f90\u5c04\u6536\u96c6\u7684UPS\u5149\u8c31\u3002\u63d2\u56fe\u663e\u793a\u4e8c\u6b21\u7535\u5b50\u5c3e\u9608\u503c\u7684\u653e\u5927\u89c6\u56fe\uff1b<\/p>\n

\uff08f\uff09\u9650\u5236\u5728N-CNTs\u4e2d\u7528\u4e8eORR\u8fc7\u7a0b\u7684Co\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe<\/strong>5 CNT<\/strong>\uff0c<\/strong>N-CNTs<\/strong>\u548c<\/strong>Co4 @ CNTs<\/strong>\u7684<\/strong>DFT<\/strong>\u6a21\u62df\u7ed3\u679c<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5355\u58c1CNTs\u793a\u610f\u56fe\uff088,0\uff09\uff1b<\/p>\n

\uff08b\uff09\u5177\u6709\u4e0d\u540c\u6c2e\u6e90\uff08\u77f3\u58a8N\uff0c\u5421\u5576N\u548c\u5421\u54afN\uff09\u548c\u5404\u79cd\u6c2e\u542b\u91cf\uff080-15\uff05\uff09\u7684\u7eaf\u78b3\u7eb3\u7c73\u7ba1\u548cN-CNTs\u7684\u5de5\u4f5c\u529f\u80fd\u6982\u8ff0\uff1b<\/p>\n

\uff08c\uff09\u5728\u8d39\u7c73\u80fd\u7ea7\u9644\u8fd1\uff0c\u8d39\u7c73\u80fd\u7ea7\u4e3a0eV\u7684\u7eafCNT\uff0c\u77f3\u58a8N-CNT\uff0c\u5421\u5576N-CNT\u548c\u5421\u54afN-CNT\u7684\u72b6\u6001\u7684\u8ba1\u7b97\u603b\u5bc6\u5ea6\uff1b<\/p>\n

\uff08d\uff09Co4<\/sub>@CNTs\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08e\uff09\u5728\u5782\u76f4\u4e8ec\u8f74\u7684\u5e73\u9762\u4e0a\u8ba1\u7b97\u7684\u9759\u7535\u7535\u4f4d\u5206\u5e03\u4e0e\u7eafCNT\u548cCo4<\/sub>@ CNT\u7684b\u8f74\u7684\u51fd\u6570\u5e73\u5747\u3002\u8d39\u7c73\u80fd\u7ea7\u57280eV\u4e0b\u5bf9\u9f50\uff1b<\/p>\n

\uff08e\uff09\u7684\u63d2\u56fe\u662f\uff08d\uff09\u7684\u622a\u9762\u56fe\uff0c\u663e\u793a\u4e86\u5185\u90e8Co4<\/sub>\u7eb3\u7c73\u7c07\u4e0e\u5916\u90e8CNT\u4e4b\u95f4\u7684\u7535\u5b50\u76f8\u4e92\u4f5c\u7528\uff1b<\/p>\n

\uff08f\uff09\u8ba1\u7b97\u7684\u7eafCNTs\u548cCo4<\/sub>@CNT\u7684\u6001\u7684\u603b\u5bc6\u5ea6\uff0c\u8d39\u7c73\u80fd\u7ea7\u57280eV\u4e0b\u6392\u5217\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5<\/strong>\uff1aGeneral Oriented Formation of Carbon Nanotubes from Metal-Organic Frameworks<\/a> (JACS\uff0c2017, \u00a0DOI: 10.1021\/jacs.7b01942\uff09<\/p>\n

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