{"id":85362,"date":"2017-06-08T06:30:23","date_gmt":"2017-06-07T22:30:23","guid":{"rendered":"\/\/m.iemloyee.com\/?p=85362"},"modified":"2017-10-17T23:15:20","modified_gmt":"2017-10-17T15:15:20","slug":"%e6%b8%85%e5%8d%8e%e5%a4%a7%e5%ad%a6%e9%ad%8f%e9%a3%9echem-soc-rev-%e7%bb%bc%e8%bf%b0%ef%bc%9a%e6%b0%b4%e5%b9%b3%e9%98%b5%e5%88%97%e7%8a%b6%e7%a2%b3%e7%ba%b3%e7%b1%b3%e7%ae%a1%e7%9a%84%e7%94%9f","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=85362","title":{"rendered":"\u6e05\u534e\u5927\u5b66\u9b4f\u98deChem. Soc. Rev.\u7efc\u8ff0\uff1a\u6c34\u5e73\u9635\u5217\u72b6\u78b3\u7eb3\u7c73\u7ba1\u7684\u751f\u957f\u673a\u7406\u3001\u53ef\u63a7\u5408\u6210\u3001\u8868\u5f81\u3001\u6027\u8d28\u548c\u5e94\u7528"},"content":{"rendered":"
\u3010\u5f15\u8a00\u3011<\/span><\/strong><\/p>\n \u81ea1991\u5e74\u88ab\u65e5\u672c\u79d1\u5b66\u5bb6Sumio Iijima\u62a5\u9053\u4ee5\u6765\uff0c\u78b3\u7eb3\u7c73\u7ba1(CNTs)\u5c31\u56e0\u5176\u4f18\u7f8e\u7684\u51e0\u4f55\u7ed3\u6784\u548c\u4f18\u5f02\u7684\u6027\u80fd\u53d7\u5230\u4e86\u79d1\u5b66\u754c\u548c\u4ea7\u4e1a\u754c\u7684\u5e7f\u6cdb\u5173\u6ce8\uff0c\u5e76\u5b9e\u73b0\u4e86\u5343\u5428\u7ea7\u7684\u91cf\u4ea7\u5236\u5907\u3002\u6839\u636e\u5f62\u8c8c\u7684\u5dee\u5f02\uff0cCNTs\u53ef\u5206\u4e3a\u56e2\u805a\u72b6\u78b3\u7eb3\u7c73\u7ba1\u3001\u5782\u76f4\u9635\u5217\u72b6\u78b3\u7eb3\u7c73\u7ba1\u548c\u6c34\u5e73\u9635\u5217\u72b6\u78b3\u7eb3\u7c73\u7ba1(HACNTs)3\u79cd\u3002HACNTs\u662f\u5728\u5e73\u6574\u57fa\u5e95\u4e0a\u751f\u957f\u7684\u5e73\u884c\u6392\u5217\u7684\u78b3\u7eb3\u7c73\u7ba1\u7c7b\u578b\uff0c\u80fd\u591f\u9075\u5faa\u81ea\u7531\u751f\u4ea7\u7684\u6a21\u5f0f\uff0c\u56e0\u6b64\u5177\u6709\u5b8c\u7f8e\u7ed3\u6784\u3001\u8d85\u4f4e\u7f3a\u9677\u7a0b\u5ea6\u3001\u5398\u7c73\u7ea7\u4ee5\u4e0a\u957f\u5ea6\u4ee5\u53ca\u4f18\u5f02\u7684\u7406\u5316\u6027\u8d28\uff0c\u662f\u900f\u660e\u663e\u793a\u3001\u5fae\u7535\u5b50\u3001\u91cf\u5b50\u7ebf\u3001\u573a\u53d1\u5c04\u6676\u4f53\u7ba1\u3001\u8d85\u5f3a\u7ea4\u7ef4\u3001\u822a\u7a7a\u822a\u5929\u7b49\u9886\u57df\u7684\u5c16\u7aef\u57fa\u7840\u6750\u6599\u3002\u5b9e\u73b0HACNTs\u7ed3\u6784\u7684\u53ef\u63a7\u5236\u5907\u53ca\u6027\u80fd\u8c03\u63a7\u662f\u8fd1\u5341\u51e0\u5e74\u6765\u78b3\u7eb3\u7c73\u7ba1\u9886\u57df\u7814\u7a76\u7684\u70ed\u70b9\u548c\u96be\u70b9\u3002<\/p>\n \u8fd1\u65e5\uff0c\u6e05\u534e\u5927\u5b66\u9b4f\u98de\u6559\u6388(\u901a\u8baf\u4f5c\u8005)<\/strong>\u7b49\u4eba\u5e94\u9080\u5728Chem. Soc. Rev.<\/b>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cHorizontally aligned carbon nanotube arrays: growth mechanism, controlled synthesis, characterization, properties and applications<\/b>\u201d\u7684\u7efc\u8ff0\u6587\u7ae0\u3002\u8be5\u6587\u7cfb\u7edf\u56de\u987e\u4e86\u8fc7\u53bb\u5341\u51e0\u5e74\u4e2dHACNTs\u5728\u751f\u957f\u673a\u7406\u3001\u53ef\u63a7\u5408\u6210\u3001\u8868\u5f81\u624b\u6bb5\u3001\u6027\u80fd\u8c03\u63a7\u4ee5\u53ca\u5e94\u7528\u7b49\u65b9\u9762\u53d6\u5f97\u7684\u7814\u7a76\u6210\u679c\uff0c\u5e76\u5bf9HACNTs\u672a\u6765\u53d1\u5c55\u9762\u4e34\u7684\u6311\u6218\u4ee5\u53ca\u673a\u9047\u3001\u65b0\u7684\u65b9\u5411\u505a\u51fa\u4e86\u5c55\u671b\u3002<\/p>\n \u7efc\u8ff0\u603b\u89c8\u56fe<\/strong><\/p>\n 1.\u7b80\u4ecb<\/span><\/strong><\/p>\n CNTs\u662f\u7531sp2<\/sup>\u6742\u5316\u7684C-C\u952e\u7ec4\u6210\u7684\uff0c\u5177\u6709\u529b\u5b66\u3001\u7535\u5b66\u3001\u70ed\u5b66\u3001\u58f0\u5b66\u3001\u5149\u5b66\u7b49\u591a\u65b9\u9762\u7684\u4f18\u5f02\u6027\u80fd\u548c\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\u3002\u7ecf\u8fc720\u591a\u5e74\u7684\u53d1\u5c55\uff0cCNTs\u7684\u7814\u7a76\u5df2\u7ecf\u4ece\u6700\u521d\u7684\u57fa\u672c\u7ed3\u6784\u548c\u6027\u8d28\u7684\u8868\u5f81\uff0c\u62d3\u5c55\u5230\u4e86\u5927\u89c4\u6a21\u5236\u5907\u53ca\u5e94\u7528\uff0c\u53d6\u5f97\u4e86\u4e00\u6279\u6807\u5fd7\u6027\u7684\u6210\u679c\u3002\u7136\u800c\u73b0\u6709\u7684CNTs\u53ca\u5176\u5e94\u7528\u5374\u8fdc\u672a\u5145\u5206\u53d1\u6325\u5176\u5e94\u6709\u7684\u6027\u80fd\uff0c\u8fd9\u4e3b\u8981\u662f\u56e0\u4e3a\u5236\u5907\u5177\u6709\u5b8c\u7f8e\u7ed3\u6784\u548c\u5b8f\u89c2\u5c3a\u5bf8\u7684CNTs\u7684\u5927\u89c4\u6a21\u5236\u5907\u6280\u672f\u8fd8\u4e0d\u6210\u719f\u3002HACNTs\u88ab\u8ba4\u4e3a\u662f\u66f4\u6613\u5b9e\u73b0\u5b8c\u7f8e\u7ed3\u6784\u548c\u5b8f\u89c2\u5c3a\u5bf8\u7684CNTs\u7c7b\u578b\uff0c\u56e0\u6b64\u4e00\u76f4\u662f\u78b3\u6750\u6599\u9886\u57df\u7814\u7a76\u7684\u70ed\u70b9\uff0c\u8fd1\u5e74\u6765\u5728\u5176\u53ef\u63a7\u5236\u5907\u7b49\u65b9\u9762\u53d6\u5f97\u4e86\u5f88\u591a\u91cd\u5927\u7684\u8fdb\u5c55\uff0c\u5982\u56fe1\u6240\u793a\uff0c\u4e3a\u5176\u5927\u89c4\u6a21\u5e94\u7528\u5960\u5b9a\u4e86\u4e00\u5b9a\u57fa\u7840\u3002\u5f53\u7136\u4e5f\u9762\u4e34\u5f88\u591a\u95ee\u9898\uff0c\u4f8b\u5982\u957f\u5ea6\u6709\u9650\u3001\u9762\u5bc6\u5ea6\u6781\u4f4e\u3001\u624b\u6027\u53ef\u63a7\u5dee\u7b49\u3002\u56e0\u6b64\uff0c\u68b3\u7406HACNTs\u5df2\u7ecf\u53d6\u5f97\u6210\u679c\uff0c\u5206\u6790\u5b58\u5728\u7684\u95ee\u9898\u548c\u539f\u56e0\uff0c\u63a2\u8ba8\u53ef\u80fd\u7684\u89e3\u51b3\u65b9\u6848\uff0c\u5bf9HACNTs\u7684\u540e\u7eed\u7814\u7a76\u5927\u6709\u88e8\u76ca\u3002<\/p>\n \u56fe1 HACNTs\u7684\u7ed3\u6784\u3001\u6027\u8d28\u3001\u5e94\u7528\u4ee5\u53ca\u8fd1\u5e74\u6765\u7684\u6807\u5fd7\u6027\u6210\u679c<\/strong><\/p>\n 2.HACNTs\u7684\u751f\u957f\u673a\u7406<\/strong><\/span><\/p>\n \u5408\u6210CNTs\u4e3b\u8981\u67093\u79cd\u65b9\u5f0f\uff1a\u7535\u5f27\u653e\u7535\u6cd5\u3001\u6fc0\u5149\u70e7\u8680\u6cd5\u548c\u5316\u5b66\u6c14\u76f8\u6c89\u79ef(CVD)\u3002\u5176\u4e2d\uff0cCVD\u6cd5\u7684\u53c2\u6570\u66f4\u6613\u63a7\u5236\u3001\u5177\u6709\u66f4\u4f4e\u7684\u53cd\u5e94\u6e29\u5ea6\u3001\u66f4\u6613\u5b9e\u73b0\u5b8f\u91cf\u5236\u5907\uff0c\u662f\u8fd1\u5e74\u6765\u5408\u6210CNTs\uff0c\u7279\u522b\u662fHACNTs\u7684\u4e3b\u6d41\u65b9\u6cd5\u3002\u56e0\u6b64\uff0c\u6df1\u5165\u7406\u89e3CVD\u6cd5\u5236\u5907CNTs\u7684\u751f\u957f\u673a\u7406\u5bf9\u5408\u6210\u7ed3\u6784\u548c\u5f62\u8c8c\u53ef\u63a7\u7684CNTs\u5177\u6709\u5341\u5206\u91cd\u8981\u7684\u610f\u4e49\u3002\u6839\u636e\u751f\u957f\u673a\u7406\u7684\u5dee\u5f02\uff0c\u4e3b\u8981\u67093\u79cd\uff1a\u57fa\u4e8e\u539f\u5b50\u5c42\u9762\u7684\u5f62\u6838\u957f\u5927\u673a\u7406\u3001\u57fa\u4e8e\u5206\u5b50\u5c42\u9762\u7684\u9876\u7aef\u548c\u5e95\u7aef\u751f\u957f\u6a21\u5f0f\u673a\u7406\u3001\u57fa\u4e8e\u9635\u5217\u5c42\u9762\u7684Schulz-Flory\u5206\u5e03\u751f\u957f\u673a\u7406\u3002<\/p>\n 2.1 CNTs\u7684\u5f62\u6838\u3001\u751f\u957f\u673a\u7406<\/strong><\/p>\n \u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u50ac\u5316\u7684CNTs\u751f\u957f\uff0c\u5f62\u6838\u662f\u7b2c\u4e00\u4e2a\u5173\u952e\u6b65\u9aa4\uff0c\u53ef\u4ee5\u5206\u4e3a3\u4e2a\u9636\u6bb5\uff1aC\u539f\u5b50\u7684\u6eb6\u89e3\u9636\u6bb5\u3001C\u539f\u5b50\u7684\u9ad8\u5ea6\u8fc7\u9971\u548c\u9636\u6bb5\u3001C\u539f\u5b50\u7684\u6790\u51fa\u548cCNTs\u7684\u751f\u957f\u9636\u6bb5\u3002\u5728CNTs\u7684\u5f62\u6838\u4e0e\u751f\u957f\u8fc7\u7a0b\u4e2d\uff0c\u7a33\u5b9a\u7684C\u6e90\u662f\u4fdd\u8bc1\u5176\u8fde\u7eed\u751f\u957f\u7684\u5173\u952e\uff0c\u5176\u4ed6\u7684\u5f71\u54cd\u56e0\u7d20\u8fd8\u6709\u6e29\u5ea6\u3001\u50ac\u5316\u5242\u7684\u79cd\u7c7b\u548c\u5c3a\u5bf8\u3001C\/\u91d1\u5c5e\u7684\u7ed3\u5408\u529b\u3001C\u7684\u6d53\u5ea6\u4e0e\u5206\u5e03\u3002\u5bf9\u4e8e\u5177\u6709\u87ba\u65cb\u7ed3\u6784\u7684CNTs\uff0c\u7814\u7a76\u8005\u63d0\u51fa\u4e86\u4e00\u79cd\u7c7b\u4f3c\u87ba\u578b\u4f4d\u9519\u7684\u7406\u8bba\u89e3\u91ca\u5176\u87ba\u65cb\u89d2\u8d8a\u5927\u751f\u957f\u8d8a\u5bb9\u6613\u7684\u751f\u957f\u884c\u4e3a\u3002\u5c3d\u7ba1\u8fc7\u6e21\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u53ef\u4ee5\u6709\u6548\u5730\u50ac\u5316CNTs\u7684\u751f\u957f\uff0c\u4f46\u5176\u5bf9HACNTs\u7684\u5e94\u7528\u4f1a\u9020\u6210\u4e00\u5b9a\u9650\u5236\uff0c\u7279\u522b\u662f\u5728\u5fae\u7eb3\u7535\u5b50\u9886\u57df\u3002\u56e0\u6b64\uff0c\u8bb8\u591a\u7814\u7a76\u8005\u4e5f\u4e13\u6ce8\u4e8e\u65e0\u91d1\u5c5e\u50ac\u5316\u7684CNTs\u5236\u5907\u3002<\/p>\n 2.2 HACNTs\u7684\u9876\u7aef\u751f\u957f\u548c\u5e95\u7aef\u751f\u957f\u673a\u7406<\/span><\/strong><\/p>\n 2.2.1 \u9876\u7aef\u751f\u957f\u6a21\u5f0f<\/strong><\/p>\n \u9876\u7aef\u751f\u957f(Tip-growth)\u6a21\u5f0f\u662f\u6307CNTs\u7684\u751f\u957f\u8fc7\u7a0b\u4e2d\uff0c\u5176\u50ac\u5316\u5242\u9897\u7c92\u4e00\u76f4\u4fdd\u6301\u5728\u78b3\u7eb3\u7c73\u7ba1\u7684\u9876\u7aef\uff0c\u5728\u6c14\u6d41\u7684\u5f15\u5bfc\u4e0b\u5e26\u52a8\u65b0\u751f\u6210\u7684\u78b3\u7eb3\u7c73\u7ba1\u4e0d\u65ad\u5411\u524d\u751f\u957f\uff0c\u5982\u56fe2\u6240\u793a\u3002\u5728CNTs\u7684CVD\u751f\u957f\u8fc7\u7a0b\u4e2d\uff0c\u7531\u4e8e\u53cd\u5e94\u6c14\u6d41\u548c\u57fa\u4f53\u4e4b\u95f4\u5b58\u5728\u4e00\u5b9a\u7684\u6e29\u5ea6\u5dee\uff0c\u56e0\u6b64\u4f1a\u5728\u5782\u76f4\u4e8e\u57fa\u4f53\u65b9\u5411\u4ea7\u751f\u4e00\u4e2a\u70ed\u6d6e\u529b\uff0c\u4f7f\u5f97\u90e8\u5206\u78b3\u7eb3\u7c73\u7ba1\u5e26\u50ac\u5316\u9897\u7c92\u4e00\u7aef\u79bb\u5f00\u57fa\u4f53\u8868\u9762\u6f02\u6d6e\u5728\u53cd\u5e94\u6c14\u6d41\u4e2d\uff0c\u5728\u6c14\u6d41\u7684\u5e26\u52a8\u4e0b\u4e0d\u65ad\u5411\u524d\u751f\u957f\u3002\u9876\u7aef\u751f\u957f\u6a21\u5f0f\u7684\u5173\u952e\u5c31\u662fCNTs\u751f\u957f\u7684\u521d\u59cb\u9636\u6bb5\uff0cCNTs\u7684\u4e00\u7aef\u5fc5\u987b\u79bb\u5f00\u57fa\u4f53\u8868\u9762\u3002<\/p>\n \u56fe2 \u9876\u7aef\u751f\u957f\u6a21\u5f0f\u793a\u610f\u56fe\u53ca\u5b9e\u8bc1<\/strong><\/p>\n (a)<\/strong>\u9876\u7aef\u751f\u957f\u673a\u7406\u793a\u610f\u56fe\uff1b<\/p>\n (b)<\/strong>\u9876\u7aef\u5177\u6709\u9897\u7c92\u7684\u5b9a\u5411\u957f\u7eb3\u7c73\u7ba1\u7684\u539f\u5b50\u529b\u663e\u5fae\u955c(AFM)\u56fe\uff1b<\/p>\n (c)<\/strong>\u5206\u522b\u5728\u8868\u9762\u548c\u7a7f\u8fc7\u72ed\u7f1d\u7684\u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1(SWCNTs)\u7684\u9ad8\u500d\u626b\u63cf\u7535\u5b50\u663e\u5fae\u955c(SEM)\u56fe\u3002\u6807\u5c3a:100\u03bcm\uff1b<\/p>\n (d-e)<\/strong>\u5206\u522b\u4e3a\u56fe(c)\u4e2d\u7ea2\u8272\u77e9\u5f62\u7684\u653e\u5927SEM\u56fe\uff0c\u663e\u793aSWCNTs\u7a7f\u8fc7\u4e86\u72ed\u7f1d\u7684\u4e24\u4e2a\u8fb9\u7f18\u3002\u6807\u5c3a:5\u03bcm\uff1b<\/p>\n (f)<\/strong>SWCNTs\u957f\u5927\u901a\u8fc7\u5fae\u5c0f\u969c\u788d\u7269\u7684SEM\u56fe\uff1b<\/p>\n (g)<\/strong>\u751f\u957f\u5728SiO2<\/sub>\/Si\u57fa\u4f53\u4e0a\u7684SMCNTs\u7684SEM\u56fe\u3002<\/p>\n 2.2.2 \u5e95\u7aef\u751f\u957f\u6a21\u5f0f<\/strong><\/p>\n \u9664\u4e86\u9876\u7aef\u751f\u957f\u6a21\u5f0f\uff0c\u5f88\u591a\u5b9e\u9a8c\u4e5f\u8bc1\u5b9e\u4e86\u5e95\u7aef\u751f\u957f\u6a21\u5f0f\u3002\u5e95\u7aef\u751f\u957f(Base-growth)\u6a21\u5f0f\u662f\u5728\u78b3\u7eb3\u7c73\u7ba1\u7684\u751f\u957f\u8fc7\u7a0b\u4e2d\uff0c\u50ac\u5316\u5242\u9897\u7c92\u5728\u57fa\u4f53\u4e0a\u4fdd\u6301\u4e0d\u52a8\uff0c\u65b0\u751f\u6210\u7684\u78b3\u7eb3\u7c73\u7ba1\u5728\u6574\u4e2a\u78b3\u7eb3\u7c73\u7ba1\u7684\u5e95\u7aef\u3002<\/p>\n 2.2.3 \u9876\u7aef\u751f\u957f\u4e0e\u5e95\u7aef\u751f\u957f\u7684\u5bf9\u6bd4<\/strong><\/p>\n \u5728\u8d85\u957f\u78b3\u7eb3\u7c73\u7ba1\u7684\u5236\u5907\u8fc7\u7a0b\u4e2d\uff0c\u9876\u7aef\u751f\u957f\u4e0e\u5e95\u7aef\u751f\u957f\u6a21\u5f0f\u662f\u5171\u5b58\u7684\u3002\u54ea\u79cd\u6a21\u5f0f\u5360\u636e\u4e3b\u5bfc\u5219\u53d6\u51b3\u4e8e\u5b9e\u9a8c\u6761\u4ef6\uff0c\u7279\u522b\u662f\u57fa\u4f53\u3002\u4e00\u822c\u5728\u77f3\u82f1\u57fa\u5e95\u4e0a\u5236\u5907\u7684HACNTs\u9075\u5faa\u5e95\u7aef\u751f\u957f\u6a21\u5f0f\uff0c\u800c\u5728\u7845\u7247\u4e0a\u5219\u9075\u5faa\u9876\u7aef\u751f\u957f\u6a21\u5f0f\u3002\u9876\u7aef\u751f\u957f\u53ef\u4ee5\u6d88\u9664\u57fa\u4f53\u5bf9CNTs\u751f\u957f\u7684\u5f71\u54cd\uff0c\u56e0\u6b64\u88ab\u8ba4\u4e3a\u66f4\u6709\u5229\u4e8e\u5236\u5907\u51fa\u7ed3\u6784\u5b8c\u7f8e\u3001\u751f\u957f\u901f\u5ea6\u5feb\u3001\u5177\u6709\u5b8f\u89c2\u957f\u5ea6\u6c34\u5e73\u7684HACNTs\uff1b\u4f46\u662f\u5e95\u7aef\u751f\u957f\u6a21\u5f0f\u5374\u66f4\u6613\u83b7\u5f97\u5177\u6709\u66f4\u9ad8\u9762\u5bc6\u5ea6\u7684HACNT\u9635\u5217\u3002<\/p>\n 2.3 HACNTs\u7684Schulz-Flory\u5206\u5e03\u751f\u957f\u673a\u7406<\/strong><\/p>\n \u4e0a\u8ff0\u4e24\u79cd\u673a\u7406\u53ef\u4ee5\u4ece\u539f\u5b50\u548c\u5206\u5b50\u5c42\u9762\u6210\u529f\u89e3\u91caCNTs\u7684\u751f\u957f\u8fc7\u7a0b\uff0c\u4f46\u5374\u4ec5\u9002\u7528\u4e8e\u5355\u6839\u78b3\u7eb3\u7c73\u7ba1\u7684\u751f\u957f\u8fc7\u7a0b\uff0c\u65e0\u6cd5\u89e3\u91ca\u78b3\u7eb3\u7c73\u7ba1\u6c34\u5e73\u9635\u5217\u7684\u7fa4\u4f53\u751f\u957f\u884c\u4e3a\u3002\u6e05\u534e\u5927\u5b66\u9b4f\u98de\u6559\u6388\u7b49\u5f15\u5165\u4e86Schulz-Flory\u5206\u5e03\u5f88\u597d\u5730\u89e3\u91ca\u4e86\u78b3\u7eb3\u7c73\u7ba1\u9635\u5217\u5c42\u9762\u7684\u751f\u957f\u8fc7\u7a0b\u548c\u673a\u7406\u3002<\/p>\n 2.3.1 Schulz-Flory\u5206\u5e03\u7684\u5b9a\u4e49\u4ee5\u53caHACNTs\u4e0e\u7ebf\u6027\u9ad8\u5206\u5b50\u7684\u76f8\u4f3c\u6027<\/strong><\/p>\n Schulz-Flory\u5206\u5e03\u662f\u4e00\u4e2a\u63cf\u8ff0\u7ebf\u6027\u9ad8\u5206\u5b50\u6570\u91cf\u5206\u5e03\u7684\u65b9\u7a0b\u5f0f\uff0c\u8868\u8fbe\u5f0f\u4e3aPx<\/sub>=px-1<\/sup>(1-p)\uff0c\u5176\u4e2dPx<\/sub>\u662f\u5355\u4f53\u6570\u4e3ax\u7684\u9ad8\u5206\u5b50\u94fe\u6240\u5360\u7684\u6bd4\u4f8b\uff0cp\u662f\u9ad8\u5206\u5b50\u94fe\u6bcf\u589e\u52a01\u4e2a\u5355\u4f53\u7684\u6982\u7387\uff0c1-p\u662f\u9ad8\u5206\u5b50\u94fe\u589e\u957f\u7ec8\u6b62\u7684\u6982\u7387\u3002\u53ef\u89c1\uff0c\u94fe\u8d8a\u957f\u7684\u9ad8\u5206\u5b50\u7684\u6bd4\u4f8b\u4f1a\u8d8a\u5c0f\u3002<\/p>\n CNTs\u53ef\u4ee5\u770b\u6210\u662fC\u539f\u5b50\u7ec4\u6210\u7684\u4e00\u7ef4\u87ba\u65cb\u72b6\u7ebf\u6027\u9ad8\u5206\u5b50\uff0c\u78b3\u7eb3\u7c73\u7ba1\u7684\u751f\u957f\u53ef\u4ee5\u770b\u6210\u662f\u4e00\u4e2aC\u539f\u5b50\u94fe\u7684\u5f62\u6210\u8fc7\u7a0b\u3002\u5bf9\u4e8eHACNTs\u751f\u957f\u6765\u8bf4\uff0c\u4e0d\u8003\u8651\u78b3\u6e90\u7684\u79cd\u7c7b\uff0c\u53ef\u4ee5\u8ba4\u4e3a\u6240\u6709\u7684\u78b3\u6e90\u5206\u5b50\u90fd\u6709\u76f8\u540c\u7684\u6d3b\u6027\u8fdb\u5165\u5230\u751f\u957f\u7684CNTs\u4e2d\uff0c\u662f\u4e00\u4e2a\u52a8\u529b\u5b66\u63a7\u5236\u7684\u8fc7\u7a0b\u3002\u6839\u636e\u9876\u7aef\u751f\u957f\u6a21\u5f0f\uff0c\u5728\u751f\u957f\u4e2d\u7684CNTs\u662f\u6ca1\u6709\u65b0\u7684\u5f62\u6838\u70b9\u7684\u3002\u56e0\u6b64\uff0c\u7406\u8bba\u4e0aHACNTs\u7684\u751f\u957f\u662f\u975e\u5e38\u7b26\u5408Schulz-Flory\u5206\u5e03\u5e94\u7528\u7684\u524d\u63d0\u7684\u3002<\/p>\n \u56fe3 CNTs\u751f\u957f\u4e0e\u7ebf\u6027\u9ad8\u5206\u5b50\u805a\u5408\u7684\u76f8\u4f3c\u6027<\/strong><\/p>\n (a-b)<\/strong>CNTs\u7684\u7c7b\u4f3c\u87ba\u578b\u4f4d\u9519\u751f\u957f\u7684\u793a\u610f\u56fe\uff1b<\/p>\n (c)<\/strong>CNTs\u5e73\u5747\u957f\u5ea6\u4e0e\u751f\u957f\u65f6\u95f4\u7684\u5173\u7cfb\u3002<\/p>\n 2.3.2 \u57fa\u4e8eSchulz-Flory\u5206\u5e03\u5bf9HACNT\u751f\u957f\u7684\u63cf\u8ff0<\/strong><\/p>\n CNTs\u751f\u957f\u7684\u5f71\u54cd\u56e0\u7d20\u867d\u7136\u5f88\u591a\uff0c\u4f46\u5176\u8fde\u7eed\u751f\u957f\u4e3b\u8981\u53d6\u51b3\u4e8e\uff1a(1)\u50ac\u5316\u5242\u6d3b\u6027\u662f\u5426\u4fdd\u6301\u4e0d\u53d8\uff1b(2)\u78b3\u6e90\u4f9b\u5e94\u662f\u5426\u5145\u8db3\u3002\u4e00\u822cHACNT\u751f\u957f\u7684\u78b3\u6e90\u4f9b\u5e94\u662f\u5145\u8db3\u7684\uff0c\u56e0\u6b64\u53ef\u4ee5\u4ece\u50ac\u5316\u6d3b\u6027\u53d8\u5316\u7684\u89d2\u5ea6\u8003\u5bdf\u5176\u751f\u957f\u8fc7\u7a0b\u3002\u5047\u8bbe\u50ac\u5316\u5242\u6d3b\u6027\u4e0d\u53d8\u7684\u6982\u7387\u4e3a\u03b1\uff0c\u6839\u636eSchulz-Flory\u5206\u5e03\uff0c\u540c\u4e00\u6279HACNTs\u4e2d\u957f\u5ea6\u4e3aL\u7684CNTs\u7684\u6bd4\u4f8b\u662fPL<\/sub>=\u03b1(L-1)<\/sup>(1-\u03b1)\u3002\u628aHACNTs\u8d77\u59cb\u5904\u5bc6\u5ea6\u5b9a\u4e3a1\uff0c\u90a3\u4e48\u6cbf\u751f\u957f\u65b9\u5411\u5728L\u5904\u7684\u5bc6\u5ea6\u4e3adL<\/sub>=\u03b1(L-1)<\/sup>\u3002\u4ece\u516c\u5f0f\u4e2d\u53ef\u4ee5\u770b\u51fa\uff0c\u8981\u60f3\u51cf\u5c11CNTs\u751f\u957f\u8fc7\u7a0b\u4e2d\u7684\u5bc6\u5ea6\u4e0b\u964d\u60c5\u51b5\u5e76\u4ea7\u751f\u5c3d\u53ef\u80fd\u591a\u7684\u957fCNTs\uff0c\u5728\u4fdd\u8bc1\u78b3\u6e90\u5145\u8db3\u60c5\u51b5\u4e0b\uff0c\u552f\u4e00\u9014\u5f84\u662f\u63d0\u9ad8\u50ac\u5316\u5242\u6d3b\u6027\u6982\u7387\u3002<\/p>\n \u56fe4 \u57fa\u4e8eSchulz-Flory\u5206\u5e03\u7684HACNTs\u751f\u957f\u884c\u4e3a<\/strong><\/p>\n (a)<\/strong>\u57fa\u4e8eSchulz-Flory\u5206\u5e03\uff0c\u8d85\u957fCNTs\u9876\u7aef\u751f\u957f\u6a21\u5f0f\u793a\u610f\u56fe\uff1b<\/p>\n (b)<\/strong>\u4e0d\u540c\u50ac\u5316\u6d3b\u6027\u6982\u7387(\u03b1)\u4e0b\uff0cCNT\u6cbf\u957f\u5ea6\u65b9\u5411\u7684\u7406\u8bba\u6bd4\u4f8b\u5206\u5e03\uff1b<\/p>\n (c)<\/strong>\u4e0d\u540c\u03b1\u4e0b\uff0cCNT\u6cbf\u957f\u5ea6\u65b9\u5411\u7684\u7406\u8bba\u5bc6\u5ea6\u5206\u5e03\uff1b<\/p>\n (d)<\/strong>\u8d85\u957fCNTs\u7684Mosaic SEM\u56fe\uff1b<\/p>\n (e)<\/strong>\u56fe(d)\u4e2dCNTs\u7684\u6570\u91cf\u5206\u5e03\uff1b<\/p>\n (f)<\/strong>4\u4e2a\u4e0d\u540c\u03b1\u4e0b\uff0c\u8d85\u957fCNTs\u6cbf\u957f\u5ea6\u65b9\u5411\u7684\u5bc6\u5ea6\u5206\u5e03\uff1b<\/p>\n (g)<\/strong>4\u4e2a\u4e0d\u540c\u03b1\u4e0b\uff0c\u8d85\u957fCNTs\u6cbf\u957f\u5ea6\u65b9\u5411\u7684\u6bd4\u4f8b\u5206\u5e03\u3002<\/p>\n 3. HACNTs\u7684\u7ed3\u6784\u63a7\u5236<\/span><\/strong><\/p>\n CNTs\u7684\u7ed3\u6784\uff0c\u4f8b\u5982\u76f4\u5f84\u3001\u7ba1\u58c1\u6570\u3001\u624b\u6027\u3001\u7f3a\u9677\u5bc6\u5ea6\u7b49\uff0c\u5bf9\u5176\u6027\u80fd\u6709\u663e\u8457\u7684\u5f71\u54cd\u3002\u56e0\u6b64\uff0c\u5236\u5907\u9ad8\u7eafCNTs\u5bf9\u5176\u5e94\u7528\u5177\u6709\u91cd\u8981\u610f\u4e49\uff0c\u8fd9\u91cc\u7684\u9ad8\u7eaf\u4e0d\u4ec5\u662f\u7ec4\u5206\u4e0a\u7684\u9ad8\u7eaf\u8fd8\u5305\u62ec\u7ed3\u6784\u7684\u4e00\u81f4\u6027\u3002<\/p>\n 3.1 HACNTs\u76f4\u5f84\u4e0e\u7ba1\u58c1\u6570\u7684\u63a7\u5236<\/strong><\/p>\n 3.1.1 \u76f4\u5f84\u7684\u63a7\u5236<\/strong><\/p>\n CNT\u9635\u5217\u76f4\u5f84\u7684\u63a7\u5236\u5bf9\u5176\u6027\u80fd\u548c\u5728\u7535\u5b50\u5668\u4ef6\u4e2d\u7684\u96c6\u6210\u5341\u5206\u5173\u952e\u3002\u8fc7\u53bb\u8fd120\u5e74\u4e2d\u4e3b\u8981\u53d1\u5c55\u7684\u63a7\u5236\u7b56\u7565\u5305\u62ec\u50ac\u5316\u5242\u9009\u62e9\u3001\u6e29\u5ea6\u4f18\u5316\u3001\u8fdb\u6599\u6c14\u538b\u3001\u6d41\u91cf\u3001\u7ec4\u6210\u6539\u53d8\u7b49\u3002\u5bf9\u4e8e\u50ac\u5316\u5242\u6765\u63a7\u5236CNTs\u7684\u76f4\u5f84\uff0c\u4e3b\u8981\u65b9\u6cd5\u6709\u8c03\u8282\u91d1\u5c5e\u50ac\u5316\u5242\u9897\u7c92\u5c3a\u5bf8\u7684\u5206\u5e03\u3001\u5bf9\u91d1\u5c5e\u50ac\u5316\u5242\u8fdb\u884c\u9884\u5904\u7406\u3001\u9009\u62e9\u5408\u91d1\u50ac\u5316\u5242\u548c\u4f7f\u7528\u65e0\u91d1\u5c5e\u50ac\u5316\u5242\u3002<\/p>\n \u56fe5 \u91d1\u5c5e\u50ac\u5316\u5242\u9897\u7c92\u5c3a\u5bf8\u5bf9CNTs\u76f4\u5f84\u7684\u63a7\u5236<\/strong><\/p>\n (a-c)<\/strong>\u4e0d\u540c\u6db2\u76f8\u4e2d\u5236\u5907\u7684Fe\u7eb3\u7c73\u56e2\u7c07\u7684\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c(TEM)\u56fe\u3002(a)\u6cb9\u9178\uff0c(b)\u6708\u6842\u9178\uff0c(c)\u8f9b\u9178\uff1b<\/p>\n (d-f)<\/strong>\u5206\u522b\u662f\u56fe(a-c)\u4e2dFe\u7eb3\u7c73\u56e2\u7c07\u5bf9\u5e94\u7684\u76f4\u5f84\u5206\u5e03\u67f1\u72b6\u56fe\uff1b<\/p>\n (g-l)<\/strong>\u91c7\u7528\u4e24\u79cdRh\u7eb3\u7c73\u9897\u7c92\u4f5c\u4e3a\u50ac\u5316\u5242\u5236\u5907\u7684\u5bf9\u9f50\u7684\u9ad8\u5bc6\u5ea6SWCNT\u9635\u5217\uff1b<\/p>\n (m)<\/strong>900\u00b0C\u4e0b\u4e59\u9187-CVD\u6cd5\u5728SiO2<\/sub>\/Si\u7247\u4e0a\u5236\u5907\u7684\u5b9a\u5411SCWCNT\u9635\u5217\u7684SEM\u56fe\uff1b<\/p>\n (n)<\/strong>\u56fe(a)\u4e2dFe\u7eb3\u7c73\u56e2\u7c07\u4e3a\u50ac\u5316\u5242\u5236\u5907\u7684\u5355\u6839CNTs\u7684TEM\u56fe\uff1b<\/p>\n (o)<\/strong>\u56fe(a)\u4e2dFe\u7eb3\u7c73\u56e2\u7c07\u4e3a\u50ac\u5316\u5242\u5236\u5907\u7684SWCNTs\u7684\u76f4\u5f84\u5206\u5e03\u67f1\u72b6\u56fe\u3002<\/p>\n \u56fe6 \u91d1\u5c5e\u50ac\u5316\u5242\u9884\u5904\u7406\u5bf9CNTs\u76f4\u5f84\u7684\u63a7\u5236<\/strong><\/p>\n (a)<\/strong>Fe\u7eb3\u7c73\u9897\u7c92\u5728\u8d85\u9ad8\u771f\u7a7a\u4e0b\u9000\u706b\u5904\u7406\u7684\u6f14\u53d8\u53ca\u5176\u4f5c\u4e3a\u50ac\u5316\u5242\u751f\u957fSWCNTs\u7684\u793a\u610f\u56fe\uff1b<\/p>\n (b,d,f)<\/strong>\u5728\u84dd\u5b9d\u77f3r\u9762\u4e0a\u751f\u957f\u7684CNTs\u7684SEM\u56fe\uff1b<\/p>\n (c,e,g)<\/strong>\u5728\u84dd\u5b9d\u77f3r\u9762\u4e0a\u751f\u957f\u7684CNTs\u7684\u76f4\u5f84\u5206\u5e03\u56fe\uff1b<\/p>\n (h)<\/strong>CVD\u6cd5\u5728\u79bb\u6563\u7684\u7eb3\u7c73\u9897\u7c92\u4e0a\u5236\u5907SWCNT\u7684\u6d41\u7a0b\u793a\u610f\u56fe\u3002<\/p>\n \u56fe7 \u6e29\u5ea6\u63a7\u5236CNTs\u7684\u76f4\u5f84<\/strong><\/p>\n (a-d)<\/strong>\u5206\u522b\u5728900\u3001920\u3001940\u548c960\u2103\u4e0b\u957f\u6210\u7684SWCNT\u7684\u76f4\u5f84\u5206\u5e03\u56fe\uff1b<\/p>\n (e-f)<\/strong>\u76f4\u5f84\u53d8\u5316\u4e0e\u521d\u59cb\u76f4\u5f84\u7684\u5173\u7cfb\uff1b<\/p>\n (g)<\/strong>\u6e29\u63a7\u66f2\u7ebf\uff1b<\/p>\n (h)<\/strong>\u6309\u56fe(g)\u4e2d\u6e29\u63a7\u66f2\u7ebf\u957f\u6210\u7684\u8d85\u957fSWCNT\u7684\u62c9\u66fc\u5149\u8c31\uff1b<\/p>\n (i-l)<\/strong>\u53e6\u4e00\u7ec4SWCNT\u7684AFM\u56fe\uff1b<\/p>\n (m)<\/strong>\u4e0d\u540c\u6e29\u5ea6\u4e0b\u5236\u5907\u7684HACNTs\u7684\u7ba1\u58c1\u6570\u7684\u5206\u5e03\u56fe\uff1b<\/p>\n (n)<\/strong>\u4e0d\u540c\u6e29\u5ea6\u4e0b\u5236\u5907\u7684HACNTs\u7684\u5916\u5f84\u5206\u5e03\u56fe\u3002<\/p>\n 3.1.2 \u7ba1\u58c1\u6570\u7684\u63a7\u5236<\/strong><\/p>\n \u5728HACNTs\u7684\u5236\u5907\u4e2d\uff0c\u5927\u591a\u6570\u7814\u7a76\u662f\u96c6\u4e2d\u5728\u63a7\u5236\u5408\u6210SWCNTs\uff0c\u4f46\u4e5f\u6709\u90e8\u5206\u7814\u7a76\u6d89\u53ca\u53cc\u58c1\u78b3\u7eb3\u7c73\u7ba1(DWCNTs)\u3001\u4e09\u58c1\u78b3\u7eb3\u7c73\u7ba1(TWCNTs)\u548c\u5c11\u58c1\u78b3\u7eb3\u7c73\u7ba1(FWCNTs)\u7684\u53ef\u63a7\u5408\u6210\u3002\u5728\u7ba1\u58c1\u6570\u7684\u63a7\u5236\u4e2d\uff0c\u6700\u5173\u952e\u7684\u662f\u50ac\u5316\u5242\u9897\u7c92\u7684\u5c3a\u5bf8\u548c\u7ed3\u6784\u3002<\/p>\n 3.2 HACNTs\u7684\u91d1\u5c5e\/\u534a\u5bfc\u4f53\u7279\u6027\u8c03\u63a7<\/strong><\/p>\n 2013\u5e74\uff0cIBM\u7684\u7814\u7a76\u4eba\u5458\u63d0\u51fa\uff0c\u4e3a\u4e86\u5c06HACNT\u5e94\u7528\u5230\u96c6\u6210\u7535\u8def\u4e2d\uff0c\u5fc5\u987b\u8981\u6c42HACNT\u9635\u5217\u542b\u6709\u5927\u4e8e99.9999%\u7684\u534a\u5bfc\u4f53\u7279\u6027\u7684SWCNT\uff0c\u4e14\u6bcf\u03bcm\u7684\u5bc6\u5ea6\u5e94\u8fbe\u5230125\u6839\u4ee5\u4e0a\u3002\u7136\u800c\uff0c\u73b0\u6709\u7684CNTs\u662f\u91d1\u5c5e\u6027CNTs\u548c\u534a\u5bfc\u4f53\u6027CNTs\u7684\u6df7\u5408\u7269\uff0c\u4e25\u91cd\u963b\u788d\u4e86\u5176\u5728\u7eb3\u7c73\u7535\u5b50\u5668\u4ef6\u7b49\u9886\u57df\u7684\u5e94\u7528\u3002\u56e0\u6b64\uff0c\u5236\u5907\u9009\u62e9\u6027\u5236\u5907\u91d1\u5c5e\u548c\/\u6216\u534a\u5bfc\u4f53\u7279\u6027\u7684HACNTs\u81f3\u5173\u91cd\u8981\u3002<\/p>\n 3.2.1 \u539f\u4f4d\u9009\u62e9\u6027\u5408\u6210\u534a\u5bfc\u4f53\u7279\u6027\u7684CNTs<\/strong><\/p>\n \u4e3b\u8981\u5305\u62ec\u901a\u8fc7\u50ac\u5316\u5242\u9009\u62e9\u3001\u78b3\u6e90\u63a7\u5236\u4ee5\u53ca\u7b49\u79bb\u5b50\/\u7d2b\u5916(UV)\u7167\u5c04\u6765\u5b9e\u73b0\u5177\u6709\u534a\u5bfc\u4f53\u7279\u6027\u7684CNTs\u7684\u9009\u62e9\u6027\u751f\u957f\u3002<\/p>\n \u56fe8 \u50ac\u5316\u5242\u8c03\u63a7\u5177\u6709\u534a\u5bfc\u4f53\u7279\u6027\u7684CNTs\u7684\u9009\u62e9\u6027\u751f\u957f<\/strong><\/p>\n (a)<\/strong>\u4ee5Mo2<\/sub>C\u4e3a\u50ac\u5316\u5242\uff0c\u5728\u77f3\u82f1\u57fa\u4f53\u4e0a\u751f\u957f\u6c34\u5e73\u6392\u5217\u7684\u5177\u6709\u534a\u5bfc\u4f53\u7279\u6027\u7684SWCNT\u9635\u5217\u7684\u793a\u610f\u56fe\uff1b<\/p>\n (b)<\/strong>\u516d\u65b9Mo2<\/sub>C\u7eb3\u7c73\u9897\u7c92\u7684\u9ad8\u500d\u900f\u5c04\u7535\u5b50\u663e\u5fae(HRTEM)\u56fe\uff1b<\/p>\n (c)<\/strong>Mo2<\/sub>C\u7eb3\u7c73\u9897\u7c92\u7684\u539f\u5b50\u6a21\u578b\u56fe(\u7eff\u8272:Mo\uff0c\u767d\u8272:C)\uff1b<\/p>\n (d)<\/strong>CNTs\u5728Mo2<\/sub>C\u7eb3\u7c73\u9897\u7c92\u4e0a\u9009\u62e9\u6027\u751f\u957f\u7684\u793a\u610f\u56fe\uff1b<\/p>\n (e)<\/strong>\u7528514nm\u6fc0\u5149\u7167\u5c04\u8f6c\u79fb\u5230Si\/SiO2<\/sub>\u57fa\u4f53(300nm)\u4e0a\u7684\u7eb3\u7c73\u7ba1\u7684RBM\u533a\u57df\u7684\u62c9\u66fc\u5149\u8c31\uff1b<\/p>\n (f)<\/strong>\u7528CeO2<\/sub>\u8d1f\u8f7d\u7684Fe\u6216Co\u505a\u50ac\u5316\u5242\uff0c\u5728Si\u57fa\u4f53\u4e0a\u9009\u62e9\u6027\u751f\u957f\u5177\u6709\u534a\u5bfc\u4f53\u7279\u6027\u7684SWCNTs\u793a\u610f\u56fe\uff1b<\/p>\n (g)<\/strong>\u957f\u6210\u7684SWCNTs\u7684SEM\u56fe\uff1b<\/p>\n (h-i)<\/strong>\u5206\u522b\u7528532nm(h)\u548c633nm(i)\u6fc0\u5149\u7167\u5c04\u672a\u8fd8\u539f\u7684Fe\/CeO2<\/sub>\u50ac\u5316\u5408\u6210\u7684SWCNTs\u7684\u62c9\u66fc\u5149\u8c31\uff1b<\/p>\n (j-k)<\/strong>\u5728532nm(j)\u548c633nm(k)\u6fc0\u5149\u4e0b\uff0c\u5206\u522b\u7528H2<\/sub>\u8fd8\u539f0\u548c10min\u7684Fe\/CeO2<\/sub>\u3001Fe\/SiO2<\/sub>\u505a\u50ac\u5316\u5242\u5408\u6210\u7684CNTs\u4e2d\u91d1\u5c5e\u6027SWCNTs(M)\u548c\u534a\u5bfc\u4f53\u6027SWCNTs(S)\u7684\u7edf\u8ba1\uff1b<\/p>\n (l)<\/strong>\u7f3a\u6c27TiO2<\/sub>\u7eb3\u7c73\u9897\u7c92\u50ac\u5316\u7684\u5177\u6709\u534a\u5bfc\u4f53\u7279\u6027\u7684SWCNTs\u7684\u9009\u62e9\u6027\u751f\u957f\u793a\u610f\u56fe\uff1b<\/p>\n (m)<\/strong>\u4ee5633nm\u6fc0\u53d1\u8f6c\u79fb\u5230SiO2<\/sub>\/Si\u57fa\u4f53\u4e0a\u7684SWCNT\u6837\u54c1\u7684\u62c9\u66fc\u5149\u8c31\u7684\u5f84\u5411\u547c\u5438\u6a21\u5f0f\u5cf0\uff1b<\/p>\n (n)<\/strong>Vds<\/sub>=100mV\u65f6\uff0c\u534a\u5bfc\u4f53SWCNT\u5668\u4ef6\u7684\u5178\u578b\u4f20\u8f93\u7279\u6027\u66f2\u7ebf\uff1b<\/p>\n (o)<\/strong>C\u5305\u8986Co\u7eb3\u7c73\u9897\u7c92\u548c\u5177\u6709\u534a\u5bfc\u4f53\u7279\u6027\u7684SWCNTs\u751f\u957f\u7684\u793a\u610f\u56fe\uff1b<\/p>\n (p)<\/strong>\u5728633nm\u4e0b\uff0cSWCNTs\u7684\u62c9\u66fc\u5149\u8c31\uff1b<\/p>\n (q)<\/strong>\u7535\u5b50\u884d\u5c04\u5206\u679095\u6839SWCNTs\u4e2d\u91d1\u5c5e\u6027\u548c\u534a\u5bfc\u4f53\u6027SWCNTs\u7684\u6bd4\u4f8b\u7684\u997c\u72b6\u56fe\u3002<\/p>\n \u56fe9 \u7b49\u79bb\u5b50\u4f53\/UV\u8c03\u63a7CNTs\u7684\u9009\u62e9\u6027\u751f\u957f<\/strong><\/p>\n (a)<\/strong>\u5408\u6210SWCNTs\u7684PECVD\u53cd\u5e94\u5668\u7684\u793a\u610f\u56fe\uff1b<\/p>\n (b)<\/strong>\u81ea\u5236\u7684CVD\u7cfb\u7edf\u7684\u793a\u610f\u56fe\uff1b<\/p>\n (c-e)<\/strong>\u4e0d\u540c\u53c2\u6570\u4e0b\u751f\u957f\u7684SWCNTs\u7684SEM\u56fe\uff1b<\/p>\n (f)<\/strong>\u5728514.5nm\u6fc0\u53d1\u4e0b\uff0c\u672a\u91c7\u7528UV\u7167\u5c04\u7684CNTs\u7684\u62c9\u66fc\u5149\u8c31\uff1b<\/p>\n (g-h)<\/strong>\u5206\u522b\u5728514.5nm\u548c632.8nm\u6fc0\u53d1\u4e0b\uff0c\u91c7\u7528UV\u7167\u5c04\u7684CNTs\u7684\u62c9\u66fc\u5149\u8c31\u3002<\/p>\n 3.2.2 \u975e\u539f\u4f4d\u9009\u62e9\u6027\u9664\u53bb\u91d1\u5c5e\u6027CNTs<\/strong><\/p>\n \u5c3d\u7ba1\u79d1\u7814\u5de5\u4f5c\u8005\u82b1\u8d39\u4e86\u5927\u91cf\u7cbe\u529b\uff0c\u4f46\u5177\u6709\u534a\u5bfc\u4f53\u7279\u6027\u7684SWCNTs\u7684\u539f\u4f4d\u751f\u957f\u5374\u59cb\u7ec8\u6ca1\u80fd\u8fbe\u5230\u8981\u6c42\u7684\u7eaf\u5ea6\u3002\u56e0\u6b64\uff0c\u901a\u8fc7\u540e\u5904\u7406\u6765\u975e\u539f\u4f4d\u9664\u53bb\u91d1\u5c5e\u6027\u7684SWCNTs\u6210\u4e3a\u4e86\u83b7\u5f97\u9ad8\u7eaf\u534a\u5bfc\u4f53\u6027SWCNTs\u7684\u4e00\u79cd\u53ef\u884c\u624b\u6bb5\u3002\u9664\u53bb\u91d1\u5c5e\u6027SWCNTs\u7684\u4e3b\u8981\u65b9\u5f0f\u6709\u7535\u51fb\u7a7f\u3001\u5229\u7528\u70ed\u6bdb\u7ec6\u6548\u5e94\u3001\u5316\u5b66\u523b\u8680\u3001\u8f90\u7167\u7b49\u3002<\/p>\n \u56fe10 \u7535\u51fb\u7a7f\u9664\u53bb\u91d1\u5c5e\u6027SWCNTs<\/strong><\/p>\n (a-d)<\/strong>\u5206\u522b\u662f\u5728\u7a7a\u6c14\u4e2d\u548c\u5728\u6709\u673a\u8584\u819c\u4e2d\u7535\u51fb\u7a7f\u7684\u793a\u610f\u56fe\uff1b<\/p>\n (e-f)<\/strong>\u7535\u51fb\u7a7f\u524d\u540e\u5728\u5206\u5b50\u73bb\u7483\u819c\u4e2d\u7684SWCNT\u9635\u5217\u7684SEM\u56fe\uff1b<\/p>\n (g)<\/strong>\u56fe(e-f)\u4e2d\u573a\u6548\u5e94\u6676\u4f53\u7ba1(FET)\u4f20\u8f93\u7279\u6027\uff0c\u8868\u660e\u9009\u62e9\u6027\u51fb\u7a7f\u4e86\u91d1\u5c5e\u6027SWCNTs\uff1b<\/p>\n (h)<\/strong>\u5341\u5b57\u5806\u53e0\u7684SWCNT\u9635\u5217\u7684SEM\u56fe\uff1b<\/p>\n (i-j)<\/strong>\u57fa\u4e8eSWCNT\u7684\u4e00\u7ec4FETs\u7684\u4ee3\u8868\u533a\u57df\u7684SEM\u56fe\uff1b<\/p>\n (k-m)<\/strong>\u5341\u5b57\u5806\u53e0\u7684SWCNT\u9635\u5217\u7684\u65e0\u95e8\u69db\u51fb\u7a7f\u8fc7\u7a0b\u7684\u793a\u610f\u56fe\u3002<\/p>\n 3.2.3 \u539f\u4f4d\u9009\u62e9\u6027\u5408\u6210\u91d1\u5c5e\u6027CNTs<\/strong><\/p>\n \u56fe11 \u7535\u573a\u8f85\u52a9CVD\u539f\u4f4d\u5408\u6210HACNTs<\/strong><\/p>\n (a-f)<\/strong>\u7535\u573a\u5f71\u54cd\u8d85\u957fCNTs\u751f\u957f\u7684SEM\u56fe\uff1b<\/p>\n (g-h)<\/strong>\u7535\u573a\u5f71\u54cd\u91d1\u5c5e\u6027CNTs\u548c\u5177\u6709\u534a\u5bfc\u4f53\u7279\u6027\u7684CNTs\u751f\u957f\u7684\u793a\u610f\u56fe\u3002<\/p>\n 3.3 HACNTs\u7684\u624b\u6027\u63a7\u5236<\/strong><\/p>\n HACNTs\u7684\u7535\u5b66\u6027\u8d28\u4e3b\u8981\u7531\u5176\u624b\u6027\u7ed3\u6784\u63a7\u5236\uff0c\u4fdd\u6301CNTs\u7684\u624b\u6027\u4e00\u81f4\u6027\u662f\u5176\u5728\u96c6\u6210\u7535\u8def\u4e2d\u5e94\u7528\u7684\u5fc5\u8981\u6761\u4ef6\u3002\u56e0\u6b64\uff0c\u83b7\u5f97\u5177\u6709\u7ed3\u6784\u4e00\u81f4\u6027\u548c\u9ad8\u624b\u6027\u7eaf\u5ea6\u7684HACNTs\u4e0d\u4ec5\u5bf9\u57fa\u7840\u7814\u7a76\u610f\u4e49\u91cd\u5927\uff0c\u800c\u4e14\u5bf9\u5176\u5728\u8bb8\u591a\u6280\u672f\u9886\u57df\u7684\u5e94\u7528\u81f3\u5173\u91cd\u8981\u3002<\/p>\n 3.3.1 CNTs\u624b\u6027\u7ed3\u6784\u5f62\u6210\u3001\u8c03\u63a7\u548c\u9009\u62e9\u7684\u673a\u7406<\/strong><\/p>\n \u8bb8\u591a\u73af\u5883\u56e0\u7d20\uff0c\u4f8b\u5982\u6e29\u5ea6\u3001\u8fdb\u6599\u3001\u50ac\u5316\u5242\u7b49\uff0c\u90fd\u4f1a\u5f71\u54cdCNTs\u7684\u5f62\u6838\u548c\u957f\u5927\uff0c\u6700\u7ec8\u5f71\u54cd\u5176\u624b\u6027\u7ed3\u6784\u3002\u4f8b\u5982\u6839\u636e\u7c7b\u4f3c\u87ba\u578b\u4f4d\u9519\u7406\u8bba\uff0c\u6276\u6905\u578b\u7684CNTs\u4ece\u70ed\u529b\u5b66\u548c\u52a8\u529b\u5b66\u7684\u89d2\u5ea6\u90fd\u6bd4z\u5b57\u578b\u7684CNTs\u66f4\u5bb9\u6613\u751f\u957f\u3002<\/p>\n 3.3.2 CNTs\u7684\u624b\u6027\u63a7\u5236\u65b9\u6cd5<\/strong><\/p>\n \u6839\u636eCNTs\u7684\u624b\u6027\u5f71\u54cd\u56e0\u7d20\uff0c\u4e3b\u8981\u53d1\u5c55\u8d77\u6765\u7684\u8c03\u63a7HACNTs\u7684\u624b\u6027\u7684\u65b9\u5f0f\u6709\u50ac\u5316\u5242\u63a7\u5236\u3001\u8fdb\u6599\u63a7\u5236\u3001CNT\u79cd\u5b50\u63a7\u5236\u3001\u77f3\u58a8\u70ef\/\u5bcc\u52d2\u70ef\u6a21\u677f\u63a7\u5236\u3001\u57fa\u4f53\u63a7\u5236\u3002<\/p>\n \u56fe12 \u50ac\u5316\u5242\u8c03\u63a7HACNTs\u7684\u624b\u6027\u9009\u62e9<\/strong><\/p>\n (a)<\/strong>\u5728FeCu\/MgO\u50ac\u5316\u5242\u4e0a\u751f\u957fSWCNT\u7684\u793a\u610f\u56fe\uff1b<\/p>\n (b)<\/strong>600\u2103\u4e0b\uff0c\u5206\u522b\u5728FeRu\u548c\u5546\u7528CoMoCAT\u7ba1\u72b6\u50ac\u5316\u5242\u4e0a\u751f\u957fSWCNT\uff0c\u6240\u83b7\u5f97\u7684(6,5)SWCNT\u4e0e(8,4)\u3001(7,5)\u3001(7,6)\u7ba1\u7684PL\u5f3a\u5ea6\u6bd4\uff1b<\/p>\n (c)<\/strong>850\u2103\u4e0b\uff0c\u5206\u522b\u5728FeRu\u548cHiPco\u7ba1\u72b6\u50ac\u5316\u5242\u4e0a\u751f\u957fSWCNT\uff0c\u6240\u83b7\u5f97\u7684(8,4)SWCNT\u4e0e(6,5)\u3001(7,6)\u3001(9,4)\u7ba1\u7684PL\u5f3a\u5ea6\u6bd4\uff1b<\/p>\n (d)<\/strong>W-Co\u7eb3\u7c73\u6676\u50ac\u5316\u5242\u7684\u5236\u5907\u4ee5\u53ca\u5177\u6709\u7279\u5b9a(n,m)\u7684SWCNT\u7684\u6a21\u677f\u6cd5\u751f\u957f\uff1b<\/p>\n (e)<\/strong>\u901a\u8fc7\u62c9\u66fc\u6d4b\u91cf\u7684SWCNT\u624b\u6027\u5730\u56fe\u4e0a\u7ea63300\u6839\u7eb3\u7c73\u7ba1\u7684\u4e0d\u540c\u624b\u6027\u7684\u76f8\u5bf9\u4e30\u5ea6\uff1b<\/p>\n (f)<\/strong>\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba(DFT)\u6a21\u62df\u7684W6<\/sub>Co7<\/sub>\u7eb3\u7c73\u6676\u4e0a\u7684SWCNTs\u751f\u957f\uff1b<\/p>\n (g)<\/strong>\u5728W6<\/sub>Co7<\/sub>\u7684(116)\u6676\u9762\u4e0a\u4e0d\u540c\u624b\u6027SWCNTs\u7684\u7ed3\u5408\u80fd\uff1b<\/p>\n (h)<\/strong>\u5728\u90e8\u5206SWCNT\u624b\u6027\u5730\u56fe\u4e0a361RBMs\u4e2d\u4e0d\u540c\u624b\u6027CNTs\u7684\u76f8\u5bf9\u4e30\u5ea6\uff1b<\/p>\n (i-j)<\/strong>\u4e32\u8054\u5f0fCVD\u6cd5\u7684\u793a\u610f\u56fe\uff1b<\/p>\n (k)<\/strong>DFT\u8ba1\u7b97\u7684SWNTs\u4e0eFe\u3001Co\u3001Ni\u50ac\u5316\u5242\u7684\u754c\u9762\u5f62\u6210\u80fd\uff1b<\/p>\n (l)<\/strong>\u4e0d\u540cRBM\u5206\u5e03\u7684\u62c9\u66fc\u5206\u6790\u3002<\/p>\n 3.4 HACNTs\u7684\u7f3a\u9677\u63a7\u5236<\/strong><\/p>\n \u5b9e\u9645\u751f\u957f\u7684CNTs\u6709\u8bb8\u591a\u7c7b\u578b\u7684\u7f3a\u9677\uff0c\u4f8b\u5982\u63ba\u6742\u7269\u3001\u7a7a\u4f4d\u3001\u4e94\u8fb9\u5f62\u3001\u4e03\u8fb9\u5f62\u7b49\uff0c\u90fd\u4f1a\u663e\u8457\u5f71\u54cdCNTs\u7684\u7535\u5b66\u3001\u70ed\u5b66\u548c\u529b\u5b66\u6027\u80fd\u3002\u5728CNTs\u7ba1\u58c1\u4e0a\u5b58\u5728\u6570\u5bf9\u62d3\u6251\u7f3a\u9677\u5c31\u4f1a\u6025\u5267\u964d\u4f4e\u5176\u529b\u5b66\u5f3a\u5ea6\uff0c\u901a\u5e38\u4f1a\u8fbe\u5230\u4e00\u4e2a\u6570\u91cf\u7ea7\u4ee5\u4e0a\u3002\u56e0\u6b64\uff0c\u5728\u8d85\u957fCNTs\u7684\u751f\u957f\u8fc7\u7a0b\u4e2d\u63a7\u5236\u7f3a\u9677\u7684\u5f62\u6210\u4ee5\u83b7\u5f97\u5177\u6709\u5b8c\u7f8e\u51e0\u4f55\u7ed3\u6784\u7684CNTs\u624d\u80fd\u5b9e\u73b0\u5176\u672c\u5f81\u6027\u80fd\u3002<\/p>\n \u8fd9\u90e8\u5206\u4e3b\u8981\u4ecb\u7ecd\u4e86CNTs\u4e2d\u7f3a\u9677\u7684\u4ea7\u751f\u3001\u8fd0\u52a8\u4ee5\u53ca\u6108\u5408\uff0c\u5e76\u63d0\u51fa\u4e86\u751f\u957f\u65e0\u7f3a\u9677CNTs\u7684\u7b56\u7565\uff0c\u4e3b\u8981\u5305\u62ec\u50ac\u5316\u5242\u7684\u9009\u62e9\u3001\u751f\u957f\u6a21\u5f0f\u548c\u57fa\u4f53\u7684\u9009\u62e9\u3001\u751f\u957f\u6e29\u5ea6\u7684\u63a7\u5236\u4ee5\u53ca\u8fdb\u6599\u9009\u62e9\u3002\u5728\u65e0\u7f3a\u9677CNTs\u7684\u751f\u957f\u57fa\u7840\u4e0a\uff0c\u63d0\u51fa\u4e86\u65e0\u7f3a\u9677\u8d85\u957fHACNTs\u7684\u5408\u6210\u65b9\u6cd5\u3002\u00a0<\/p>\n \u56fe13 TWCNTs\u957f\u7a0b\u5747\u4e00\u7684\u539f\u5b50\u7ed3\u6784<\/strong><\/p>\n (a)<\/strong>100mm\u957fTWCNT\u7684\u793a\u610f\u56fe\u53ca\u5176\u8ddd\u5f00\u59cb\u751f\u957f\u70b9\u4e3a25\u300160\u300170mm\u5904\u7684HRTEM\u56fe\uff1b<\/p>\n
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