{"id":85107,"date":"2017-06-09T06:30:16","date_gmt":"2017-06-08T22:30:16","guid":{"rendered":"\/\/m.iemloyee.com\/?p=85107"},"modified":"2017-06-09T08:39:52","modified_gmt":"2017-06-09T00:39:52","slug":"%e5%8d%97%e5%bc%80%e5%a4%a7%e5%ad%a6%e5%8c%96%e5%ad%a6%e5%ad%a6%e9%99%a2%e4%bd%95%e8%89%af%e5%b9%b4%e6%95%99%e6%8e%88%ef%bc%9a%e4%ba%8c%e6%b0%a7%e5%8c%96%e7%a2%b3%e5%9b%ba%e5%ae%9a%e6%96%b9%e9%9d%a2","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=85107","title":{"rendered":"\u5357\u5f00\u5927\u5b66\u5316\u5b66\u5b66\u9662\u4f55\u826f\u5e74\u6559\u6388\uff1a\u4e8c\u6c27\u5316\u78b3\u56fa\u5b9a\u65b9\u9762\u65b0\u7a81\u7834"},"content":{"rendered":"<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u5357\u5f00\u5927\u5b66\u5316\u5b66\u5b66\u9662\u4f55\u826f\u5e74\u6559\u6388\u8bfe\u9898\u7ec4\u5728\u4e8c\u6c27\u5316\u78b3\u56fa\u5b9a\u65b9\u9762\u7684\u65b0\u7a81\u7834\u3002\u8be5\u8bfe\u9898\u7ec4\u5229\u7528\u4e09\u7532\u94f5\u4e59\u5185\u916f\uff08Betaine\uff0c\u4e5f\u53eb\u751c\u83dc\u78b1\uff09\u4f5c\u4e3a\u9ad8\u6548\u3001\u53ef\u6301\u7eed\u7684\u6709\u673a\u5c0f\u5206\u5b50\u50ac\u5316\u5242\uff0c\u5728\u80fa\u548c\u4e8c\u82ef\u57fa\u7845\u70f7\u5b58\u5728\u4e0b\u5b9e\u73b0\u4e86\u4e8c\u6c27\u5316\u78b3\u4e8c\u6c27\u5316\u78b3\u5206\u7ea7\u53ef\u63a7\u5730\u8fd8\u539f\u529f\u80fd\u5316\u53cd\u5e94\uff0c\u8fd9\u662f\u9996\u4f8b\u540c\u65f6\u5b9e\u73b0\u4e8c\u6c27\u5316\u78b3\u53ef\u8c03\u76842-\u30014-\u30016-\u7535\u5b50\u8fd8\u539f\u4e0eC-N\u952e\u6784\u7b51\u76f8\u7ed3\u5408\u7684\u62a5\u9053\uff0c\u53ef\u7528\u4e8e\u7532\u9170\u80fa\u3001\u7f29\u919b\u80fa\u548c\u7532\u80fa\u7c7b\u5316\u5408\u7269\u7684\u5408\u6210\u548c\u5236\u5907\u3002\u76f8\u5173\u5185\u5bb9\u4ee5Betaine Catalysis for Hierarchical Reduction of CO<sub>2<\/sub> with Amines and Hydrosilane To Form Formamides, Aminals, and Methylamines\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u77e5\u540d\u671f\u520aAngew. 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\u2103 \u53cd\u5e94\uff0c\u4e13\u4e00\u5730\u5f62\u6210\u7532\u80fa\u5316\u5408\u7269\uff1b\u800c\u572810\u4e2a\u5927\u6c14\u538b\u300150 \u2103\u53cd\u5e94\uff0c\u5219\u83b7\u5f97\u7532\u9170\u5316\u4ea7\u7269\u3002\u8be5\u53cd\u5e94\u6761\u4ef6\u6e29\u548c\uff0c\u5e95\u7269\u9002\u7528\u6027\u5e7f\u6cdb\uff0c\u4ea7\u7387\u826f\u597d\uff0c\u5e76\u4e14\u628a\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u548c\u6784\u7b51C-N\u952e\u7ed3\u5408\u8d77\u6765\uff0c\u5408\u6210\u4e86\u591a\u79cd\u901a\u5e38\u6765\u81ea\u4e8e\u77f3\u6cb9\u539f\u6599\u7684\u5316\u5b66\u54c1\u548c\u50a8\u80fd\u6750\u6599\uff0c\u6269\u5927\u4e86\u76f4\u63a5\u4ece\u4e8c\u6c27\u5316\u78b3\u83b7\u53d6\u5316\u5408\u7269\u7684\u8303\u56f4\uff0c\u5c06\u4f1a\u5728\u4e00\u5b9a\u7a0b\u5ea6\u4ee3\u66ff\u73b0\u6709\u7684\u77f3\u6cb9\u5316\u5b66\u5de5\u4e1a\uff0c\u5177\u6709\u5de8\u5927\u7684\u53d1\u5c55\u6f5c\u529b\uff0c\u5728\u4e8c\u6c27\u5316\u78b3\u56fa\u5b9a\u548c\u5de5\u4e1a\u751f\u4ea7\u4e2d\u90fd\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1a<a href=\"http:\/\/chem.nankai.edu.cn\/ejymzhylm.aspx?t=4&amp;m=5&amp;n=3131\" target=\"_blank\" rel=\"noopener noreferrer\">http:\/\/chem.nankai.edu.cn\/ejymzhylm.aspx?t=4&amp;m=5&amp;n=3131<\/a>\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201702734\/full\" target=\"_blank\" rel=\"noopener noreferrer\">Betaine Catalysis for Hierarchical Reduction of CO2 with Amines and Hydrosilane To Form Formamides, Aminals, and Methylamines<\/a>\uff08Angew. Chem. Int. 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