{"id":84734,"date":"2017-06-02T06:30:21","date_gmt":"2017-06-01T22:30:21","guid":{"rendered":"\/\/m.iemloyee.com\/?p=84734"},"modified":"2017-06-01T23:49:00","modified_gmt":"2017-06-01T15:49:00","slug":"%e5%ba%9e%e6%ac%a2aem%e6%9c%80%e6%96%b0%e7%bb%bc%e8%bf%b0%ef%bc%9a%e8%bf%87%e6%b8%a1%e9%87%91%e5%b1%9e%e5%9f%bamof%e5%9c%a8%e8%83%bd%e9%87%8f%e5%ad%98%e5%82%a8%e4%b8%ad%e7%9a%84%e5%ba%94%e7%94%a8","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=84734","title":{"rendered":"\u5e9e\u6b22AEM\u6700\u65b0\u7efc\u8ff0\uff1a\u8fc7\u6e21\u91d1\u5c5e\u57faMOF\u5728\u80fd\u91cf\u5b58\u50a8\u4e2d\u7684\u5e94\u7528"},"content":{"rendered":"
\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n \u8fd1\u5e74\u6765\uff0c\u793e\u4f1a\u5bf9\u53ef\u518d\u751f\u80fd\u6e90\u7684\u9700\u6c42\u65e5\u76ca\u589e\u5927\uff0c\u80fd\u6e90\u7684\u5b58\u50a8\u95ee\u9898\u4e5f\u53d7\u5230\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u76ee\u524d\uff0c\u80fd\u6e90\u5b58\u50a8\u6280\u672f\u4e3b\u8981\u6709\u7535\u5bb9\u5668\u548c\u7535\u6c60\u4e24\u79cd\uff0c\u7ec4\u6210\u8fd9\u4e9b\u80fd\u91cf\u5b58\u50a8\u5668\u4ef6\u7684\u6750\u6599\u51b3\u5b9a\u4e86\u50a8\u80fd\u5668\u4ef6\u7684\u80fd\u91cf\u5bc6\u5ea6\u548c\u529f\u7387\u5bc6\u5ea6\u3002\u5176\u4e2d\uff0c\u6709\u673a\u91d1\u5c5e\u6846\u67b6\uff08\u7b80\u79f0MOF\uff09\u4f5c\u4e3a\u4e00\u79cd\u901a\u8fc7\u81ea\u7ec4\u88c5\u5c06\u91d1\u5c5e\u79bb\u5b50\u548c\u6709\u673a\u914d\u4f53\u7ec4\u6210\u7684\u6676\u4f53\u6750\u6599\u53d7\u5230\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\uff0c\u5176\u5b54\u9699\u5ea6\u9ad8\u3001\u6bd4\u8868\u9762\u79ef\u5927\u3001\u7ed3\u6784\u548c\u529f\u80fd\u6027\u53ef\u8c03\u7b49\u4f18\u70b9\u4f7f\u5176\u6210\u4e3a\u4e86\u6781\u5177\u53d1\u5c55\u6f5c\u529b\u7684\u50a8\u80fd\u6750\u6599\u3002<\/p>\n \u8fd1\u65e5\uff0c\u6765\u81ea\u626c\u5dde\u5927\u5b66\u7684\u5e9e\u6b22\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\u5728Advanced Energy Material<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201c<\/strong>Transition-Metal (Fe, Co, Ni) Based Metal-Organic Frameworks for Electrochemical Energy Storage<\/strong>\u201d<\/strong>\u7684\u7efc\u8ff0\u6587\u7ae0\u3002\u8be5\u7efc\u8ff0\u4e3b\u8981\u4ecb\u7ecd\u4e86\u8fc7\u6e21\u91d1\u5c5e\uff08Fe\u3001Co\u3001Ni\uff09\u57faMOF\u6750\u6599\u53ca\u5176\u884d\u751f\u7269\u5728\u8d85\u7ea7\u7535\u5bb9\u5668\u548c\u9502\u79bb\u5b50\u7535\u6c60\u4e2d\u7684\u76f8\u5173\u5e94\u7528\uff0c\u6982\u8ff0\u4e86\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u8c03\u63a7MOF\u6750\u6599\u7684\u4e2d\u5fc3\u539f\u5b50\u548c\u914d\u4f53\u7b49\u76f8\u5173\u7ec4\u6210\u90e8\u5206\uff0c\u8fdb\u800c\u4f18\u5316\u7535\u5bb9\u5668\u4ee5\u53ca\u7535\u6c60\u7efc\u5408\u6027\u80fd\u7684\u51fa\u8272\u8868\u73b0\u3002<\/p>\n 1. \u7b80\u4ecb<\/strong><\/p>\n \u968f\u7740\u4eba\u7c7b\u5bf9\u4e8e\u53ef\u518d\u751f\u80fd\u6e90\u9700\u6c42\u91cf\u7684\u4e0d\u65ad\u589e\u5927\uff0c\u5bfb\u627e\u80fd\u591f\u4f5c\u4e3a\u50a8\u80fd\u8bbe\u5907\u6750\u6599\u7684\u76f8\u5173\u7814\u7a76\u5c31\u663e\u5f97\u5341\u5206\u91cd\u8981\u3002\u76ee\u524d\u5e38\u7528\u7684\u50a8\u80fd\u8bbe\u5907\u4e3b\u8981\u6709\u7535\u5bb9\u5668\u548c\u7535\u6c60\uff0c\u5176\u4e2d\uff0c\u7535\u5bb9\u5668\u5177\u6709\u8f83\u5927\u7684\u529f\u7387\u5bc6\u5ea6\uff0c\u4f46\u662f\u5176\u80fd\u91cf\u5bc6\u5ea6\u5341\u5206\u6709\u9650\uff0c\u800c\u7535\u6c60\u867d\u7136\u80fd\u591f\u901a\u8fc7\u9009\u62e9\u6bd4\u5bb9\u91cf\u9ad8\u7684\u7535\u6781\u6750\u6599\u5b9e\u73b0\u8f83\u597d\u7684\u80fd\u91cf\u5bc6\u5ea6\u7684\u50a8\u80fd\u8bbe\u5907\uff0c\u4f46\u5176\u529f\u7387\u5bc6\u5ea6\u6210\u4e3a\u4e86\u5236\u7ea6\u5176\u53d1\u5c55\u7684\u5173\u952e\u56e0\u7d20\u3002<\/p>\n \u76ee\u524d\uff0c\u5177\u5907\u9ad8\u5ea6\u53ef\u8c03\u63a7\u6027\u7684MOF\u53d7\u5230\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\uff0c\u901a\u8fc7\u8c03\u63a7\u6750\u6599\u7684\u4e2d\u5fc3\u539f\u5b50\u3001\u6709\u673a\u914d\u4f53\u80fd\u591f\u5b9e\u73b0\u5bf9MOF\u7684\u7ed3\u6784\u63a7\u5236\uff0c\u4e14MOF\u7684\u539f\u6750\u6599\u6210\u672c\u8f83\u4f4e\uff0c\u5982Fe\u3001Co\u3001Ni\u7b49\u91d1\u5c5e\u76d0\u4f5c\u4e3aMOF\u7684\u539f\u6750\u6599\u4e5f\u6613\u4e8e\u5236\u5f97\u3002\u672c\u6587\u4e2d\u4e3b\u8981\u8ff0\u53ca\u7684\u8fc7\u6e21\u91d1\u5c5e\u57faMOF\u4e3b\u8981\u9488\u5bf9Fe\u3001Co\u3001Ni\u4e09\u79cd\u5728\u5730\u7403\u4e0a\u50a8\u91cf\u4e30\u5bcc\u7684\u8fc7\u6e21\u91d1\u5c5e\u5143\u7d20\uff0c\u7531\u8fd9\u4e09\u79cd\u5143\u7d20\u6784\u6210\u7684MOF\u5df2\u7ecf\u6210\u529f\u5728\u76f8\u5173\u50a8\u80fd\u8bbe\u5907\u4e0a\u5f97\u5230\u5e94\u7528\u5e76\u5f97\u5230\u4e86\u957f\u8db3\u7684\u53d1\u5c55\u3002<\/p>\n \u56fe<\/strong>1 Fe<\/strong>\u3001<\/strong>Co<\/strong>\u3001<\/strong>Ni<\/strong>\u7684\u50a8\u91cf\u53ca\u5176<\/strong>MOF<\/strong>\u8fd1\u5e74\u6765\u5728\u50a8\u80fd\u9886\u57df\u7684\u53d1\u5c55<\/strong><\/p>\n \uff08<\/strong>a<\/strong>\uff09<\/strong>\u8fc7\u6e21\u91d1\u5c5e\uff08Fe\uff0cCo\uff0cNi\uff09\u5728\u5730\u58f3\u4e2d\u5206\u5e03\u60c5\u51b5\u997c\u56fe\uff1b<\/p>\n \uff08<\/strong>b<\/strong>\uff09<\/strong>\u8fd1\u5341\u5e74\u6765\uff0c\u8fc7\u6e21\u91d1\u5c5e\uff08Fe\uff0cCo\uff0cNi\uff09\u57faMOF\u53ca\u5176\u884d\u751f\u7269\u7528\u4e8e\u5404\u7535\u5316\u5b66\u50a8\u80fd\u53d1\u8868\u6587\u7ae0\u6570\u7684\u67f1\u72b6\u56fe\uff1b<\/p>\n \uff08<\/strong>c<\/strong>\uff09<\/strong>\u8fd1\u5341\u5e74\u6765\uff0c\u5206\u522b\u4ee5Fe\uff0cCo\uff0cNi\u4e3a\u57fa\u7684MOF\u53ca\u5176\u884d\u751f\u7269\u7528\u4e8e\u7535\u5316\u5b66\u50a8\u80fd\u53d1\u8868\u6587\u7ae0\u6570\u7684\u6298\u7ebf\u56fe\u3002<\/p>\n 2. MOF<\/strong>\u6750\u6599\u5728\u8d85\u7ea7\u7535\u5bb9\u5668\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n \u8d85\u7ea7\u7535\u5bb9\u5668\u4f5c\u4e3a\u65b0\u578b\u7684\u7535\u5bb9\u5668\uff0c\u5177\u5907\u80fd\u591f\u5feb\u901f\u5145\u653e\u7535\u7684\u80fd\u529b\uff0c\u800c\u5176\u7535\u6781\u6750\u6599\u5bf9\u4e8e\u5668\u4ef6\u7684\u6027\u80fd\u8d77\u5230\u4e86\u51b3\u5b9a\u6027\u4f5c\u7528\uff0c\u8981\u63d0\u5347\u8d85\u7ea7\u7535\u5bb9\u5668\u6027\u80fd\u7684\u5173\u952e\u5728\u4e8e\u63d0\u5347\u7535\u6781\u6750\u6599\u7684\u6bd4\u8868\u9762\u79ef\u5927\u5c0f\uff0c\u7531\u4e8eMOF\u5177\u6709\u9ad8\u5ea6\u53ef\u63a7\u7684\u7ed3\u6784\u540c\u65f6\u80fd\u591f\u4ea7\u751f\u591a\u5b54\u5f62\u8c8c\uff0c\u56e0\u6b64\u6210\u4e3a\u4e86\u8d85\u7ea7\u7535\u5bb9\u5668\u7535\u6781\u7684\u7406\u60f3\u6750\u6599\u3002\u7136\u800c\uff0c\u5236\u7ea6MOF\u5728\u8d85\u7ea7\u7535\u5bb9\u5668\u4e2d\u53d1\u5c55\u7684\u5173\u952e\u95ee\u9898\u662fMOF\u7684\u5bfc\u7535\u6027\u8f83\u5dee\uff0c\u5728\u5b9e\u9645\u7684\u5e94\u7528\u4e2d\u7814\u7a76\u8005\u5df2\u7ecf\u901a\u8fc7\u8bbe\u8ba1\u76f8\u5173\u7684\u6263\u5f0f\u8d85\u7ea7\u7535\u5bb9\u5668\u7ed3\u6784\u89e3\u51b3\u4e86\u5176\u5bfc\u7535\u6027\u95ee\u9898\u3002<\/p>\n \u56fe<\/strong>2 nMOF<\/strong>\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u7ed3\u6784\u8bbe\u8ba1\u56fe<\/strong><\/p>\n 2.1 Fe<\/strong>\u57fa<\/strong>MOF<\/strong>\u53ca\u5176\u884d\u751f\u7269\u7684\u5e94\u7528<\/strong><\/p>\n \u4e3a\u4e86\u63d0\u5347MOF\u7684\u5bfc\u7535\u6027\u80fd\uff0c\u5e38\u901a\u8fc7\u590d\u5408\u78b3\u7eb3\u7c73\u7ba1\u6765\u63d0\u5347\u6750\u6599\u6574\u4f53\u7684\u5bfc\u7535\u6027\u4ee5\u671f\u83b7\u5f97\u66f4\u597d\u7684\u6027\u80fd\uff0c\u73b0\u5df2\u6709\u591a\u79cdFe\u57faMOF\u6750\u6599\u80fd\u591f\u901a\u8fc7\u6b64\u65b9\u6cd5\u5236\u5907\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u7535\u6781\u6750\u6599\u3002\u7136\u800c\uff0c\u539f\u59cb\u7684Fe\u57faMOF\u5e94\u7528\u4e8e\u8d85\u7ea7\u7535\u5bb9\u5668\u4e2d\u7684\u76f8\u5173\u62a5\u9053\u5341\u5206\u6709\u9650\uff0c\u5728\u63a2\u7a76\u4e2d\u5e38\u901a\u8fc7\u4ee5Fe\u57faMOF\u4f5c\u4e3a\u524d\u9a71\u4f53\uff0c\u76f4\u63a5\u5236\u5907\u5f97\u5230\u6c27\u5316\u7269\u4e0e\u78b3\u6750\u6599\u7684\u590d\u5408\u6750\u6599\u6216\u78b3\u5316Fe\u57faMOF\u7684\u5e72\u51dd\u80f6\u5f97\u5230\u6700\u7ec8\u7684\u6d3b\u6027\u6750\u6599\u3002<\/p>\n \u56fe<\/strong>3 Fe<\/strong>\u57fa\u884d\u751f\u7269\u7684\u5236\u5907\u53ca\u5176\u5728\u8d85\u7ea7\u7535\u5bb9\u5668\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n \uff08<\/strong>a<\/strong>\uff09<\/strong> \u4ee5NPC\u4e3a\u8d1f\u6781\u3001MOXC-Fe\u4e3a\u6b63\u6781\u7684\u975e\u5bf9\u79f0\u8d85\u7ea7\u7535\u5bb9\u5668\u548c\u6750\u6599\u5236\u5907\u793a\u610f\u56fe\uff1b<\/p>\n \uff08<\/strong>b<\/strong>\uff09<\/strong>\u975e\u5bf9\u79f0\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u7ec4\u88c5\uff1b<\/p>\n \uff08<\/strong>c<\/strong>\uff09<\/strong>\u975e\u5bf9\u79f0\u7535\u5bb9\u5668\u7684Ragone\u56fe\u5bf9\u6bd4\uff1b<\/p>\n 2.2\u00a0Co<\/strong>\u57fa<\/strong>MOF<\/strong>\u53ca\u5176\u884d\u751f\u7269\u7684\u5e94\u7528<\/strong><\/p>\n \u76f4\u63a5\u5229\u7528Co\u57faMOF\u4f5c\u4e3a\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u6d3b\u6027\u7269\u8d28\u9700\u8981\u501f\u52a9\u78b3\u6750\u6599\u6765\u63d0\u5347\u5bfc\u7535\u6027\uff0c\u800c\u5728\u5176\u884d\u751f\u7269\u7684\u5e94\u7528\u4e2d\uff0c\u901a\u5e38\u901a\u8fc7\u5236\u5907\u5f97\u5230\u4e0d\u540c\u5f62\u8c8c\u7684\u6750\u6599\u8fdb\u884c\u5668\u4ef6\u6027\u80fd\u7684\u4f18\u5316\uff0cCo\u57faMOF\u5c31\u5305\u62ec\u6811\u679d\u72b6\u3001\u591a\u5b54\u3001\u4e2d\u7a7a\u3001\u83f1\u5f62\u5341\u4e8c\u9762\u4f53\u3001\u5206\u5c42\u7ea7\u7ed3\u6784\u7b49\u591a\u79cd\u591a\u6837\u7684\u5f62\u8c8c\uff0c\u5728\u8d85\u7ea7\u7535\u5bb9\u5668\u4e2d\u5df2\u7ecf\u5f97\u5230\u4e86\u5e7f\u6cdb\u7684\u5e94\u7528\u3002<\/p>\n \u56fe<\/strong>4 Co<\/strong>\u57fa<\/strong>MOF<\/strong>\u7684\u76f8\u5173\u5e94\u7528\u53ca\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n \uff08<\/strong>a<\/strong>\uff09<\/strong>PANI\u8fde\u63a5\u7684MOF\u548cMOF\u4e2d\u7535\u5b50\u4e0e\u7535\u89e3\u8d28\u4f20\u5bfc\u793a\u610f\u56fe\u3002<\/p>\n \uff08<\/strong>b<\/strong>\uff09<\/strong>PANI-ZIF-67-CC\u7535\u6781\u7684\u4e24\u6b65\u5236\u4f5c\u5de5\u827a\uff1b<\/p>\n \uff08<\/strong>c<\/strong>\uff09<\/strong>\u4e0d\u540c\u626b\u901f\u6761\u4ef6\u4e0b\u7684PANI-ZIF-67-CC\u7535\u6781\u5faa\u73af\u4f0f\u5b89\u56fe\uff1b<\/p>\n \uff08<\/strong>d<\/strong>\uff09<\/strong>\u56fa\u6001\u8d85\u7ea7\u7535\u5bb9\u5668\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u6052\u7535\u6d41\u5145\u653e\u7535\u66f2\u7ebf\u3002<\/p>\n \u56fe<\/strong>5 Co<\/strong>\u57fa\u884d\u751f\u7269\u6750\u6599\u7684\u5236\u5907\u53ca\u5176\u5e94\u7528\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n \uff08<\/strong>a<\/strong>\uff09<\/strong>\u5408\u6210\u591a\u5b54Co3<\/sub>O4<\/sub>\u805a\u96c6\u4f53\u7684\u5b9e\u9a8c\u6d41\u7a0b\uff1b<\/p>\n \uff08<\/strong>b<\/strong>\uff09<\/strong>\u5408\u6210\u6811\u679d\u72b6\u7eb3\u7c73\u7ed3\u6784Co3<\/sub>O4<\/sub>\u7684\u5b9e\u9a8c\u6d41\u7a0b\uff1b<\/p>\n \uff08<\/strong>c<\/strong>\uff09<\/strong>JUC-155\u7684\u7ec4\u6210\u57fa\u672c\u5355\u4f4d\uff1b<\/p>\n \uff08<\/strong>d<\/strong>\uff09<\/strong>ZIF-67\u83f1\u5f62\u5341\u4e8c\u9762\u4f53\u7684SEM\u56fe\u50cf\uff0c\u63d2\u56fe\u4e3a\u83f1\u5f62\u5341\u4e8c\u9762\u4f53\uff1b<\/p>\n \uff08<\/strong>e<\/strong>\uff09<\/strong>\u591a\u5b54\u4e2d\u7a7aCo3<\/sub>O4<\/sub>\u83f1\u5f62\u5341\u4e8c\u9762\u4f53\u7684SEM\u56fe\u50cf\uff1b<\/p>\n \uff08<\/strong>f<\/strong>\uff09<\/strong>\u5728\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\uff0c\u591a\u5b54\u4e2d\u7a7aCo3<\/sub>O4<\/sub>\u83f1\u5f62\u5341\u4e8c\u9762\u4f53\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\uff1b<\/p>\n \uff08<\/strong>g<\/strong>\uff09<\/strong>\u591a\u5b54\u4e2d\u7a7aCo3<\/sub>O4<\/sub>\u83f1\u5f62\u5341\u4e8c\u9762\u4f53\u7535\u6781\u7684\u6bd4\u7535\u5bb9\uff1b<\/p>\n \uff08<\/strong>h<\/strong>\uff09<\/strong>\u591a\u5b54\u4e2d\u7a7aCo3<\/sub>O4<\/sub>\u83f1\u5f62\u5341\u4e8c\u9762\u4f53\u7684\u6bd4\u7535\u5bb9\u5faa\u73af\u6027\u80fd\u66f2\u7ebf\u3002<\/p>\n 2.3 Ni<\/strong>\u57fa<\/strong>MOF<\/strong>\u53ca\u5176\u884d\u751f\u7269\u7684\u5e94\u7528<\/strong><\/p>\n \u5728\u50a8\u80fd\u5668\u4ef6\u4e2d\uff0cMOF\u4e00\u822c\u901a\u8fc7\u4e24\u79cd\u9014\u5f84\u8fdb\u884c\u5e94\u7528\uff1a\u4e00\u662f\u901a\u8fc7\u4ee5\u8be5\u6750\u6599\u4f5c\u4e3a\u524d\u9a71\u4f53\u78b3\u5316\u5f97\u5230\u6240\u9700\u7684\u91d1\u5c5e\u6c27\u5316\u7269\u6216\u91d1\u5c5e\u6c27\u5316\u7269\u4e0e\u78b3\u7684\u590d\u5408\u6750\u6599\uff0c\u901a\u8fc7\u8fd9\u79cd\u65b9\u6cd5\u80fd\u591f\u5f97\u5230\u5355\u79cd\u91d1\u5c5e\u6c27\u5316\u7269\u6216\u5176\u4e0e\u78b3\u6750\u6599\u7684\u590d\u5408\u7269\uff1b\u4e8c\u662f\u76f4\u63a5\u5229\u7528\u5236\u5907\u5f97\u5230\u7684\u539fMOF\u6750\u6599\u4f5c\u4e3a\u7535\u6781\uff0c\u8fd9\u79cd\u65b9\u6cd5\u6781\u5177\u6311\u6218\u6027\u4e14\u6027\u80fd\u8f83\u5dee\uff0c\u4f46\u4e0d\u53ef\u5426\u8ba4\u7684\u662f\uff0c\u901a\u8fc7\u9009\u62e9\u914d\u4f4d\u7684\u82b3\u9999\u70c3\u6216\u542b\u5171\u8f6d\u03c0\u952e\u7684\u7ed3\u6784\u80fd\u591f\u663e\u8457\u63d0\u5347\u6750\u6599\u7684\u5bfc\u7535\u6027\u80fd\u3002<\/p>\n \u56fe<\/strong>6 Ni<\/strong>\u57fa<\/strong>MOF<\/strong>\u7684\u7ed3\u6784\u53ca\u5176\u76f4\u63a5\u7ec4\u88c5\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u6027\u80fd<\/strong><\/p>\n \uff08<\/strong>a<\/strong>\uff09<\/strong>Ni3<\/sub>(HITP)2<\/sub>\u7684\u5206\u5b50\u7ed3\u6784\u793a\u610f\u56fe\uff1b<\/p>\n \uff08<\/strong>b<\/strong>\uff09<\/strong>\u5728\u7406\u60f3\u5316Ni3<\/sub>(HITP)2<\/sub>\u5b54\u9699\u56fe\u4e2d\uff0c\u7535\u89e3\u8d28Et4<\/sub>N+<\/sup>\u3001BF4-<\/sup>\u548c\u4e59\u8148\u6eb6\u5242\u5206\u5b50\u7684\u586b\u5145\u60c5\u51b5\uff1b<\/p>\n \uff08<\/strong>c<\/strong>\uff09<\/strong>\u57282A g-1<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5faa\u73af10000\u5708\u4e4b\u540e\u7684\u7535\u5bb9\u4fdd\u6301\u7387\uff1b<\/p>\n \uff08<\/strong>d<\/strong>\uff09<\/strong>Ni3<\/sub>(HITP)2<\/sub>\u7c89\u672b\u5728\u4e09\u7535\u6781\u6d4b\u8bd5\u4e2d\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\uff1b<\/p>\n \u57fa\u4e8eNi\u7684MOF\u6613\u4e8e\u901a\u8fc7\u70ed\u5904\u7406\u5236\u5f97\u591a\u5b54\u7684\u954d\u7684\u6c27\u5316\u7269\u53ca\u5176\u4e0e\u78b3\u6750\u6599\u7684\u590d\u5408\u6750\u6599\uff0c\u591a\u6837\u5316\u7684\u5f62\u8c8c\u4e30\u5bcc\u4e86\u5176\u5728\u8d85\u7ea7\u7535\u5bb9\u5668\u4e2d\u7684\u5e94\u7528\uff0c\u5305\u62ec\u7eb3\u7c73\u7ba1\u3001\u7eb3\u7c73\u82b1\u3001\u7eb3\u7c73\u9488\u72b6\u4ee5\u53ca\u4e0e\u78b3\u6750\u6599\u6784\u6210\u5305\u8986\u7b49\u5f62\u8c8c\uff0c\u5176\u4e0d\u4ec5\u80fd\u591f\u4f5c\u4e3a\u8d85\u7ea7\u7535\u5bb9\u5668\u4e2d\u7684\u7535\u6781\u6750\u6599\uff0c\u5728\u975e\u5bf9\u79f0\u5668\u4ef6\u4e2d\u4e5f\u80fd\u5e94\u7528\u4e8e\u6b63\u6781\u6750\u6599\u4e2d\u3002<\/p>\n \u56fe<\/strong>7 Co<\/strong>\u57fa<\/strong>MOF<\/strong>\u884d\u751f\u7269\u7684\u6750\u6599\u5236\u5907\u4e0e\u8d85\u7ea7\u7535\u5bb9\u5668\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n \uff08<\/strong>a<\/strong>\uff09<\/strong>DMOF\u7684\u5408\u6210\u8fc7\u7a0b\u793a\u610f\u56fe\u548c3D Ni-DMOF-ADC\u7684\u7ebf\u6846\u7ed3\u6784\u56fe\uff1b<\/p>\n \uff08<\/strong>b<\/strong>\uff09<\/strong>\u591a\u5b54NiO\u7eb3\u7c73\u7403\u8f74\u7684\u5b9e\u9a8c\u5236\u5907\u6d41\u7a0b\uff1b<\/p>\n \uff08<\/strong>c<\/strong>\uff09<\/strong>\u78b3\u7eb3\u7c73\u7ba1\u4e0eNiO\u8d85\u8584\u7eb3\u7c73\u7247\u590d\u5408\u6750\u6599\u7684\u975e\u5bf9\u79f0\u8d85\u7ea7\u7535\u5bb9\u5668\u793a\u610f\u56fe\u3002<\/p>\n \uff08<\/strong>d<\/strong>\uff09<\/strong>\u5408\u6210CNT@NiO\u590d\u5408\u6750\u6599\u7684\u5b9e\u9a8c\u5236\u5907\u6d41\u7a0b\uff1b<\/p>\n \uff08<\/strong>e<\/strong>\uff09<\/strong>RGO\u548cNi\u63ba\u6742\u7684MOF-5\u590d\u5408\u6750\u6599\u7684\u5b9e\u9a8c\u5236\u5907\u6d41\u7a0b\u4ee5\u53ca\u5176\u5177\u6709\u4fc3\u8fdb\u6709\u6548\u548c\u9ad8\u6548\u7684\u7535\u8377\u8f6c\u79fb\u8fc7\u7a0b\u7684\u534f\u540c\u4f5c\u7528\u7684\u793a\u610f\u56fe\uff1b<\/p>\n \uff08<\/strong>f<\/strong>\uff09<\/strong>PCP\u7684FESEM\u56fe\u50cf\uff0c\u63d2\u56fe\u663e\u793a\u83f1\u5f62\u5341\u4e8c\u9762\u4f53\u548c\u622a\u9876\u83f1\u5f62\u5341\u4e8c\u9762\u4f53\uff1b<\/p>\n \uff08<\/strong>g<\/strong>\uff09<\/strong>\u548c\uff08<\/strong>h<\/strong>\uff09<\/strong>\u4e3aNiO\u7eb3\u7c73\u7ba1\u7684SEM\u548cTEM\u56fe\u50cf\uff1b<\/p>\n \uff08<\/strong>i<\/strong>\uff09<\/strong>Zn\u63ba\u6742\u524d\u540e\u7684Ni-MOF\u53ef\u80fd\u4ea7\u751f\u7684\u7ed3\u6784\u53d8\u5316\uff1b<\/p>\n \uff08<\/strong>j<\/strong>\uff09<\/strong>\u57fa\u4e8eNiO-a\/g\u4e0eNG\u6216AC\u7535\u6781\u7684\u975e\u5bf9\u79f0\u7535\u5bb9\u5668\u7684\u5faa\u73af\u6027\u80fd\u5bf9\u6bd4\uff1b<\/p>\n \uff08<\/strong>k<\/strong>\uff09<\/strong>\u572810 A g-1\u7535\u6d41\u5bc6\u5ea6\u6761\u4ef6\u4e0b\uff0c\u57fa\u4e8eNi-DMOF\u7684\u975e\u5bf9\u79f0\u8d85\u7ea7\u7535\u5bb9\u5668\u5faa\u73af\u6027\u80fd\uff1b<\/p>\n \uff08<\/strong>l<\/strong>\uff09<\/strong>Ni-DMOF-ADC\u7684\u6bd4\u7535\u5bb9\u3002<\/p>\n 2.4 MOF<\/strong>\u6df7\u5408\u7269\u53ca\u5176\u884d\u751f\u7269\u7684\u5e94\u7528<\/strong><\/p>\n \u5bf9\u4e8eNi\u57faMOF\u6765\u8bf4\uff0c\u5176\u6df7\u5408\u7269\u884d\u751f\u7269\u4e3b\u8981\u662f\u57fa\u4e8e\u6c22\u6c27\u5316\u7269\u53d1\u5c55\u8d77\u6765\u7684\uff0c\u5e38\u89c1\u7684\u4e0d\u540c\u6676\u4f53\u7ed3\u6784\u548c\u5f62\u8c8c\u7684Ni(OH)2<\/sub>\u662f\u4e00\u79cdp\u578b\u534a\u5bfc\u4f53\u6750\u6599\uff0c\u500d\u7387\u6027\u80fd\u548c\u5bfc\u7535\u6027\u5dee\u6210\u4e3a\u4e86\u5236\u7ea6\u5176\u5e94\u7528\u7684\u5173\u952e\u95ee\u9898\u3002\u5728\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u5e94\u7528\u4e2d\uff0c\u7814\u7a76\u8005\u901a\u8fc7\u5f15\u5165\u5176\u4ed6\u91d1\u5c5e\u79bb\u5b50\u6216\u4e0e\u5176\u4ed6\u91d1\u5c5e\u5143\u7d20\u5f62\u6210\u5171\u91d1\u5c5e\uff0c\u4ece\u800c\u63d0\u5347MOF\u7684\u7efc\u5408\u6027\u80fd\uff0c\u8fd9\u80fd\u591f\u66f4\u597d\u5730\u7528\u4e8e\u8d85\u7ea7\u7535\u5bb9\u5668\u4e2d\u3002<\/p>\n \u56fe<\/strong>8\u00a0<\/strong>\u6df7\u5408<\/strong>Ni<\/strong>\u57fa<\/strong>MOF<\/strong>\u53ca\u5176\u884d\u751f\u7269\u7684\u5236\u5907\u548c\u5e94\u7528\u4e8e\u8d85\u7ea7\u7535\u5bb9\u5668\u4e2d\u7684\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n \uff08<\/strong>a<\/strong>\uff09<\/strong>\u548c\uff08<\/strong>b<\/strong>\uff09<\/strong>\u4e3aNix<\/sub>Co1-x<\/sub>(OH)2<\/sub>\u590d\u5408\u6750\u6599\u7684SEM\u3001TEM\u4ee5\u53caHRTEM\u56fe\u50cf\uff1b<\/p>\n \uff08<\/strong>c<\/strong>\uff09<\/strong>MOF\u884d\u751f\u7269Nix<\/sub>Co1-x<\/sub>(OH)2<\/sub> \/\/ AC\u5668\u4ef6\u7684Ragone\u56fe\uff1b<\/p>\n
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