{"id":84262,"date":"2017-06-12T06:30:07","date_gmt":"2017-06-11T22:30:07","guid":{"rendered":"\/\/m.iemloyee.com\/?p=84262"},"modified":"2017-06-07T13:25:02","modified_gmt":"2017-06-07T05:25:02","slug":"%e4%b8%ad%e7%a7%91%e9%99%a2%e5%8c%96%e5%ad%a6%e6%89%80jacs%ef%bc%9a%e5%9c%a8%e6%97%a0%e5%af%8c%e5%8b%92%e7%83%af%e4%b8%b2%e8%81%94%e6%9c%89%e6%9c%ba%e5%a4%aa%e9%98%b3%e8%83%bd%e7%94%b5%e6%b1%a0","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=84262","title":{"rendered":"\u4e2d\u79d1\u9662\u5316\u5b66\u6240JACS\uff1a\u5728\u65e0\u5bcc\u52d2\u70ef\u4e32\u8054\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u901a\u8fc7\u5fae\u8c03\u5149\u654f\u548c\u4ea4\u4e92\u5c42\u5b9e\u73b0\u8d85\u8fc713%\u7684\u6548\u7387"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u6eb6\u6db2\u6cd5\u5236\u5907\u7684\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u7684\u5149\u654f\u5c42\u7531\u6709\u673a\u534a\u5bfc\u4f53\u7ec4\u6210\uff0c\u7531\u4e8e\u5176\u4f18\u70b9\u80fd\u591f\u901a\u8fc7\u5ec9\u4ef7\u6253\u5370\u6280\u672f\u5236\u5907\u8d28\u8f7b\u3001\u5927\u6bd4\u8868\u9762\u79ef\u548c\u67d4\u6027\u592a\u9633\u80fd\u677f\u800c\u53d7\u5230\u5173\u6ce8\u3002\u56e0\u4e3a\u6709\u673a\u534a\u5bfc\u4f53\u7684\u5149\u5438\u6536\u6765\u6e90\u4e8e\u6700\u9ad8\u5360\u636e\u5206\u5b50\u8f68\u9053\uff08HOMO\uff09\u548c\u6700\u4f4e\u672a\u5360\u636e\u8f68\u9053\uff08LUMO\uff09\u4e4b\u95f4\u7684\u03c0-\u03c0*<\/sup>\u8f6c\u53d8\uff0c\u8fd9\u4e9b\u6750\u6599\u663e\u793a\u51fa\u7684\u5438\u6536\u5cf0\u5728\u534a\u6700\u5927\u5904\u5177\u6709\u7a84\u7684\u5168\u5bbd\u9650\u5236\u4e86\u5bf9\u592a\u9633\u5149\u7684\u6536\u96c6\uff0c\u56e0\u6b64\u901a\u8fc7\u5806\u53e0\u5177\u6709\u8fde\u7eed\u8865\u507f\u5438\u6536\u5149\u8c31\u7684\u4e24\u5c42\u548c\u66f4\u591a\u5c42\u5149\u654f\u5c42\u7ec4\u5efa\u4e32\u8054\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u4f5c\u4e3a\u63d0\u9ad8\u5149\u5438\u6536\u7684\u6709\u6548\u65b9\u6cd5\u3002\u5728\u5149\u654f\u6750\u6599\u4e2d\uff0c\u4f20\u7edf\u7684\u4ea4\u4e92\u5c42\u7531\u4e24\u5c42\u7ed3\u6784\u7ec4\u6210\u5305\u62ec\u4e00\u4e2ap\u578b\u548cn\u578b\u4ea4\u4e92\u5c42\u6750\u6599\uff0c\u540c\u65f6\u5728\u4e32\u8054\u7684\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u4f1a\u5f71\u54cd\u5176\u5149\u654f\u6027\u80fd\u3002<\/p>\n

\u6700\u8fd1\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u5316\u5b66\u7814\u7a76\u6240\u4faf\u5251\u8f89\u7814\u7a76\u5458\u3001\u8bb8\u535a\u4e3a\u526f\u7814\u7a76\u5458\uff08\u5171\u540c\u901a\u8baf\uff09<\/strong>\u5728Journal of the American Chemical Society<\/strong> \u4e0a\u4ee5\u201cFine-Tuned Photoactive and Interconnection Layers for Achieving over 13% Efficiency in a Fullerene-Free Tandem Organic Solar Cell<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u6587\u7ae0\uff0c\u6587\u7ae0\u4e2d\u7814\u7a76\u8005\u4eec\u8bbe\u8ba1\u4e86\u4e00\u79cd\u65b0\u578b\u65e0\u5bcc\u52d2\u70ef\u5177\u67091.68V\u5149\u7981\u5e26\u7684\u63a5\u6536\u5668\u63a5\u6536\u524d\u65b9\u592a\u9633\u5149\uff0c\u5e76\u4e14\u4f18\u5316\u4e00\u4e2a\u5177\u67091.36eV Eg<\/sub>opt<\/sup>\u65e0\u5bcc\u52d2\u70ef\u6d3b\u6027\u5c42\u7684\u76f8\u4f4d\u5206\u79bb\u5f62\u6001\u5236\u5907\u540e\u65b9\u5b50\u5355\u5143\u3002\u4e24\u4e2a\u5b50\u5355\u5143\u5177\u6709\u4f4e\u80fd\u8017\u3001\u9ad8\u8868\u9762\u91cf\u5b50\u6548\u7387\u3001\u5149\u54cd\u5e94\u8c31\u4e92\u8865\uff1b\u53e6\u5916\uff0c\u4ea4\u4e92\u5c42\u7531ZnO\u3001\u4e2d\u6027\u81ea\u63ba\u6742\u5bfc\u7535\u805a\u5408\u7269\u3001PCP-Na\u7ec4\u6210\uff0c\u5728\u8fd1\u7ea2\u5916\u533a\u57df\u5177\u6709\u9ad8\u900f\u5149\u7cfb\u6570\u3002<\/p>\n

\u82f1\u6587\u7f29\u5199\u6ce8\u91ca\uff1a<\/strong><\/p>\n

PCE\u00a0<\/strong> \u529f\u7387\u8f6c\u6362\u6548\u7387\uff1b\u00a0 ICL<\/strong>\u00a0\u00a0 \u4ea4\u4e92\u5c42\uff1b\u00a0 OSCs\u00a0<\/strong> \u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\uff1b\u00a0\u00a0 NBG\u00a0<\/strong> \u7a84\u5e26\u9699\uff1b\u00a0 EOE<\/strong>\u00a0 \u5916\u90e8\u91cf\u5b50\u6548\u7387\uff1b\u00a0\u00a0 NF\u00a0<\/strong> \u65e0\u5bcc\u52d2 \u70ef\uff1bWBG\u00a0<\/strong> \u5bbd\u5e26\u9699\uff1b\u00a0 ICT<\/strong> \u5206\u5b50\u95f4\u7535\u8377\u8f6c\u79fb\uff1b\u00a0 FF\u00a0<\/strong> \u586b\u5145\u56e0\u5b50\uff1b<\/p>\n

ITCC-M \u00a0<\/strong> \u00a03,9-bis((Z)-1-(6-(dicyanomethylene)-2-methyl-5,6-dihydro-6H-cyclopenta[b]thiophen-6-one-5-yl)ethylene)-5,5,11,11-tetrakis(4-hexylphenyl)dithieno[2,3-d:2\u2032,3\u2032-d\u2032]-sindaceno[1,2-b:5,6-b\u2032]dithiophene<\/p>\n

ITIC<\/strong> \u00a0 \u00a03,9-bis(2-methylene-(3-(1,1-dicyanomethylene)-indanone)-5,5,11,11-tetrakis(4-hexylphenyl)dithieno[2,3-d:2\u2032,3\u2032-d\u2032]-s-indaceno[1,2-b:5,6-b\u2032]dithiophene<\/p>\n

PBDBT<\/strong> \u00a0 \u00a0poly[(2,6-(4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)benzo[1,2-b:4,5-b\u2032]dithiophene)-co-(1,3-bis(5-thiophene-2-yl)-5,7-bis(2-ethylhexyl)benzo[1,2-c:4,5-c]dithiophene-4,8-dione)]<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00 \u4e32\u8054\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u6750\u6599\u6027\u8d28<\/strong><\/p>\n

\"\"<\/p>\n

a,c)\u524d\u534a\u7535\u6c60\u7ed9\u7535\u5b50\u548c\u540e\u534a\u7535\u6c60\u53d7\u7535\u5b50\u6750\u6599\u7684\u5206\u5b50\u7ed3\u6784\uff1b<\/p>\n

d)\u5728\u4e32\u8054\u7535\u6c60\u4e2d\u4ea4\u4e92\u5c42\uff0cPCO-Na\u7684\u5206\u5b50\u7ed3\u6784\uff1b<\/p>\n

b)\u4e32\u8054\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u7684\u5668\u4ef6\u7ed3\u6784\uff1b<\/p>\n

e)ITIC\u5206\u5b50\u7ed3\u6784\uff1b<\/p>\n

f)\u7814\u7a76\u4e2d\u6240\u7528\u5230\u6750\u6599\u7684\u80fd\u7ea7\u539f\u7406\u56fe\u3002<\/p>\n

\u56fe\u4e8c ITIC\u548cITIC-M\u7684\u6027\u8d28<\/strong><\/p>\n

\"\"<\/p>\n

a)\u5728B3LYP\/6-31G(d,p)\u6c34\u5e73\u4e0b\u8ba1\u7b97ITIC\u548cITIC-M\u7684\u8868\u9762HOMO\u548cLUMO\uff1b<\/p>\n

b) ITIC\u548cITIC-M\u7684\u6b63\u5e38\u5438\u6536\u5cf0\u56fe\u8c31\uff1b<\/p>\n

c,d)PBDB-T:ITIC\u548cPBDB-T:ITIC-M\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u7684J-V\u66f2\u7ebf\u548cEQE\u66f2\u7ebf\u3002<\/p>\n

\u56fe\u4e09\u00a0PBDTTT-E-T:IEICO\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a,b) \u5728\u4e0d\u540c\u60c5\u51b5\u4e0b\u5236\u5907\u7684PBDTTT-E-T:IEICO\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u7684J-V\u66f2\u7ebf\u548cEQE\uff1b<\/p>\n

c-e) PBDTTT-E-T:IEICO\u5f2f\u66f2\u8584\u819c\u7684AFM\u5730\u5f62\u56fe\u3001AFM\u76f8\u56fe\u548cTEM\u56fe\uff08c:\u6ca1\u6709SVA\uff1bd:\u5728CB\u84b8\u6c7d\u4e2d\u66b4\u97321min\uff1be: \u5728CB\u84b8\u6c7d\u4e2d\u66b4\u97324min\uff09\u3002<\/p>\n

\u56fe\u56db\u00a0ZnO\/PCP-Na\u5668\u4ef6\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a)\u4e0d\u540cPCP-Na\u539a\u5ea6ZnO\/PCP-Na ICLs\u7684\u900f\u5c04\u5149\u8c31\uff1b<\/p>\n

b) ZnO\/PCP-Na \u5668\u4ef6\u7684\u4e8c\u6781\u7ba1\u7279\u6027\u66f2\u7ebf\uff1b<\/p>\n

c,d)\u4e32\u8054\u7535\u6c60\u524d\u534a\u7535\u6c60\u548c\u540e\u534a\u7535\u6c60\u7684J-V\u66f2\u7ebf\u548cEQE\u66f2\u7ebf\uff1b<\/p>\n

e)72\u5355\u4e2a\u4f53\u7535\u6c60 \u7684PCE\u6570\u636e\u76f4\u65b9\u56fe\uff1b<\/p>\n

f)\u4f9d\u636e\u5165\u5c04\u5149\u5bc6\u5ea6\u7684\u4e32\u8054\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u7684PCE\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u8005\u4eec\u901a\u8fc7\u5b8c\u5168\u4f18\u5316\u4e24\u7535\u6c60\u548cICL\u7684\u6d3b\u6027\u5c42\u5236\u5907\u5f97\u5230\u9ad8\u5ea6\u6709\u6548\u5730\u65e0\u5bcc\u52d2\u70ef\u4e32\u8054\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\uff0c\u8bbe\u8ba1WBG\u524d\u534a\u7535\u6c60\u3001\u65b0\u578bSM NF\u9694\u819c\u3001ITCC-M\u7528\u4e8e\u5b9e\u73b0\u7a84\u5438\u9644\u8c31\uff0c\u5177\u6709\u9ad8\u7684Voc<\/sub>\uff1b\u901a\u8fc7\u4f18\u5316NBG\u540e\u534a\u7535\u6c60\u3001\u9633\u6781\u7f13\u51b2\u5c42\u548c\u6d3b\u6027\u5c42\u7684\u76f8\u5206\u79bb\u5f62\u6001\u53ef\u4ee5\u5728\u8fd1\u7ea2\u5916\u533a\u57df\u5b9e\u73b0\u9ad8EQE\u3002\u901a\u8fc7\u4f7f\u7528\u4f18\u5316\u539a\u5ea6\u7684ICL\u5b9e\u73b0\u7535\u8377\u6536\u96c6\u548c\u590d\u5408\u8fd8\u6709\u9ad8\u900f\u5149\u7cfb\u6570\uff0c\u5236\u5907\u5f97\u5230\u7684\u4e32\u8054\u7535\u6c60\u7684PCEs\u57280.02-1sun\u7684\u5149\u7167\u4e0b\u53ef\u8fbe13%-14%\u3002\u603b\u4f53\u6765\u8bf4\uff0c\u6587\u7ae0\u4e2d\u7684\u5de5\u4f5c\u4e0d\u4ec5\u8bc1\u5b9e\u4e86\u7cfb\u7edf\u7684\u5de5\u4f5c\u53ef\u4ee5\u5b9e\u73b0\u4f18\u5f02\u7684\u5149\u7535\u7ed3\u679c\uff0c\u8fd8\u663e\u793a\u51fa\u65e0\u5bcc\u52d2\u70ef\u4e32\u8054\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u7684\u8d85\u9ad8\u6027\u80fd\u3002\u4f46\u662f\u7531\u4e8e\u6700\u4f18\u5668\u4ef6\u7684\u5168\u90e8EQE\u4ecd\u4e0d\u662f\u5f88\u9ad8\uff0c\u586b\u5145\u56e0\u5b50FF\u4e5f\u53ea\u67090.639\uff0c\u56e0\u6b64\u5728\u5176\u5149\u7535\u6027\u80fd\u4e0a\u672a\u6765\u8fd8\u6709\u5f88\u5927\u5730\u63d0\u5347\u7a7a\u95f4\u3002<\/p>\n

\u539f\u6587\u94fe\u63a5<\/strong>\uff1aFine-Tuned Photoactive and Interconnection Layers for Achieving over 13% Efficiency in a Fullerene-Free Tandem Organic Solar Cell<\/a>.( J. Am. Chem. Soc. , 2017, DOI: 10.1021\/jacs.7b01493)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u7ec4Jane915126\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065952\u201d\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c<\/strong>\u4e0a\u6d4b\u8bd5\u8c37<\/a><\/strong>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u6eb6\u6db2\u6cd5\u5236\u5907\u7684\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u7684\u5149\u654f\u5c42\u7531\u6709\u673a\u534a\u5bfc\u4f53\u7ec4\u6210\uff0c\u7531\u4e8e\u5176\u4f18\u70b9\u80fd\u591f\u901a\u8fc7\u5ec9\u4ef7\u6253\u5370\u6280\u672f\u5236\u5907\u8d28\u8f7b\u3001\u5927\u6bd4\u8868\u9762\u79ef\u548c\u67d4\u6027\u592a\u9633\u80fd\u677f\u800c\u53d7\u5230\u5173\u6ce8\u3002\u56e0\u4e3a\u6709\u673a\u534a\u5bfc\u4f53\u7684\u5149\u5438\u6536…<\/p>\n","protected":false},"author":369,"featured_media":85451,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[78],"class_list":["post-84262","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-photovoltaic"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/84262"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/369"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=84262"}],"version-history":[{"count":9,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/84262\/revisions"}],"predecessor-version":[{"id":85582,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/84262\/revisions\/85582"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/85451"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=84262"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=84262"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=84262"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}