{"id":83853,"date":"2017-05-29T14:30:27","date_gmt":"2017-05-29T06:30:27","guid":{"rendered":"\/\/m.iemloyee.com\/?p=83853"},"modified":"2017-05-29T09:48:02","modified_gmt":"2017-05-29T01:48:02","slug":"%e5%90%89%e6%9e%97%e5%a4%a7%e5%ad%a6%e5%bc%a0%e7%ab%8b%e5%86%9b%e8%af%be%e9%a2%98%e7%bb%84jacs%ef%bc%9a%e6%96%b0%e5%9e%8bcu-in%e5%9f%ba%e9%92%99%e9%92%9b%e7%9f%bf%e5%85%89%e4%bc%8f%e6%9d%90%e6%96%99","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=83853","title":{"rendered":"\u5409\u6797\u5927\u5b66\u5f20\u7acb\u519b\u8bfe\u9898\u7ec4JACS\uff1a\u65b0\u578bCu-In\u57fa\u9499\u949b\u77ff\u5149\u4f0f\u6750\u6599"},"content":{"rendered":"<p><strong>\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n<p>\u5bfb\u627e\u65b0\u578b\u4e0d\u542bPb\u3001\u7a33\u5b9a\u3001\u9ad8\u6027\u80fd\u9499\u949b\u77ff\u7c7b\u5149\u4f0f\u6750\u6599\u662f\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7814\u7a76\u9886\u57df\u4e9f\u5f85\u89e3\u51b3\u3001\u5bcc\u6709\u6311\u6218\u6027\u7684\u7814\u7a76\u8bfe\u9898\u3002\u5df2\u5f00\u5c55\u7684\u7814\u7a76\u5de5\u4f5c\u5305\u62ec\u5c06Pb<sup>2+<\/sup>\u66ff\u6362\u4e3a\u540c\u65cf\u65e0\u6bd2\u5143\u7d20\uff08\u5982Ge<sup>2+<\/sup>\/Sn<sup>2+<\/sup>\uff09\u3001\u5927\u5c0f\u76f8\u5f53\u7684\uff0b2\u4ef7\u9633\u79bb\u5b50\uff08\u5982Sr<sup>2+<\/sup>\/Ba<sup>2+<\/sup>\uff09,\u57fa\u4e8eSb<sup>3+<\/sup>\/Bi<sup>3+<\/sup>\u7684\u7c7b\u9499\u949b\u77ff\u6750\u6599\uff0c\u7528M<sup>+<\/sup>+M<sup>3+<\/sup>\u79bb\u5b50\u66ff\u63622Pb<sup>2+<\/sup>\u7684\u53cc\u9499\u949b\u77ff\u6750\u6599\uff0c\u786b\u5c5e\u9499\u949b\u77ff\u578b\u6750\u6599\u7b49\u3002\u7136\u800c\uff0c\u76ee\u524d\u5b9e\u9a8c\u4e0a\u5b9e\u73b0\u7684\u6750\u6599\u4ea6\u6216\u7981\u5e26\u5bbd\u5ea6\u8fc7\u5927\uff0c\u4ea6\u6216\u70ed\u529b\u5b66\u7a33\u5b9a\u6027\u5dee\uff0c\u4ea6\u6216\u8f7d\u6d41\u5b50\u4f20\u8f93\u6027\u80fd\u4f4e\uff0c\u5448\u73b0\u7684\u6574\u4f53\u592a\u9633\u80fd\u5149\u4f0f\u6027\u80fd\u90fd\u8fdc\u4f4e\u4e8e\u542bPb\u5364\u5316\u7269\u9499\u949b\u77ff\u7c7b\u6750\u6599\u3002\u5176\u4e2d\uff0c\u53cc\u9499\u949b\u77ff\u5364\u5316\u7269\uff08A<sub>2<\/sub>M<sup>\uff0b<\/sup>M<sup>3+<\/sup>X<sub>6<\/sub>\uff09\u662f\u57fa\u4e8e\u56db\u9762\u4f53\u7ed3\u6784\u534a\u5bfc\u4f53\u6750\u6599\u4e2d\u201cCation Transmutation\u201d\u7406\u5ff5\u8bbe\u8ba1\u51fa\u7684\uff3bZhao et al. <em>JACS<\/em> 139, 2630 (2017)\uff3d\u3001\u5177\u6709\u591a\u6837\u5316\u7ec4\u5206\u642d\u914d\u7684\u4e00\u7c7b\u6750\u6599\u3002\u5b9e\u9a8c\u4e0a\u5408\u6210\u7684\u53cc\u9499\u949b\u77ff\u6750\u6599\u5747\u57fa\u4e8eBi<sup>3+<\/sup>\uff08\u5982Cs<sub>2<\/sub>[NaBi]Cl<sub>6<\/sub>\uff0cCs<sub>2<\/sub>[AgBi]Cl<sub>6<\/sub>\uff0cCs<sub>2<\/sub>[AgBi]Br<sub>6<\/sub>\uff09\uff0c\u5177\u6709\u8fc7\u5927\u7684\u95f4\u63a5\u5e26\u9699\uff0c\u96be\u4ee5\u6ee1\u8db3\u592a\u9633\u80fd\u7535\u6c60\u5bf9\u53ef\u89c1\u5149\u5438\u6536\u7387\u7684\u8981\u6c42\u3002\u5bfb\u627e\u5176\u4ed6\u5177\u6709\u76f4\u63a5\u5e26\u9699\u7684\u53cc\u9499\u949b\u77ff\u5364\u5316\u7269\u6750\u6599\u662f\u503c\u5f97\u63a2\u7d22\u7684\u7814\u7a76\u65b9\u5411\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p><strong>\u5409\u6797\u5927\u5b66\u5f20\u7acb\u519b\u8bfe\u9898\u7ec4<\/strong>\u5c06\u4ece\u7ecf\u5178\u9ec4\u94dc\u77ff\u5149\u4f0f\u6750\u6599\u4e2d\u8403\u53d6\u7684\u8bbe\u8ba1\u7406\u5ff5\u4e0e\u9ad8\u901a\u91cf\u6750\u6599\u6a21\u62df\u7b5b\u9009\u6280\u672f\u76f8\u7ed3\u5408\uff0c<strong>\u5728\u300a<\/strong><strong>Journal of the American Chemical Society<\/strong><strong>\u300b\u4e0a\u53d1\u8868\u4ee5<\/strong><span style=\"color: #0000ff;\"><strong>\u201cCu\u2013In Halide Perovskite Solar Absorbers\u201d<\/strong><\/span><strong>\u4e3a\u9898\u7684\u6587\u7ae0<\/strong><strong>[<em>J. Am. Chem. Soc.<\/em>\u00a0139, 6718 (2017)]<\/strong>\uff0c\u8bbe\u8ba1\u51fa\u4e86\u65b0\u578b\u7684\u76f4\u63a5\u5e26\u9699Cu-In\u57fa\u53cc\u9499\u949b\u77ff\u5364\u5316\u7269\u6750\u6599\u3002\u7814\u7a76\u5de5\u4f5c\u5f97\u5230\u4e86\u4e2d\u7ec4\u90e8\u9752\u5e74\u5343\u4eba\u8ba1\u5212\u53ca\u56fd\u5bb6\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u9879\u76ee\u7684\u8d44\u52a9\uff0c\u4e0e\u7f8e\u56fd\u79d1\u7f57\u62c9\u591a\u5927\u5b66\u53ca\u5929\u666e\u5927\u5b66\u7684\u5408\u4f5c\u8005\u5171\u540c\u5b8c\u6210\uff0c\u5f20\u7acb\u519b\u6559\u6388\u4e3a\u8bba\u6587\u7684\u552f\u4e00\u901a\u8baf\u4f5c\u8005\u3002<\/p>\n<p>\u8bfe\u9898\u7ec4\u5728\u524d\u671f\u57fa\u4e8e\u56db\u9762\u4f53\u7ed3\u6784\u534a\u5bfc\u4f53\u6750\u6599\u4e2d\u201cCation Transmutation\u201d\u7406\u5ff5\u8bbe\u8ba1\u53cc\u9499\u949b\u77ff\u5364\u5316\u7269\u5de5\u4f5c\uff3bZhao et al. <em>JACS<\/em> 139, 2630 (2017)\uff3d\u7684\u57fa\u7840\u4e4b\u4e0a\uff0c\u5229\u7528\u7ecf\u5178\u9ec4\u94dc\u77ff\u5149\u4f0f\u6750\u6599\uff08Cu(In,Ga)Se<sub>2<\/sub>-CIGS\uff09\u4e2d\u8403\u53d6\u7684\u8bbe\u8ba1\u539f\u5219\uff0c\u7ed3\u5408\u5bf9Sb<sup>3+<\/sup>\/Bi<sup>3+<\/sup>\u57fa\u53cc\u9499\u949b\u6750\u6599\u5e26\u9699\u76f4\u63a5<em>vs<\/em>\u95f4\u63a5\u7279\u6027\u7684\u6df1\u5165\u7406\u89e3\uff0c\u521b\u65b0\u6027\u5730\u4ee5M<sup>+<\/sup>(d<sup>10<\/sup>s<sup>0<\/sup>)+M<sup>3+<\/sup>(s<sup>0<\/sup>p<sup>0<\/sup>)\u9633\u79bb\u5b50\u7ec4\u5408\uff08\u5373[Cu<sup>+<\/sup>\/Ag<sup>+<\/sup> + In<sup>3+<\/sup>\/Ga<sup>3+<\/sup>]\uff09\u66ff\u63622Pb<sup>2+<\/sup>\uff0c\u63d0\u51fa\u4e86\u4e00\u7c7b\u65b0\u578b\u7684\u76f4\u63a5\u5e26\u9699\u9499\u949b\u77ff\u6750\u6599\u2014\u2014Cu-In\u57fa\u53cc\u9499\u949b\u77ff\u5364\u5316\u7269\u3002\u5e94\u7528\u7b2c\u4e00\u6027\u539f\u7406\u9ad8\u901a\u91cf\u6750\u6599\u8ba1\u7b97\u65b9\u6cd5\uff0c\u56e2\u961f\u5bf9\u5019\u9009\u6750\u6599\u7ed3\u6784\u8fdb\u884c\u4e86\u4ee5\u5bfb\u627e\u9ad8\u5149\u4f0f\u6027\u80fd\u3001\u7a33\u5b9a\u7684\u592a\u9633\u80fd\u6750\u6599\u4e3a\u76ee\u6807\u7684\u6750\u6599\u7b5b\u9009\uff0c\u627e\u5230\u4e86\u4e00\u7cfb\u5217\u540c\u65f6\u6ee1\u8db3\u70ed\u529b\u5b66\u548c\u6676\u683c\u52a8\u529b\u5b66\u7a33\u5b9a\u6027\uff0c\u76f4\u63a5\u5e26\u9699\uff0c\u5177\u6709\u8f7b\u7535\u5b50\u53ca\u8f7b\u91cd\u7a7a\u7a74\u6df7\u5408\u6709\u6548\u8d28\u91cf\u7684\u65b0\u578b\u6f5c\u5728\u5149\u4f0f\u6750\u6599\u3002\u5176\u4e2dRb<sub>2<\/sub>[CuIn]Cl<sub>6<\/sub>, Rb<sub>2<\/sub>[AgIn]Br<sub>6<\/sub>, Cs<sub>2<\/sub>[AgIn]Br<sub>6<\/sub>\u8ba1\u7b97\u5e26\u9699\u4ecb\u4e8e1.36\uff0d1.50 eV, \u5bf9\u4e8e\u4e00\u5b9a\u539a\u5ea6\u7684\u8584\u819c\uff0c\u5176\u7406\u8bba\u6700\u5927\u5149\u7535\u8f6c\u5316\u6548\u7387\u53ef\u4e0eCH<sub>3<\/sub>NH<sub>3<\/sub>PbI<sub>3<\/sub>\u76f8\u6bd4\u62df\u3002<\/p>\n<p>\u5728\u6587\u7ae0\u53d1\u8868\u8fc7\u7a0b\u4e2d\uff08\u56de\u590d\u5ba1\u7a3f\u4eba\u610f\u89c1\u65f6\uff09\uff0c\u7406\u8bba\u9884\u6d4b\u7684\u6750\u6599Cs<sub>2<\/sub>[AgIn]Cl<sub>6<\/sub>\u88ab\u5b9e\u9a8c\u5408\u6210\u5370\u8bc1\uff3bVolonakis et al. <em>J. Phys. Chem. Lett. <\/em>8, 772 (2017)\uff3d\uff0c\u8bc1\u5b9e\u6750\u6599\u5177\u6709\u76f4\u63a5\u5e26\u9699\u3002<\/p>\n<p>\u503c\u5f97\u4e00\u63d0\u7684\u662f\uff0c\u8bfe\u9898\u7ec4\u57fa\u4e8e\u201c\u9ad8\u901a\u91cf\u8ba1\u7b97\u201d\u6750\u6599\u8bbe\u8ba1\u6846\u67b6\uff0c\u5f00\u53d1\u4e86\u5177\u6709\u81ea\u4e3b\u77e5\u8bc6\u4ea7\u6743\u3001\u4ee5\u5409\u6797\u5927\u5b66\u547d\u540d\u7684\u201cJUMP<sup>2<\/sup>\u201d\u6750\u6599\u8bbe\u8ba1\u8f6f\u4ef6\u5305\uff08\u5168\u79f0\u4e3aJilin University Materials-design Python Package\uff0c\u6b63\u5728\u7533\u8bf7\u8f6f\u4ef6\u8457\u4f5c\u6743\uff0c\u5373\u5c06\u53d1\u5e03Beta\u6d4b\u8bd5\u7248\uff09\u3002\u5176\u4e3b\u8981\u529f\u80fd\u662f\u9762\u5411\u7528\u6237\u9700\u6c42\uff0c\u7075\u6d3b\u8bbe\u8ba1\u5927\u6279\u91cf\u5019\u9009\u6750\u6599\uff0c\u6784\u5efa\u6a21\u5757\u5316\u3001\u53ef\u53cd\u590d\u8c03\u7528\u7684\u7b2c\u4e00\u6027\u539f\u7406\u6750\u6599\u6a21\u62df\u6d41\u7a0b\uff0c\u7edf\u4e00\u63d0\u53d6\u3001\u7cfb\u7edf\u5206\u6790\u8ba1\u7b97\u7ed3\u679c\uff0c\u89c4\u8303\u6570\u636e\u7ed3\u6784\u4ee5\u5f62\u6210\u6570\u636e\u5e93\uff0c\u540c\u65f6\u7ed3\u5408\u4eba\u5de5\u667a\u80fd\u4e0e\u673a\u5668\u5b66\u4e60\u65b9\u6cd5\uff0c\u4f18\u5316\u8bbe\u8ba1\u65b0\u6750\u6599\uff0c\u5e76\u63d0\u53d6\u201c\u7ec4\u5206\uff0d\u7ed3\u6784\uff0d\u6027\u8d28\u201d\u7684\u89c4\u5f8b\u6027\u8ba4\u77e5\u3002\u5e94\u7528\u81ea\u4e3b\u53d1\u5c55\u7684\u6750\u6599\u8bbe\u8ba1\u65b9\u6cd5\uff0c\u56e2\u961f\u6b63\u6709\u6548\u7ed3\u5408\u201c\u6750\u6599\u5927\u6570\u636e\u201d\u4e0e\u201c\u4eba\u5de5\u667a\u80fd\u201d\uff0c\u9488\u5bf9\u66f4\u591a\u7684\u534a\u5bfc\u4f53\u529f\u80fd\u6750\u6599\u4f53\u7cfb\uff0c\u4f18\u5316\u8bbe\u8ba1\u6ee1\u8db3\u7279\u5b9a\u529f\u80fd\uff08\u5982\u7535\u5b50\u8f93\u8fd0\u3001\u5149\u7535\u8f6c\u6362\u3001\u70ed\u7535\u8f6c\u6362\u7b49\uff09\u7684\u65b0\u578b\u534a\u5bfc\u4f53\u6750\u6599\uff0c\u52a0\u901f\u65b0\u6750\u6599\u7814\u53d1\u8fdb\u7a0b\uff0c\u4e3a\u5b9e\u9a8c\u5408\u6210\u5236\u5907\u63d0\u4f9b\u7406\u8bba\u6307\u5f15\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe\u4e00\uff1a\u57fa\u4e8e\u201c<\/strong><strong>Cation Transmutation<\/strong><strong>\u201d\u7406\u5ff5\u8bbe\u8ba1\u65e0<\/strong><strong>Pb<\/strong><strong>\u53cc\u9499\u949b\u77ff\u5364\u5316\u7269\u6750\u6599<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-83855 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/05\/\u6750\u6599\u4eba\u6295\u7a3f-1.png\" alt=\"\" width=\"600\" height=\"903\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/05\/\u6750\u6599\u4eba\u6295\u7a3f-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/05\/\u6750\u6599\u4eba\u6295\u7a3f-1-199x300.png 199w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09\u201cCation Transmutation\u201d\u7406\u5ff5\u793a\u610f\u56fe\uff1b<\/p>\n<p>\uff08b,c,d\uff09\u57fa\u4e8e \u201cCation Transmutation\u201d\u7406\u5ff5\u8bbe\u8ba1\u7684Bi<sup>3+<\/sup>\u57fa\u53cc\u9499\u949b\u77ff\u5364\u5316\u7269\u3001\u9ec4\u94dc\u77ff\u7c7b\u6750\u6599\u3001Cu-In\u57fa\u53cc\u9499\u949b\u77ff\u5364\u5316\u7269\u7684\u8fc7\u7a0b\u53ca\u5bf9\u5e94\u6750\u6599\u7684\u7535\u5b50\u7ed3\u6784\u3002<em>E<\/em><sub>g<\/sub><sup>d<\/sup>, <em>E<\/em><sub>g<\/sub><sup>ind<\/sup>\u5206\u522b\u4ee3\u8868\u76f4\u63a5\u5e26\u9699\u548c\u95f4\u63a5\u5e26\u9699\u3002<\/p>\n<ul>\n<li>Bi<sup>3+<\/sup>\u57fa\u53cc\u9499\u949b\u77ff\uff1a2Pb<sup>2+<\/sup>\u2192Ag<sup>+<\/sup> + Bi<sup>3+<\/sup>\uff1a\u7535\u5b50\u7ed3\u6784\u8868\u73b0\u4e3a\u7531\u4ef7\u5e26\u8fb9X\u70b9\u5230\u5bfc\u5e26\u8fb9L\u70b9\u7684\u95f4\u63a5\u5e26\u9699\uff0c\u5149\u5438\u6536\u6548\u7387\u4f4e\u3002<\/li>\n<li>\u9ec4\u94dc\u77ff\uff1a2Zn<sup>2+<\/sup>\u2192Ag<sup>+<\/sup> + In<sup>3+<\/sup>\uff1a\u7535\u5b50\u7ed3\u6784\u8868\u73b0\u4e3a\u7531\u4ef7\u5e26\u8fb9\u0393\u70b9\u5230\u5bfc\u5e26\u8fb9\u0393\u70b9\u7684\u76f4\u63a5\u5e26\u9699\uff0c\u5e26\u8fb9\u8dc3\u8fc1\u4e3b\u8981\u662fCu\/Ag(d)\/Se(p)\u2192Ga\/In(s\/p)\u8fc7\u7a0b\u3002<\/li>\n<li>Cu-In\u57fa\u53cc\u9499\u949b\u77ff: 2Pb<sup>2+<\/sup>\u2192Ag<sup>+<\/sup> + In<sup>3+<\/sup>\uff1a\u7535\u5b50\u7ed3\u6784\u8868\u73b0\u4e3a\u0393\u70b9\u7684\u76f4\u63a5\u5e26\u9699\uff0c\u5e26\u8fb9\u8dc3\u8fc1\u4e3b\u8981\u662fCu\/Ag(d)\/X(p)\u2192Ga\/In(s\/p)\u8fc7\u7a0b\u3002<\/li>\n<\/ul>\n<p><strong>\u56fe\u4e8c\uff1a\u521d\u6b65\u7b5b\u9009\u6f5c\u5728\u7684<\/strong><strong>Cu-In<\/strong><strong>\u57fa\u53cc\u9499\u949b\u77ff\u5149\u4f0f\u6750\u6599<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-83856 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/05\/\u6750\u6599\u4eba\u6295\u7a3f-2.png\" alt=\"\" width=\"600\" height=\"348\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/05\/\u6750\u6599\u4eba\u6295\u7a3f-2.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/05\/\u6750\u6599\u4eba\u6295\u7a3f-2-300x174.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u7b5b\u9009\u6807\u51c6\uff1a\u5e26\u9699\uff08<em>E<\/em><sub>g<\/sub>\uff09\u57280.5~3.0 eV;\u4ec5\u6d89\u53ca\u4e8c\u5143\u7ade\u4e89\u76f8\u5206\u89e3\u8def\u5f84\u7684\u5206\u89e3\u7113(\u0394<em>H<\/em><sub>dec<\/sub>)\u5927\u4e8e\u96f6\u3002<\/p>\n<ul>\n<li>\u6574\u4f53\u89c4\u5f8b\uff1a\u5e26\u9699\u503c\u8d8a\u5927\u7684\u6750\u6599\u5728\u80fd\u91cf\u4e0a\u8d8a\u7a33\u5b9a\u3002<\/li>\n<li>13\u4e2a\u6750\u6599\u6ee1\u8db3\u4e86\u521d\u6b65\u7b5b\u9009\u6761\u4ef6\u3002<\/li>\n<\/ul>\n<p><strong>\u56fe\u4e09\uff1a\u8003\u8651\u66f4\u591a\u7ade\u4e89\u76f8\u7684<\/strong><strong>Cu-In<\/strong><strong>\u57fa\u53cc\u9499\u949b\u77ff\u7a33\u5b9a\u6027\u5206\u6790<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-83857 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/05\/\u6750\u6599\u4eba\u6295\u7a3f-3.png\" alt=\"\" width=\"600\" height=\"526\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/05\/\u6750\u6599\u4eba\u6295\u7a3f-3.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/05\/\u6750\u6599\u4eba\u6295\u7a3f-3-300x263.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08\uff41, b\uff09 Cs<sub>2<\/sub>[AgIn]Br<sub>6<\/sub>\uff08c, d\uff09Rb<sub>2<\/sub>[CuIn]Cl<sub>6<\/sub>\u7684\u5206\u6790\u7ed3\u679c\uff08Ag\u5316\u5b66\u52bf\u53d8\u5316\u0394<em>\u03bc<\/em>=0\u548c\u0394<em>\u03bc<\/em>=-0.5 eV\uff09\u3002\u7eff\u8272\u8868\u660e\u70ed\u529b\u5b66\u7a33\u5b9a\u533a\u95f4\u3002<\/p>\n<ul>\n<li>\u8ba1\u7b97\u7ed3\u679c\u8868\u660e\u5728\u5bccAg<sup>+<\/sup>\/Cu<sup>+<\/sup>\u72b6\u51b5\u4e0b\uff0c\u901a\u8fc7\u8c03\u63a7Cs<sup>+<\/sup>\/Rb<sup>+<\/sup>\/In<sup>+<\/sup>\u7684\u5316\u5b66\u52bf\u53ef\u5b9e\u9a8c\u5408\u6210Cs<sub>2<\/sub>AgInBr<sub>6<\/sub>\u548cRb<sub>2<\/sub>CuInCl<sub>6<\/sub>\u3002<\/li>\n<\/ul>\n<p><strong>\u56fe\u56db\uff1a<\/strong><strong>Cu-In<\/strong><strong>\u57fa\u53cc\u9499\u949b\u77ff\u7684\u6676\u683c\u52a8\u529b\u5b66\u7a33\u5b9a\u6027\u5206\u6790<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-83858 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/05\/\u6750\u6599\u4eba\u6295\u7a3f-4.png\" alt=\"\" width=\"600\" height=\"350\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/05\/\u6750\u6599\u4eba\u6295\u7a3f-4.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/05\/\u6750\u6599\u4eba\u6295\u7a3f-4-300x175.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>0K\u53ca 300K\u65f6\uff08\uff41\uff0cd\uff09Cs<sub>2<\/sub>AgInCl<sub>6<\/sub>\uff08\uff42, e\uff09Cs<sub>2<\/sub>AgInBr<sub>6<\/sub>\uff08c, f\uff09Cs<sub>2<\/sub>AgBiCl<sub>6<\/sub>\u7684\u58f0\u5b50\u8c31\u3002<\/p>\n<ul>\n<li>\u5728\u96f6\u6e29\u4e0b\uff0cCs<sub>2<\/sub>AgInCl<sub>6<\/sub>\u65e0\u865a\u9891\uff0c\u800cCs<sub>2<\/sub>AgInBr<sub>6<\/sub>\u5149\u5b66\u652f\u6709\u865a\u9891\uff1b\u5b9e\u9a8c\u5df2\u5408\u6210\u6750\u6599Cs<sub>2<\/sub>AgBiCl<sub>6<\/sub>\u540c\u6837\u5448\u73b0\u865a\u5149\u5b66\u652f\u3002<\/li>\n<li>\u6709\u9650\u6e29\u5ea6\uff08300 K\uff09\u4e0b, Cs<sub>2<\/sub>AgInCl<sub>6<\/sub>, Cs<sub>2<\/sub>AgInBr<sub>6<\/sub>, Cs<sub>2<\/sub>AgBiCl<sub>6<\/sub>\u5747\u65e0\u865a\u9891\u3001\u6676\u683c\u52a8\u529b\u5b66\u7a33\u5b9a\u3002\u58f0\u5b50\u71b5\u5728\u58f0\u5b50\u8c31\u91cd\u6574\u5316\u8fc7\u7a0b\u4e2d\u8d77\u4e86\u91cd\u8981\u4f5c\u7528\uff0c\u6709\u5229\u4e8e\u7ed3\u6784\u5728\u5ba4\u6e29\u4e0b\u7a33\u5b9a\u3002<\/li>\n<\/ul>\n<p><strong>\u56fe\u4e94\uff1a\u7535\u5b50\u6001\u5bc6\u5ea6\uff0c\u6676\u4f53\u8f68\u9053\u91cd\u53e0\u5e03\u5c45\u5206\u6790\u53ca\u8f7d\u6d41\u5b50\u6709\u6548\u8d28\u91cf<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-83859 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/05\/\u6750\u6599\u4eba\u6295\u7a3f-5.png\" alt=\"\" width=\"600\" height=\"548\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/05\/\u6750\u6599\u4eba\u6295\u7a3f-5.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/05\/\u6750\u6599\u4eba\u6295\u7a3f-5-300x274.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a, b\uff09Cs<sub>2<\/sub>AgInBr<sub>6<\/sub>\u7684\u7535\u5b50\u6001\u5bc6\u5ea6\u53ca\u6676\u4f53\u8f68\u9053\u91cd\u53e0\u5e03\u5c45\u5206\u6790\uff0c\u53ca\u4e0eAgInSe<sub>2<\/sub>\u7ed3\u679c\uff08c, d\uff09\u7684\u5bf9\u6bd4\uff1b\uff08e\uff09\u8f7d\u6d41\u5b50\u6709\u6548\u8d28\u91cf\u3002<\/p>\n<ul>\n<li>Cu-In\u57fa\u53cc\u9499\u949b\u77ff\u7684\u5e26\u8fb9\u6001\u4e0e\u9ec4\u94dc\u77ff\u7c7b\u4f3c\uff1a\u4ef7\u5e26\u8fb9\u7531Ag\/Cu(<em>d<\/em>)\uff0dX(<em>p<\/em>)\u7684\u53cd\u952e\u6742\u5316\u8f68\u9053\u6784\u6210, \u5bfc\u5e26\u8fb9\u4e3b\u8981\u7531Ga\/In(<em>s\/p<\/em>)\u8f68\u9053\u6784\u6210\u3002<\/li>\n<li>\u4f18\u5316\u8bbe\u8ba1\u7684Cu-In\u57fa\u53cc\u9499\u949b\u77ff\u6750\u6599\u7684\u5177\u6709\u8f7b\u7535\u5b50\u3001\u8f7b\u91cd\u7a7a\u7a74\u6df7\u5408\u6709\u6548\u8d28\u91cf\u3002<\/li>\n<\/ul>\n<p><strong>\u56fe\u516d\uff1a\u4f18\u5316\u8bbe\u8ba1\u7684<\/strong><strong>Cu-In<\/strong><strong>\u57fa\u53cc\u9499\u949b\u77ff\u6750\u6599\u7684\u5149\u5438\u6536\u8c31\u53ca\u7406\u8bba\u6700\u5927\u5149\u7535\u8f6c\u5316\u6548\u7387<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-83854 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/05\/\u6750\u6599\u4eba\u6295\u7a3f-6.png\" alt=\"\" width=\"600\" height=\"294\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/05\/\u6750\u6599\u4eba\u6295\u7a3f-6.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/05\/\u6750\u6599\u4eba\u6295\u7a3f-6-300x147.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08\uff41\uff09\u5149\u5438\u6536\u8c31\uff1b<\/p>\n<p>\uff08\uff42\uff09\u5177\u6709\u7406\u60f3\u5e26\u9699\u503c\u7684\u4e09\u4e2a\u6750\u6599Rb<sub>2<\/sub>CuInCl<sub>6<\/sub>\u3001Cs<sub>2<\/sub>AgInBr<sub>6<\/sub>\u4ee5\u53caRb<sub>2<\/sub>AgInBr<sub>6<\/sub>\u7684\u7406\u8bba\u6700\u5927\u5149\u7535\u8f6c\u5316\u6548\u7387\u3002CH<sub>3<\/sub>NH<sub>3<\/sub>PbI<sub>3<\/sub>\u548cCuInSe<sub>2<\/sub>\u7684\u7ed3\u679c\u5217\u51fa\u4f5c\u4e3a\u6bd4\u8f83\u3002<\/p>\n<ul>\n<li>\u4e09\u4e2a\u5177\u6709\u7406\u60f3\u5e26\u9699\u503c\u7684\u6750\u6599Rb<sub>2<\/sub>CuInCl<sub>6<\/sub>\u3001Cs<sub>2<\/sub>AgInBr<sub>6<\/sub>, Rb<sub>2<\/sub>AgInBr<sub>6<\/sub>\u7684\u7406\u8bba\u6700\u5927\u5149\u7535\u8f6c\u5316\u6548\u7387\u5728\u8584\u819c\u539a\u5ea62 \u03bcm\u65f6\u4e0eCH<sub>3<\/sub>NH<sub>3<\/sub>PbI<sub>3<\/sub>\u53ef\u6bd4\u62df\u3002<\/li>\n<\/ul>\n<p><strong>\u6587\u7ae0\u94fe\u63a5\uff1a<\/strong><a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.7b02120\">Cu\u2013In Halide Perovskite Solar Absorbers<\/a> (Xin-Gang Zhao, Dongwen Yang, Yuanhui Sun, Tianshu Li, Lijun Zhang(*), Liping Yu, and Alex Zunger, <strong><em>J. Am. Chem. Soc.<\/em><\/strong> 139, 6718 (2017)\uff0cDOI: 10.1021\/jacs.7b02120)\u3002<\/p>\n<p>\u672c\u6587\u7531\u5409\u6797\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u8d75\u4fe1\u521a\u6295\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91 \u6df1\u6d77\u4e07\u91cc \u7f16\u8f91\u6574\u7406\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u80cc\u666f\u4ecb\u7ecd\u3011 \u5bfb\u627e\u65b0\u578b\u4e0d\u542bPb\u3001\u7a33\u5b9a\u3001\u9ad8\u6027\u80fd\u9499\u949b\u77ff\u7c7b\u5149\u4f0f\u6750\u6599\u662f\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7814\u7a76\u9886\u57df\u4e9f\u5f85\u89e3\u51b3\u3001\u5bcc\u6709\u6311\u6218\u6027\u7684\u7814\u7a76\u8bfe\u9898\u3002\u5df2\u5f00\u5c55\u7684\u7814\u7a76\u5de5\u4f5c\u5305\u62ec\u5c06Pb2+\u66ff\u6362\u4e3a\u540c\u65cf\u65e0&#8230;<\/p>\n","protected":false},"author":2219,"featured_media":83855,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[1762],"class_list":["post-83853","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-1762"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/83853"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2219"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=83853"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/83853\/revisions"}],"predecessor-version":[{"id":83862,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/83853\/revisions\/83862"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/83855"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=83853"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=83853"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=83853"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}