{"id":83845,"date":"2017-05-28T06:30:31","date_gmt":"2017-05-27T22:30:31","guid":{"rendered":"\/\/m.iemloyee.com\/?p=83845"},"modified":"2017-05-27T21:43:58","modified_gmt":"2017-05-27T13:43:58","slug":"%e6%b8%85%e5%8d%8e%e5%a4%a7%e5%ad%a6adv-mater-%ef%bc%9a%e5%85%b7%e6%9c%89%e4%bb%bb%e6%84%8f%e7%bb%93%e6%9e%84%e7%9a%84%e8%b6%85%e9%ab%98%e7%94%b5%e5%af%bc%e7%8e%87%e8%81%9a%e5%90%88%e7%89%a9%e6%b0%b4","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=83845","title":{"rendered":"\u6e05\u534e\u5927\u5b66\u77f3\u9ad8\u5168\u56e2\u961fAdv. Mater.\uff1a\u5177\u6709\u4efb\u610f\u7ed3\u6784\u7684\u8d85\u9ad8\u7535\u5bfc\u7387\u805a\u5408\u7269\u6c34\u51dd\u80f6"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u5bfc\u7535\u805a\u5408\u7269\uff08CP\uff09\u7531\u4e8e\u5176\u72ec\u7279\u7684\u5171\u8f6d\u94fe\u5f0f\u7ed3\u6784\u548c\u4f18\u5f02\u7684\u6027\u80fd\u800c\u500d\u53d7\u5173\u6ce8\u3002\u5728\u4f17\u591a\u5bfc\u7535\u805a\u5408\u7269\u6750\u6599\u5f53\u4e2d\uff0cCP\u6c34\u51dd\u80f6\uff08CPHs\uff09\u662f\u4e00\u7c7b\u6027\u80fd\u8fe5\u5f02\u7684\u9ad8\u5206\u5b50\uff0c\u540c\u65f6\u5177\u5907CPs\u548c\u6c34\u51dd\u80f6\u7684\u4f18\u70b9\u3002\u73b0\u6709\u4e24\u79cdCPH\u5236\u5907\u65b9\u6cd5\uff1ai\uff09\u82b3\u65cf\u5355\u4f53\u5728\u91c7\u7528\u7edd\u7f18\u805a\u5408\u7269\u57fa\u8d28\u4f5c\u4e3a\u7269\u7406\u6846\u67b6\u4e2d\u7684\u805a\u5408\uff0c\u7531\u4e8e\u5176\u72ec\u7279\u7684\u7edd\u7f18\u7279\u6027\uff0c\u4f7f\u5f97CPHs\u5177\u6709\u8f83\u4f4e\u7535\u5bfc\u7387\uff080.01~1 S\u00b7m-1<\/sup>\uff09\u548c\u5f31\u7535\u5316\u5b66\u6d3b\u6027\uff1bii\uff09\u901a\u8fc7\u6dfb\u52a0\u4ea4\u8054\u5242\uff0c\u5728\u805a\u5408\u8fc7\u7a0b\u4e2d\u4ea4\u8054CP\u94fe\u3002\u4f46\u5373\u4f7f\u56fa\u4f53\u542b\u91cf\u8f83\u9ad8\uff0c\u6c34\u51dd\u80f6\u7684\u7535\u5bfc\u7387\u4ecd\u7136\u76f8\u5bf9\u8f83\u4f4e\uff0811S\u00b7m-1<\/sup>\uff09\u3002\u6b64\u5916\uff0c\u8fd9\u4e9b\u6280\u672f\u76ee\u524d\u8fd8\u6ee1\u8db3\u4e0d\u4e86\u4e0d\u540c\u7ed3\u6784CPHs\u7684\u5236\u5907\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u671f\uff0c\u6e05\u534e\u5927\u5b66\u77f3\u9ad8\u5168\u6559\u6388\u8bfe\u9898\u7ec4<\/strong>\u901a\u8fc7\u57280.1mol\/L\u786b\u9178\u4e2d\u70ed\u5904\u7406PEDOT:PSS(PH1000)\u7684\u60ac\u6d6e\u6db2\uff0c\u7136\u540e\u53bb\u9664\u5176\u4f59\u90e8\u5206\uff0c\u5236\u5907\u5f97\u5230PEDOT:PSS\u6c34\u51dd\u80f6\u3002\u8be5\u6c34\u51dd\u80f6\u5177\u67094%\u7684\u4f4e\u56fa\u4f53\u542b\u91cf\u548c880S\/m\u7684\u6781\u9ad8\u5bfc\u7535\u7387\uff0c\u5176\u53ef\u5851\u6027\u826f\u597d\uff0c\u53ef\u4ee5\u5236\u5907\u6210\u4e0d\u540c\u7684\u5f62\u72b6\uff0c\u4ece\u800c\u5e94\u7528\u4e8e\u5b9e\u9645\u751f\u6d3b\u5f53\u4e2d\uff0c\u4f8b\u5982\uff1a\u53ef\u4ee5\u52a0\u5de5\u6210\u819c\uff0c\u7ea4\u7ef4\u548c\u4efb\u610f\u5c3a\u5bf8\u7684\u67f1\u3002\u5229\u7528\u5e72\u71e5\u7684PEDOT:PSS\u6c34\u51dd\u80f6\u7ea4\u7ef4\uff0c\u5de5\u4f5c\u4eba\u5458\u5236\u5907\u5f97\u5230\u4e86\u5177\u6709\u9ad8\u5bfc\u7535\u6027\u548c\u673a\u68b0\u5f3a\u5ea6\u7684\u591a\u5b54\u7ea4\u7ef4\uff0c\u53ef\u7528\u4e8e\u5236\u5907\u65e0\u96c6\u7535\u6781\u56fa\u6001\u67d4\u6027\u8d85\u7ea7\u7535\u5bb9\u5668\u3002\u8be5\u7ea4\u7ef4\u8d85\u7ea7\u7535\u5bb9\u5668\u57280.54A\/cm3<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u4f53\u79ef\u7535\u5bb9\u53ef\u9ad8\u8fbe202F\/cm3<\/sup>\uff0c\u4e14\u5177\u6709\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\u3002\u6b64\u5916\uff0c\u8be5\u8d85\u7ea7\u7535\u5bb9\u5668\u8fd8\u663e\u793a\u51fa\u4e86\u4f18\u5f02\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u548c\u9ad8\u7075\u654f\u6027\uff0c\u6709\u671b\u5e94\u7528\u4e8e\u53ef\u7a7f\u6234\u5f0f\u50a8\u80fd\u88c5\u7f6e\u3002\u8be5\u6210\u679c\u4ee5\u201cUltrahigh-Conductivity Polymer Hydrogels with Arbitrary Structures<\/strong>\u201d\u4e3a\u9898\u4e8e2017\u5e745\u670817\u65e5\u53d1\u8868\u5728Adv. Mater<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\uff1a<\/strong>\u4e0d\u540c\u5f62\u8c8c\u7684<\/strong>PEDOT:PSS<\/strong>\u6c34\u51dd\u80f6\u7684\u5f62\u8c8c\u53ca\u6d41\u53d8\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a-e)PEDOT:PSS\u4e0d\u540c\u7684\u51e0\u4f55\u5f62\u72b6\u56fe\uff0c\u6bd4\u4f8b\u5c3a=1cm\uff1b<\/p>\n

(f) PEDOT:PSS\u6c34\u51dd\u80f6\u51b7\u51bb\u4e4b\u524d\u7684SEM\u56fe\uff1b<\/p>\n

(g) PEDOT:PSS\u6c34\u51dd\u80f6\u51b7\u51bb\u4e4b\u540e\u7684SEM\u56fe\uff1b<\/p>\n

(h) PH1000\u60ac\u6d6e\u6db2\uff0cPH1000-SA\u60ac\u6d6e\u6db2\uff0cPEDOT:PSS\u6c34\u51dd\u80f6\u548cAT-\u6c34\u51dd\u80f6\u7a33\u5b9a\u7684\u6d41\u53d8\u884c\u4e3a\u3002<\/p>\n

\u56fe\u4e8c\uff1a<\/strong>PEDOT:PSS<\/strong>\u6c34\u51dd\u80f6\u53ca\u5176\u5bf9\u7167\u7ec4\u7684\u5149\u8c31\u6d4b\u8bd5<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u51b7\u51bb\u5e72\u71e5\u7684PH1000\u60ac\u6d6e\u6db2\uff0cPEDOT\uff1aPSS\u6c34\u51dd\u80f6\u548cAT\u6c34\u51dd\u80f6\u7684\u62c9\u66fc\u5149\u8c31\uff1b<\/p>\n

(b)\u51b7\u51bb\u5e72\u71e5\u7684PH1000\u60ac\u6d6e\u6db2\u548cPEDOT\uff1aPSS\u6c34\u51dd\u80f6\u7684ESR\u5149\u8c31\uff1b<\/p>\n

(c) 1mg\/ mL PH1000\u548c1mg \/mLPH1000-SA\u60ac\u6d6e\u6db2\u7684\u03b6\u7535\u4f4d\u5206\u5e03\uff1b<\/p>\n

(d)\u51b7\u51bb\u5e72\u71e5\u7684PH1000\u60ac\u6d6e\u6db2\uff0cPEDOT\uff1aPSS\u6c34\u51dd\u80f6\u548cAT-\u6c34\u51dd\u80f6\u7684S 2p XPS\u5149\u8c31\uff1b<\/p>\n

(e)PSSNa\u548cPSS\u7684 IR\u56fe\u8c31\uff0c\u63d2\u56fe\u4e3a\u6536\u96c6\u5230\u7684\u56fa\u4f53PSS\u6570\u5b57\u56fe\u7247\uff1b<\/p>\n

(f) \u900f\u6790\u7684PEDOT\uff1aPSS\u6c34\u51dd\u80f6\u548c\u5e02\u552ePSSNa\uff08Mw = 70 000\uff09\u7684\u6e17\u900f\u7269\u4e2d\u6536\u96c6\u7684PSS\u7684UV-vis\u5149\u8c31\u3002<\/p>\n

\u56fe\u4e09\uff1a\u9178\u5904\u7406\u66f2\u7ebf\u4ee5\u53ca\u4e0e\u5176\u4ed6\u6587\u732e\u5bf9\u6bd4\u7535\u5bfc\u7387<\/strong><\/p>\n

\"\"<\/p>\n

(a) AT-\u6c34\u51dd\u80f6\u7684\u56fa\u4f53\u542b\u91cf\u4e0e\u7528\u4e8e\u9178\u5904\u7406\u7684H 2 <\/sub>SO 4<\/sub>\u6d53\u5ea6\u7684\u66f2\u7ebf\u56fe\uff1b<\/p>\n

(b)AT Hydrogel\u7684\u7535\u5bfc\u7387\u4e0e\u5176\u56fa\u4f53\u542b\u91cf\u7684\u66f2\u7ebf\u56fe\uff0c\u4ee5\u53caAT-\u6c34\u51dd\u80f6\u4e0e\u4e0e\u5df2\u62a5\u9053\u7684\u5176\u4ed6CPHs\u548c\u78b3\u57fa\u6c34\u51dd\u80f6\u7684\u7535\u5bfc\u7387\u6bd4\u8f83\u3002<\/p>\n

\u56fe\u56db\uff1a\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u6d4b\u8bd5<\/strong><\/p>\n

\"\"<\/p>\n

(a-b) \u7531AT-\u6c34\u51dd\u80f6\u5236\u5907\u7684\u5e72\u7ea4\u7ef4\u7684\u6a2a\u622a\u9762SEM\u56fe\u50cf\uff1b<\/p>\n

(c)\u56fa\u6001\u7ea4\u7ef4\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u8bf4\u660e\u793a\u610f\u56fe\uff1b<\/p>\n

(d)\u56fa\u6001\u7ea4\u7ef4\u8d85\u7ea7\u7535\u5bb9\u5668\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

(e-f) \u7ea4\u7ef4\u8d85\u7ea7\u7535\u5bb9\u5668\u5728\u4e0d\u540c\u626b\u63cf\u901f\u7387\uff08mV s-1\uff09\u4e0b\u7684CV\u66f2\u7ebf\u548c\u6052\u6d41\u5145\u653e\u7535\u66f2\u7ebf\uff1b(g) \u7ea4\u7ef4\u8d85\u7ea7\u7535\u5bb9\u5668\u57280.1-105Hz\u9891\u7387\u8303\u56f4\u5185\u7684Nyquist\u56fe\uff1b<\/p>\n

(h) PEDOT\uff1aPSS\u7ea4\u7ef4\u8d85\u7ea7\u7535\u5bb9\u5668\u4e0e\u5df2\u62a5\u9053\u7684\u7535\u5bb9\u5668\u7684\u4f53\u79ef\u7535\u5bb9\u6bd4\u8f83\uff1b<\/p>\n

SWNT\u4ee3\u8868\u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1\uff0cCNT\u4ee3\u8868\u78b3\u7eb3\u7c73\u7ba1\uff0cN-rGO\u4ee3\u8868\u6c2e\u63ba\u6742\u8fd8\u539f\u77f3\u58a8\u70ef\u6c27\u5316\u7269\uff0cCMC\u4ee3\u8868\u7fa7\u7532\u57fa\u7ea4\u7ef4\u7d20\u94a0\u548cCF\u4ee3\u8868\u78b3\u7ea4\u7ef4\uff1b<\/p>\n

(i)\u572811 A cm -3\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u7ea4\u7ef4\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u6bd4\u7535\u5bb9-\u5faa\u73af\u66f2\u7ebf\uff0810000\u6b21\u5faa\u73af\uff09\uff1b<\/p>\n

(f)\u4e0d\u540c\u5f2f\u66f2\u7a0b\u5ea6\u4e0b\uff0c\u7ea4\u7ef4\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u67d4\u6027\u6d4b\u8bd5\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u901a\u8fc7\u5728\u9178\u6027\u4ecb\u8d28\u4e2d\u51dd\u80f6\u5316PH1000\u60ac\u6d6e\u6db2\uff0c\u7814\u7a76\u4eba\u5458\u6210\u529f\u5236\u5907\u4e86\u5177\u6709880S \/m\u9ad8\u5bfc\u7535\u6027\u7684PEDOT\uff1aPSS\u6c34\u51dd\u80f6\uff08AT-\u6c34\u51dd\u80f6\uff09\u3002\u8be5\u6c34\u51dd\u80f6\u5177\u5907\u72ec\u7279\u7684\u591a\u5b54\u7ed3\u6784\u548c\u4f18\u5f02\u7684\u673a\u68b0\u548c\u7535\u5b66\u6027\u8d28\uff0c\u4e3b\u8981\u5f52\u56e0\u4e8ePH100\u7684\u7edd\u7f18PSS\u7ec4\u5206\u7684\u90e8\u5206\u53bb\u9664\u548cPEDOT\u94fe\u7684\u5171\u8f6d\u957f\u5ea6\u7684\u4f38\u957f\u3002\u901a\u8fc7\u8be5\u9879\u6280\u672f\uff0c\u53ef\u4ee5\u5b9e\u73b0\u4e0d\u540c\u7ed3\u6784\u7684AT-\u6c34\u51dd\u80f6\u7684\u5236\u5907\uff0c\u4ece\u800c\u7528\u4e8e\u73b0\u5b9e\u751f\u6d3b\u4e4b\u4e2d\u3002\u6b64\u5916\uff0c\u5229\u7528AT-\u6c34\u51dd\u80f6\u5236\u4f5c\u7684\u5e72\u7ea4\u7ef4\u4f5c\u4e3a\u7535\u6781\uff0c\u6784\u5efa\u5168\u56fa\u6001\u7ea4\u7ef4\u8d85\u7ea7\u7535\u5bb9\u5668\uff0c\u8be5\u8d85\u7ea7\u7535\u5bb9\u5668\u8868\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u4f18\u4e8e\u5148\u524d\u62a5\u9053\u4e2d\u7684\u6240\u63d0\u53ca\u7684\u6750\u6599\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Ultrahigh-Conductivity Polymer Hydrogels with rbitrary Structures<\/a>(Adv. Mater., 2017, DOI:10.1002\/adma.201700974)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u9676\u5a1c\u7f16\u8bd1\uff0c\u8d75\u98de\u9f99\u5ba1\u6838\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u3002<\/a><\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u5bfc\u7535\u805a\u5408\u7269\uff08CP\uff09\u7531\u4e8e\u5176\u72ec\u7279\u7684\u5171\u8f6d\u94fe\u5f0f\u7ed3\u6784\u548c\u4f18\u5f02\u7684\u6027\u80fd\u800c\u500d\u53d7\u5173\u6ce8\u3002\u5728\u4f17\u591a\u5bfc\u7535\u805a\u5408\u7269\u6750\u6599\u5f53\u4e2d\uff0cCP\u6c34\u51dd\u80f6\uff08CPHs\uff09\u662f\u4e00\u7c7b\u6027\u80fd\u8fe5\u5f02\u7684\u9ad8\u5206\u5b50\uff0c\u540c\u65f6\u5177\u5907CP…<\/p>\n","protected":false},"author":230,"featured_media":83849,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2],"tags":[386],"class_list":["post-83845","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","category-keji","tag-superccapacitor"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/83845"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/230"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=83845"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/83845\/revisions"}],"predecessor-version":[{"id":83977,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/83845\/revisions\/83977"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/83849"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=83845"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=83845"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=83845"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}