{"id":83235,"date":"2017-06-03T06:30:25","date_gmt":"2017-06-02T22:30:25","guid":{"rendered":"\/\/m.iemloyee.com\/?p=83235"},"modified":"2017-06-03T10:54:37","modified_gmt":"2017-06-03T02:54:37","slug":"%e5%88%98%e7%94%9f%e5%bf%a0sci-chi-chem-120%e6%af%ab%e7%b1%b3%e5%8d%95%e6%99%b6%e9%92%99%e9%92%9b%e7%9f%bf%ef%bc%9a%e9%9d%a2%e5%90%91%e5%8f%af%e8%a1%8c%e7%9a%84%e5%ba%94%e7%94%a8","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=83235","title":{"rendered":"\u79d1\u6280\u8d44\u8baf\u5199\u4f5c\u5927\u8d5b\uff5c\u5218\u751f\u5fe0\u6559\u6388Sci. China Chem.\uff1a120\u6beb\u7c73\u5355\u6676\u9499\u949b\u77ff-\u9762\u5411\u53ef\u884c\u7684\u5e94\u7528"},"content":{"rendered":"
<\/p>\n
\u6750\u6599\u4eba\u9996\u5c4a\u79d1\u6280\u8d44\u8baf\u5199\u4f5c\u5927\u8d5b\u81ea5\u670813\u65e5\u53d1\u5e03\u5f81\u7a3f\u901a\u77e5\u4ee5\u6765\uff08\u53c2\u8d5b\u8be6\u60c5\u8bf7\u6233\u6211<\/a>\uff09\uff0c\u53d7\u5230\u8bfb\u8005\u4eec\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u672c\u6587\u662f\u7531SCI\u671f\u520aScience China Chemistry\u7f16\u8f91\u90e8\u6295\u7a3f\u3002<\/p>\n \u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n \u76ee\u524d\u5927\u578b\u5355\u6676\u7845\u6676\u7247\u7684\u53d1\u5c55\u5df2\u7ecf\u6539\u53d8\u4e86\u8bb8\u591a\u884c\u4e1a\u7684\u8fdb\u7a0b\uff0c\u5305\u62ec\u7535\u5b50\u548c\u592a\u9633\u80fd\u7535\u6c60\u3002\u56e0\u6b64\uff0c\u5927\u578b\u5355\u6676\u9499\u949b\u77ff\u6676\u4f53\u548c\u6676\u7247\u7684\u53ef\u7528\u6027\u5c06\u5f7b\u5e95\u6539\u53d8\u5176\u5728\u5149\u4f0f\u3001\u5149\u7535\u5b50\u3001\u6fc0\u5149\u3001\u5149\u7535\u68c0\u6d4b\u5668\u3001LED\u7b49\u9886\u57df\u7684\u5e7f\u6cdb\u5e94\u7528\u3002\u5230\u76ee\u524d\u4e3a\u6b62\uff0c\u53d7\u5927\u5355\u6676\uff08SC\uff09\u6750\u6599\u7684\u4e0d\u53ef\u7528\u9650\u5236\uff0c\u6240\u6709\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5747\u57fa\u4e8e\u5fae\u6676\u548c\u975e\u6676\u7ec4\u5206\u3002\u7531\u4e8e\u5fae\u6676\u9499\u949b\u77ff\u6750\u6599\u4e2d\u5b58\u5728\u5927\u91cf\u6676\u7c92\u3001\u8fb9\u754c\u3001\u7a7a\u9699\u548c\u8868\u9762\u7f3a\u9677\uff0c\u56e0\u6b64\u9884\u8ba1\u8fd9\u4e9b\u7f3a\u9677\u548c\u91cd\u7ec4\u4f4d\u70b9\u4f1a\u5f15\u8d77\u663e\u8457\u7684\u6548\u7387\u635f\u5931\u3002<\/p>\n \u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n \u8fd1\u65e5\uff0c\u6765\u81ea\u9655\u897f\u5e08\u8303\u5927\u5b66<\/strong>\u7684\u5218\u751f\u5fe0\u6559\u6388<\/strong>\u548c\u6768\u5468\u535a\u58eb\uff08\u5171\u540c\u901a\u8baf\uff09<\/strong>\u7b49\u4eba\u53d1\u73b0\u4e86\u4e00\u79cd\u4f7f\u5f97\u5355\u6676\u9499\u949b\u77ff\u957f\u5927\u7684\u65b9\u6cd5\uff0c\u5305\u62ec\u5355\u5364\u5316\u7269\u6676\u4f53\uff1aCH3<\/sub>NH3<\/sub>PbX3<\/sub> \u00a0 (X=I, \u00a0Br, \u00a0Cl)\uff0c\u53cc\u5364\u5316\u7269\uff1aCH3<\/sub>NH3<\/sub>Pb(Clx<\/sub>Br1\u2212x<\/sub>)3<\/sub>\u00a0 \u548cCH3<\/sub>NH3<\/sub>Pb(Brx<\/sub>I1\u2212x<\/sub>)3<\/sub>\uff0c\u6700\u5927\u7684\u6676\u4f53\u957f120\u6beb\u7c73\u3002\u53e6\u5916\uff0c\u8be5\u56e2\u961f\u8fd8\u53d1\u73b0\u4e86\u4e00\u79cd\u5c06\u9499\u949b\u77ff\u6676\u4f53\u5206\u6210\u8584\u6676\u7247\u7684\u65b9\u6cd5\u3002\u76f8\u5173\u7684\u7814\u7a76\u6210\u679c\u4ee5\u201c120 Millimeter Single-Crystalline Perovskite and Wafers: To-wards Viable Applications\u201d<\/strong>\u4e3a\u9898\u53d1\u8868\u5728\u4e86Science China Chemistry<\/strong>\u4e0a\u3002<\/p>\n \u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n \u56fe1\u00a0\u6750\u6599\u8868\u5f81<\/strong><\/p>\n a\uff09<\/strong>\u4ece CH3<\/sub>NH3<\/sub>PbI3<\/sub>\u6676\u4f53\u7684\u751f\u957f\u6eb6\u6db2\u4e2d\u83b7\u53d6\u7684\u56fe\u7247<\/p>\n b\uff09<\/strong>\u5927\u9499\u949b\u77ffCH3<\/sub>NH3<\/sub>PbI3<\/sub>\u6676\u4f53\u7684PGC\uff08\u301c50\u03bcm\uff09\u7684X\u5c04\u7ebf\u884d\u5c04\u56fe\u548c2\u03b8\u626b\u63cf<\/p>\n c\uff09<\/strong>\u6676\u7247\u5207\u7247\u8fc7\u7a0b\u7684\u793a\u610f\u56fe<\/p>\n d\uff09<\/strong>\u5927\u9499\u949b\u77ffCH3<\/sub>NH3<\/sub>PbI3<\/sub>\u6676\u4f53\u88ab\u5207\u7247<\/p>\n \u56fe2\u00a0SC\u9499\u949b\u77ff\u6750\u6599\u7684\u8868\u5f81<\/strong><\/p>\n a\uff09<\/strong>\u00a0\u5206\u522b\u4e3aMPTF\u3001PGC\u3001LSC\u3001SCW\u7684UV Vis NIR\u5438\u6536\u5149\u8c31<\/p>\n b\uff09<\/strong> MPTF\u3001PGC\u3001LSC\u3001SCW\u7684PL\u5149\u8c31<\/p>\n c\uff09<\/strong>14\u4e2a\u4e0d\u540c\u4f4d\u7f6e\u7684PL\u5149\u8c31<\/p>\n d\uff09<\/strong>\u5728\u9ed1\u6697\u4e0b\u663e\u793aVTFL\u626d\u7ed3\u70b9\u884c\u4e3aI-V\u66f2\u7ebf<\/p>\n e\uff09<\/strong>\u7528PL\u5747\u5300\u5ea6\u6d4b\u91cf\u768453.5 \u00d7 34.5 \u00d7 1.4 mm\u7684CH3<\/sub>NH3<\/sub>PbI3<\/sub>\u6676\u4f53<\/p>\n f\uff09<\/strong>\u7528\u6355\u6349\u72b6\u6001\u5bc6\u5ea6\u6d4b\u91cf\u7684\u56fe\u7247<\/p>\n g\uff09<\/strong>\u970d\u5c14\u6548\u5e94\u6d4b\u91cf\u56fe\u7247<\/p>\n \u56fe3\u00a0SC\u9499\u949b\u77ff\u7684\u56fe\u7247<\/strong><\/p>\n a\uff09<\/strong>CH3<\/sub>NH3<\/sub>Pb(Bry<\/sub>I1\u2212y<\/sub>)3<\/sub>\uff08y=0-1\uff09\u7684\u56fe\u7247<\/p>\n b\uff09<\/strong>CH3<\/sub>NH3<\/sub>Pb(Clx<\/sub>Br1\u2212x<\/sub>)3<\/sub>\uff08x=0-1\uff09\u7684\u56fe\u7247<\/p>\n c,d\uff09<\/strong>\u5206\u522b\u4e3aCH3<\/sub>NH3<\/sub>Pb(Clx<\/sub>Br1\u2212x<\/sub>)3<\/sub>\u548cCH3<\/sub>NH3<\/sub>Pb(Bry<\/sub>I1\u2212y<\/sub>)3<\/sub>\u7684XRD\u56fe<\/p>\n \u56fe4\u00a0\u5149\u5b66\u8868\u5f81<\/strong><\/p>\n a\uff09<\/strong>CH3<\/sub>NH3<\/sub>Pb(Clx<\/sub>Br1\u2212x<\/sub>)3<\/sub>\u548cCH3<\/sub>NH3<\/sub>Pb(Bry<\/sub>I1\u2212y<\/sub>)3<\/sub>\u7c89\u672b\u7684UV Vis NIR\u5438\u6536\u5149\u8c31<\/p>\n b\uff09<\/strong>CH3<\/sub>NH3<\/sub>Pb(Clx<\/sub>Br1\u2212x<\/sub>)3<\/sub>\u548cCH3<\/sub>NH3<\/sub>Pb(Bry<\/sub>I1\u2212y<\/sub>)3<\/sub>\u7c89\u672b\u7684PL\u5149\u8c31<\/p>\n c\uff09<\/strong>\u5364\u7d20\u9499\u949b\u77ff\u7684\u80fd\u91cf\u53d6\u5411<\/p>\n \u56fe5\u00a0\u5355\u6676\u9499\u949b\u77ff\u6676\u7247\u548c\u5fae\u6676\u9499\u949b\u77ff\u8584\u819c\u5149\u7535\u63a2\u6d4b\u5668\u7684\u8868\u5f81<\/strong><\/p>\n a\uff0cb\uff09<\/strong>\u5728\u5355\u6676\u9499\u949b\u77ff\u6676\u7247\u4e0a\u5236\u9020\u768424\u548c28\u5e73\u9762\u578b\u5149\u7535\u63a2\u6d4b\u5668\u7684\u56fe\u7247<\/p>\n c\uff0cd\uff09<\/strong>\u57281,2,4,6,8,10\u548c12V\u7684\u4e0d\u540c\u504f\u7f6e\u7535\u538b\u4e0b\u6d4b\u91cf\u7684\u68c0\u6d4b\u5668\u7684\u5149\u7535\u6d41\u54cd\u5e94<\/p>\n e\uff09<\/strong>\u5355\u6676\u9499\u949b\u77ff\u6676\u7247\u4e0e\u5fae\u6676\u4e4b\u95f4\u5149\u7535\u6d41\u54cd\u5e94\u7684\u6bd4\u8f83<\/p>\n \u3010\u603b\u7ed3\u3011<\/strong><\/p>\n \u672c\u6587\u5f00\u53d1\u4e86\u4e00\u79cd\u6709\u6548\u7684\u6280\u672f\u6765\u4f7f\u5f97\u4e00\u7cfb\u5217\u5927\u578b\u9499\u949b\u77ff\u578b\u6750\u6599\u957f\u5927\uff0c\u968f\u7740\u534a\u5bfc\u4f53\u6676\u7247\u6210\u4e3a\u592a\u9633\u80fd\u7535\u6c60\u3001\u7535\u5b50\u5b66\u3001\u5149\u7535\u5b50\u6027\u8d28\u7684\u57fa\u7840\uff0c\u5927\u578b\u9499\u949b\u77ff\u6676\u7247\u7684\u53ef\u7528\u6027\u53ef\u80fd\u5f7b\u5e95\u6539\u53d8\u5176\u5728\u592a\u9633\u80fd\u7535\u6c60\u3001LED\u3001\u6fc0\u5149\u5668\u3001\u5149\u7535\u63a2\u6d4b\u5668\u548c\u5176\u4ed6\u5149\u7535\u5668\u4ef6\u4e2d\u7684\u5e94\u7528\u3002<\/p>\n \u3010\u4f5c\u8005\u7b80\u4ecb\u3011<\/strong><\/p>\n \u5218\u751f\u5fe0\uff0c\u7537\uff0c1963\u5e74\u751f\uff0c\u5b81\u590f\u5e73\u7f57\u4eba\uff0c\u9655\u897f\u5e08\u8303\u5927\u5b66\u6559\u6388\u3001\u56fd\u5bb6\u201c\u5343\u4eba\u8ba1\u5212\u201d\u7279\u8058\u6559\u6388\u30021983\u5e74\u83b7\u9655\u897f\u5e08\u8303\u5927\u5b66\u7406\u5b66\u5b66\u58eb\u5b66\u4f4d\uff0c1986\u5e74\u83b7\u5170\u5dde\u5927\u5b66\u7406\u5b66\u7855\u58eb\u5b66\u4f4d\uff0c1992\u5e74\u83b7\u7f8e\u56fd\u897f\u5317\u5927\u5b66\u5de5\u5b66\u535a\u58eb\u5b66\u4f4d\uff0c\u7814\u7a76\u65b9\u5411\u4e3a\u7269\u7406\u5316\u5b66\u3002\u5218\u751f\u5fe0\u6559\u6388\u7684\u7814\u7a76\u9886\u57df\u96c6\u4e2d\u5728\u7eb3\u7c73\u6750\u6599\u3001\u8584\u819c\u6750\u6599\u3001\u592a\u9633\u80fd\u5149\u4f0f\u6750\u6599\u3001\u7535\u5149\u8584\u819c\u7684\u7535\u5316\u5b66\u6c89\u79ef\u3001\u6fc0\u5149\u8868\u9762\u5904\u7406\u548c\u5149\u4f0f\u6280\u672f\u7684\u5f00\u53d1\u3001\u653e\u5927\u548c\u751f\u4ea7\u3002<\/p>\n \u7814\u7a76\u6210\u679c\u53d1\u8868\u5728\u4e16\u754c\u8457\u540d\u520a\u7269\u4e0a\uff0c\u5305\u62ec\u7f8e\u56fd\u7684Science<\/em>\u548c\u82f1\u56fd\u7684Nature<\/em>\u3002\u7814\u7a76\u6210\u679c\u5f15\u8d77\u4e86\u5e7f\u6cdb\u91cd\u89c6\uff0c\u5176\u53d1\u8868\u5728Science<\/em>\u4e0a\u7684C60<\/sub>\u5206\u5b50\u7ed3\u6784\u88ab\u56fd\u9645\u8457\u540d\u6742\u5fd7\u957f\u671f\u7528\u4f5c\u5c01\u9762\u7167\u7247\uff0c\u53d1\u8868\u5728\u82f1\u56fdNature<\/em>\u4e0a\u7684\u6210\u679c\u88ab\u8bb8\u591a\u62a5\u7eb8\u3001\u520a\u7269\u62a5\u9053\u8bc4\u8bba\uff0c\u591a\u7bc7\u8bba\u6587\u6210\u4e3a\u88ab\u201c\u6700\u591a\u5f15\u7528\u7684\u8bba\u6587\u201d\uff08most cited paper\uff09\u3002\u4e3b\u8981\u53d1\u660e\u548c\u4e13\u5229\u4e2d\u6709\u591a\u9879\u5df2\u8f6c\u5316\u6210\u5de5\u827a\u548c\u4ea7\u54c1\uff0c\u5176\u5b83\u5927\u90e8\u5206\u88ab\u5e94\u7528\u5728\u751f\u4ea7\u4e0a\uff0c\u5176\u4e2d\u201c\u900f\u660e\u592a\u9633\u80fd\u8584\u819c\u7535\u6c60\u201d\u8363\u83b7\u53f7\u79f0\u201c\u53d1\u660e\u5bb6\u7684\u5965\u65af\u5361\u5956\u201d\u7684\u201c\u4e16\u754c\u6700\u4f73\u53d1\u660e\u5956\u201d\uff08R&D 100\uff09\u30021998\u5e74\u5165\u9009 \u201c\u4e16\u754c\u79d1\u5b66\u5bb6\u5de5\u7a0b\u5e08\u540d\u4eba\u5f55\u201d\u30022011\u5e74\uff0c\u5218\u751f\u5fe0\u6559\u6388\u5165\u9009\u56fd\u5bb6\u7b2c\u516d\u6279\u201c\u5343\u4eba\u8ba1\u5212\u201d\u521b\u65b0\u4eba\u624d\u957f\u671f\u9879\u76ee\u3002<\/p>\n \u4e3b\u8981\u6210\u5c31\uff1a<\/strong><\/p>\n High Efficiency, Large Area, Nanocrystalline Silicon Based, Triple-Junction Solar Cells, Mat. Res. Soc. Symp., (2011) 1321.<\/p>\n The Structure of the C60<\/sub> \u00acmolecule: X-ray crystal structure determination of a twin at 110K, Science, 254 (1991) 408.<\/p>\n Method of Manufacturing Thin Film Photovoltaic Modules, US patent 7259321. Ultra Lightweight Photovoltaic Device and Method For Its Manufacture, US patent 7517465.<\/p>\n \u6587\u732e\u94fe\u63a5<\/strong>\uff1a120 Millimeter Single-Crystalline Perovskite and Wafers: To-wards Viable Applications<\/a>\uff08Sci. China Chem., 2017, DOI:10.1007\/s11426-017-9081-3 \uff09<\/p>\n \u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u7ec4Allen\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065952\u201d\u3002<\/p>\n \u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n \u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n \u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1axiaofire-18\uff0c\u5434\u73ab\uff0c\u6211\u4eec\u4f1a\u62c9\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n \u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e\u6750\u6599\u4eba<\/a>\u3001\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong>\u00a0<\/p>\n
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\n Partially Transparent Photovoltaic Modules, US patent 6858461.<\/p>\n