{"id":82910,"date":"2017-05-27T06:30:27","date_gmt":"2017-05-26T22:30:27","guid":{"rendered":"\/\/m.iemloyee.com\/?p=82910"},"modified":"2017-05-25T17:50:39","modified_gmt":"2017-05-25T09:50:39","slug":"%e6%9d%8e%e6%98%a0%e4%bc%9fchem-soc-rev-%e6%9c%80%e6%96%b0%e7%bb%bc%e8%bf%b0%ef%bc%9a%e9%87%91%e5%b1%9e%e6%9c%89%e6%9c%ba%e6%a1%86%e6%9e%b6%e5%86%85%e7%ba%b3%e7%b1%b3%e7%bb%93%e6%9e%84%e7%9a%84","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=82910","title":{"rendered":"\u674e\u6620\u4f1fChem.Soc.Rev.\u6700\u65b0\u7efc\u8ff0\uff1a\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u5185\u7eb3\u7c73\u7ed3\u6784\u7684\u53ef\u63a7\u8bbe\u8ba1"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

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\u8fd1\u65e5\uff0c\u6765\u81ea\u534e\u5357\u7406\u5de5\u5927\u5b66\u7684\u674e\u6620\u4f1f\u6559\u6388<\/strong>\u548c\u79d1\u5c14\u591a\u74e6\u5927\u5b66\u7684Rafael Luque\u6559\u6388\uff08\u5171\u540c\u901a\u8baf<\/strong>\uff09\u7b49\u4eba\u7684\u4ee5\u201cControllable design of tunable nanostructures inside metal\u2013organic frameworks<\/strong>\u201d\u4e3a\u9898\u7684\u7efc\u8ff0\u6587\u7ae0\u53d1\u8868\u5728\u4e86Chemical Society Reviews<\/strong>\u671f\u520a\u4e0a\u3002\u6587\u7ae0\u603b\u7ed3\u4e86\u53ef\u8c03\u8c10MOF\u7eb3\u7c73\u6750\u6599\u7684\u6700\u65b0\u53d1\u5c55\uff0c\u91cd\u70b9\u4ecb\u7ecd\u4e86\u8fd9\u4e9b\u590d\u5408\u6750\u6599\u7684\u5236\u5907\u4ee5\u53ca\u534f\u540c\u6027\u80fd\uff0c\u8ba8\u8bba\u4e86\u8fd9\u4e9b\u6df7\u5408\u590d\u5408\u6750\u6599\u5728\u5404\u79cd\u5e94\u7528\u4e2d\u7684\u4f18\u8d8a\u6027\u80fd\u4ee5\u53ca\u9762\u4e34\u7684\u6311\u6218\u3002<\/p>\n

\"\"<\/p>\n

\u7efc\u8ff0\u603b\u89c8\u56fe<\/strong><\/p>\n

1 \u7b80\u4ecb<\/h3>\n

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\u7531\u4e8e\u5bf9\u53ef\u6301\u7eed\u5316\u5b66\u7684\u5174\u8da3\u7684\u589e\u591a\uff0c\u8d8a\u6765\u8d8a\u591a\u7684\u7814\u7a76\u4eba\u5458\u5f00\u59cb\u81f4\u529b\u4e8e\u5236\u9020\u5de5\u4e1a\u4e0a\u53ef\u5e94\u7528\u7684\u590d\u5408\u6750\u6599\uff0c\u5176\u4e2d\u5305\u62ec\u5c01\u88c5\u5728\u591a\u5b54\u4e3b\u4f53\u7684NEs\u6750\u6599\u5982\u78b3\u8d28\u6750\u6599\u3001\u4ecb\u5b54\u4e8c\u6c27\u5316\u7845\u3001\u91d1\u5c5e\u6c27\u5316\u7269\u548c\u805a\u5408\u7269\u3002 \u8fd9\u4e9b\u591a\u5b54\u6750\u6599\u5141\u8bb8\u5316\u5b66\u7269\u8d28\u81ea\u7531\u5730\u8fdb\u5165\u5d4c\u5165\u5f0fNEs\uff0c\u5e76\u9632\u6b62NEs\u7684\u805a\u96c6\uff0c\u4ece\u800c\u589e\u5f3a\u5b83\u4eec\u7684\u7a33\u5b9a\u6027\u3002 \u6b64\u5916\uff0c\u4e3b\u4f53\u6750\u6599\u53ef\u4ee5\u63d0\u4f9b\u989d\u5916\u7684\u6d3b\u6027\u4f4d\u70b9\u6765\u4e0e\u5c01\u88c5\u7684NEs\u534f\u540c\u4f5c\u7528\uff0c\u4f7f\u5f97\u590d\u5408\u6750\u6599\u53ef\u4ee5\u8868\u73b0\u51fa\u4e0e\u5176\u7ec4\u5206\u4e0d\u540c\u7684\u6027\u8d28\u3002\u8fd9\u4e9b\u590d\u5408\u6750\u6599\u76f8\u5bf9\u4e8e\u5355\u72ec\u6210\u5206\u7684\u589e\u5f3a\u6027\u80fd\u6fc0\u53d1\u4e86\u641c\u7d22\u65b0\u7c7b\u578b\u7684\u591a\u5b54\u6750\u6599\u4f5c\u4e3a\u4e3b\u4f53\u7684\u7814\u7a76\u5174\u8da3\u3002<\/p>\n

\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOFs\uff09\u6216\u591a\u5b54\u914d\u4f4d\u805a\u5408\u7269\u7684\u591a\u5b54\u7ed3\u6676\u6750\u6599\uff0c\u5176\u7531\u91d1\u5c5e\u79bb\u5b50\u6216\u7c07\u7ec4\u6210\uff0c\u91d1\u5c5e\u79bb\u5b50\u6216\u7c07\u901a\u8fc7\u6709\u673a\u8fde\u63a5\u4f53\u8fde\u63a5\u5e76\u5177\u6709\u660e\u786e\u5b9a\u4e49\u7684\u5b54\u7ed3\u6784\u3001\u5927\u7684\u8868\u9762\u79ef\u548c\u7ed3\u6784\u67d4\u6027\uff0c\u8fd9\u4e9b\u5c5e\u6027\u4f7fMOFs\u9002\u7528\u4e8e\u5404\u79cd\u5e94\u7528\u7684\u4e3b\u4f53\u3002\u5728MOFs\u4e2d\uff0c\u7eb3\u7c73\u5c3a\u5ea6\u7684\u5ba2\u4f53\uff0c\u5982\u91d1\u5c5e\u7eb3\u7c73\u7c92\u5b50\uff08NPs\uff09\u3001\u91cf\u5b50\u70b9\uff08QDs\uff09\u3001\u591a\u91d1\u5c5e\u6c27\u9178\u76d0\uff08POMs\uff09\u3001\u6709\u673a\u548c\u91d1\u5c5e\u6709\u673a\u5206\u5b50\u3001\u751f\u7269\u5927\u5206\u5b50\u548c\u91d1\u5c5e\u6709\u673a\u591a\u9762\u4f53\u7684\u5c01\u88c5\u5df2\u7ecf\u7528\u4e8e\u6c14\u4f53\u5438\u9644\u548c\u50a8\u5b58\u3001\u68c0\u6d4b\u3001\u975e\u5747\u76f8\u50ac\u5316\u548c\u5206\u5b50\u91ca\u653e\u7cfb\u7edf\u7b49\u9886\u57df\u3002<\/p>\n

\"\"<\/p>\n

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2\u00a0MOFs\u4f5c\u4e3aNEs\u7684\u4e3b\u4f53<\/h3>\n

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3 \u5728MOFs\u4e2d\u5c01\u88c5NEs\u7684\u65b9\u6cd5<\/h3>\n

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\"\"<\/p>\n

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3.1\u00a0 \u8239\u4e2d\u74f6\u7b56\u7565\uff08MOFs\u5185\u7684NEs\u88c5\u914d\uff09<\/h4>\n

\u74f6\u4e2d\u8239\u7b56\u7565\u6d89\u53ca\u5230\u5df2\u7ecf\u5f62\u6210\u7684MOFs\u77e9\u9635\u4e2d\u7684NEs\u7ec4\u88c5\uff0c\u8fd9\u53ef\u4ee5\u901a\u8fc7\u4e24\u79cd\u65b9\u6cd5\u6765\u5b9e\u73b0\uff0c\u5373\u7ec4\u88c5\u540e\u5e76\u5165\u548c\u9884\u7ec4\u88c5\u5e76\u5165\u3002\u8fd9\u53d6\u51b3\u4e8eNEs\u524d\u4f53\u600e\u6837\u88ab\u63ba\u5165\u57fa\u8d28\u4e2d\u3002\u5728\u7ec4\u88c5\u540e\u5e76\u5165\u65b9\u6cd5\u4e2d\uff0cNEs\u524d\u4f53\u88ab\u5f15\u5165\u5230\u5df2\u7ecf\u5f62\u6210\u7684\u6846\u67b6\u4e2d\uff0c\u800c\u5728\u7ec4\u88c5\u524d\u63ba\u5165\u65b9\u6cd5\u4e2d\uff0c\u5b83\u4eec\u901a\u8fc7\u5728\u7ec4\u88c5MOFs\u4e4b\u524d\u88ab\u951a\u5b9a\u5230\u63a5\u5934\u6765\u5f15\u5165\u3002\u8fd9\u4e24\u79cd\u65b9\u6cd5\u90fd\u4f9d\u8d56\u4e8eMOFs\u5b54\u9699\u9650\u5236NEs\u7684\u751f\u957f\uff0c\u4f7f\u5176\u4fdd\u6301\u8f83\u5c0f\u7684\u5c3a\u5bf8\u3002\u901a\u8fc7\u8fd9\u4e9b\u65b9\u6cd5\u4ea7\u751f\u7684NEs\u548cMOFs\u4e4b\u95f4\u7684\u754c\u9762\u76f8\u5bf9\u7b80\u5355\u3002<\/p>\n

3.2\u00a0\u74f6\u7ed5\u8239\u7684\u7b56\u7565\uff08\u56f4\u7ed5NEs\u7ec4\u88c5MOFs\uff09<\/h4>\n

\u74f6\u7ed5\u8239\u7b56\u7565\u6d89\u53ca\u5df2\u7ecf\u5408\u6210\u7684NEs\u5468\u56f4\u7684MOFs\u524d\u4f53\u7684\u7ec4\u88c5\u3002\u901a\u5e38\u8fd9\u79cd\u7b56\u7565\u6d89\u53ca\u4e24\u6b65\u6cd5:\uff081\uff09\u51c6\u5907\u5177\u6709\u5747\u5300\u5c3a\u5bf8\u3001\u5f62\u72b6\u548c\u7ed3\u6784\u7684NEs\u82af\uff082\uff09\u5728NEs\u8868\u9762\u7ec4\u88c5MOFs\u3002\u5c01\u7aef\u5242\u6216\u8868\u9762\u6d3b\u6027\u5242\u5bf9\u4e8e\u7a33\u5b9aNEs\u548c\u4fc3\u8fdbNEs\u7684MOFs\u8fc7\u5ea6\u589e\u957f\u662f\u5fc5\u4e0d\u53ef\u5c11\u7684\u3002<\/p>\n

3.3\u00a0 \u5939\u5fc3\u7ec4\u88c5 \uff08\u5728MOFs\u5c42\u4e4b\u95f4\u5d4c\u5165NEs\uff09<\/h4>\n

\u5939\u5fc3\u7ec4\u88c5\u7b56\u7565\u6d89\u53caMOFs\u6838\u5fc3\u7684\u5408\u6210\uff0c\u7136\u540e\u662f\u5728MOFs\u6838\u5fc3\u4e0a\u6c89\u79efNEs\u548c\u968f\u540e\u5177\u6709\u53ef\u8c03\u539a\u5ea6MOFs\u58f3\u7684\u8fc7\u5ea6\u751f\u957f\u3002 \u6b64\u5916\uff0c\u901a\u8fc7\u91cd\u590dNEs\u6c89\u79ef\u548cMOFs\u8fc7\u5ea6\u751f\u957f\u7684\u6b65\u9aa4\u53ef\u4ee5\u83b7\u5f97\u5177\u6709\u53ef\u63a7\u7ed3\u6784\u7684\u591a\u5c42\u6750\u6599\u3002\u8fd9\u79cd\u7b56\u7565\u80fd\u591f\u5f88\u597d\u5730\u63a7\u5236\u5c01\u88c5\u7684NEs\u7684\u4f4d\u7f6e\u3001\u7ec4\u6210\u548c\u5f62\u72b6\u3002<\/p>\n

3.4\u00a0\u539f\u4f4d\u5c01\u88c5\uff08MOFs\u548cNEs\u540c\u65f6\u5408\u6210\uff09<\/h4>\n

\u4e3a\u4e86\u8282\u7701\u65f6\u95f4\u548c\u7cbe\u529b\u5e76\u964d\u4f4e\u6210\u672c\uff0c\u6700\u8fd1\u5f00\u53d1\u4e86\u4e00\u79cd\u64cd\u4f5c\u7b80\u5355\u7684\u7528\u4e8e\u5236\u5907NE@MOF\u590d\u5408\u6750\u6599\u7684\u539f\u4f4d\u5c01\u88c5\u7b56\u7565\u3002\u8be5\u7b56\u7565\u6d89\u53ca\u5c06\u6240\u6709\u5fc5\u9700\u6210\u5206\uff08\u4f8b\u5982NEs\u548cMOFs\u7684\u524d\u4f53\uff09\u6df7\u5408\u5728\u6eb6\u6db2\u4e2d\uff0c\u7531\u6b64\u540c\u65f6\u5236\u5907NEs\u548cMOFs\uff0cMOFs\u58f3\u4ec5\u5728NEs\u7684\u8868\u9762\u4e0a\u751f\u957f\u800c\u4e0d\u81ea\u751f\u6838\u3002\u5b9e\u9a8c\u53c2\u6570\u7684\u63a7\u5236\uff08\u4f8b\u5982\u524d\u4f53\u3001\u6eb6\u5242\u3001\u8868\u9762\u6d3b\u6027\u5242\u3001\u53cd\u5e94\u6e29\u5ea6\u548c\u8c03\u8282\u5242\uff09\u5bf9\u4e8e\u5e73\u8861NEs\u548cMOFs\u7684\u81ea\u6210\u6838\u548c\u751f\u957f\u901f\u7387\u4ee5\u53ca\u5c06\u5b83\u4eec\u7ec4\u88c5\u6210\u5355\u4e2a\u7eb3\u7c73\u7ed3\u6784\u662f\u5f88\u5fc5\u8981\u7684\u3002\u7279\u522b\u5730\uff0c\u6709\u673a\u8fde\u63a5\u4f53\u6216\u6eb6\u5242\u4e2d\u5b98\u80fd\u56e2\u7684\u9009\u62e9\u5bf9\u4e8e\u7a33\u5b9a\u539f\u4f4d\u5f62\u6210\u7684NEs\u548c\u4fc3\u8fdbNEs\u8868\u9762\u4e0a\u7684MOFs\u7684\u5f02\u6838\u5316\u662f\u5f88\u91cd\u8981\u7684\u3002\u7531\u4e8e\u5176\u64cd\u4f5c\u7b80\u5355\u3001\u751f\u4ea7\u6210\u672c\u4f4e\u53ca\u5176\u53ef\u6269\u5c55\u6027\uff0c NE@MOF\u590d\u5408\u6750\u6599\u7684\u5408\u6210\u53ef\u80fd\u4e3aMOFs\u6750\u6599\u7684\u5b9e\u9645\u5e94\u7528\u94fa\u8def\u3002<\/p>\n

4\u00a0\u5c01\u88c5\u5728MOFs\u4e2d\u7684NEs\u79cd\u7c7b<\/h3>\n

4.1\u00a0\u91d1\u5c5eNPs<\/h4>\n

\u91d1\u5c5eNPs\u7531\u4e8e\u5176\u9ad8\u7684\u5316\u5b66\u6d3b\u6027\u548c\u7279\u5f02\u6027\u800c\u5f15\u8d77\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u7136\u800c\uff0c\u5b83\u4eec\u7684\u9ad8\u8868\u9762\u80fd\u4f7f\u5b83\u4eec\u5728\u70ed\u529b\u5b66\u4e0a\u4e0d\u7a33\u5b9a\uff0c\u56e0\u6b64\u6613\u4e8e\u805a\u96c6\u548c\u7194\u5408\u3002\u91d1\u5c5eNPs\u5728MOFs\u4e2d\u7684\u56fa\u5b9a\u53ef\u4ee5\u9632\u6b62NPs\u7684\u805a\u96c6\uff0c\u5e76\u4f7f\u5176\u5728\u975e\u5747\u76f8\u50ac\u5316\u3001\u50a8\u6c14\u548c\u5316\u5b66\u4f20\u611f\u7b49\u4e2d\u5f97\u5230\u66f4\u597d\u7684\u5e94\u7528\u3002\u56fa\u5b9a\u91d1\u5c5eNPs\u53ef\u4ee5\u5206\u4e3a\u56db\u4e2a\u57fa\u672c\u7c7b\u522b\uff1a\u5b54\u5185\u7ed3\u6784\uff0c\u7531MOF\u5b54\u4e2d\u7684\u91d1\u5c5eNPs\u7ec4\u6210; \u6838\u58f3\u7ed3\u6784\uff0c\u7531MOFs\u58f3\u5305\u88f9\u7684\u91d1\u5c5e\u82af\u7ec4\u6210; \u5375\u58f3\u7ed3\u6784\u7531\u4e2d\u7a7aMOFs\u58f3\u5185\u7684\u91d1\u5c5e\u82af\u7ec4\u6210; \u5939\u5fc3\u7ed3\u6784\uff0c\u5176\u7531\u5d4c\u5165\u5728MOFs\u5c42\u4e2d\u7684\u91d1\u5c5eNPs\u7ec4\u6210\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3\u00a0\u5305\u88f9\u5728MOFs\u5b54\u4e2d\u7684Pd@Ag\u6838\u58f3NPs\u7684\u5236\u5907<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe4\u00a0\u5177\u67091D\u5b54\u7684MOF-545\u6a21\u578b\u4f5c\u4e3a\u7eb3\u7c73\u7ebf\u9635\u5217\u5408\u6210\u7684\u6a21\u677f<\/strong><\/p>\n

4.2\u00a0\u91cf\u5b50\u70b9\uff08QDs\uff09<\/h4>\n

\u91cf\u5b50\u70b9\uff08\u5c3a\u5bf8\u8303\u56f4\u4e3a2-10nm\uff09\u7531\u4e8e\u5176\u72ec\u7279\u7684\u5c3a\u5bf8\u4e0e\u7535\u5b50\u548c\u5149\u5b66\u6027\u8d28\u606f\u606f\u76f8\u5173\u7684\u6027\u80fd\uff0c\u5728\u8fc7\u53bb\u4e8c\u5341\u5e74\u4e2d\u53d7\u5230\u76f8\u5f53\u5927\u7684\u5173\u6ce8\u3002\u91cf\u5b50\u70b9\u5728MOFs\u5185\u7684\u5c01\u88c5\u53ef\u4ee5\u63d0\u9ad8\u5176\u7a33\u5b9a\u6027\u5e76\u8c03\u8282\u7535\u5b50-\u7a7a\u7a74\u590d\u5408\u7387\u3002\u51e0\u79cd\u7c7b\u578b\u7684\u91cf\u5b50\u70b9\uff08\u4f8b\u5982\u6c27\u5316\u7269\u3001\u786b\u65cf\u5316\u7269\u3001\u6c2e\u5316\u7269\u548c\u78b3\u57fa\u7684\u91cf\u5b50\u70b9\uff09\u5df2\u88ab\u6574\u5408\u5230MOFs\u4e2d\uff0c\u5e76\u4e14\u6240\u5f97\u5230\u7684\u590d\u5408\u6750\u6599\u8868\u73b0\u51fa\u4f7f\u5176\u5728\u76f8\u5173\u9886\u57df\u4e2d\u6709\u7528\u7684\u6027\u8d28\uff0c\u4f8b\u5982\u5149\u50ac\u5316\u3001\u8d85\u7ea7\u7535\u5bb9\u5668\u548c\u68c0\u6d4b\u3002<\/p>\n

\"\"<\/p>\n

\u56fe5\u00a0\u901a\u8fc7\u81ea\u6a21\u677f\u6cd5\u5408\u6210ZnO@ZIF-8\u7eb3\u7c73\u68d2\u9635\u5217<\/strong><\/p>\n

4.3 \u591a\u91d1\u5c5e\u6c27\u9178\u76d0\uff08POMs\uff09<\/h4>\n

POMs\u662f\u7eb3\u7c73\u5c3a\u5bf8\u91d1\u5c5e\u6c27\u5316\u7269\u805a\u9634\u79bb\u5b50\u5bb6\u65cf\u7684\u6210\u5458\uff0c\u5177\u6709\u4e30\u5bcc\u7684\u7ed3\u6784\u548c\u5316\u5b66\u53d8\u5316\u4ee5\u53ca\u53ef\u8c03\u7684\u5f62\u72b6\u3001\u5927\u5c0f\u3001\u6eb6\u89e3\u5ea6\u3001\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u548c\u9178\u5ea6\u3002\u7136\u800c\uff0c\u5b83\u4eec\u7684\u5e94\u7528\u53d7\u5230\u5176\u6bd4\u8868\u9762\u79ef\u5c0f\u3001\u4f4e\u7a33\u5b9a\u6027\u548c\u5728\u6c34\u6eb6\u6db2\u4e2d\u7684\u9ad8\u6eb6\u89e3\u5ea6\u7684\u9650\u5236\u3002\u5c06POMs\u7eb3\u5165MOFs\u662f\u7a33\u5b9a\u548c\u4f18\u5316POMs\u4ee5\u63d0\u9ad8\u5176\u6548\u7528\u7684\u6709\u6548\u65b9\u6cd5\u3002\u5236\u5907POM@MOF\u590d\u5408\u6750\u6599\u6709\u51e0\u79cd\u6210\u719f\u7684\u6709\u6548\u65b9\u6cd5\uff1a\u5c06POMs\u7c07\u6d78\u6e0d\u5230MOFs\u5b54\u4e2d\uff0c\u5408\u6210\u5df2\u7ecf\u5f62\u6210\u7684MOFs\u7b3c\u4e2d\u7684POMs\uff0c\u4ee5\u53ca\u5728POMs\u5b58\u5728\u4e0b\u5408\u6210MOFs\u3002\u867d\u7136\u6d78\u6e0d\u65b9\u6cd5\u662f\u76f4\u63a5\u7684\uff0c\u5b83\u9650\u4e8e\u5177\u6709\u5927\u4e8e\u76f8\u5e94POMs\u7a97\u53e3\u7684MOFs\u3002\u6b64\u5916\uff0c\u4e00\u4e9bPOMs\u5206\u5b50\u4e0d\u53ef\u907f\u514d\u5730\u6c89\u79ef\u5728MOFs\u7684\u5916\u8868\u9762\u4e0a\u3002\u867d\u7136\u4e5f\u5c1d\u8bd5\u4e86\u5df2\u7ecf\u5f62\u6210\u7684MOFs\u5185POMs\u7684\u5408\u6210\u3002\u7136\u800c\uff0cPOMs\u7684\u5408\u6210\u901a\u5e38\u9700\u8981\u5f3a\u9178\u6027\u6761\u4ef6\uff0c\u8fd9\u4f1a\u5bfc\u81f4MOFs\u7684\u964d\u89e3\u3002\u8fd1\u6765\u53d7\u5230\u91cd\u89c6\u7684POMs\u4e0aMOFs\u7684\u7ec4\u88c5\u5df2\u88ab\u8bc1\u660e\u5bf9\u4e8e\u6df7\u5408\u590d\u5408\u6750\u6599\u7684\u6784\u5efa\u662f\u6709\u7528\u7684\u3002\u9884\u671f\u5176\u6709\u6548\u7ec4\u88c5\u53d6\u51b3\u4e8e\u5bf9\u53cd\u5e94\u53c2\u6570\u7684\u63a7\u5236\uff0c\u4f8b\u5982\u91d1\u5c5e\u6c27\u5316\u7269\u9634\u79bb\u5b50\u548c\u6742\u539f\u5b50\u7684\u6d53\u5ea6\u548c\u7c7b\u578b\u3001pH\u3001\u914d\u4f53\u548c\u53cd\u5e94\u6e29\u5ea6\u3002<\/p>\n

\"\"<\/p>\n

\u56fe6\u00a0\u7531POMs\u548c\u6c34\u8c03\u5236\u7684[Cu3<\/sub>\uff08BTC\uff092<\/sub>]n<\/sub>\u7eb3\u7c73\u6676\u4f53\u7684\u5236\u5907<\/strong><\/p>\n

4.4\u00a0\u91d1\u5c5e\u6709\u673a\u5206\u5b50<\/h4>\n

\u76ee\u524d\u5df2\u7ecf\u5e7f\u6cdb\u7814\u7a76\u4e86\u5747\u76f8\u6709\u673a\u548c\u91d1\u5c5e\u6709\u673a\u5206\u5b50\uff08\u4f8b\u5982\u535f\u5549\u53ca\u5176\u91d1\u5c5e\u884d\u751f\u7269\u3001salen\u7edc\u5408\u7269\u3001\u91d1\u5c5e\u915e\u83c1\u7edc\u5408\u7269\u548c\u67d3\u6599\uff09\u4f5c\u4e3a\u7528\u4e8e\u7406\u89e3\u548c\u6a21\u62df\u751f\u7269\u7cfb\u7edf\u529f\u80fd\u7684\u5de5\u5177\u3002\u7136\u800c\uff0c\u7531\u4e8e\u6d3b\u6027\u4f4d\u70b9\u4e4b\u95f4\u7684\u53cd\u5e94\u548c\u6c27\u5316\u6027\u81ea\u5206\u89e3\u7684\u7ed3\u679c\uff0c\u8fd9\u4e9b\u5206\u5b50\u7684\u6d3b\u6027\u5bff\u547d\u7531\u4e8e\u81ea\u805a\u96c6\u800c\u53d7\u5230\u9650\u5236\u3002\u8fd9\u4e9b\u5206\u5b50\u5728MOFs\u4e2d\u88ab\u56fa\u5b9a\uff0c\u5176\u6d3b\u6027\u4f4d\u70b9\u53ef\u4ee5\u88ab\u5206\u79bb\u548c\u4fdd\u62a4\uff0c\u8fd9\u662f\u514b\u670d\u8fd9\u4e2a\u7f3a\u70b9\u6709\u6548\u7684\u65b9\u6cd5\u3002\u53ef\u4ee5\u901a\u8fc7\u63ba\u5165\u6709\u673a\u63a5\u5934\u6216\u5305\u5c01\u5728MOFs\u5b54\u4e2d\u5c06\u91d1\u5c5e\u6709\u673a\u7edc\u5408\u7269\u5f15\u5165MOFs\u7684\u65b9\u6cd5\u6765\u89e3\u51b3\u3002\u00a0<\/p>\n

\"\"<\/p>\n

\u56fe7\u00a0\u5728\u63a5\u5934\u4ea4\u6362\u6761\u4ef6\u4e0b\uff0c\u5c06\u76f8\u5bf9\u8f83\u5927\u3001\u591a\u6837\u5316\u7684\u5ba2\u4f53\u5206\u5b50\u7ed3\u5408\u5230MOFs\u4e2d<\/strong><\/p>\n

4.5\u00a0\u751f\u7269\u5927\u5206\u5b50<\/strong><\/h4>\n

\u529f\u80fd\u751f\u7269\u5927\u5206\u5b50\uff08\u4f8b\u5982\u86cb\u767d\u8d28\u3001DNA\u548c\u9176\uff09\u5728\u836f\u7269\u548c\u5316\u5b66\u5408\u6210\u4e2d\u7684\u5e94\u7528\u4e00\u76f4\u662f\u79d1\u5b66\u5bb6\u7684\u7814\u7a76\u76ee\u6807\u3002\u5982\u679c\u6d3b\u6027\u751f\u7269\u5927\u5206\u5b50\u5728\u5de5\u4e1a\u4e0a\u5f97\u5230\u5e94\u7528\uff0c\u5fc5\u987b\u589e\u5f3a\u5176\u70ed\u7a33\u5b9a\u6027\uff0c\u6709\u673a\u6eb6\u5242\u7684\u8010\u53d7\u6027\uff0c\u53ef\u56de\u6536\u6027\u548c\u4fdd\u8d28\u671f\uff0c\u800c\u4e0d\u4f1a\u5f71\u54cd\u5176\u6d3b\u6027\u3002MOFs\u5df2\u7ecf\u88ab\u8bc1\u660e\u662f\u7528\u4e8e\u56fa\u5b9a\u751f\u7269\u5927\u5206\u5b50\u4ee5\u4fdd\u62a4\u5b83\u4eec\u514d\u4e8e\u5931\u6d3b\u53cd\u5e94\u6761\u4ef6\uff08\u4f8b\u5982\u5347\u9ad8\u7684\u6e29\u5ea6\u3001\u6709\u673a\u6eb6\u5242\u548c\u53d8\u6027\u5242\uff09\u5e76\u63d0\u9ad8\u5176\u53ef\u56de\u6536\u6027\u7684\u6709\u6548\u5e73\u53f0\u3002\u5728\u8fd9\u65b9\u9762\uff0cFarha\u7b49\u4eba\u6700\u8fd1\u56de\u987e\u4e86\u5c01\u88c5\u5728MOFs\u4e2d\u7684\u9176\u7cfb\u7edf\uff0c\u7528\u4e8e\u8bbe\u8ba1\u5728\u6311\u6218\u6027\u50ac\u5316\u6761\u4ef6\u4e0b\u4f7f\u7528\u7684\u7a33\u5b9a\u548c\u6d3b\u6027\u50ac\u5316\u5242\u3002\u76ee\u524d\u5df2\u7ecf\u62a5\u9053\u4e86\u7528\u4e8e\u5728MOFs\u4e2d\u56fa\u5b9a\u751f\u7269\u5927\u5206\u5b50\u7684\u51e0\u79cd\u7b56\u7565\uff0c\u5305\u62ec\u7269\u7406\u5438\u9644\u3001\u5171\u4ef7\u9644\u7740\u3001\u67d3\u6599\u6807\u8bb0\u548c\u5305\u5c01\u3002<\/p>\n

\"\"<\/p>\n

\u56fe8\u00a0\u56fa\u5b9a\u5728MOFs\u4e2d\u89d2\u8d28\u9176\u6d3b\u6027\u4f4d\u70b9\u7684\u53ef\u884c\u6027<\/strong><\/p>\n

4.6\u00a0\u91d1\u5c5e\u6709\u673a\u591a\u9762\u4f53<\/h4>\n

\u91d1\u5c5e\u6709\u673a\u591a\u9762\u4f53\uff08MOPs\uff09\u662f\u901a\u8fc7\u91d1\u5c5e\u79bb\u5b50\u548c\u5b98\u80fd\u5316\u8fde\u63a5\u4f53\u7684\u914d\u4f4d\u5408\u6210\u7684\u4e00\u7c7b\u65b0\u7684\u79bb\u6563\u65e0\u673a-\u6709\u673a\u914d\u4f4d\u7edc\u5408\u7269\u3002\u7531\u4e8e\u5176\u53ef\u8c03\u7ed3\u6784\u548c\u9ad8\u5bf9\u79f0\u6027\uff0cMOPs\u5728\u5438\u6536\u3001\u50ac\u5316\u548c\u5206\u5b50\u611f\u5e94\u7b49\u9886\u57df\u7684\u4f7f\u7528\u5f15\u8d77\u4e86\u76f8\u5f53\u7684\u5173\u6ce8\u3002\u7136\u800c\uff0cMOPs\u5728\u6fc0\u6d3b\u540e\u805a\u5408\u7684\u8d8b\u52bf\u964d\u4f4e\u4e86\u5b83\u4eec\u7684\u8868\u73b0\u3002Li \u7b49\u4eba\u6700\u8fd1\u8bc1\u660eMOPs\u5728MOF\u8154\u4e2d\u7684\u5c01\u88c5\u53ef\u4ee5\u5206\u79bb\u5355\u72ec\u7684MOPs\uff0c\u4ece\u800c\u589e\u5f3a\u5176\u53cd\u5e94\u6027\u548c\u7a33\u5b9a\u6027\u3002\u9009\u62e9MIL-101\uff08Cr\uff09\u4f5c\u4e3a\u8fd9\u4e9b\u7814\u7a76\u7684\u4e3b\u4f53\uff0cM6<\/sub>L4<\/sub>\uff08M =\uff08en\uff09Pd\uff08NO3<\/sub>\uff092<\/sub>\uff0cen =\u4e59\u4e8c\u80fa\uff0cL = 1,3,5-\u4e09\uff084-\u5421\u5576\u57fa\uff09-2,4,6-\u4e09\u55ea\uff09\u662f\u6a21\u578bMOP\u5ba2\u4f53\u3002\u9996\u5148\u5c06MIL-101\uff08Cr\uff09\u548cL\u52a0\u5165\u5230\u758f\u6c34\u6027\u6eb6\u5242\uff08\u6b63\u5df1\u70f7\uff09\u4e2d\uff0c\u7136\u540e\u52a0\u5165\u5c11\u91cf\u542b\u6709\u524d\u4f53M\u7684\u6c34\u6eb6\u6db2\uff08\u6c34\u6eb6\u6db2\u7684\u4f53\u79ef\u4f4e\u4e8e\u5b54\u4f53\u79ef\uff09\u3002\u7531\u4e8eMIL-101\u7684\u5185\u8868\u9762\u7684\u4eb2\u6c34\u6027\u76f8\u5bf9\u4e8e\u5916\u8868\u9762\u7684\u4eb2\u6c34\u6027\u66f4\u9ad8\uff0cM\u7684\u524d\u4f53\u7684\u6c34\u6eb6\u6db2\u5bb9\u6613\u5730\u901a\u8fc7\u6bdb\u7ec6\u7ba1\u529b\u5f15\u5165\u5230MOF\u5b54\u4e2d\u3002\u6b64\u5916\uff0cM6<\/sub>L4<\/sub>\u5bb9\u6613\u5728\u6c34\u4e2d\u81ea\u7ec4\u88c5\uff0c\u7531\u4e8e\u5316\u5b66\u5e73\u8861\u7684\u53d8\u5316\uff0c\u5c06L\u63a8\u5165MIL-101\u6bdb\u5b54\u3002\u4ee5\u8fd9\u79cd\u65b9\u5f0f\uff0c\u5c3a\u5bf8\u6bd4MOF\u8154\u5927\u7684M6<\/sub>L4<\/sub>\u5206\u5b50\u53ef\u4ee5\u5d4c\u5165\u5728MIL-101\u5b54\u5185\u3002<\/p>\n

\"\"<\/p>\n

\u56fe9\u00a0M6<\/sub>L4<\/sub>\u548cM6<\/sub>L4<\/sub>\u2282MIL-101\u7684\u5236\u5907<\/strong><\/p>\n

4.7 \u5176\u4ed6NEs<\/h4>\n

\u5176\u4ed6NEs\uff0c\u5305\u62ec\u805a\u5408\u7269\u3001\u79bb\u5b50\u6db2\u4f53\uff08ILs\uff09\u3001\u4e8c\u6c27\u5316\u7845\u548c\u78b3\u7eb3\u7c73\u7ed3\u6784\uff0c\u53ef\u4ee5\u4e0eMOFs\u5f62\u6210\u590d\u5408\u6750\u6599\u5e76\u751f\u6210\u65b0\u7684\u591a\u529f\u80fd\u6df7\u5408\u6750\u6599\u3002<\/p>\n

5\u00a0\u5c01\u88c5\u5728MOFs\u4e2dNEs\u7684\u6027\u80fd<\/h3>\n

\u7531\u4e8eMOFs\u7684\u7eb3\u7c73\u7ed3\u6784\u548c\u7535\u5b50\u8c03\u8282\u4f5c\u7528\uff0c\u5c01\u88c5\u5728\u8fd9\u4e9b\u6750\u6599\u4e2d\u7684NEs\u7684\u6027\u8d28\u4e0e\u6e38\u79bbNEs\u7684\u6027\u8d28\u4e0d\u540c\u3002NEs\u5177\u6709\u9ad8\u8868\u9762\u80fd\uff0c\u56e0\u6b64\u70ed\u529b\u5b66\u4e0d\u7a33\u5b9a\uff0c\u5728\u6076\u52a3\u6761\u4ef6\u4f8b\u5982\u9ad8\u6e29\u4e0b\u5177\u6709\u805a\u96c6\u503e\u5411\u3002NEs\u5728MOFs\u5185\u7684\u5c01\u88c5\u662f\u63d0\u9ad8\u5176\u7a33\u5b9a\u6027\u7684\u6709\u6548\u7b56\u7565\u3002MOFs\u7684\u51e0\u4f55\u7ed3\u6784\u53ef\u4ee5\u6700\u5c0f\u5316\u5c01\u88c5NEs\u7684\u6d78\u51fa\u548c\u805a\u96c6\u3002\u5177\u6709\u901a\u8fc7\u5c0f\u7a97\u53e3\u4e92\u8fde\u7684\u5927\u7a7a\u81543D MOFs\u7279\u522b\u9002\u7528\u4e8eNEs\u7684\u7a33\u5b9a\u3002\u7b3c\u72b6MOFs\u8fd8\u53ef\u7528\u4e8e\u5c06\u529f\u80fd\u6027NEs\u5206\u79bb\u6210\u5355\u4e2a\u5b54\uff0c\u8fd9\u5141\u8bb8NEs\u66b4\u9732\u4e8e\u53cd\u5e94\u7269\u5e76\u9632\u6b62NEs\u7684\u4e8c\u6b21\u805a\u5316\u5bfc\u81f4\u7684\u6d3b\u6027\u4e27\u5931\u3002\u901a\u5e38\u5728\u4f7f\u7528\u91d1\u5c5e\u7edc\u5408\u7269\u7684\u5747\u76f8\u50ac\u5316\u4e2d\u53ef\u4ee5\u89c2\u5bdf\u5230\u4e8c\u6b21\u805a\u5316\u548c\u968f\u4e4b\u800c\u6765\u7684\u6d3b\u6027\u4e27\u5931\u3002NE@MOF\u590d\u5408\u6750\u6599\u4e5f\u53ef\u4ee5\u4f5c\u4e3a\u5206\u5b50\u7b5b\uff0c\u56e0\u4e3a\u5b83\u4eec\u5177\u6709\u660e\u786e\u7684\u591a\u5b54\u7ed3\u6784\uff0c\u5728\u9009\u62e9\u6027\u50ac\u5316\u548c\u611f\u6d4b\u65b9\u9762\u5177\u6709\u663e\u8457\u7684\u5e94\u7528\u3002<\/p>\n

6 \u603b\u7ed3\u4e0e\u5c55\u671b<\/h3>\n

MOFs\u4f5c\u4e3aNEs\u5c01\u88c5\u7684\u5e73\u53f0\u63d0\u4f9b\u4e86\u8bb8\u591a\u4f18\u52bf\u3002\u76ee\u524d\u5df2\u7ecf\u5f00\u53d1\u4e86\u5404\u79cd\u6709\u6548\u7684\u7b56\u7565\u6765\u5c01\u88c5\u51e0\u4e4e\u6240\u6709\u5df2\u77e5\u7c7b\u578b\u7684\u5177\u6709MOFs\u4e2d\u53ef\u8c03\u8c10\u7ed3\u6784\u7684\u529f\u80fdNEs\u3002 NE@MOF\u590d\u5408\u6750\u6599\u4e0d\u4ec5\u8868\u73b0\u51fa\u5176\u5404\u81ea\u6210\u5206\u7684\u6027\u8d28\uff0c\u800c\u4e14\u8fd8\u53ef\u4ee5\u663e\u793a\u534f\u540c\u589e\u5f3a\u7684\u6027\u80fd\u3002\u7136\u800c\uff0cMOFs\u4f5c\u4e3a\u5236\u5907\u6df7\u5408\u590d\u5408\u6750\u6599\u7684\u4e3b\u4f53\u7684\u7814\u7a76\u4ecd\u5904\u4e8e\u8d77\u6b65\u9636\u6bb5\uff0c\u8bb8\u591a\u6311\u6218\u4ecd\u6709\u5f85\u89e3\u51b3\u3002\u76f8\u4fe1\u7ecf\u8fc7\u7814\u7a76\u4eba\u5458\u7684\u52aa\u529b NE@MOF\u590d\u5408\u6750\u6599\u5728\u4e0d\u4e45\u7684\u5c06\u6765\u53ef\u4ee5\u5728\u5de5\u4e1a\u4e0a\u5f97\u5230\u66f4\u597d\u7684\u5e94\u7528\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5<\/strong>\uff1aControllable design of tunable nanostructures inside metal\u2013organic frameworks<\/a>\uff08Chem.Soc.Rev.,2017,DOI: 10.1039\/C6CS00537C\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u751f\u7269\u6750\u6599\u7ec4Allen\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u53c2\u4e0e\u751f\u7269\u6750\u6599\u8bdd\u9898\u8ba8\u8bba\u6216\u4e86\u89e3\u751f\u7269\u6750\u6599\u5c0f\u7ec4\u62db\u52df\u8be6\u60c5\uff0c\u8bf7\u52a0\u5165\u6750\u6599\u4eba\u751f\u7269\u6750\u6599\u4ea4\u6d41\u7fa4\uff08124806506\uff09\u3002<\/p>\n

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