{"id":8058,"date":"2016-04-17T08:00:16","date_gmt":"2016-04-17T00:00:16","guid":{"rendered":"\/\/m.iemloyee.com\/?p=8058"},"modified":"2016-04-20T19:45:56","modified_gmt":"2016-04-20T11:45:56","slug":"jacs%e6%96%87%e7%8c%ae%e8%a7%a3%e8%af%bb%ef%bc%9a%e7%ab%af%e5%9f%ba%e6%b0%af%e4%bb%a3%e8%81%9a%e7%94%b2%e5%9f%ba%e4%b8%99%e7%83%af%e9%85%b8%e7%94%b2%e9%85%af%e7%9a%84%e6%9c%ab%e7%ab%af%e9%80%89","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=8058","title":{"rendered":"JACS\u6587\u732e\u89e3\u8bfb\uff1a\u7aef\u57fa\u6c2f\u4ee3\u805a\u7532\u57fa\u4e19\u70ef\u9178\u7532\u916f\u7684\u672b\u7aef\u9009\u62e9\u6027\u916f\u4ea4\u6362\uff1a\u4e00\u79cd\u6a21\u5757\u5316\u65b9\u6cd5\u6765\u5408\u6210\u9065\u722a\u548c\u7cbe\u786e\u529f\u80fd\u5316\u7684\u9ad8\u5206\u5b50"},"content":{"rendered":"<p style=\"text-align: left;\">\u5408\u6210\u7684\u5927\u5206\u5b50\u7684\u7cbe\u786e\u529f\u80fd\u5316\u662f\u521b\u9020\u72ec\u7279\u4e14\u6709\u9009\u62e9\u6027\u529f\u80fd\u7684\u5173\u952e\u3002\u76ee\u524d\uff0c\u5728\u7cbe\u786e\u805a\u5408\u65b9\u9762\u5df2\u7ecf\u53ef\u4ee5\u5408\u6210\u591a\u79cd\u529f\u80fd\u7684\u9ad8\u5206\u5b50\u3002\u53ef\u9009\u62e9\u6027\u548c\u9ad8\u6548\u7684\u6709\u673a\u53cd\u5e94\u4e0e\u7cbe\u786e\u7684\u805a\u5408\u76f8\u7ed3\u5408\uff0c\u662f\u4e00\u79cd\u591a\u529f\u80fd\u4e14\u4fbf\u5229\u7684\u65b9\u6cd5\u3002\u524d\u8005\u53ef\u4ee5\u9009\u62e9\u6027\u7684\u66f4\u6539\u76ee\u6807\u94fe\u6bb5\u548c\/\u6216\u590d\u5408\u7269\uff0c\u540e\u8005\u53ef\u4ee5\u63a7\u5236\u5206\u5b50\u91cf\u548c\u672b\u7aef\u7ed3\u6784\u3002<\/p>\n<p>\u672c\u6587\u62a5\u9053\u4e86\u5728\u949b\u9187\u76d0\u50ac\u5316\u5242\u548c\u9187\u7684\u6761\u4ef6\u4e0b\u5b9e\u73b0\u7aef\u57fa\u6c2f\u4ee3\u805a\u7532\u57fa\u4e19\u70ef\u9178\uff08PMMAs\uff09\u7684\u672b\u7aef\u9009\u62e9\u6027\u916f\u4ea4\u6362\u3002\u8fd9\u4e3a\u5408\u6210\u9065\u722a\u548c\u7cbe\u786e\u529f\u80fd\u5316\u9ad8\u5206\u5b50\u63d0\u4f9b\u4e86\u4e00\u4e2a\u65b0\u7684\u6a21\u5757\u5316\u65b9\u6cd5\u3002<\/p>\n<p><strong>\u65b9\u68481. \uff08a\uff09\u7aef\u57fa\u6c2f\u4ee3\u9065\u722a\u548c\uff08b\uff09\u7528\u6d3b\u6027\u81ea\u7531\u57fa\u805a\u5408\uff0c\u7aef\u57fa\u6c2f\u4ee3PMMAs\u7684\u672b\u7aef\u9009\u62e9\u6027\u916f\u4ea4\u6362\u5b9e\u73b0\u7cbe\u786e\u529f\u80fd\u5316\u9ad8\u5206\u5b50\u3002<\/strong><\/p>\n<p style=\"text-align: left;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-8062\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/1-7.png\" alt=\"1\" width=\"508\" height=\"476\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/1-7.png 508w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/1-7-300x281.png 300w\" sizes=\"(max-width: 508px) 100vw, 508px\" \/><\/p>\n<p>\u4e0e\u4f20\u7edf\u7684\u9065\u722a\u805a\u5408\u7269\u76f8\u6bd4\uff0cEt-PMMA-Cl\u7684\u916f\u4ea4\u6362\u53ef\u4ee5\u5b9a\u91cf\u5730\u63d0\u4f9b\u7aef\u57fa\u6c2f\u4ee3\u7684\u9065\u722aPMMAs\u3002\u5728\u81ea\u7531\u57fa\u6d3b\u6027\u805a\u5408\u4e2d\uff0c\u6c2f\u4ee3\u9065\u722a\u805a\u5408\u7269\u4f1a\u4f5c\u4e3a\u4e00\u4e2a\u5927\u5206\u5b50\u5f15\u53d1\u5242\u3002\u56e0\u6b64\uff0c\u6d3b\u6027\u81ea\u7531\u57fa\u805a\u5408\u548c\u672b\u7aef\u9009\u62e9\u6027\u916f\u4ea4\u6362\u7684\u8fed\u4ee3\u8fc7\u7a0b\u5b9e\u73b0\u7cbe\u786e\u529f\u80fd\u5316\u9ad8\u5206\u5b50\uff0c\u53ef\u4ee5\u5c06\u4e00\u4e2a\u529f\u80fd\u7cbe\u786e\u7684\u5f15\u5165\u5230\u5927\u5206\u5b50\u7279\u5b9a\u7684\u4f4d\u7f6e\uff08\u672b\u7aef\uff0c\u4e2d\u5fc3\u7b49\uff09\u3002\u8fd9\u6837\u7cbe\u786e\u7684\u529f\u80fd\u5316\u5728\u81ea\u7531\u57fa\u805a\u5408\u4e2d\u662f\u5f88\u96be\u5b9e\u73b0\u7684\u3002<\/p>\n<p style=\"text-align: left;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-8064\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/2-8.png\" alt=\"2\" width=\"494\" height=\"512\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/2-8.png 494w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/2-8-289x300.png 289w\" sizes=\"(max-width: 494px) 100vw, 494px\" \/><\/p>\n<p style=\"text-align: left;\"><strong>\u56fe1. \u572880 \u00b0C\u6761\u4ef6\u4e0b\uff0c\u7528Ti(Oi-Pr)4 \u548c isopropanol (i-PrOH)\u505a\u50ac\u5316\u5242\uff0c Et-PMMA-Cl\u7684\u672b\u7aef\u9009\u62e9\u6027\u916f\u4ea4\u6362\u53cd\u5e94\u3002 Et-PMMA-Cl(a, c)\u7684\u6838\u78c1\u5171\u632f\u6c22\u8c31 (a, b, in CD2Cl2) \u548c\u57fa\u8d28\u8f85\u52a9\u6fc0\u5149\u89e3\u5438\u7535\u79bb\u98de\u884c\u65f6\u95f4\u8d28\u8c31(c, d) \u548c\u916f\u4ea4\u6362\u540e\u83b7\u5f97\u7684\u4ea7\u7269 (b, d)\u3002<\/strong><\/p>\n<p style=\"text-align: left;\">PMMA\u6709\u03b1-\u672b\u7aef\u4e59\u57fa\u5b98\u80fd\u56e2(a: 4.1\u22123.9 ppm)\u548c\u03c9-\u672b\u7aef\u6c2f(b\u2032: 3.7 ppm) [Mn(NMR, \u03b1) = 3800, Mn (NMR, \u03c9) = 4000]\u3002<\/p>\n<p style=\"text-align: center;\"><strong>\u88681. \u5404\u79cd\u9187\u7c7b\u7684\u672b\u7aef\u8f6c\u79fb\u53cd\u5e94<\/strong><\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-8065\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/t1-1.png\" alt=\"t1\" width=\"454\" height=\"602\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/t1-1.png 454w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/t1-1-226x300.png 226w\" sizes=\"(max-width: 454px) 100vw, 454px\" \/><\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-8066\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/3-9.png\" alt=\"3\" width=\"473\" height=\"608\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/3-9.png 473w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/3-9-233x300.png 233w\" sizes=\"(max-width: 473px) 100vw, 473px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe2. \u4eceEt-PMMA-Cl\u7684\u916f\u4ea4\u6362\u53cd\u5e94\u5f97\u5230\u7684\u7aef\u57fa\u6c2f\u53d6\u4ee3\u7684\u9065\u722a\u805a\u5408\u7269\u7684\u57fa\u8d28\u8f85\u52a9\u6fc0\u5149\u89e3\u5438\u7535\u79bb\u98de\u884c\u65f6\u95f4\u8d28\u8c31\u3002 (a) Et-PMMA-Cl (b) \u4e59\u9187; (c) \u5341\u4e8c\u70f7\u9187;(d) 4,4,5,5,5-\u4e94\u6c1f\u620a\u9187 ; (e) \u82ef\u7532\u9187; (f) \u8418\u7532\u9187 ; (g) \u70ef\u4e19\u9187\u3002<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-8067\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/4-8.png\" alt=\"4\" width=\"511\" height=\"481\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/4-8.png 511w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/4-8-300x282.png 300w\" sizes=\"(max-width: 511px) 100vw, 511px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe3. \u901a\u8fc7\u6d3b\u6027\u81ea\u7531\u57fa\u805a\u5408\u548c\u672b\u7aef\u9009\u62e9\u6027\u916f\u4ea4\u6362\u8fed\u4ee3\u8fc7\u7a0b\u5f97\u5230\u7684\u4e00\u79cd\u7cbe\u786e\u529f\u80fd\u5316\u7684\u9065\u722a\u805a\u5408\u7269 (olefin-PMMAEMA-PMMA-Allyl MA-Cl) \u3002<\/strong><\/p>\n<p>\u8fed\u4ee3\u7684\u65b9\u6cd5\u53ef\u7528\u4e8e\u8bbe\u8ba1\u591a\u79cd\u7cbe\u786e\u529f\u80fd\u5316\u7684\u548c\u5468\u671f\u6027\u5e8f\u5217\u63a7\u5236\u7684\u9ad8\u5206\u5b50\u3002\u8fd9\u79cd\u65b9\u6cd5\u7684\u4f18\u70b9\u662f\uff1a<br \/>\n\uff081\uff09\u7528\u591a\u5143\u9187\u7075\u6d3b\u65b9\u4fbf\u7684\u5b9e\u73b0\u529f\u80fd\u5316\u5355\u5143\u7684\u8bbe\u8ba1\u3002<br \/>\n\uff082\uff09\u901a\u8fc7\u6d3b\u6027\u81ea\u7531\u57fa\u805a\u5408\u5b9e\u73b0\u9ad8\u5206\u5b50\u94fe\u7684\u7cbe\u786e\u3001\u7075\u6d3b\u548c\u4f4d\u7f6e\u7279\u5b9a\u7684\u529f\u80fd\u5316\u3002<\/p>\n<p style=\"text-align: center;\"><strong>\u56fe\u88681. \u7cbe\u786e\u529f\u80fd\u5316\u7684\u5d4c\u6bb5\u5171\u805a\u7269<\/strong><br \/>\n<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-8076\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/5-8.png\" alt=\"5\" width=\"429\" height=\"269\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/5-8.png 429w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/5-8-300x188.png 300w\" sizes=\"(max-width: 429px) 100vw, 429px\" \/><\/p>\n<p style=\"text-align: center;\">\u8fd9\u4e9b\u5d4c\u6bb5\u5171\u805a\u7269\u5bf9\u4e8e\u5fae\u89c2\u76f8\u5206\u79bb\u7684\u6750\u6599\u548c\u6838\u58f3\u7ed3\u6784\u7684\u7eb3\u7c73\u80f6\u56ca\u7684\u9009\u62e9\u6027\u754c\u9762\u529f\u80fd\u5316\u975e\u5e38\u6709\u7528\u3002<\/p>\n<p><strong>\u603b\u7ed3\uff1a<\/strong><\/p>\n<p>\u672c\u6587\u521b\u5efa\u4e86\u4e00\u79cd\u5408\u6210\u7aef\u57fa\u6c2f\u4ee3\u9065\u722a\u548c\u7cbe\u786e\u529f\u80fd\u5316\u9ad8\u5206\u5b50\u7684\u6a21\u5757\u5316\u65b9\u6cd5\uff0c\u80fd\u591f\u975e\u5e38\u5bb9\u6613\u4e14\u9ad8\u6548\u5730\u5c06\u591a\u79cd\u529f\u80fd\u56e2\u5f15\u5165PMMAs\u6240\u9700\u7684\u4f4d\u7f6e\u3002<\/p>\n<p>\u8be5\u6210\u679c\u8fd1\u671f\u53d1\u8868\u5728JACS (IF=12.113) \u4e0a\uff0c\u8bba\u6587\u94fe\u63a5\uff1a<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.6b01239\" target=\"_blank\">Terminal-Selective Transesterification of Chlorine-Capped Poly(Methyl Methacrylate)s: A Modular Approach to Telechelic and Pinpoint-Functionalized Polymers<\/a>\uff08\u975e\u539f\u7f51\u9875\u8bfb\u8005\uff0c\u8bf7\u5230\u6750\u6599\u725b\u4e0b\u8f7d\uff09<\/p>\n<p>\u8be5\u6587\u732e\u89e3\u8bfb\u7531\u6750\u6599\u4eba\u79d1\u666e\u56e2\u961f\u5b66\u672f\u7ec4CrazySnail\u6295\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n<p>\u6b22\u8fce\u52a0\u5165\u6750\u6599\u4eba\u79d1\u666e\u56e2\u961f\uff0c\u4e00\u8d77\u8fdb\u884c\u6750\u6599\u9876\u520a\u5b66\u672f\u52a8\u6001\u7684\u8ddf\u8e2a\u548c\u62a5\u9053\u4ee5\u53caSCI\u76f8\u5173\u77e5\u8bc6\u79d1\u666e\u7b49\u3002\u52a0\u5165\u65b9\u5f0f\uff1a\uff081\uff09\u52a0\u5165\u6750\u6599\u4eba\u6587\u732e\u68c0\u7d22\u7fa4\uff08410109144\uff09\uff0c\u79c1\u4fe1\u7ba1\u7406\u5458\u201c\u6210\u90fd-\u5c0f\u5c0f\uff08QQ:763044722\uff09\u201d\u62a5\u540d\uff1b\uff082\uff09<a href=\"http:\/\/cailiaoren.mikecrm.com\/f.php?t=6qSdMU\" target=\"_blank\">\u70b9\u6b64\u5904\u62a5\u540d<\/a>\u3002<\/p>\n<p>\u6b22\u8fce\u5404\u5927\u8bfe\u9898\u7ec4\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c<a href=\"mailto:\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\" target=\"_blank\">\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u5408\u6210\u7684\u5927\u5206\u5b50\u7684\u7cbe\u786e\u529f\u80fd\u5316\u662f\u521b\u9020\u72ec\u7279\u4e14\u6709\u9009\u62e9\u6027\u529f\u80fd\u7684\u5173\u952e\u3002\u76ee\u524d\uff0c\u5728\u7cbe\u786e\u805a\u5408\u65b9\u9762\u5df2\u7ecf\u53ef\u4ee5\u5408\u6210\u591a\u79cd\u529f\u80fd\u7684\u9ad8\u5206\u5b50\u3002\u53ef\u9009\u62e9\u6027\u548c\u9ad8\u6548\u7684\u6709\u673a\u53cd\u5e94\u4e0e\u7cbe\u786e\u7684\u805a\u5408\u76f8\u7ed3\u5408\uff0c\u662f\u4e00\u79cd\u591a\u529f&#8230;<\/p>\n","protected":false},"author":92,"featured_media":8074,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[42],"class_list":["post-8058","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-gaofenzi"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/8058"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/92"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=8058"}],"version-history":[{"count":9,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/8058\/revisions"}],"predecessor-version":[{"id":8203,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/8058\/revisions\/8203"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/8074"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=8058"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=8058"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=8058"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}