{"id":80378,"date":"2017-05-14T06:30:15","date_gmt":"2017-05-13T22:30:15","guid":{"rendered":"\/\/m.iemloyee.com\/?p=80378"},"modified":"2017-05-13T19:59:33","modified_gmt":"2017-05-13T11:59:33","slug":"nature-energy%ef%bc%9a%cf%80%e5%85%b1%e8%bd%ad%e5%90%ab%e6%b0%ae%e6%9d%82%e7%8e%af%e5%88%86%e5%ad%90%e5%9f%ba%e6%9c%89%e6%9c%ba%e9%98%b4%e6%9e%81%e4%b8%ad%e7%9a%84%e5%8f%af%e9%80%86%e5%a4%9a%e7%94%b5","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=80378","title":{"rendered":"Nature Energy\uff1a\u03c0\u5171\u8f6d\u542b\u6c2e\u6742\u73af\u5206\u5b50\u57fa\u6709\u673a\u9634\u6781\u4e2d\u7684\u53ef\u9006\u591a\u7535\u5b50\u6c27\u5316\u8fd8\u539f\u5316\u5b66"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u968f\u7740\u7535\u52a8\u6c7d\u8f66\u548c\u667a\u80fd\u53ef\u518d\u751f\u80fd\u6e90\u7f51\u7edc\u4e2d\u7684\u5927\u89c4\u6a21\u7535\u6c60\u7cfb\u7edf\u7684\u9700\u6c42\u8d8a\u6765\u8d8a\u5927\uff0c\u8d8a\u6765\u8d8a\u591a\u7814\u7a76\u8005\u4f7f\u7528\u6709\u673a\u6750\u6599\u4f5c\u4e3a\u53ef\u5145\u7535\u7535\u6c60\u4e2d\u7684\u7535\u6781\u3002\u8fd9\u4e9b\u6709\u673a\u6750\u6599\u5305\u62ec\uff1a\u5bfc\u7535\u805a\u5408\u7269\u3001\u6709\u673a\u786b\u5316\u5408\u7269\u3001\u7a33\u5b9a\u7684\u81ea\u7531\u57fa\u5316\u5408\u7269\u3001\u6709\u673a\u78b3\u590d\u5408\u7269\u57fa\u8349\u9178\u76d0\u548c\u918c\/\u915a\u884d\u751f\u7269\u3002<\/p>\n

\u7136\u800c\uff0c\u8fd9\u4e9b\u6709\u673a\u6d3b\u6027\u590d\u5408\u7269\u5728\u8d28\u5b50\u60f0\u6027\u7535\u89e3\u6db2\u4e2d\u6eb6\u89e3\uff0c\u9020\u6210\u5faa\u73af\u8fc7\u7a0b\u4e2d\u5feb\u901f\u7684\u5bb9\u91cf\u8870\u51cf\u3002\u53e6\u4e00\u4e2a\u6311\u6218\u662f\uff0c\u7531\u4e8e\u6709\u673a\u5206\u5b50\u7684\u4f4e\u672c\u5f81\u7535\u5b50\u7535\u5bfc\u7387\uff0c\u6709\u673a\u57fa\u7535\u6781\u7684\u529f\u7387\u5bb9\u91cf\u8f83\u4f4e\u3002<\/p>\n

\u5728\u57fa\u7840\u5c42\u9762\uff0c\u7406\u89e3\u5728\u591a\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u7684\u52a8\u529b\u5b66\u548c\u6709\u5173\u7ed3\u6784\u53d8\u5316\uff0c\u4ee5\u53ca\u51b3\u5b9a\u5728\u7535\u6c60\u4f7f\u7528\u8fc7\u7a0b\u4e2d\u7684\u6700\u5927\u8f6c\u79fb\u7535\u5b50\u6570\uff0c\u8fd9\u5341\u5206\u91cd\u8981\u3002\u8fd9\u4e00\u5171\u8bc6\u63d0\u4f9b\u4e86\u4e00\u6761\u8bbe\u8ba1\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7535\u6781\u6750\u6599\u7684\u601d\u8def\u3002\u7136\u800c\uff0c\u7531\u4e8e\u5927\u90e8\u5206\u6709\u673a\u6750\u6599\u5177\u6709\u65e0\u5b9a\u578b\u7ed3\u6784\uff0c\u963b\u788d\u4e86\u7ed3\u6784\u8868\u5f81\u6280\u672f\u7684\u4f7f\u7528\uff0c\u5982XRD\u3001TEM\u7b49\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6765\u81ea\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66\u7684<\/strong>Kian Ping Loh<\/strong>\u6559\u6388<\/strong>\u548c\u53a6\u95e8\u5927\u5b66\u7684\u6768\u52c7\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u5728Nature\u5b50\u520aNature Energy<\/strong>\u4e0a\u53d1\u8868\u9898\u4e3a\u201dReversible multi-electron redox chemistry of <\/strong>\u03c0<\/strong>-conjugated N-containing heteroaromatic molecule-based organic cathodes<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u8be5\u6587\u7ae0\u53d7\u9ad8\u8fc1\u79fb\u7387\u6709\u673a\u534a\u5bfc\u4f53\u03c0\u5171\u8f6d\u4f53\u7cfb\u542f\u53d1\uff0c\u63d0\u51fa\u4e86\u4e00\u79cd\u5236\u5907\u6df7\u5408\u6c2e\u6742\u73af\u539f\u5b503Q\u5206\u5b50\u7684\u65b9\u6cd5\uff0c\u53ef\u4ee5\u7528\u4e8e\u53ef\u5145\u7535\u6709\u673a\u7535\u6c60\u9634\u6781\u3002\u57283Q\u4e2d\u7684\u591a\u7535\u5b50\u6d3b\u6027\u5421\u55ea\u5355\u5143\u63d0\u4f9b\u4e86\u9ad8\u5bb9\u91cf\uff0c\u5ef6\u5c55\u7684\u5171\u8f6d\u03c0\u4f53\u7cfb\u52a0\u5feb\u4e86\u7535\u5b50\u5728\u7535\u6781\u4e2d\u7684\u4f20\u8f93\u3002\u901a\u8fc7\u6df7\u5408\u77f3\u58a8\u70ef\u5f62\u6210\u5bfc\u7535\u590d\u5408\u7269\uff0c3Q\/\u77f3\u58a8\u70ef\u6df7\u5408\u7535\u6781\u5c55\u793a\u4e86\u9ad8\u5bb9\u91cf\u4ee5\u53ca\u957f\u671f\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\uff1a\u6c27\u5316\u8fd8\u539f\u6709\u673a\u5206\u5b50\u7684\u5408\u6210\u65b9\u6cd5\u3002<\/strong><\/p>\n

\"\"<\/strong>a)\u4e09\u79cd\u4f20\u7edf\u5408\u6210\u8def\u5f84\uff1a\u8fde\u63a5\u3001\u805a\u5408\u3001\u6210\u76d0\uff1b<\/p>\n

b)\u672c\u6587\u7b56\u7565\uff1b<\/p>\n

c)\u57fa\u4e8e\u51b7\u51dd\u53cd\u5e94\u5408\u6210\u55b9\u5594\u5549\u884d\u751f\u7269\uff1a2Q\u30013Q\u3002<\/p>\n

\u56fe\u4e8c\uff1a\u55b9\u5594\u5549\u53ca\u5176\u884d\u751f\u7269\u7684\u5316\u5b66\u7ed3\u6784\u4ee5\u53ca\u80fd\u91cf\u56fe\u3002<\/strong><\/p>\n

\"\"
\n a)\u55b9\u5594\u5549\u53ca\u5176\u884d\u751f\u7269\u5316\u5b66\u7ed3\u6784\uff1b<\/p>\n

b)\u4f7f\u7528DFT\u65b9\u6cd5\u8ba1\u7b97DME\u6eb6\u6db2\u4e2d\u5206\u5b50\u7684\u76f8\u5bf9\u80fd\u91cf\u4ee5\u53ca\u5206\u5b50\u6700\u4f18\u7ed3\u6784\uff1b<\/p>\n

c)500\u03bcm\u8303\u56f4\u7684\u6676\u4f53\u5149\u5b66\u56fe\u50cf\uff1b<\/p>\n

d\/e) 3Q\u5355\u6676\u7ed3\u6784\u7684\u7403\u68cd\u6a21\u578b\u3002<\/p>\n

\u56fe\u4e09\uff1a\u03c0\u5171\u8f6d\u6742\u8fd8\u539f\u5b50\u590d\u5408\u7269\u57fa\u7535\u6781\u7684\u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81\u3002<\/strong><\/p>\n

\"\"<\/p>\n

a\/c) 2Q\/3Q\u5728400mAg-1<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5bb9\u91cf-\u7535\u538b\u56fe\u3002<\/p>\n

b\/d) 2Q\/3Q\u57281.6Ag-1<\/sup>\u548c3.2Ag-1<\/sup>\u7535\u6d41\u5bc6\u5bc6\u5ea6\u4e0b\u7684\u5faa\u73af\u7279\u6027\u3002<\/p>\n

e\/f) 2Q\/3Q\u572810000\u6b21\u5faa\u73af\u4e0b\u7684\u500d\u7387\u7279\u6027\u3002<\/p>\n

g\/h) 2Q\/3Q\u57288Ag-1<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u957f\u671f\u7a33\u5b9a\u6027\u3002<\/p>\n

\u56fe\u56db\uff1a\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u7684\u7ed3\u6784\u53d8\u5316\u3002<\/strong><\/p>\n

\"\"
\n a) \u653e\u7535\u8fc7\u7a0b\u4e2d\u9884\u6d4b\u76843Q\u9502\u5316\u7ed3\u6784\u3002<\/p>\n

b) 0.05C\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7b2c\u4e8c\u4e2a\u5faa\u73af\u4e2d\u76843Q\/Li\u76f4\u6d41\u5145\u653e\u7535\u56fe\u3002<\/p>\n

c\/d) \u4e0d\u540c\u5145\u7535\u72b6\u6001\u4e0b\u7535\u6781\u6750\u6599\u975e\u539f\u4f4d15<\/sup>N\u548c13<\/sup>C\u7684\u56fa\u6001NMR\u56fe\u8c31\u3002<\/p>\n

e) 0.05C\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7b2c\u4e00\u6b21\u548c\u7b2c\u4e8c\u6b21\u5faa\u73af\u4e2d3Q\/Li\u7684\u76f4\u6d41\u5145\u653e\u7535\u8fc7\u7a0b\u3002<\/p>\n

f\/g) \u4e0d\u540c\u5145\u653e\u7535\u72b6\u6001\u4e0b\u7535\u6781\u6750\u6599\u975e\u539f\u4f4d15<\/sup>N\u548c13<\/sup>C\u56fa\u6001NMR\u56fe\u8c31\u3002<\/p>\n

\u56fe\u4e94\uff1a\u6a21\u62df\u7684\u9502\u5316\u8fc7\u7a0b\u3002<\/strong><\/p>\n

\"\"<\/p>\n

a)\u9502\u5316\/\u53bb\u9502\u5316\u8fc7\u7a0b\u4e2d\u9502\u590d\u5408\u7269(3Q-xLi)\u7684\u53d8\u5316\u4e0e\u53cd\u5e94\u7535\u52bf\u3001\u80fd\u91cf\u4e4b\u95f4\u7684\u5173\u7cfb\uff1b<\/p>\n

b)\u6a21\u62df\u9502\u5316\u8fc7\u7a0b\u4e2d\u7684\u7ed3\u6784\u53d8\u5316\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u03c0\u5171\u8f6d\u6742\u73af\u5206\u5b50\u53ef\u4ee5\u4f5c\u4e3a\u56fa\u6001\u6709\u673a\u9634\u6781\uff0c\u5e76\u5728\u53ef\u5145\u7535\u9502\u7535\u6c60\u4e2d\u5c55\u793a\u9ad8\u6bd4\u5bb9\u91cf\u4e0e\u4f18\u8d8a\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u6742\u73af\u5206\u5b50\u878d\u5408\u4e86\u53ef\u4ee5\u63d0\u4f9b\u591a\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u4f4d\u70b9\u55b9\u5594\u5549\u6784\u7b51\u5355\u5143\uff0c\u5e76\u63d0\u9ad8\u7535\u89e3\u6db2\u4e2d\u7684\u7a33\u5b9a\u6027\u3002\u6b64\u5916\uff0c\u7528\u77f3\u58a8\u70ef\u6df7\u5408\u8be5\u79cd\u5206\u5b50\uff0c\u4f7f\u7528\u4e59\u919a\u57fa\u7535\u89e3\u6db2\u5f62\u6210\u6709\u6548\u5730SEI\u819c\uff0c\u4f7f\u5f97\u6709\u673a\u7535\u6781\u5c55\u73b0\u51fa\u9ad8\u5bb9\u91cf\u4e0e\u957f\u5faa\u73af\u5bff\u547d\u3002\u975e\u539f\u4f4dNMR\u7814\u7a76\u4e86\u5728\u55b9\u5594\u5549\u6784\u7b51\u5355\u5143\u4e2d\uff0c\u76f8\u51733Q\u7684\u9ad8\u5bb9\u91cf\u4ee5\u53ca\u5728\u55b9\u5594\u5549\u4e2d\u5421\u55ea\u6c2e\u539f\u5b50\u9502\u5316\u7684\u591a\u6d3b\u6027\u4f4d\u70b9\u3002\u516d\u4e2a\u9502\u5316\/\u53bb\u9502\u5316\u4e2d\u95f4\u6001\u4e0e3Q\u4e2d\u7684\u516d\u5421\u55ea\u6c2e\u539f\u5b50\u76f8\u7b26\u5408\uff0c\u5728\u6613\u4e8e\u53d1\u751f\u7684\u7535\u5b50\u8f6c\u6362\u53cd\u5e94\u4e2d\uff0c\u8be5\u4e2d\u95f4\u6001\u53d1\u751f\u53d8\u5316\u5e76\u8d21\u732e3Q\u4ee5\u9ad8\u5bb9\u91cf\u3002\u8be5\u591a\u5c42\u9762\u7684\u65b9\u6cd5\u5f00\u62d3\u4e86\u4e00\u79cd\u5c06\u5c0f\u578b\u6709\u673a\u5206\u5b50\u57fa\u9634\u6781\u6750\u6599\u7528\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\u7684\u65b9\u6cd5\uff0c\u5177\u6709\u4f18\u8d8a\u80fd\u91cf\u5bc6\u5ea6\u4ee5\u53ca\u957f\u5faa\u73af\u5bff\u547d\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Reversible multi-electron redox chemistry of \u03c0-conjugated N-containing heteroaromatic olecule-based organic cathodes<\/a>(Nature energy: 1 10.1038\/nenergy.2017.74)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u7ec4Jespen\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u70b9\u8fd9\u91cc\u52a0\u5165\u6750\u6599\u4eba\u7684\u5927\u5bb6\u5ead<\/a>\u3002\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065952\u201d\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c<\/strong>\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u968f\u7740\u7535\u52a8\u6c7d\u8f66\u548c\u667a\u80fd\u53ef\u518d\u751f\u80fd\u6e90\u7f51\u7edc\u4e2d\u7684\u5927\u89c4\u6a21\u7535\u6c60\u7cfb\u7edf\u7684\u9700\u6c42\u8d8a\u6765\u8d8a\u5927\uff0c\u8d8a\u6765\u8d8a\u591a\u7814\u7a76\u8005\u4f7f\u7528\u6709\u673a\u6750\u6599\u4f5c\u4e3a\u53ef\u5145\u7535\u7535\u6c60\u4e2d\u7684\u7535\u6781\u3002\u8fd9\u4e9b\u6709\u673a\u6750\u6599\u5305\u62ec\uff1a\u5bfc\u7535\u805a\u5408\u7269\u3001\u6709\u673a…<\/p>\n","protected":false},"author":1182,"featured_media":80391,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-80378","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/80378"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/1182"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=80378"}],"version-history":[{"count":6,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/80378\/revisions"}],"predecessor-version":[{"id":80873,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/80378\/revisions\/80873"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/80391"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=80378"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=80378"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=80378"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}