{"id":79431,"date":"2017-05-10T06:30:35","date_gmt":"2017-05-09T22:30:35","guid":{"rendered":"\/\/m.iemloyee.com\/?p=79431"},"modified":"2017-05-06T19:19:17","modified_gmt":"2017-05-06T11:19:17","slug":"%e4%b8%ad%e5%b1%b1%e5%a4%a7%e5%ad%a6macromolecules-%e6%97%a0%e9%87%91%e5%b1%9e%e5%82%ac%e5%8c%96%e7%9b%b4%e6%8e%a5%e6%b0%a8%e5%9f%ba%e5%8c%96%e8%81%9a%e4%b9%99%e7%83%af","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=79431","title":{"rendered":"\u4e2d\u5c71\u5927\u5b66Macromolecules: \u65e0\u91d1\u5c5e\u50ac\u5316\u76f4\u63a5\u6c28\u57fa\u5316\u805a\u4e59\u70ef"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u805a\u70ef\u70c3\u7c7b\u7684\u805a\u5408\u7269\u662f\u4e00\u79cd\u91cd\u8981\u4e14\u5e94\u7528\u5e7f\u6cdb\u7684\u9ad8\u5206\u5b50\u6750\u6599\uff0c\u4f46\u662f\u7531\u4e8e\u5176\u672c\u8eab\u5177\u6709\u4e00\u5b9a\u7684\u758f\u6c34\u6027\uff0c\u4f7f\u5f97\u5f88\u96be\u4e0e\u5176\u4ed6\u805a\u5408\u7269\u5171\u6df7\u800c\u63d0\u5347\u9644\u52a0\u6027\u80fd\u3002\u52a0\u4e0a\u81ea\u8eab\u5e76\u65e0\u4e30\u5bcc\u7684\u5316\u5b66\u57fa\u56e2\u8fdb\u884c\u8fdb\u4e00\u6b65\u7684\u5316\u5b66\u4fee\u9970\uff0c\u4f7f\u5f97\u805a\u70ef\u70c3\u7c7b\u7684\u805a\u5408\u7269\u7684\u5e94\u7528\u53d7\u9650\u3002\u5f53\u524d\u805a\u70ef\u70c3\u7684\u5de5\u4e1a\u5316\u4fee\u9970\u662f\u9a6c\u6765\u9178\u9150\u901a\u8fc7\u81ea\u7531\u57fa\u63a5\u679d\u5728\u805a\u70ef\u70c3\u7684\u4e3b\u94fe\u4e0a\uff0c\u4f46\u662f\uff0c\u8fd9\u79cd\u65b9\u6cd5\u9700\u8981\u5927\u91cf\u7684\u8fc7\u6c27\u5316\u7269\u548c\u9a6c\u6765\u9178\u9150\u4e14\u9700\u5728\u9ad8\u6e29\u4e0b\u53cd\u5e94\u3002\u5982\u4f55\u5bf9C-H\u8fdb\u884c\u6d3b\u5316\u4e00\u76f4\u662f\u5316\u5b66\u9886\u57df\u5c24\u5176\u662f\u6709\u673a\u5316\u5b66\u9886\u57df\u5185\u4e00\u4e2a\u6025\u9700\u7a81\u7834\u7684\u91cd\u70b9\u3002\u6709\u673a\u5316\u5b66\u4e2d\u7684\u7814\u7a76\u8fdb\u5c55\u5c06\u4f1a\u6781\u5927\u7684\u63a8\u52a8\u805a\u4e59\u70ef\u7c7b\u6750\u6599\u529f\u80fd\u5316\u7684\u6b65\u4f10\u3002\u8fd1\u4e9b\u5e74\u7684\u7814\u7a76\u53d1\u73b0\uff0cN-\u7f9f\u57fa\u90bb\u82ef\u4e8c\u7532\u9170\u4e9a\u80fa(NHPI)\u80fd\u591f\u4f5c\u4e3a\u50ac\u5316\u5242\u4f7f\u5f97C-H\u65ad\u88c2\uff0c\u800c\u4e14\u53cd\u5e94\u6761\u4ef6\u6e29\u548c\u3002\u5982\u679c\u5c06\u5176\u5e94\u7528\u5728\u9ad8\u5206\u5b50\u9886\u57df\u4e2d\uff0c\u5c24\u5176\u662f\u805a\u70ef\u70c3\u7c7b\u7684\u8fdb\u4e00\u6b65\u6539\u6027\u4e2d\uff0c\u5c06\u4f1a\u6269\u5927\u805a\u70ef\u70c3\u7c7b\u6750\u6599\u7684\u5e94\u7528\u9886\u57df\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6765\u81ea\u4e2d\u5c71\u5927\u5b66\u7684\u9648\u6c38\u660e\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u8bfe\u9898\u7ec4\u5728Macromolecules<\/strong>\u6742\u5fd7\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u9898\u4e3a\u201cDirect Amination of Polyethylene by Metal-Free Reaction<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u7814\u7a76\u4eba\u5458\u9996\u6b21\u62a5\u9053\u91c7\u7528\u6709\u673a\u50ac\u5316\u5242\u6210\u529f\u5bf9\u805a\u4e59\u70ef\u6750\u6599\u8fdb\u884c\u6c28\u57fa\u5316\u3002\u4ed6\u4eec\u4f7f\u7528N-\u7f9f\u57fa\u90bb\u82ef\u4e8c\u7532\u9170\u4e9a\u80fa(NHPI)\u6709\u673a\u50ac\u5316\u5242\u6253\u7834C-H\u952e\uff0c\u4f7f\u5176\u751f\u6210\u78b3\u81ea\u7531\u57fa\uff0c\u7136\u540e\u548c-N=N-\u53cd\u5e94\u751f\u6210\u80bc\u3002\u53cd\u5e94\u6761\u4ef6\u6e29\u548c\u53ef\u63a7\uff0c\u4e0d\u4ec5\u5982\u6b64\uff0c\u6c28\u57fa\u5316\u7684\u805a\u4e59\u70ef\u53ef\u4ee5\u548c\u805a\u7532\u57fa\u4e19\u70ef\u9178\u7532\u916f\u5f88\u597d\u7684\u5171\u6df7\u3002\u8be5\u65b9\u6cd5\u6709\u52a9\u4e8e\u8fdb\u4e00\u6b65\u63a8\u52a8\u5bf9\u805a\u70ef\u70c3\u7c7b\u6750\u6599\u7684\u6539\u6027\u7814\u7a76\u5e76\u62d3\u5bbd\u5176\u5e94\u7528\u8303\u56f4\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1 \u6d3b\u5316C(sp3)\u2212H\u7684NHPI\/BTCEAD\u548cNHPI\/DBAD\u529f\u80fd\u5316\u805a\u4e59\u70ef\u7684\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe2 \u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916\u8c31\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

(A) \u805a\u4e59\u70ef (PE)\u3002<\/p>\n

(B) \u805a\u4e59\u70ef\u63a5\u679d\u4e8c(2,2,2-\u4e09\u6c2f\u4e59\u57fa)\u5076\u6c2e\u4e8c\u7fa7\u9178 (PE-g-BTCEAD)\u3002<\/p>\n

(C) \u805a\u4e59\u70ef\u63a5\u679d\u5076\u6c2e\u4e8c\u7532\u9178\u4e8c\u53d4\u4e01\u916f (PE-g-DBAD)\u3002<\/p>\n

\u56fe3 1H NMR\u8c31\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

(A) \u4ee3\u8868PE-g-BTCEAD\u7684\u8c31\u56fe\u3002<\/p>\n

(B) \u4ee3\u8868PE-g-DBAD\u7684\u8c31\u56fe\u3002<\/p>\n

\u56fe4 \u4f53\u79ef\u6392\u963b\u8272\u8c31\u56fe\u53ca\u805a\u5408\u7269\u7684\u8868\u5f81\u53c2\u6570<\/strong><\/p>\n

\"\"<\/p>\n

(A) PE-g-BTCEAD\u7684\u6570\u5747\u76f8\u5bf9\u5206\u5b50\u8d28\u91cf\u4e3a19.6kg\/mol\uff0c\u591a\u5206\u6563\u7cfb\u6570\u4e3a1.55\u3002<\/p>\n

(B) PE-g-DBAD\u7684\u6570\u5747\u76f8\u5bf9\u5206\u5b50\u8d28\u91cf\u4e3a10.1kg\/mol\uff0c\u591a\u5206\u6563\u7cfb\u6570\u4e3a1.71\u3002<\/p>\n

(C) PE\u7684\u6570\u5747\u76f8\u5bf9\u5206\u5b50\u8d28\u91cf\u4e3a7.90kg\/mol\uff0c\u591a\u5206\u6563\u7cfb\u6570\u4e3a1.83\u3002<\/p>\n

\u56fe5 \u70ed\u91cd\u5206\u6790\u66f2\u7ebf<\/strong><\/p>\n

\"\"<\/p>\n

(A) \u4ee3\u8868PE-g-BTCEAD\u3002<\/p>\n

(B) \u4ee3\u8868PE-g-DBAD\u3002<\/p>\n

\u56fe6 \u805a\u7532\u57fa\u4e19\u70ef\u9178\u7532\u916f(PMMA)\u8680\u523b\u5171\u6df7\u7269\u65ad\u88c2\u8868\u9762\u7684SEM\u56fe\u7247<\/strong><\/p>\n

\"\"<\/p>\n

(A) \u4ee3\u8868PE\/PMMA\u3002<\/p>\n

(B) \u4ee3\u8868PE-g-BTCEAD\/PMMA\u3002<\/p>\n

(C) \u4ee3\u8868PE-g-BTCEAD\/PMMA\u3002<\/p>\n

(D) \u4ee3\u8868PE-g-DBAD\/PMMA\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u4eba\u5458\u4f7f\u7528\u975e\u91d1\u5c5e\u7684NHPI\u6d3b\u5316\u805a\u4e59\u70ef\u4e3b\u94fe\u4e0a\u7684C-H\u751f\u6210C-N\uff0cC-N\u7684\u5f15\u5165\u53ef\u4ee5\u4e30\u5bcc\u5bf9\u805a\u4e59\u70ef\u8fdb\u884c\u529f\u80fd\u5316\u7684\u6539\u6027\u3002\u6c28\u57fa\u5316\u7684\u805a\u4e59\u70ef\u53ef\u4ee5\u548c\u805a\u7532\u57fa\u4e19\u70ef\u9178\u7532\u916f\u8fdb\u884c\u5171\u6df7\u3002\u8fd9\u662f\u4e3a\u6570\u4e0d\u591a\u7684\u76f4\u63a5\u5bf9\u805a\u4e59\u70ef\u4e3b\u94fe\u8fdb\u884c\u6c28\u57fa\u5316\u7684\u5b9e\u4f8b\uff0c\u5176\u63a5\u679d\u5355\u5143\u53ef\u4ece10\u4e2a\u5230100\u4e2a\u3002\u5e76\u4e14\u8fd9\u79cd\u65b9\u6cd5\u8fd8\u53ef\u4ee5\u5728\u56fa\u4f53\u805a\u4e59\u70ef\u819c\u4e0a\u8fdb\u884c\u3002\u8fd9\u79cd\u65b9\u6cd5\u6761\u4ef6\u6e29\u548c\u5e76\u4e14\u6ca1\u6709\u4f7f\u7528\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u663e\u73b0\u51fa\u6781\u4e3a\u8bf1\u4eba\u7684\u5e94\u7528\u524d\u666f\u3002\u8be5\u7814\u7a76\u4e3a\u8fdb\u4e00\u6b65\u53d1\u5c55\u805a\u70ef\u70c3\u7c7b\u9ad8\u5206\u5b50\u6750\u6599\u63d0\u4f9b\u4e86\u6781\u5177\u542f\u53d1\u6027\u7684\u601d\u8def\u3002<\/p>\n

\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb\uff1a\u9648\u6c38\u660e<\/strong>\uff0c\u4e2d\u5c71\u5927\u5b66\u6559\u6388\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\u3002\u4e2d\u79d1\u9662\u201c\u767e\u4eba\u8ba1\u5212\u201d\u83b7\u5f97\u8005\uff082000\u5e74\uff0c\u7ec8\u671f\u8003\u6838\u4f18\u79c0\uff09\u3002\u56fd\u5bb6\u6770\u51fa\u9752\u5e74\u79d1\u5b66\u57fa\u91d1\u83b7\u5f97\u8005\uff082006\u5e74\uff09\u3002\u4e2d\u56fd\u5316\u5b66\u4f1a\u9ad8\u5206\u5b50\u57fa\u7840\u7814\u7a76\u738b\u8446\u4ec1\u5956\u83b7\u5f97\u8005\uff082011\u5e74\uff09\u3002\u4e2d\u56fd\u5316\u5b66\u4f1a\u9ad8\u5206\u5b50\u5b66\u79d1\u59d4\u5458\u4f1a\u6210\u5458\uff0cPolymer\u671f\u520a\uff08Elsevier\u51fa\u7248\u7269\uff09\u526f\u4e3b\u7f16\uff0cMacromolecules\u671f\u520a\uff08ACS\u51fa\u7248\u7269\uff09\u987e\u95ee\u59d4\u5458\u4f1a\u3002\u7814\u7a76\u5174\u8da3\u96c6\u4e2d\u5728\u9ad8\u5206\u5b50\u5408\u6210\u5316\u5b66\uff0c\u94fe\u7ed3\u6784\u7cbe\u5bc6\u63a7\u5236\u65b9\u6cd5\uff0c\u805a\u5408\u7269\u7684\u81ea\u7ec4\u88c5\u53ca\u7eb3\u7c73\u6750\u6599\u548c\u65b0\u578b\u529f\u80fd\u9ad8\u5206\u5b50\u6750\u6599\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5: Direct Amination of Polyethylene by Metal-Free Reaction<\/a><\/strong>\u00a0(Macromolecules ,2017, DOI: 10.1021\/acs.macromol.6b02572)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u9ad8\u5206\u5b50\u5b66\u672f\u7ec4\u4ee3\u5a01\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002\u53c2\u4e0e\u9ad8\u5206\u5b50\u8bdd\u9898\u8ba8\u8bba\u6216\u4e86\u89e3\u9ad8\u5206\u5b50\u7ec4\u62db\u52df\u8be6\u60c5\uff0c\u8bf7\u52a0\u9ad8\u5206\u5b50\u4ea4\u6d41\u7fa4\uff08298064863\uff09\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n

\"\"<\/p>\n

\u505a\u4e00\u4e2a\u7231\u5206\u4eab\u7684\u79d1\u7814\u4eba\uff0c\u8bf7\u5173\u6ce8\u5927\u5206\u5b50<\/span>\u516c\u4f17\u53f7\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u805a\u70ef\u70c3\u7c7b\u7684\u805a\u5408\u7269\u662f\u4e00\u79cd\u91cd\u8981\u4e14\u5e94\u7528\u5e7f\u6cdb\u7684\u9ad8\u5206\u5b50\u6750\u6599\uff0c\u4f46\u662f\u7531\u4e8e\u5176\u672c\u8eab\u5177\u6709\u4e00\u5b9a\u7684\u758f\u6c34\u6027\uff0c\u4f7f\u5f97\u5f88\u96be\u4e0e\u5176\u4ed6\u805a\u5408\u7269\u5171\u6df7\u800c\u63d0\u5347\u9644\u52a0\u6027\u80fd\u3002\u52a0\u4e0a\u81ea\u8eab\u5e76\u65e0\u4e30\u5bcc\u7684\u5316\u5b66\u57fa\u56e2\u8fdb…<\/p>\n","protected":false},"author":24,"featured_media":79432,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[42],"class_list":["post-79431","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-gaofenzi"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/79431"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/24"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=79431"}],"version-history":[{"count":6,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/79431\/revisions"}],"predecessor-version":[{"id":79620,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/79431\/revisions\/79620"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/79432"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=79431"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=79431"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=79431"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}