{"id":79399,"date":"2017-05-08T06:30:50","date_gmt":"2017-05-07T22:30:50","guid":{"rendered":"\/\/m.iemloyee.com\/?p=79399"},"modified":"2017-05-05T23:37:34","modified_gmt":"2017-05-05T15:37:34","slug":"%e5%a4%a7%e8%bf%9e%e5%8c%96%e7%89%a9%e6%89%80%e4%ba%8c%e6%b0%a7%e5%8c%96%e7%a2%b3%e5%82%ac%e5%8c%96%e8%bd%ac%e5%8c%96%e7%a0%94%e7%a9%b6%e8%8e%b7%e8%bf%9b%e5%b1%95","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=79399","title":{"rendered":"\u5927\u8fde\u5316\u7269\u6240\u4e8c\u6c27\u5316\u78b3\u50ac\u5316\u8f6c\u5316\u7814\u7a76\u83b7\u8fdb\u5c55"},"content":{"rendered":"

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u78b3\u8d44\u6e90\u5c0f\u5206\u5b50\u4e0e\u6c22\u80fd\u5229\u7528\u521b\u65b0\u7279\u533a\u7814\u7a76\u7ec4\u7814\u7a76\u5458\u5b59\u5251\u3001\u845b\u5e86\u6770\u56e2\u961f\u901a\u8fc7\u8bbe\u8ba1\u4e00\u79cd\u65b0\u578bNa-Fe3<\/sub>O4<\/sub>\/HZSM-5\u591a\u529f\u80fd\u590d\u5408\u50ac\u5316\u5242\uff0c\u6210\u529f\u5b9e\u73b0\u4e86CO2<\/sub>\u76f4\u63a5\u52a0\u6c22\u5236\u53d6\u9ad8\u8f9b\u70f7\u503c\u6c7d\u6cb9\u3002\u76f8\u5173\u7814\u7a76\u6210\u4ee5\u201cDirectly converting CO2<\/sub> into a gasoline fuel\u201d\u4e3a\u9898\u53d1\u8868\u5728\u300a\u81ea\u7136-\u901a\u8baf\u300b\uff08Nature Communications<\/em>\uff0cDOI\uff1a10.1038\/ncomms15174\uff09\u4e0a\uff0c\u5e76\u88ab\u5ba1\u7a3f\u4eba\u8bc4\u4ef7\u4e3a\u201cCO2<\/sub>\u50ac\u5316\u8f6c\u5316\u9886\u57df\u7684\u7a81\u7834\u6027\u8fdb\u5c55\u201d\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1\u00a0<\/strong> Na-Fe3<\/sub>O4<\/sub><\/strong>\u50ac\u5316\u5242\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff0cc\uff09\u5206\u522b\u662f\u672a\u53cd\u5e94\u7684\u548c\u8001\u5316\u7684Na-Fe3<\/sub>O4<\/sub>\u50ac\u5316\u5242\u7684TEM\u56fe\u50cf\uff0c\u6807\u5c3a\u4e3a100nm\u3002<\/p>\n

\uff08b\uff0cd\uff09\u5206\u522b\u662f\u672a\u53cd\u5e94\u7684\u548c\u8001\u5316\u7684Na-Fe3<\/sub>O4<\/sub>\u50ac\u5316\u5242\u7684HRTEM\u56fe\u50cf\uff0c\u6807\u5c3a\u4e3a10nm\u3002<\/p>\n

\uff08e\uff09\u672a\u53cd\u5e94\u7684\u548c\u8001\u5316\u7684Na-Fe3<\/sub>O4<\/sub>\u50ac\u5316\u5242\u7684XRD\u56fe\u8c31\u3002<\/p>\n

\uff08f\uff09\u8001\u5316\u7684Na-Fe3<\/sub>O4<\/sub>\u50ac\u5316\u5242\u7684M\u00f6ssbauer\u8c31\u3002<\/p>\n

\u56fe<\/strong>2 CO2<\/sub><\/strong>\u52a0\u6c22\u5236\u6c7d\u6cb9\u7684\u53cd\u5e94\u6d41\u7a0b<\/strong><\/p>\n

\"\"<\/p>\n

Na-Fe3<\/sub>O4<\/sub>\/HZSM-5\u591a\u529f\u80fd\u590d\u5408\u50ac\u5316\u5242\u50ac\u5316CO2<\/sub>\u6c22\u5316\u7684\u4e09\u4e2a\u6b65\u9aa4\uff1a\uff081\uff09\u9996\u5148\u901a\u8fc7RWGS\u5f97\u5230CO\uff0c\uff082\uff09\u968f\u540e\u901a\u8fc7FTS\u5c06CO\u6c22\u5316\u4e3a\u03b1\u70ef\u70c3\u4e2d\u95f4\u4f53\uff0c\uff083\uff09\u901a\u8fc7\u9178\u50ac\u5316\u9f50\u805a\u3001\u5f02\u6784\u5316\u548c\u82b3\u6784\u5316\u53cd\u5e94\u5f62\u6210\u6c7d\u6cb9\u70c3\u3002<\/p>\n

\u3010\u7814\u7a76\u5185\u5bb9\u3011<\/strong><\/p>\n

\u5316\u77f3\u80fd\u6e90\u7684\u5927\u91cf\u6d88\u8017\u4f7f\u6e29\u5ba4\u6c14\u4f53\u5982CO2<\/sub>\u6392\u653e\u91cf\u6025\u5267\u589e\u52a0\uff0c\u5f15\u8d77\u4e86\u5168\u7403\u6c14\u5019\u53d8\u6696\u7b49\u65e5\u76ca\u4e25\u5cfb\u7684\u73af\u5883\u95ee\u9898\u3002\u6c7d\u6cb9\u662f\u5168\u7403\u7528\u91cf\u6700\u5927\u7684\u71c3\u6599\u4e4b\u4e00\uff0c\u5982\u679c\u4ee5CO2<\/sub>\u4f5c\u4e3a\u539f\u6599\u751f\u4ea7\u6c7d\u6cb9\uff0c\u5c06\u662f\u4e00\u79cd\u6f5c\u5728\u66ff\u4ee3\u5316\u77f3\u71c3\u6599\u7684\u6e05\u6d01\u80fd\u6e90\u7b56\u7565\uff0c\u4e0d\u4ec5\u53ef\u6709\u6548\u964d\u4f4eCO2<\/sub>\u9020\u6210\u7684\u6e29\u5ba4\u6548\u5e94\uff0c\u8fd8\u53ef\u51cf\u8f7b\u5bf9\u4f20\u7edf\u5316\u77f3\u80fd\u6e90\u7684\u4f9d\u8d56\u3002\u4f46\u662fCO2<\/sub>\u7684\u6d3b\u5316\u4e0e\u9009\u62e9\u6027\u8f6c\u5316\u4ecd\u9762\u4e34\u5de8\u5927\u6311\u6218\u3002<\/p>\n

\u8be5\u7814\u7a76\u56e2\u961f\u957f\u671f\u81f4\u529b\u4e8e\u78b3\u8d44\u6e90\u5c0f\u5206\u5b50\u4e2d\u5408\u6210\u6c14\u53caCO2<\/sub>\u7684\u50ac\u5316\u8f6c\u5316\u7814\u7a76\uff08Fuel<\/em>, 2011,90, 2051-2054; Fuel<\/em>, 2014, 134, 11-16; Catal. Sci. Technol.<\/em>, 2016, 6, 4786-4793\uff09\uff0c\u5728\u591a\u529f\u80fd\u50ac\u5316\u5242\u8bbe\u8ba1\u65b9\u9762\u79ef\u7d2f\u4e86\u8f83\u4e3a\u4e30\u5bcc\u7684\u7ecf\u9a8c\u3002\u8be5\u5de5\u4f5c\u4e2d\uff0c\u7814\u7a76\u56e2\u961f\u8bbe\u8ba1\u4e86\u4e00\u79cd\u9ad8\u6548\u7a33\u5b9a\u7684Na-Fe3<\/sub>O4<\/sub>\/HZSM-5\u591a\u529f\u80fd\u590d\u5408\u50ac\u5316\u5242\uff0c\u5728\u63a5\u8fd1\u5de5\u4e1a\u751f\u4ea7\u7684\u6761\u4ef6\u4e0b\uff0c\u8be5\u50ac\u5316\u5242\u5b9e\u73b0\u4e86CH4<\/sub>\u548cCO\u7684\u4f4e\u9009\u62e9\u6027\uff0c\u70c3\u7c7b\u4ea7\u7269\u4e2d\u6c7d\u6cb9\u998f\u5206\u70c3\uff08C5<\/sub>-C11<\/sub>\uff09\u7684\u9009\u62e9\u6027\u8fbe\u523078%\u3002\u6c7d\u6cb9\u998f\u5206\u4e3b\u8981\u4e3a\u9ad8\u8f9b\u70f7\u503c\u7684\u5f02\u6784\u70f7\u70c3\u548c\u82b3\u70c3\uff0c\u57fa\u672c\u6ee1\u8db3\u56fdV\u6807\u51c6\u5bf9\u82ef\u3001\u82b3\u70c3\u548c\u70ef\u70c3\u7684\u7ec4\u6210\u8981\u6c42\u3002\u8be5\u50ac\u5316\u5242\u8fd8\u5177\u6709\u8f83\u597d\u7684\u7a33\u5b9a\u6027\uff0c\u53ef\u8fde\u7eed\u7a33\u5b9a\u8fd0\u8f6c1000\u5c0f\u65f6\u4ee5\u4e0a\u3002\u5bf9CO2<\/sub>\u76f4\u63a5\u8f6c\u5316\u5236\u53d6\u6c7d\u6cb9\u7684\u53cd\u5e94\u9014\u5f84\u7814\u7a76\u8868\u660e\uff0c\u5bf9\u591a\u6d3b\u6027\u4f4d\u7ed3\u6784\u53ca\u5176\u4eb2\u5bc6\u6027\u6548\u5e94\uff08proximity effect\uff09\u7684\u7cbe\u51c6\u8c03\u63a7\u662f\u5b9e\u73b0CO2<\/sub>\u52a0\u6c22\u5236\u6c7d\u6cb9\u7684\u5173\u952e\u3002\u8be5\u6280\u672f\u4e0d\u4ec5\u4e3aCO2<\/sub>\u52a0\u6c22\u5236\u6db2\u4f53\u71c3\u6599\u7684\u7814\u7a76\u62d3\u5c55\u4e86\u65b0\u601d\u8def\uff0c\u8fd8\u4e3a\u95f4\u6b47\u6027\u53ef\u518d\u751f\u80fd\u6e90\uff08\u98ce\u80fd\u3001\u592a\u9633\u80fd\u3001\u6c34\u80fd\u7b49\uff09\u7684\u5229\u7528\u63d0\u4f9b\u4e86\u65b0\u9014\u5f84\u3002<\/p>\n

\u4e0a\u8ff0\u7814\u7a76\u5de5\u4f5c\u5f97\u5230\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u548c\u201c\u767e\u4eba\u8ba1\u5212\u201d\u7b49\u9879\u76ee\u7684\u8d44\u52a9\u3002<\/p>\n

\u539f\u6587\u94fe\u63a5\uff1ahttp:\/\/www.cas.cn\/syky\/201705\/t20170504_4599156.shtml<\/a>.<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDirectly converting CO2<\/sub> into a gasoline fuel<\/a>.<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5218\u4e07\u6625\u7f16\u8f91\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u6210\u679c\u7b80\u4ecb\u3011 \u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u78b3\u8d44\u6e90\u5c0f\u5206\u5b50\u4e0e\u6c22\u80fd\u5229\u7528\u521b\u65b0\u7279\u533a\u7814\u7a76\u7ec4\u7814\u7a76\u5458\u5b59\u5251\u3001\u845b\u5e86\u6770\u56e2\u961f\u901a\u8fc7\u8bbe\u8ba1\u4e00\u79cd\u65b0\u578bNa-Fe3O4\/HZSM-5\u591a\u529f\u80fd\u590d…<\/p>\n","protected":false},"author":603,"featured_media":79401,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[116],"class_list":["post-79399","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-keji","tag-catalyst"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/79399"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/603"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=79399"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/79399\/revisions"}],"predecessor-version":[{"id":79500,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/79399\/revisions\/79500"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/79401"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=79399"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=79399"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=79399"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}