{"id":79318,"date":"2017-05-06T06:30:45","date_gmt":"2017-05-05T22:30:45","guid":{"rendered":"\/\/m.iemloyee.com\/?p=79318"},"modified":"2017-05-07T12:52:52","modified_gmt":"2017-05-07T04:52:52","slug":"jacs-%e5%8a%a8%e6%80%81%e9%9a%94%e5%b1%82%e9%85%8d%e4%bd%93%e6%8f%92%e5%85%a5%e6%b3%95-%e6%9e%84%e5%bb%ba%e5%a4%9a%e4%bb%bb%e5%8a%a1%e6%88%96%e5%8f%af%e5%8f%98%e4%bb%bb%e5%8a%a1mof","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=79318","title":{"rendered":"JACS: \u52a8\u6001\u9694\u5c42\u914d\u4f53\u63d2\u5165\u6cd5: \u6784\u5efa\u591a\u4efb\u52a1\u6216\u53ef\u53d8\u4efb\u52a1MOF"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\uff08MOF\uff09\u662f\u4e00\u7c7b\u5728\u6c14\u4f53\u5438\u9644\u3001\u5316\u5b66\u5206\u79bb\u3001\u5206\u5b50\u63a2\u6d4b\u3001\u5f02\u76f8\u50ac\u5316\u548c\u836f\u7269\u8f93\u9001\u7b49\u9886\u57df\u5177\u6709\u5e7f\u6cdb\u5e94\u7528\u524d\u666f\u7684\u65b0\u578b\u591a\u5b54\u6750\u6599\u3002\u7531\u4e8eMOF\u9ad8\u6602\u7684\u5408\u6210\u548c\u4f7f\u7528\u6210\u672c\uff0c\u4e25\u91cd\u9650\u5236\u4e86MOF\u5728\u5de5\u4e1a\u5316\u65b9\u9762\u7684\u5e94\u7528\u3002\u56e0\u6b64\u5982\u4f55\u53d1\u5c55\u65b0\u7684\u5408\u6210\u548c\u4f7f\u7528\u7b56\u7565\uff0c\u964d\u4f4eMOF\u7684\u5e94\u7528\u6210\u672c\uff0c\u662f\u76ee\u524d\u4e9f\u5f85\u89e3\u51b3\u7684\u95ee\u9898\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

2016\u5e74\uff0c\u4e2d\u5c71\u5927\u5b66\u82cf\u6210\u52c7\u6559\u6388\u8bfe\u9898\u7ec4<\/strong>\u53d1\u5c55\u4e86\u4e00\u79cd\u4ee5\u7a33\u5b9a\u7684MOF LIFM-28\u4e3a\u57fa\u7840\u7684\u53ef\u9006\u540e\u5408\u6210\u9694\u5c42\u914d\u4f53\u88c5\u5378\u6cd5\uff08Angew. Chem. Int. Ed., <\/i><\/em>2016,55<\/i><\/em>, 9932-9936\uff09\u3002\u901a\u8fc7\u8be5\u65b9\u6cd5\uff0c\u53ef\u4ee5\u5728LIFM-28\u7684Zr6<\/sub>\u7c07\u7684\u7279\u5b9a\u4f4d\u70b9\u53ef\u9006\u5730\u63d2\u5165\u3001\u5378\u8f7d\u529f\u80fd\u57fa\u56e2\uff0c\u5b9e\u73b0\u5bf9\u67d4\u6027\u6846\u67b6\u547c\u5438\u884c\u4e3a\u7684\u7cbe\u786e\u8c03\u63a7\uff0c\u4ee5\u53ca\u5bf9\u5b54\u9053\u8868\u9762\u7684\u76ee\u6807\u6027\u529f\u80fd\u5316\u4fee\u9970\u3002<\/p>\n

\u5728\u6b64\u57fa\u7840\u4e0a\uff0c\u4ed6\u4eec\u4e8e\u8fd1\u65e5\u5c06\u8be5\u540e\u5408\u6210\u65b9\u6cd5\u53d1\u5c55\u4e3a\u52a8\u6001\u9694\u5c42\u914d\u4f53\u63d2\u5165\u6cd5\uff0c\u5e94\u7528\u4e8e\u672c\u5f81MOF\u529f\u80fd\u7684\u539f\u4f4d\u8f6c\u6362\uff0c\u63d0\u51fa\u4e00\u79cd\u591a\u4efb\u52a1\u6216\u53ef\u53d8\u4efb\u52a1MOF\u7684\u5e94\u7528\u7b56\u7565\uff0c\u5b9e\u73b0\u540c\u4e00\u79cd\u672c\u5f81MOF\u7684\u591a\u529f\u80fd\u539f\u4f4d\u8f6c\u6362\uff0c\u5e76\u6210\u529f\u83b7\u5f97\u4e86\u521b\u8bb0\u5f55\u7684\u7532\u70f7\u50a8\u5b58\u5de5\u4f5c\u5bb9\u91cf\u7684\u529f\u80fd\u5316MOF\uff0c\u8bc1\u660e\u4e86\u8be5\u7b56\u7565\u5bf9MOF\u8fdb\u884c\u529f\u80fd\u4f18\u5316\u7684\u6709\u6548\u6027\u3002\u5229\u7528\u8be5\u7b56\u7565\u53ef\u4ee5\u8d4b\u4e88\u540c\u4e00\u79cd\u672c\u5f81MOF\u6267\u884c\u591a\u79cd\u4efb\u52a1\u7684\u80fd\u529b\uff0c\u5b9e\u73b0MOF\u7684\u91cd\u590d\u5229\u7528\uff0c\u907f\u514dMOF\u7684\u4ece\u5934\u5408\u6210\u4ee5\u51cf\u5c11MOF\u7684\u603b\u9700\u6c42\u91cf\uff0c\u6700\u7ec8\u8fbe\u5230\u964d\u4f4eMOF\u5e94\u7528\u6210\u672c\u7684\u76ee\u7684\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cDynamic Spacer Installation for Multirole Metal-Organic Frameworks: A New Direction toward Multifunctional MOFs Achieving Ultrahigh Methane Storage Working Capacity<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728J. Am. Chem. Soc.<\/i><\/em><\/strong>\u6742\u5fd7\u4e0a\u3002<\/p>\n

\u4e3a\u89e3\u51b3MOF\u5408\u6210\u6210\u672c\u9ad8\u6602\u7684\u95ee\u9898\uff0c\u6700\u7b80\u5355\u7684\u529e\u6cd5\u5f53\u7136\u662f\u5408\u6210\u4fbf\u5b9c\u7684MOF\u3002\u4f46\u662f\u6210\u672c\u4f4e\u5ec9\u7684MOF\u5f80\u5f80\u4e0d\u4e00\u5b9a\u6ee1\u8db3\u9ad8\u6027\u80fd\u7684\u8981\u6c42\uff0c\u6240\u4ee5\u4e9f\u5f85\u5f00\u53d1\u5176\u4ed6\u7684\u4f4e\u6210\u672c\u7b56\u7565\uff0c\u4ee5\u964d\u4f4eMOF\u6750\u6599\u6574\u4e2a\u751f\u547d\u5468\u671f\u7684\u5e94\u7528\u6210\u672c\u3002\u5728\u519b\u4e8b\u9886\u57df\uff0c\u4e00\u67b6\u53ef\u53d8\u66f4\u4efb\u52a1\u6218\u6597\u673a\u901a\u8fc7\u5728\u77ed\u65f6\u95f4\u5185\u66f4\u6362\u8f6f\u4ef6\u6216\u8005\u786c\u4ef6\uff0c\u53ef\u4ee5\u6267\u884c\u4e0d\u540c\u7684\u4efb\u52a1\uff1b\u800c\u4e00\u67b6\u591a\u529f\u80fd\u6218\u6597\u673a\u901a\u8fc7\u642d\u8f7d\u6240\u6709\u7c7b\u578b\u7684\u8bbe\u5907\u548c\u8f6f\u4ef6\uff0c\u53ef\u4ee5\u5728\u4e0d\u540c\u7684\u4efb\u52a1\u4e2d\u626e\u6f14\u4e0d\u540c\u7684\u89d2\u8272\u3002\u4e0e\u53ea\u80fd\u6267\u884c\u7279\u5b9a\u4efb\u52a1\u7684\u5355\u529f\u80fd\u6218\u6597\u673a\u76f8\u6bd4\uff0c\u8fd9\u4e24\u79cd\u6218\u6597\u673a\u8bbe\u8ba1\u7b56\u7565\u90fd\u53ef\u4ee5\u6709\u6548\u5730\u964d\u4f4e\u751f\u4ea7\u6210\u672c\u3002\u8be5\u5de5\u4f5c\u7684\u8bbe\u8ba1\u601d\u8def\u6b63\u662f\u5229\u7528\u4e86\u4ee5\u4e0a\u591a\u7528\u9014\u6218\u673a\u7684\u8bbe\u8ba1\u7b56\u7565\uff0c\u901a\u8fc7\u53d1\u5c55\u53ef\u53d8\u66f4\u4efb\u52a1MOF\u6216\u591a\u4efb\u52a1MOF\uff0c\u5b9e\u73b0\u964d\u4f4eMOF\u5e94\u7528\u6210\u672c\u7684\u76ee\u7684\u3002\u53ef\u53d8\u66f4\u4efb\u52a1MOF\u6216\u591a\u529f\u80fdMOF\u9700\u8981\u5177\u5907\u4ee5\u4e0b\u4e24\u79cd\u57fa\u672c\u6027\u80fd\uff1a\uff081\uff09\u53ef\u4ee5\u88c5\u5378\u4e0d\u540c\u7684\u529f\u80fd\u6a21\u5757\uff1b\uff082\uff09\u53ef\u4ee5\u4efb\u610f\u5207\u6362\u88c5\u8f7d\u7684\u529f\u80fd\u6a21\u5757\u3002\u517c\u5177\u8fd9\u4e24\u79cd\u7279\u6027\u7684MOF\u975e\u5e38\u7f55\u89c1\uff0c\u56e0\u6b64\uff0c\u5c3d\u7ba1\u591a\u529f\u80fd\u5316MOF\u7684\u7b56\u7565\u5df2\u7ecf\u88ab\u5927\u91cf\u62a5\u9053\uff0c\u4f46\u8fd9\u79cd\u53ef\u53d8\u66f4\u4efb\u52a1\u7684\u8bbe\u8ba1\u7b56\u7565\u8fd8\u662f\u7b2c\u4e00\u6b21\u88ab\u5f00\u53d1\uff0c\u63d0\u4f9b\u4e86\u4e00\u79cd\u975e\u5e38\u5de7\u5999\u800c\u53c8\u53ef\u884c\u7684MOF\u4f4e\u6210\u672c\u5e94\u7528\u7b56\u7565\u3002\u4f5c\u8005\u5229\u7528MOF LIFM-28\u5b58\u5728\u52a8\u6001\u914d\u4f4d\u952e\u7684\u7279\u6027\uff0c\u901a\u8fc7\u53ef\u9006\u5730\u529f\u80fd\u5316\u548c\u53bb\u529f\u80fd\u5316\uff0c\u5b9e\u73b0\u4e0d\u540c\u529f\u80fd\u7684\u539f\u4f4d\u8f6c\u6362\uff0c\u6f14\u793a\u4e86\u53ef\u53d8\u66f4\u4efb\u52a1\u7b56\u7565\u7684\u6709\u6548\u6027\u3002<\/p>\n

LIFM-28\u5177\u6709bcu<\/i><\/em>\u62d3\u6251\u7ed3\u6784\uff0c\u51768-\u8fde\u63a5\u7684Zr6<\/sub>\u91d1\u5c5e\u7c07\uff0c\u5728a\/b\u8f74\u548cc\u8f74\u65b9\u5411\u5206\u522b\u5177\u6709\u53ef\u4ee5\u8fde\u63a5\u4e0d\u540c\u957f\u5ea6\u9694\u5c42\u914d\u4f53\u7684\u52a8\u6001\u914d\u4f4d\u70b9\u3002\u7ecf\u8fc7\u540e\u4fee\u9970\u5c06\u4e24\u79cd\u5206\u522b\u643a\u5e26\u76f8\u540c\u6216\u8005\u4e0d\u540c\u5b98\u80fd\u56e2\u7684\u9694\u5c42\u914d\u4f53\u63d2\u5165\u5230LIFM-28\u6846\u67b6\u4e2d\uff0c\u53ef\u4ee5\u5b9e\u73b0\u5176\u5355\u529f\u80fd\u6216\u591a\u529f\u80fd\u5316\u3002\u5e76\u4e14\u8be5\u914d\u4f53\u63d2\u5165\u8fc7\u7a0b\u4e3a\u52a8\u6001\u53ef\u9006\u8fc7\u7a0b\uff0c\u5c06MOF\u6d78\u6ce1\u4e8e\u6c34\u4e2d\u53ef\u4ee5\u5bb9\u6613\u5730\u5b9e\u73b0\u914d\u4f53\u7684\u62c6\u5378\u548cLIFM-28\u7684\u518d\u56de\u6536\u3002\u56de\u6536\u7684LIFM-28\u53ef\u4ee5\u88ab\u518d\u6b21\u529f\u80fd\u5316\u3002\u4f5c\u8005\u901a\u8fc7\u5728LIFM-28\u4e2d\u63d2\u5165\u4e0d\u540c\u7ec4\u5408\u7684\u529f\u80fd\u5316\u9694\u5c42\u914d\u4f53\uff0c\u83b7\u5f97\u4e86\u529f\u80fd\u4f18\u5316\u7684LIFM-70\u201486\uff0c\u800c\u4e14\u53ef\u4ee5\u5c06\u5b83\u4eec\u6062\u590d\u5230LIFM-28\u53cd\u590d\u5229\u7528\u3002\u8fd9\u4e9b\u529f\u80fd\u4f18\u5316\u53ef\u4ee5\u9488\u5bf9\u4e0d\u540c\u7684\u6027\u80fd\u76ee\u6807\uff0c\u5982CO2<\/sub>\u5438\u9644\u4e0e\u5206\u79bb\u3001\u6c1f\u5229\u6602\u5438\u9644\u4e0e\u5206\u79bb\u3001\u7532\u70f7\u50a8\u5b58\u3001\u8367\u5149\u53d1\u5c04\u3001\u5f02\u76f8\u50ac\u5316\u3001\u6709\u673a\u70b9\u51fb\u53cd\u5e94\u7b49\u7b49\u3002\u901a\u8fc7\u53ef\u9006\u7684\u52a8\u6001\u9694\u5c42\u914d\u4f53\u63d2\u5165\uff0c\u53ef\u4ee5\u5c06LIFM-28\u8fdb\u884c\u4e0d\u540c\u529f\u80fd\u7684\u8f6c\u6362\u3002\u5c24\u5176\u7a81\u51fa\u7684\u662f\uff0c\u4f5c\u8005\u83b7\u5f97\u4e86\u57285-80 bar\uff0c298K\u4e0b\uff0c\u7532\u70f7\u50a8\u5b58\u4f53\u79ef\u5de5\u4f5c\u5bb9\u91cf\u7684\u6700\u9ad8\u7eaa\u5f55\uff0c\u9ad8\u8fbe218\u548c213 cm3<\/sup>(STP) cm-3<\/sup>\uff08LIFM-82\u548cLIFM-83\uff09\uff0c\u5176\u6027\u80fd\u8d85\u8d8a\u4e86\u8457\u540d\u7684HKUST-1\u548c\u7eaa\u5f55\u4fdd\u6301\u8005MOF-905\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u56fe1. LIFM-28\u7684\u7ed3\u6784\u8f6c\u5316<\/b><\/strong><\/p>\n

\"\"<\/p>\n

(a)\u672c\u5f81MOF LIFM-28\u7684\u5408\u6210\u3002\u5176Zr6<\/sub>\u7c07\u4e0a\u7684\u52a8\u6001\u914d\u4f4d\u70b9\u5206\u522b\u4f4d\u4e8e\u5e73\u884c\u4e8ec\u8f74\u65b9\u5411\u7684Site A\u548ca\/b\u8f74\u65b9\u5411\u7684Site B\u3002\u6846\u67b6\u4e2d\u53ef\u63d2\u5165\u4e0d\u540c\u957f\u5ea6\u9694\u5c42\u914d\u4f53\u7684\u7a7a\u95f4\u5206\u522b\u662f\u5e73\u884c\u4e8ec\u8f74\u65b9\u5411\u3001\u53ef\u63d2\u5165\u8f83\u77ed\u914d\u4f53\u7684Pocket A\uff0c\u548c\u5e73\u884c\u4e8ea\/b\u8f74\u65b9\u5411\u3001\u53ef\u63d2\u5165\u8f83\u957f\u914d\u4f53\u7684Pocket B\u3002(b)\u901a\u8fc7\u4e00\u6b65\u540e\u4fee\u9970\u63d2\u5165\u529f\u80fd\u5316\u7684BPDC\u548cTPDC\u9694\u5c42\u914d\u4f53\uff0cLIFM-28\u53ef\u4ee5\u8f6c\u53d8\u4e3a\u529f\u80fd\u5316MOF LIFM-70\u201485\u3002(c)\u9694\u5c42\u914d\u4f53\u63d2\u5165\u524d\u540e\u6846\u67b6\u7684\u62d3\u6251\u8f6c\u53d8\u3002(d)\u672c\u5f81MOF\u4e2d\u76844\u79cd\u5b54\u9053\u7c7b\u578b\u3002(e)\u5728\u63d2\u5165\u9694\u5c42\u914d\u4f53\u4e4b\u540e\uff0cChannel-A\/B\/C\u5747\u88ab\u963b\u585e\uff0c\u529f\u80fd\u5316MOF\u4e2d\u7684\u4ec5\u4fdd\u7559Channel-D\u76f4\u7ebf\u578b\u5b54\u9053\u4ee5\u53ca\u7b3c-\u7a97\u53e3\u8fde\u901a\u72b6\u5f2f\u66f2\u5b54\u9053\u3002<\/p>\n

\u56fe2.\u529f\u80fd\u5316\u914d\u4f53\u53ca\u529f\u80fd\u5316MOF<\/b><\/strong>s<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u5229\u7528\u4e24\u7c7b\u957f\u77ed\u4e0d\u540c\u7684\u529f\u80fd\u5316\u914d\u4f53\u8fdb\u884c\u6b63\u4ea4\u4f18\u5316\u7ec4\u5408\uff0c\u5206\u522b\u6784\u9020\u4e86\u4e0d\u540c\u529f\u80fd\u7684MOF LIFM-70\u201486\u3002\u901a\u8fc7\u52a8\u6001\u9694\u5c42\u914d\u4f53\u63d2\u5165\u548c\u62c6\u5378\uff0c\u5b9e\u73b0MOF\u4efb\u52a1\u7684\u53d8\u66f4\u4e0e\u529f\u80fd\u8f6c\u6362\u3002<\/p>\n

LIFM-28\u4f5c\u4e3a\u53ef\u53d8\u66f4\u4efb\u52a1\u7b56\u7565\u7684\u672c\u5f81MOF\u7684\u5173\u952e\u662f\u53ef\u4ee5\u901a\u8fc7\u62c6\u5378\u63d2\u5165\u7684\u529f\u80fd\u914d\u4f53\uff0c\u5b9e\u73b0\u52a8\u6001\u53bb\u529f\u80fd\u5316\u3002LIFM-70\u201486\u53ef\u4ee5\u7b80\u5355\u901a\u8fc7\u6c34\u6d78\u6ce1\u91cd\u65b0\u8f6c\u5316\u4e3aLIFM-28\u3002\u4f5c\u8005\u6d4b\u8bd5\u4e86\u4eceLIFM-28\u5230LIFM-77\u3001LIFM-82\u3001LIFM-83\u3001LIFM-86\u7684\u5faa\u73af\u63d2\u5165\u3001\u62c6\u5378\u5b9e\u9a8c\uff0c\u5229\u7528\u7c89\u672bXRD\u548c\u6838\u78c1\u6c22\u8c31\uff0c\u6f14\u793a\u4e86LIFM-28\u5728\u4e0d\u540c\u529f\u80fd\u7248\u672c\u4e4b\u95f4\u7684\u5207\u6362\u3002\u5728\u7b2c\u4e00\u8f6e\u8f6c\u6362\u4e2d\uff0c\u5c06\u4e00\u6279LIFM-28\u6676\u4f53\u8f6c\u5316\u4e3aLIFM-77\uff0c\u518d\u6062\u590d\u4e3aLIFM-28\u3002\u7136\u540e\u5728\u7b2c\u4e8c\u8f6e\u8f6c\u6362\u4e2d\uff0c\u6f14\u793a\u4e86\u8fd9\u6279\u56de\u6536\u7684LIFM-28\u548cLIFM-83\u4e4b\u95f4\u7684\u4e92\u76f8\u8f6c\u5316\u3002\u63a5\u4e0b\u6765\u5206\u522b\u662fLIFM-28\u548cLIFM-82\u3001LIFM-86\u4e4b\u95f4\u7684\u4e92\u76f8\u8f6c\u5316\u3002\u4ee5\u4e0a\u5b9e\u9a8c\u5145\u5206\u8bc1\u660e\u4e86LIFM-28\u4f5c\u4e3a\u53ef\u53d8\u66f4\u4efb\u52a1MOF\u7684\u4e24\u5927\u7279\u70b9\uff1a\u53ef\u4ee5\u6784\u5efa\u4e0d\u540c\u7684\u529f\u80fd\u7248\u672c\uff0c\u5e76\u53ef\u4ee5\u5728\u4e0d\u540c\u7684\u529f\u80fd\u7248\u672c\u4e4b\u95f4\u8fdb\u884c\u5207\u6362\u3002<\/p>\n

\u56fe3.\u529f\u80fdMOF\u7684\u6c14\u4f53\u5438\u9644\u7ed3\u679c<\/b><\/strong><\/p>\n

\"\"<\/p>\n

(a, b) IAST\u6cd5\u62df\u5408\u7684273K\u4e0b\uff0cCO2<\/sub>\/CH4<\/sub>\u00a0(50:50)\u3001CO2<\/sub>\/N2<\/sub>\u00a0(15:85)\u548cR22\/N2<\/sub>\u00a0(10:90)\u7684\u5438\u9644\u9009\u62e9\u6027\u3002(c, d)298K\u4e0b\u7684\u7532\u70f7\u5438\u9644\u66f2\u7ebf\u3002<\/p>\n

\u65e2\u7136LIFM-28\u4e2d\u53ef\u4ee5\u7cbe\u51c6\u5730\u63d2\u5165\u4e24\u79cd\u53ef\u643a\u5e26\u4e0d\u540c\u5b98\u80fd\u56e2\u7684\u9694\u5c42\u914d\u4f53\uff0c\u5c31\u53ef\u4ee5\u65b9\u4fbf\u5730\u4f7f\u7528\u6b63\u4ea4\u4f18\u5316\u6cd5\u6765\u83b7\u5f97\u5177\u6709\u6700\u4f18\u6027\u80fd\u7684\u529f\u80fd\u5316MOF\u3002\u4ee5MOF\u5e94\u7528\u4e2d\u7684\u4e3b\u8981\u65b9\u5411\uff0cCO2<\/sub>\u6355\u83b7\u3001\u7532\u70f7\u50a8\u5b58\u548c\u6c1f\u5229\u6602\u5206\u79bb\u4e3a\u4f8b\uff0c\u6f14\u793a\u53ef\u53d8\u66f4\u4efb\u52a1\u7b56\u7565\u53ef\u4ee5\u9488\u5bf9\u4e0d\u540c\u76ee\u7684\uff0c\u5206\u522b\u8fdb\u884c\u6c14\u4f53\u5438\u9644\u6027\u80fd\u4f18\u5316\u3002\u5c06\u643a\u5e26\u80fa\u57fa\u7684L3<\/sup>\u3001L4<\/sup>\u548cL10<\/sup>\u63d2\u5165LIFM-28\uff0c\u83b7\u5f97LIFM-77\u548cLIFM-79\uff08Figure 2\uff09\u3002\u5176\u5355\u80de\u5185\u5206\u522b\u542b\u67096\u4e2a\u548c4\u4e2a\u80fa\u57fa\u3002\u6c14\u4f53\u5438\u9644\u663e\u793a\uff0c\u80fa\u57fa\u7684\u5bc6\u5ea6\u8d8a\u9ad8\uff0c\u5bf9CO2<\/sub>\u7684\u5438\u9644\u548c\u5206\u79bb\u6027\u80fd\u8d8a\u597d\uff08Figure 3\uff09\u3002\u7c7b\u4f3c\u7684\uff0c\u5c06\u542b\u7532\u57fa\u6216\u6c1f\u5b98\u80fd\u56e2\u7684\u914d\u4f53\u63d2\u5165\u5230\u672c\u5f81\u6846\u67b6\u4e2d\uff0c\u5206\u522b\u83b7\u5f97\u4e86\u7532\u57fa\u529f\u80fd\u5316\u7684LIFM-82\u548c\u6c1f\u529f\u80fd\u5316\u7684LIFM-86\u3002LIFM-86\u5bf9\u6c1f\u5229\u6602R22\u7684\u5438\u9644\u4e0e\u5206\u79bb\u6548\u679c\u660e\u663e\u4f18\u4e8eLIFM-82\u3002\u8fd9\u4e9b\u7ed3\u679c\u6e05\u695a\u5730\u8868\u660e\uff0c\u5c06\u80fa\u57fa\u914d\u4f53\u5b89\u88c5\u5230\u672c\u5f81LIFM-28\uff0c\u5373\u53ef\u83b7\u5f97\u7528\u4e8eCO2<\/sub>\u6355\u83b7\u7684\u529f\u80fd\u6750\u6599\uff1b\u800c\u5b89\u88c5\u542b\u6c1f\u914d\u4f53\uff0c\u5219\u53ef\u83b7\u5f97\u7528\u4e8eR22\u5206\u79bb\u7684\u529f\u80fd\u6750\u6599\u3002<\/p>\n

\u88681.MOF\u5bc6\u5ea6\u3001\u5b54\u4f53\u79ef\u3001BET\u6bd4\u8868\u9762\u79ef\u3001\u5438\u9644\u7113\u3001\u7532\u70f7\u603b\u5438\u9644\u91cf\uff0c\u4ee5\u53ca298K\u4e0b5-80\uff085-35\uff09bar\u7684\u5de5\u4f5c\u5bb9\u91cf\u3002<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u5bf9\u4e8e\u7532\u70f7\u50a8\u5b58\u8fd9\u4e00\u5e94\u7528\u76ee\u7684\uff0c\u901a\u8fc7\u5b89\u88c5\u7532\u57fa\u529f\u80fd\u5316\u7684\u9694\u5c42\u914d\u4f53\uff0c\u5e76\u5360\u636e\u4e86Zr6<\/sub>\u7c07\u4e0a\u7684\u5f00\u653e\u91d1\u5c5e\u4f4d\u70b9\uff0c\u4f5c\u8005\u6784\u7b51\u4e86\u7532\u57fa\u529f\u80fd\u5316\u3001\u5355\u80de\u4e2d\u5206\u522b\u542b\u67096\u4e2a\u548c4\u4e2a\u7532\u57fa\u7684LIFM-82\u548cLIFM-83\u3002\u7532\u57fa\u53ef\u4ee5\u63d0\u9ad8MOF\u7684\u9ad8\u538b\u5438\u9644\u91cf\uff0c\u51cf\u5c11\u5f00\u653e\u91d1\u5c5e\u4f4d\u70b9\u53ef\u4ee5\u964d\u4f4eMOF\u7684\u4f4e\u538b\u5438\u9644\u91cf\uff0c\u4e24\u79cd\u56e0\u7d20\u76f8\u7ed3\u5408\u53ef\u4ee5\u63d0\u9ad8\u7532\u70f7\u50a8\u5b58\u7684\u5de5\u4f5c\u5bb9\u91cf\u3002\u51cf\u5c0f\u7684\u5b54\u9053\u5f00\u53e3\u548c\u5b54\u4f53\u79ef\u4e5f\u6709\u5229\u4e8e\u63d0\u9ad8\u5de5\u4f5c\u5bb9\u91cf\u3002LIFM-82\u548cLIFM-83\u5206\u522b\u5177\u6709\u9ad8\u8fbe218\u548c213 cm3<\/sup>\u00a0(STP) cm-3<\/sup>\u7684\u4f53\u79ef\u5de5\u4f5c\u5bb9\u91cf\uff0c\u8d85\u8d8a\u4e86\u8457\u540d\u7684HKUST-1\u548c\u7eaa\u5f55\u4fdd\u6301\u8005MOF-905\u3002\u8fd9\u4e00\u7ed3\u679c\u4e5f\u88ab\u968f\u540e\u7684\u91cd\u590d\u5b9e\u9a8c\u8fdb\u4e00\u6b65\u9a8c\u8bc1\u3002\u4ee5\u4e0a\u7ed3\u679c\u5145\u5206\u8bf4\u660e\uff0c\u5229\u7528\u53ef\u53d8\u66f4\u4efb\u52a1\u7b56\u7565\u6709\u53ef\u80fd\u4f18\u5316\u51fa\u5177\u6709\u4f18\u5f02\u6027\u80fd\u7684\u529f\u80fd\u6750\u6599\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u672c\u6587\u63cf\u8ff0\u4e86\u4e00\u79cd\u57fa\u4e8e\u52a8\u6001\u540e\u4fee\u9970\u7684\u7a33\u5b9aZr-MOF\u5feb\u901f\u6784\u5efa\u591a\u4efb\u52a1\u3001\u591a\u529f\u80fdMOF\u7684\u53ef\u53d8\u66f4\u4efb\u52a1\u7b56\u7565\u3002\u901a\u8fc7\u7b80\u5355\u7684\u5b89\u88c5\/\u62c6\u5378\u529f\u80fd\u5316\u914d\u4f53\uff0c\u672c\u5f81LIFM-28\u53ef\u4ee5\u9488\u5bf9\u4e0d\u540c\u7684\u5e94\u7528\u76ee\u7684\uff0c\u5728\u4e0d\u540c\u7684\u529f\u80fd\u6a21\u5f0f\u4e2d\u8fdb\u884c\u8f6c\u6362\u3002\u901a\u8fc7\u6b63\u4ea4\u4f18\u5316\uff0c\u5206\u522b\u5408\u6210\u4e86\u542b\u6709\u80fa\u57fa\u3001\u5177\u6709\u4f18\u826fCO2<\/sub>\u5438\u9644\u6027\u80fd\u7684LIFM-77\uff1b\u542b\u6709\u6c1f\u5b98\u80fd\u56e2\u3001\u53ef\u5e94\u7528\u4e8e\u6c1f\u5229\u6602\u5438\u9644\u5206\u79bb\u7684LIFM-86\uff1b\u4ee5\u53ca\u7532\u57fa\u5b98\u80fd\u5316\u3001\u5177\u6709\u6781\u9ad8\u7532\u70f7\u50a8\u5b58\u53ca\u5de5\u4f5c\u5bb9\u91cf\u7684LIFM-82\u548cLIFM-83\u3002\u5177\u5907\u50ac\u5316\u3001\u8367\u5149\u4ee5\u53ca\u8fdb\u4e00\u6b65\u540e\u4fee\u9970\u6f5c\u529b\u7684\u529f\u80fd\u5316MOF\u4e5f\u5df2\u88ab\u83b7\u5f97\u3002\u8be5\u7b56\u7565\u4e3a\u64cd\u4f5c\u7b80\u5355\u3001\u6210\u672c\u4f4e\u5ec9\u5730\u5408\u6210\u548c\u5e94\u7528\u591a\u529f\u80fdMOF\u63d0\u4f9b\u4e86\u4e00\u6761\u65b0\u7684\u9014\u5f84\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDynamic Spacer Installation for Multirole Metal\u2013Organic Frameworks: A New Direction toward Multifunctional MOFs Achieving Ultrahigh Methane Storage Working Capacity<\/a><\/strong>\u00a0(J. Am. Chem. Soc., 2017, DOI: 10.1021\/jacs.7b01320)<\/p>\n

\u672c\u6587\u7531\u82cf\u6210\u52c7\u8bfe\u9898\u7ec4\u6295\u7a3f<\/strong>\uff0c\u611f\u8c22\u63a8\u8350\u3002\u6b22\u8fce\u52a0\u5165\u6750\u6599\u4ebaMOF\u5b66\u672f\u4ea4\u6d41\u7fa4\uff08120199039\uff09\uff01<\/p>\n

\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1axiaofire-18\uff0c\u5434\u73ab\uff0c\u6211\u4eec\u4f1a\u62c9\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/span><\/p>\n

\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e\u6750\u6599\u4eba<\/a>\u3001\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u91d1\u5c5e-\u6709\u673a\u6846\u67b6\uff08MOF\uff09\u662f\u4e00\u7c7b\u5728\u6c14\u4f53\u5438\u9644\u3001\u5316\u5b66\u5206\u79bb\u3001\u5206\u5b50\u63a2\u6d4b\u3001\u5f02\u76f8\u50ac\u5316\u548c\u836f\u7269\u8f93\u9001\u7b49\u9886\u57df\u5177\u6709\u5e7f\u6cdb\u5e94\u7528\u524d\u666f\u7684\u65b0\u578b\u591a\u5b54\u6750\u6599\u3002\u7531\u4e8eMOF\u9ad8\u6602\u7684\u5408\u6210\u548c\u4f7f\u7528\u6210\u672c\uff0c…<\/p>\n","protected":false},"author":1123,"featured_media":79381,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[245],"class_list":["post-79318","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-mof"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/79318"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/1123"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=79318"}],"version-history":[{"count":5,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/79318\/revisions"}],"predecessor-version":[{"id":79736,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/79318\/revisions\/79736"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/79381"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=79318"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=79318"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=79318"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}