{"id":79230,"date":"2017-05-05T08:54:30","date_gmt":"2017-05-05T00:54:30","guid":{"rendered":"\/\/m.iemloyee.com\/?p=79230"},"modified":"2017-05-05T13:57:22","modified_gmt":"2017-05-05T05:57:22","slug":"science%e9%87%8d%e7%a3%85%ef%bc%9a%e9%80%89%e6%8b%a9%e6%80%a7%e5%8e%8c%e6%b0%a7%e5%8a%a9%e5%8a%9b%e7%94%b2%e7%83%b7%e7%9b%b4%e6%8e%a5%e8%bd%ac%e5%8c%96%e7%94%b2%e9%86%87","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=79230","title":{"rendered":"Science\u91cd\u78c5\uff1a\u9009\u62e9\u6027\u538c\u6c27\u52a9\u529b\u5927\u89c4\u6a21\u7532\u70f7\u76f4\u63a5\u8f6c\u5316\u7532\u9187"},"content":{"rendered":"<p><span style=\"color: #ff0000\"><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n<p>\u7532\u70f7\u4f5c\u4e3a\u5929\u7136\u6c14\u548c\u6e29\u5ba4\u6c14\u4f53\u7684\u4e3b\u8981\u6210\u5206\u4e4b\u4e00\uff0c\u5177\u6709\u5f88\u9ad8\u7684\u53ef\u7528\u6027\u5e76\u5df2\u7ecf\u6210\u4e3a\u5168\u7403\u79d1\u5b66\u7814\u7a76\u7684\u70ed\u70b9.\u5f00\u53d1\u4e00\u79cd\u5c06\u7532\u70f7\u8f6c\u5316\u5546\u54c1\u5316\u5b66\u54c1\u548c\u6db2\u4f53\u71c3\u6599\u7684\u6709\u6548\u529e\u6cd5\u4e5f\u662f\u76f8\u5173\u7814\u7a76\u4eba\u5458\u4eec\u5b5c\u5b5c\u4ee5\u6c42\u7684\u79d1\u7814\u76ee\u6807\u3002\u5177\u4f53\u6765\u8bf4\uff0c\u5c06\u7532\u70f7\u76f4\u63a5\u8f6c\u5316\u6210\u9002\u7528\u4e8e\u8fd0\u8f93\u548c\u5b58\u50a8\u7684\u6db2\u6001\u5316\u5408\u7269\u4ecd\u7136\u662f\u5927\u5bb6\u6240\u9762\u4e34\u7684\u4e00\u4e2a\u4e3b\u8981\u6311\u6218\u3002\u76ee\u524d\u7684\u5de5\u4e1a\u8def\u7ebf\u662f\u95f4\u63a5\u7684\uff0c\u4f9d\u9760\u521d\u6b65\u7684\u9ad8\u6e29\u9ad8\u538b\u6c27\u5316\u6210\u5408\u6210\u6c14\u3001\u6df7\u5408\u7269\u7684\u6c22\u6c14\u548c\u4e00\u6c27\u5316\u78b3\uff0c\u968f\u540e\u5176\u53c8\u53ef\u4ee5\u53cd\u5e94\u5f62\u6210\u6db2\u4f53\u7532\u9187\u548c\u70c3\u3002\u7136\u800c\uff0c\u8fd9\u4e2a\u8fc7\u7a0b\u5728\u5927\u89c4\u6a21\u751f\u4ea7\u4e2d\u4ec5\u5728\u7ecf\u6d4e\u4e0a\u662f\u53ef\u884c\u7684\uff0c\u5e76\u4e0d\u9002\u7528\u4e8e\u591a\u53d8\u7684\u5b9e\u9645\u5e94\u7528\u60c5\u51b5\u3002<\/p>\n<p><span style=\"color: #ff0000\"><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/span><\/p>\n<p>\u5317\u4eac\u65f6\u95f42017\u5e745\u67085\u65e5\uff0c\u6765\u81ea<strong>\u745e\u58eb\u4fdd\u7f57\u8c22\u5c14\u7814\u7a76\u6240\u7684<\/strong><strong>Vitaly L. Sushkevich<\/strong><strong>\u6559\u6388\u548c<\/strong><strong>Jeroen A. van Bokhoven<\/strong><strong>\u6559\u6388<\/strong><strong>(<\/strong><strong>\u5171\u540c\u901a\u8baf\u4f5c\u8005<\/strong><strong>)<\/strong>\u56e2\u961f\u5728<strong>Science<\/strong>\u4e0a\u5728\u7ebf\u53d1\u8868\u4e86\u4e00\u7bc7\u9898\u4e3a<strong>\u201c<\/strong><strong>Selective anaerobic oxidation of methane enables direct synthesis of methanol<\/strong><strong>\u201d<\/strong>\u7684\u62a5\u544a\uff0c\u6587\u4e2d\u7814\u7a76\u8005\u7814\u7a76\u4e86\u5982\u4f55\u4f7f\u7528\u6c34\u4f5c\u4e3a\u6c27\u6e90\u501f\u7531CuMOR\u5c06\u7532\u70f7\u76f4\u63a5\u8f6c\u5316\u4e3a\u7532\u9187\u3002\u8be5\u7814\u7a76\u56e2\u961f\u63d0\u51fa\u4e86\u4e00\u79cd\u9010\u6b65\u5de5\u827a\u65b9\u6cd5\uff0c\u57fa\u4e8e\u4e0e\u6c34\u7684\u90e8\u5206\u6c27\u5316\uff0c\u5728\u6c34\u6cb8\u77f3\u4e0a\u9ad8\u9009\u62e9\u6027(\u7ea697%)\u5730\u5c06\u7532\u70f7\u76f4\u63a5\u8f6c\u5316\u4e3a\u7532\u9187\u3002\u9996\u5148\u5728673 K\u4e0b\u8fdb\u884c\u6c22\u6d3b\u5316\uff0c\u968f\u540e\u5c06\u8fde\u7eed\u7684\u50ac\u5316\u5242\u66b4\u9732\u57287\u5df4\u7684\u7532\u70f7\u4e2d\uff0c\u7136\u540e\u5728473 K\u7684\u6c34\u6e29\u6761\u4ef6\u4e0b\u4e8e\u6cb8\u77f3\u4e2d\u6301\u7eed\u4ea7\u751f0.204 mole\u7684CH<sub>3<\/sub>OH (mol\/Cu)\u3002\u7814\u7a76\u8005\u901a\u8fc7\u540c\u4f4d\u7d20\u6807\u8bb0\u786e\u8ba4\u4e86\u6c34\u662f\u4f5c\u4e3a\u53cd\u5e94\u7684\u6c27\u6c14\u6765\u6e90\uff0c\u8be5\u53cd\u5e94\u4ee5\u518d\u751f\u6cb8\u77f3\u4e3a\u6d3b\u6027\u4e2d\u5fc3\uff0c\u4f7f\u5f97\u7532\u9187\u7684\u89e3\u5438\u80fd\u529b\u8f83\u597d\u3002\u540c\u65f6\uff0c\u5728\u539f\u4f4dX\u5c04\u7ebf\u5438\u6536\u5149\u8c31\u3001\u7ea2\u5916\u5149\u8c31\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u7684\u57fa\u7840\u4e0a\uff0c\u7814\u7a76\u8005\u63d0\u51fa\u4e86\u4e00\u79cd\u5728Cu<sup>\u2161<\/sup>\u6c27\u5316\u7269\u6d3b\u6027\u4e2d\u5fc3\u8fdb\u884c\u7532\u70f7\u6c27\u5316\uff0c\u7136\u540e\u901a\u8fc7\u6c34\u540c\u65f6\u5f62\u6210\u6c22\u6c14\u8fdb\u884cCu<sup>\u2160<\/sup>\u518d\u6c27\u5316\u7684\u53cd\u5e94\u673a\u7406<\/p>\n<p><span style=\"color: #ff0000\"><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n<p><span style=\"color: #0000ff\"><strong>\u56fe<\/strong><strong>1.<\/strong><strong>\u5c06\u7532\u70f7\u8f6c\u5316\u4e3a\u7532\u9187\u7684\u5404\u79cd\u5316\u5b66\u5de5\u827a\u5bf9\u6bd4<\/strong><\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-79234 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/05\/F1.large_.jpg\" alt=\"\" width=\"730\" height=\"247\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/05\/F1.large_.jpg 730w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/05\/F1.large_-300x102.jpg 300w\" sizes=\"(max-width: 730px) 100vw, 730px\" \/><\/p>\n<p><span style=\"color: #0000ff\"><strong>\u56fe<\/strong><strong>2.\u6750\u6599\u8868\u5f81\u53ca\u6d4b\u8bd5\u6570\u636e<\/strong><\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-79235 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/05\/F2.large_.jpg\" alt=\"\" width=\"695\" height=\"730\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/05\/F2.large_.jpg 695w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/05\/F2.large_-286x300.jpg 286w\" sizes=\"(max-width: 695px) 100vw, 695px\" \/><\/p>\n<p><span style=\"color: #0000ff\"><strong>\u56fe<\/strong><strong>3.<\/strong><strong>\u4f7f\u7528\u6c34\u4f5c\u4e3a\u6c27\u5316\u5242\u6c27\u5316\u7532\u70f7\u7684\u673a\u7406<\/strong><\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-79236 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/05\/F3.large_.jpg\" alt=\"\" width=\"715\" height=\"730\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/05\/F3.large_.jpg 715w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/05\/F3.large_-294x300.jpg 294w\" sizes=\"(max-width: 715px) 100vw, 715px\" \/><\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5<\/strong>: <a href=\"http:\/\/science.sciencemag.org\/content\/356\/6337\/523\" target=\"_blank\" rel=\"noopener noreferrer\"><strong>Selective anaerobic oxidation of methane enables direct synthesis of methanol<\/strong><\/a> (Science, 2017, DOI: 10.1126\/science.aam9035)<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u5b66\u672f\u7ec4 Jon \u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" rel=\"noopener noreferrer\">\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p><strong>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong><a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener noreferrer\"><strong>\u6d4b\u8bd5\u8c37<\/strong><\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u7532\u70f7\u4f5c\u4e3a\u5929\u7136\u6c14\u548c\u6e29\u5ba4\u6c14\u4f53\u7684\u4e3b\u8981\u6210\u5206\u4e4b\u4e00\uff0c\u5177\u6709\u5f88\u9ad8\u7684\u53ef\u7528\u6027\u5e76\u5df2\u7ecf\u6210\u4e3a\u5168\u7403\u79d1\u5b66\u7814\u7a76\u7684\u70ed\u70b9.\u5f00\u53d1\u4e00\u79cd\u5c06\u7532\u70f7\u8f6c\u5316\u5546\u54c1\u5316\u5b66\u54c1\u548c\u6db2\u4f53\u71c3\u6599\u7684\u6709\u6548\u529e\u6cd5\u4e5f\u662f\u76f8\u5173\u7814\u7a76\u4eba\u5458&#8230;<\/p>\n","protected":false},"author":2136,"featured_media":79240,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-79230","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/79230"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2136"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=79230"}],"version-history":[{"count":10,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/79230\/revisions"}],"predecessor-version":[{"id":79366,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/79230\/revisions\/79366"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/79240"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=79230"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=79230"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=79230"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}