{"id":79084,"date":"2017-05-04T08:39:30","date_gmt":"2017-05-04T00:39:30","guid":{"rendered":"\/\/m.iemloyee.com\/?p=79084"},"modified":"2017-05-04T19:59:34","modified_gmt":"2017-05-04T11:59:34","slug":"%e4%bb%8a%e6%97%a5nature%e9%80%9f%e9%80%92-%e5%8d%a4%e4%bb%a3%e8%84%82%e8%82%aa%e6%97%8f%e7%a2%b3%e6%b0%a2%e5%8c%96%e5%90%88%e7%89%a9%e4%b8%8e%e4%ba%8c%e6%b0%a7%e5%8c%96%e7%a2%b3%e7%9a%84%e8%bf%9c","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=79084","title":{"rendered":"\u4eca\u65e5Nature\u901f\u9012: \u5364\u4ee3\u8102\u80aa\u65cf\u78b3\u6c22\u5316\u5408\u7269\u4e0e\u4e8c\u6c27\u5316\u78b3\u7684\u8fdc\u7a0b\u7fa7\u5316"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n

\u5728\u6709\u673a\u5316\u5b66\u4e2d\u9700\u8981\u7ec4\u88c5\u590d\u5408\u5206\u5b50\u65f6\uff0c\u901a\u8fc7\u50ac\u5316\u78b3-\u78b3\u952e\u7684\u5f62\u6210\u80fd\u591f\u4f7f\u5f97\u5206\u5b50\u7684\u5408\u6210\u8def\u7ebf\u5f97\u5230\u7cbe\u7b80\u3002\u53e6\u5916\uff0c\u5728\u77f3\u6cb9\u5316\u5b66\u54c1\u548c\u751f\u7269\u76f8\u5173\u7684\u5206\u5b50\u52a0\u5165\u9971\u548c\u70c3\u662f\u4e00\u9053\u7279\u522b\u91cd\u8981\u800c\u53c8\u5e38\u89c1\u7684\u57fa\u7840\u5de5\u5e8f\u3002\u7136\u800c\uff0c\u6d89\u53ca\u5230\u7684\u4ea4\u53c9\u8026\u5408\u7406\u8bba\u4e2d\u7684\u70f7\u57fa\u4eb2\u7535\u8bd5\u5242\u53ea\u6709\u5728\u7279\u5b9a\u548c\u9884\u5148\u5b98\u80fd\u5316\u7684\u4f4d\u70b9\u624d\u80fd\u4ea7\u751f\u5f62\u6210\u50ac\u5316\u952e\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/span><\/p>\n

\u5317\u4eac\u65f6\u95f42017\u5e745\u67084\u65e5\uff0c\u6765\u81ea\u5df4\u585e\u7f57\u90a3\u79d1\u5b66\u6280\u672f\u7814\u7a76\u6240<\/strong>\u7684Ruben Martin<\/strong>\u6559\u6388(\u901a\u8baf\u4f5c\u8005)\u56e2\u961f\u4e8eNature<\/strong>\u4e0a\u5728\u7ebf\u53d1\u8868\u4e86\u4e00\u7bc7\u9898\u4e3a\u201cRemote carboxylation of halogenated aliphatic hydrocarbons with carbon dioxide<\/strong>\u201d\u7684\u6587\u7ae0\uff0c\u6587\u4e2d\u62a5\u9053\u4e86\u8be5\u7814\u7a76\u56e2\u961f\u6709\u5173\u50ac\u5316\u4e8c\u6c27\u5316\u78b3\u4ea4\u53c9\u8026\u5408\u53cd\u5e94\u6700\u65b0\u7814\u7a76\u6210\u679c\u3002\u7814\u7a76\u8005\u662f\u901a\u8fc7\u6cbf\u70c3\u4fa7\u94fe\u9009\u62e9\u6027\u8fc1\u79fb\u50ac\u5316\u5242\u6765\u8fdb\u884c\u4e00\u79cd\u50ac\u5316\u53cd\u5e94\uff0c\u8be5\u53cd\u5e94\u5177\u6709\u4f18\u5f02\u7684\u533a\u57df\u5316\u5b66\u9009\u62e9\u6027\uff0c\u6b64\u50ac\u5316\u53cd\u5e94\u80fd\u591f\u4fc3\u8fdb\u4e8c\u6c27\u5316\u78b3\u5728\u8fdc\u7a0b\u548c\u672a\u5b98\u80fd\u5316\u7684\u8102\u80aa\u4f4d\u70b9\u5904\u53d1\u751f\u7fa7\u5316\u53cd\u5e94\u3002\u540c\u65f6\uff0c\u8be5\u56e2\u961f\u7684\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0c\u53ef\u4ee5\u5207\u6362\u548c\u63a7\u5236\u4f4d\u70b9\u9009\u62e9\u6027\u4f7f\u5f97\u5728\u5b58\u5728\u5148\u9a8c\u53cd\u5e94\u6027\u66f4\u9ad8\u7684\u4f4d\u70b9\u60c5\u51b5\u4e0b\u80fd\u591f\u5b9e\u73b0\u8f83\u5c11\u53cd\u5e94\u4f4d\u70b9\u7684\u529f\u80fd\u5316\u3002\u6b64\u5916\uff0c\u7814\u7a76\u8005\u53d1\u73b0\u4ece\u77f3\u6cb9\u52a0\u5de5\u5f97\u5230\u7684\u539f\u6599\uff08\u5982\u70f7\u70c3\u548c\u672a\u7cbe\u70bc\u7684\u70ef\u70c3\u6df7\u5408\u7269\uff09\u53ef\u4ee5\u7528\u4f5c\u50ac\u5316\u53cd\u5e94\u7684\u5e95\u7269\uff0c\u6b64\u53d1\u73b0\u4e5f\u4e3a\u5c06\u76f4\u63a5\u8f6c\u5316\u77f3\u6cb9\u884d\u751f\u7684\u539f\u6599\u901a\u8fc7\u50ac\u5316\u5e73\u53f0\u6574\u5408\u5230\u6709\u4ef7\u503c\u7684\u8102\u80aa\u9178\u4e2d\u63d0\u4f9b\u4e86\u4e00\u4e2a\u53ef\u884c\u7684\u529e\u6cd5\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n

\u56fe<\/strong>1.<\/strong>\u5728\u8fdc\u7a0b<\/strong>sp3<\/sup> C-H<\/strong>\u4f4d\u70b9\u5904\u7684\u53ef\u5207\u6362\u4f4d\u70b9\u9009\u62e9\u6027\u50ac\u5316\u7fa7\u5316<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2.<\/strong>\u79bb\u6563\u70f7\u57fa\u5364\u5316\u7269\u5728\u8fdc\u7a0b<\/strong>sp3<\/sup> C-H<\/strong>\u4f4d\u70b9\u5904\u7684\u50ac\u5316\u7fa7\u5316<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>3.<\/strong>\u901a\u8fc7\u533a\u57df\u5206\u89e3\u8fc7\u7a0b\u50ac\u5316\u7fa7\u5316\u539f\u6599<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>4.<\/strong>\u5728\u8fdc\u7a0b<\/strong>sp3<\/sup> C-H<\/strong>\u4f4d\u70b9\u5904\u7684\u53ef\u5207\u6362\u4f4d\u70b9\u9009\u62e9\u6027\u7fa7\u5316\u672a\u6d3b\u5316\u70f7\u57fa\u6eb4\u5316\u7269<\/strong><\/p>\n

\"\"<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aRemote carboxylation of halogenated aliphatic hydrocarbons with carbon dioxide<\/a><\/strong> (Nature, 2017, DOI: 10.1038\/nature22316)<\/strong><\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u5b66\u672f\u7ec4 Jon \u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1axiaofire-18\uff0c\u5434\u73ab\uff0c\u6211\u4eec\u4f1a\u62c9\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/span><\/strong><\/p>\n

\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e\u6750\u6599\u4eba<\/a>\u3001\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u5728\u6709\u673a\u5316\u5b66\u4e2d\u9700\u8981\u7ec4\u88c5\u590d\u5408\u5206\u5b50\u65f6\uff0c\u901a\u8fc7\u50ac\u5316\u78b3-\u78b3\u952e\u7684\u5f62\u6210\u80fd\u591f\u4f7f\u5f97\u5206\u5b50\u7684\u5408\u6210\u8def\u7ebf\u5f97\u5230\u7cbe\u7b80\u3002\u53e6\u5916\uff0c\u5728\u77f3\u6cb9\u5316\u5b66\u54c1\u548c\u751f\u7269\u76f8\u5173\u7684\u5206\u5b50\u52a0\u5165\u9971\u548c\u70c3\u662f\u4e00\u9053\u7279\u522b\u91cd\u8981\u800c\u53c8\u5e38…<\/p>\n","protected":false},"author":2136,"featured_media":79085,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[293],"class_list":["post-79084","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-nature"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/79084"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2136"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=79084"}],"version-history":[{"count":6,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/79084\/revisions"}],"predecessor-version":[{"id":79197,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/79084\/revisions\/79197"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/79085"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=79084"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=79084"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=79084"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}