{"id":7888,"date":"2016-04-16T08:00:45","date_gmt":"2016-04-16T00:00:45","guid":{"rendered":"\/\/m.iemloyee.com\/?p=7888"},"modified":"2016-05-24T18:57:04","modified_gmt":"2016-05-24T10:57:04","slug":"nature%e6%96%87%e7%8c%ae%e5%af%bc%e8%af%bb-%e5%be%b7%e6%b3%95%e7%a0%94%e7%a9%b6%e5%9b%a2%e9%98%9f%e5%8f%91%e7%8e%b0%e6%b0%94%e4%bd%93%e5%90%b8%e9%99%84%e4%b8%ba%e8%b4%9f%e7%9a%84%e6%9d%90%e6%96%99","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=7888","title":{"rendered":"Nature\u6587\u732e\u5bfc\u8bfb: \u5fb7\u6cd5\u7814\u7a76\u56e2\u961f\u53d1\u73b0\u6c14\u4f53\u5438\u9644\u4e3a\u8d1f\u7684\u6750\u6599"},"content":{"rendered":"<p>\u5438\u9644\u73b0\u8c61\u5bf9\u4e8e\u6c14\u4f53\u5206\u79bb\u81f3\u5173\u91cd\u8981\uff0c\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u6750\u6599\uff08MOFs\uff09\u7531\u4e8e\u53ef\u4ee5\u5bf9\u5b54\u9699\u5c3a\u5bf8\u3001\u5f62\u72b6\u548c\u529f\u80fd\u8fdb\u884c\u8c03\u63a7\u6210\u4e3a\u5e7f\u53d7\u5173\u6ce8\u7684\u5438\u9644\u7c7b\u6750\u6599\u3002\u5bf9\u4e8e\u5e38\u89c4\u7684\u7b49\u6e29\u6c14\u4f53\u5438\u9644\u6765\u8bf4\uff0c\u6c14\u4f53\u7684\u5438\u9644\u91cf\u4f1a\u968f\u7740\u538b\u529b\u7684\u589e\u52a0\u800c\u589e\u52a0\u3002<\/p>\n<p>\u8fd1\u65e5\uff0c\u4e00\u4e2a\u7531\u5fb7\u56fd\u6155\u5c3c\u9ed1\u7406\u5de5\u5927\u5b66Stefan Kaskel\u6559\u6388\u7275\u5934\u7684\u5408\u4f5c\u7814\u7a76\u56e2\u961f\u53d1\u73b0\uff0c\u4e00\u79cd\u88ab\u547d\u540d\u4e3aDUT-49\u7684MOFs\u6750\u6599\u7684\u7b49\u6e29\u6c14\u4f53\u5438\u9644\u4e3a\u8d1f\u503c\uff0c\u4e5f\u5c31\u662f\u8bf4\uff0c\u5728\u4e00\u5b9a\u7684\u538b\u529b\u548c\u6e29\u5ea6\u8303\u56f4\u5185\uff0c\u968f\u7740\u538b\u529b\u7684\u589e\u52a0\uff0c\u6c14\u4f53\u4f1a\u81ea\u53d1\u7684\u8fdb\u884c\u89e3\u5438\u9644\u3002\u539f\u4f4d\u7684XRD\u5438\u9644\u5b9e\u9a8c\u548c\u91cf\u5b50\u529b\u5b66\u8ba1\u7b97\u6a21\u62df\u8868\u660e\uff0c\u8fd9\u79cd\u884c\u4e3a\u662f\u7531\u4e8e\u6750\u6599\u4e2d\u7a81\u7136\u7684\u6ede\u540e\u7ed3\u6784\u53d8\u5f62\u548c\u5b54\u9699\u6536\u7f29\u9020\u6210\u7684\u3002\u8fd9\u79cd\u6750\u6599\u6709\u671b\u5728\u5fae\u6c14\u52a8\u5143\u4ef6\u7b49\u9886\u57df\u83b7\u5f97\u5e7f\u6cdb\u5e94\u7528\u3002<\/p>\n<p><strong>\u6587\u732e\u56fe\u6ce8<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-7937 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/\u56fe1-4-1.jpg\" alt=\"\u56fe1-4\" width=\"700\" height=\"324\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/\u56fe1-4-1.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/\u56fe1-4-1-300x139.jpg 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u56fe1 \u6c14\u4f53\u5438\u9644\u7b49\u6e29\u56fe\u3001\u538b\u529b\u56fe\u548c\u52a8\u529b\u5b66\u56fe<br \/>\na: \u4e00\u79cd\u4e0d\u901a\u6c14\u5fae\u5b54\u56fa\u4f53\u7684I\u578b\u5438\u9644\u7b49\u6e29\u56fe\u53ca\u5bf9\u5e94\u7684dnads\/dp\u66f2\u7ebf\uff1b<br \/>\nb, c: DUT-49\u5728111K\u5bf9\u7532\u70f7(b)\u3001\u5728298K\u5bf9\u6b63\u4e01\u70f7(c)\u7684\u5438\u9644\u7b49\u6e29\u7ebf\uff08\u84dd\u8272\uff09\u4ee5\u53ca\u5bf9\u5e94\u7684dnads\/dp\u66f2\u7ebf\uff08\u7ea2\u8272\uff09\uff0c\u0394nNGA\u4ee3\u8868\u7b49\u6587\u732e\u4e2d\u7684NGA\u6b65\u7ea7\uff1b<br \/>\nd: \u91cd\u91cf\u5438\u9644\u4ee5\u53ca\u52a8\u6001\u626b\u63cf\u91cf\u70ed\u6cd5\u5206\u6790\uff0c\u0394mNGA\u4ee3\u8868NGA\u8fc7\u7a0b\u4e2d\u6c14\u4f53\u91ca\u653e\u7684\u8d28\u91cf\uff1b<br \/>\ne-g: \u4e09\u79cd\u5178\u578b\u5438\u9644\u884c\u4e3a\u5bf9\u5e94\u7684\u52a8\u529b\u5b66\u538b\u529b\u56fe\uff0c\u4e0d\u901a\u6c14\u5fae\u5b54\u56fa\u4f53(e), DUT-49\u5728111K\u5bf9\u7532\u70f7\u5438\u9644(f), DUT-49\u5728298K\u5bf9\u6b63\u4e01\u70f7\u5438\u9644(g), \u7070\u8272\u533a\u57df\u8868\u793a\u6c14\u4f53\u4f9b\u7ed9\u95f4\u9694\uff1b<br \/>\nh: DUT-49\u5728298K\u5bf9\u6b63\u4e01\u70f7\u5438\u9644\u5b9e\u9a8c(c,g)\u89c6\u9891\u7684\u622a\u56fe<br \/>\n\u6ce8\uff1a\u6bdb\u7ec6\u7ba1\u76f4\u5f841mm\uff0ct=0 s\u65f6\u6837\u54c1\u57fa\u5e95\u9ad8\u5ea6\u4e3a5 cm\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-7940 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/\u56fe2-3-2.jpg\" alt=\"\u56fe2-3\" width=\"700\" height=\"285\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/\u56fe2-3-2.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/\u56fe2-3-2-300x122.jpg 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u56fe2 DUT-49\u5728111K\u5bf9\u7532\u70f7\u5438\u9644\u7684\u539f\u4f4d\u7c89\u672bXRD<br \/>\na: 111K\u4e0b\u7684\u539f\u4f4d\u7532\u70f7\u5438\u9644\u548c\u89e3\u5438\u7b49\u6e29\u7ebf\uff1b\u6536\u96c6\u5230\u7684\u7c89\u672bXRD\u56fe\u6837\u5bf9\u5e94\u7684\u70b9\u5982\u56fe\u4e2d\u5b9e\u4f53\u70b9\u6240\u793a\uff0c\u63d2\u56fe\u662f\u7b49\u6e29\u7ebfNGA\u533a\u57df\u7684\u653e\u5927\uff1b<br \/>\nb: \u7c89\u672bXRD\u56fe\u6837\u6f14\u5316\uff08\u03bb = 1.5406\u57c3\uff09\u5728\u5438\u9644\uff08\u84dd\u8272\uff09\u548c\u89e3\u5438\u9644\uff08\u7ea2\u8272\uff09\u8fc7\u7a0b\u4e2d\u7684\u7b49\u9ad8\u7ebf\u56fe\uff0cop\u662f\u5f20\u5f00\u5b54\u7684\u76f8\uff08\u7acb\u65b9\uff0cF23\u7a7a\u95f4\u7fa4\uff0c\u70b9\u9635\u53c2\u6570a=46.427(4)\u57c3\uff09\uff0ccp\u662f\u6536\u7f29\u5b54\u7684\u76f8\uff08\u7acb\u65b9\uff0cPa3\u7a7a\u95f4\u7fa4\uff0c\u70b9\u9635\u53c2\u6570a=36.1603(2)\u57c3\uff09\uff0cip\u662f\u4e2d\u95f4\u5b54\u7684\u76f8\uff08\u7acb\u65b9\uff0cPa3\u7a7a\u95f4\u7fa4\uff0c\u70b9\u9635\u53c2\u6570a=45.542 (2)\u57c3\uff09\uff1b<br \/>\nc: \u5438\u9644\uff08\u84dd\u8272\uff09\u548c\u89e3\u5438\u9644\uff08\u7ea2\u8272\uff09\u8fc7\u7a0b\u4e2d\u70b9\u9635\u53c2\u6570\u7684\u53d8\u5316\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-7941 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/\u56fe3-3-1.jpg\" alt=\"\u56fe3-3\" width=\"700\" height=\"378\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/\u56fe3-3-1.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/\u56fe3-3-1-300x162.jpg 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u56fe3 DUT-49 op\u548cDUT-49 cp\u7684\u7ed3\u6784<br \/>\na, e: DUT-49 op(a)\u548ccp(e)\u4e2d\u7684\u5316\u5b66\u7ed3\u6784\u4fe1\u606f\uff1b<br \/>\nb, f: DUT-49 op(b)(\u6a21\u62df\u8868\u9762\u79ef5,049 m2g-1\u548ccp(e), \u81ea\u7531\u5b54\u9699\u4f53\u79ef2.94cm3g-1)\u548cDUT-49 cp(f)(\u6a21\u62df\u8868\u9762\u79ef2,908 m2g-1\u548ccp(e), \u81ea\u7531\u5b54\u9699\u4f53\u79ef1.13cm3g-1)\u7684\u6cbf[110]\u65b9\u5411\u7684\u6676\u4f53\u7ed3\u6784\uff0c\u539f\u5b50\u7528\u4e0d\u7528\u989c\u8272\u8868\u793a\uff08\u6df1\u7070\u8272(C)\uff0c\u84dd\u8272(N)\uff0c\u7ea2\u8272(O)\uff0c\u84dd\u7eff\u8272(Cu)\uff0c\u6d45\u7070\u8272(H)\uff09\uff0c\u4e3a\u4e86\u6e05\u6670\u6ca1\u6709\u753b\u51fa\u5ba2\u4f53\u5206\u5b50\uff1b<br \/>\nc, g: DUT-49 op(c)\u548cDUT-49 cp(g)\u6cbf\u7740[110]\u8f74\u65b9\u5411\u7684\u5b54\u9699\u793a\u610f\u56fe\uff0c\u4e0d\u540c\u5b54\u9699\u7528\u989c\u8272\u533a\u5206\uff08MOP\u5b54\u9699(\u7eff\u8272), \u56db\u9762\u4f53\u5b54\u9699(\u9ec4\u8272), \u516b\u9762\u4f53\u5b54\u9699(\u6a58\u9ec4\u8272)\uff09\uff1b<br \/>\nd: \u4eceDUT-49 op\u6536\u7f29\u5230DUT-49 cp\u8fc7\u7a0b\u4e2d\u5b54\u9699\u5c3a\u5bf8\u548c\u81ea\u7531\u5b54\u9699\u4f53\u79ef\u7684\u53d8\u5316\uff1b<br \/>\nh: \u5bc6\u5ea6\u548c\u53ef\u5f97\u51e0\u4f55\u8868\u9762\u79ef\u7684\u53d8\u5316<br \/>\n\u6ce8\uff1a\u4e2d\u95f4\u7ed3\u6784\u3001\u81ea\u7531\u5b54\u9699\u4f53\u79ef\u3001\u53ef\u5f97\u8868\u9762\u79ef\u4ee5\u53ca\u5b54\u9699\u5c3a\u5bf8\u7684\u6a21\u62df\u8be6\u89c1\u9644\u4ef6\u4e2d\u7684\u56fe40\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-7943 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/\u56fe4-3-1.jpg\" alt=\"\u56fe4-3\" width=\"700\" height=\"526\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/\u56fe4-3-1.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/04\/\u56fe4-3-1-300x225.jpg 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u56fe4 \u7532\u70f7\u5438\u9644\u7684\u6e29\u5ea6\u76f8\u5173\u6027\u548c\u8ba1\u7b97\u6a21\u62df<br \/>\na, d: \u4e0d\u540c\u6e29\u5ea6\u4e0b\u7532\u70f7\u5438\u9644\u7684\u7b49\u6e29\u56fe\uff0cd\u4e2d\u7684\u63d2\u56fe\u8868\u793a\u7b49\u6e29\u7ebf\u4e2dNGA\u533a\u57df\u7684\u653e\u5927\uff1b<br \/>\nb: DUT-49 op(\u7ea2\u8272)\u548cDUT-49 cp(\u84dd\u8272)\u5728111K\u4e0b\u7684\u5b9e\u9a8c\uff08\u7070\u8272\uff09\u548c\u57fa\u4e8e\u7684\u6676\u4f53\u7ed3\u6784\u6a21\u62df\u83b7\u5f97\u7684\u7532\u70f7\u5438\u9644\u7b49\u6e29\u56fe\uff0c\u63d2\u56fe\u8868\u793a\u7b49\u6e29\u7ebfNGA\u533a\u57df\u7684\u653e\u5927\uff1b<br \/>\nc: DUT-49 op\u5728\u7ed9\u5b9a\u538b\u529b\u4e0b\u548cDUT-49 cp\u5728\u8f6c\u53d8\u538b\u529b\u4e0b\uff08\u4e0b\u56fe\uff09\uff0c\u57281000\u4e2a\u5e73\u8861\u9aa8\u67b6\u4e2d\u7684\u7532\u70f7\uff08\u7eff\u8272\uff09\u5206\u5e03\u56fe\uff0c\u5176\u4ed6\u539f\u5b50\u7684\u989c\u8272\u4e0e\u56fe3\u4e00\u81f4\uff1b<br \/>\ne: \u5438\u9644\u8bf1\u53d1\u7ed3\u6784\u8f6c\u53d8\u7684\u5e94\u529b\u6a21\u578b\u793a\u610f\u56fe\uff0c\u5e73\u8861\u8f6c\u53d8\uff08\u7070\u8272\u7ebf\uff09\uff0c\u4e9a\u7a33\u8f6c\u53d8\uff08\u9ed1\u8272\u7bad\u5934\uff09\uff0c\u5f20\u5f00\u5b54\u76f8\uff08\u7ea2\u8272\u7ebf\uff09\uff0c\u6536\u7f29\u5b54\u76f8\uff08\u84dd\u8272\u7ebf\uff09\uff0c\u7bad\u5934\u8868\u793a\u89c2\u5bdf\u5230\u7684DUT-49\u7684\u8f6c\u53d8\u3002<\/p>\n<p>\u53c2\u8003\u539f\u6587\uff1a<a href=\"http:\/\/www.nature.com\/nature\/journal\/vaop\/ncurrent\/full\/nature17430.html?WT.ec_id=NATURE-20160407&amp;spMailingID=51092335&amp;spUserID=MjA1NTEwMjEzMgS2&amp;spJobID=900773357&amp;spReportId=OTAwNzczMzU3S0\" target=\"_blank\">A pressure-amplifying framework material with negative gas adsorption transitions<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u5438\u9644\u73b0\u8c61\u5bf9\u4e8e\u6c14\u4f53\u5206\u79bb\u81f3\u5173\u91cd\u8981\uff0c\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u6750\u6599\uff08MOFs\uff09\u7531\u4e8e\u53ef\u4ee5\u5bf9\u5b54\u9699\u5c3a\u5bf8\u3001\u5f62\u72b6\u548c\u529f\u80fd\u8fdb\u884c\u8c03\u63a7\u6210\u4e3a\u5e7f\u53d7\u5173\u6ce8\u7684\u5438\u9644\u7c7b\u6750\u6599\u3002\u5bf9\u4e8e\u5e38\u89c4\u7684\u7b49\u6e29\u6c14\u4f53\u5438\u9644\u6765\u8bf4\uff0c\u6c14\u4f53\u7684\u5438\u9644&#8230;<\/p>\n","protected":false},"author":41,"featured_media":7896,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[293],"class_list":["post-7888","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-keji","tag-nature"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/7888"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/41"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=7888"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/7888\/revisions"}],"predecessor-version":[{"id":7945,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/7888\/revisions\/7945"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/7896"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=7888"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=7888"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=7888"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}