{"id":77229,"date":"2017-04-28T06:30:34","date_gmt":"2017-04-27T22:30:34","guid":{"rendered":"\/\/m.iemloyee.com\/?p=77229"},"modified":"2017-04-24T21:12:11","modified_gmt":"2017-04-24T13:12:11","slug":"%e4%b8%ad%e7%a7%91%e9%99%a2%e5%a4%a7%e5%8c%96%e6%89%80jacs-%e9%87%91%e5%b1%9e%e6%b0%a7%e5%8c%96%e7%89%a9%e8%a1%a8%e9%9d%a2%e5%a2%9e%e5%bc%baco2%e8%bf%98%e5%8e%9f","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=77229","title":{"rendered":"\u4e2d\u79d1\u9662\u5927\u8fde\u5316\u7269\u6240JACS: \u91d1\u5c5e\u6c27\u5316\u7269\u8868\u9762\u589e\u5f3aCO2\u8fd8\u539f"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u7535\u5316\u5b66\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\uff08CO2<\/sub>RR\uff09\u662f\u5c06\u4e8c\u6c27\u5316\u78b3\u8f6c\u5316\u4e3a\u71c3\u6599\u7684\u6709\u6548\u9014\u5f84\uff0c\u4f46\u8be5\u8fc7\u7a0b\u4e2d\u4ea7\u54c1\u7684\u9009\u62e9\u6027\u548c\u80fd\u91cf\u6548\u7387\u74f6\u9888\u4e00\u76f4\u8f83\u96be\u7a81\u7834\u3002\u901a\u5e38\u4e3a\u63d0\u9ad8\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5242\u50ac\u5316\u6548\u7387\uff0c\u7814\u7a76\u8005\u5728\u5176\u5f62\u6001\u3001\u5c3a\u5bf8\u548c\u7ed3\u6784\u8c03\u63a7\u65b9\u9762\u505a\u51fa\u4e86\u5f88\u5927\u52aa\u529b\u3002\u5728\u89e3\u51b3CO2<\/sub>\u5728\u91d1\u5c5e\u50ac\u5316\u5242\u8868\u9762\u5438\u9644\u5f31\u7684\u95ee\u9898\u65b9\u9762\u4e5f\u5728\u4e0d\u65ad\u63a2\u7d22\uff0c\u5305\u62ec\u4f7f\u7528\u79bb\u5b50\u6db2\u4f53\u6216\u5176\u4ed6\u7535\u89e3\u8d28\u589e\u5f3a\u4e8c\u6c27\u5316\u78b3\u5438\u9644\u3002\u4f46\u8fd9\u4e9b\u65b9\u6cd5\u5b58\u5728\u6210\u672c\u9ad8\u3001\u8fc7\u7a0b\u590d\u6742\u3001\u4ea7\u54c1\u5206\u79bb\u96be\u7b49\u7279\u70b9\u3002\u56e0\u6b64\uff0c\u9ad8\u6548\u3001\u6027\u80fd\u4f18\u5f02\u7684CO2<\/sub>RR\u50ac\u5316\u5242\u7684\u63a2\u7d22\u5907\u53d7\u5173\u6ce8\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u79d1\u9662\u5927\u8fde\u5316\u7269\u6240\u5305\u4fe1\u548c\u9662\u58eb\u3001\u6c6a\u56fd\u96c4\u6559\u6388\u3001\u6768\u5e06\u7814\u7a76\u5458\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u56e2\u961f<\/strong>\u5728JACS\u4e0a\u53d1\u8868\u7684\u201cEnhancing CO2<\/sub> Electroreduction with the Metal\u2212Oxide Interface<\/strong>\u201d\u63d0\u51fa\u7684\u9ad8\u6d3b\u6027Au-CeOx<\/sub>\u50ac\u5316\u5242\u5438\u5f15\u4e86\u4e0d\u5c11\u4eba\u7684\u773c\u7403\u3002Au-CeOx<\/sub>\u5177\u6709\u8f83\u9ad8\u7684CO2<\/sub>RR\u9009\u62e9\u6027\u548c\u50ac\u5316\u6d3b\u6027\uff0c\u4f5c\u8005\u901a\u8fc7\u7814\u7a76\u8bc1\u5b9eCO2<\/sub>\u7684\u5438\u9644\u548c\u6d3b\u5316\u5728Au-CeOx<\/sub>\u754c\u9762\u8fc7\u7a0b\u5360\u4e3b\u5bfc\u5730\u4f4d\uff0cAu-CeOx<\/sub>\u754c\u9762\u662fCO2<\/sub>\u6d3b\u5316\u5e76\u8fd8\u539f\u4e3aCO\u7684\u6d3b\u6027\u4f4d\u70b9\u3002Au\u548cCeOx<\/sub>\u7684\u534f\u540c\u4f5c\u7528\u6709\u5229\u4e8e\u63d0\u9ad8\u7fa7\u57fa\u4e2d\u95f4\u4f53\uff08*COOH\uff09\u7684\u7a33\u5b9a\u6027\uff0c\u4ece\u800c\u4fc3\u8fdbCO2<\/sub>RR\u3002\u4e14\u5728Ag-CeOx \/ C\u754c\u9762\u4e5f\u6709\u7c7b\u4f3c\u7684CO2<\/sub>RR\u754c\u9762\u589e\u5f3a\u6548\u5e94\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1. <\/strong>Au-CeOx<\/sub> \/ C<\/strong>\u50ac\u5316\u5242\u7684\u7ed3\u6784\u548c\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n

\"\"<\/strong><\/p>\n

\uff08a\uff09Au-CeOx \/ C\u50ac\u5316\u5242\u7684HRTEM\u56fe\uff1b<\/p>\n

CO2<\/sub>\u9971\u548c0.1M KHCO3<\/sub>\u7535\u89e3\u6db2\u4e2dAu \/ C\u3001CeOx \/ C\u548cAu-CeOx \/ C\u50ac\u5316\u5242\u8868\u9762\u4ea7\u751fCO\u7684<\/p>\n

\uff08b\uff09\u6cd5\u62c9\u7b2c\u6548\u7387\uff0c\uff08c\uff09\u5c40\u90e8\u51e0\u4f55\u7535\u6d41\u5bc6\u5ea6\uff0c\uff08d\uff09\u50ac\u5316\u6d3b\u6027\u5bf9\u6bd4\uff1b\u4ee5\u53ca\u5176\u7535\u4f4d\u7684\u4f9d\u8d56\u89c4\u5f8b\u3002<\/p>\n

\u5c3d\u7ba1Au-CeOx \/ C\u7684\u7535\u5316\u5b66\u6d3b\u6027\u9762\u79ef\u8f83\u5c0f\uff0c\u4f46\u5176\u8868\u9762\u6cd5\u62c9\u7b2c\u6548\u7387\u53ef\u8fbe89.1%\uff0c\u51e0\u4f55\u7535\u6d41\u5bc6\u5ea6\u662fAu \/ C\u8868\u9762\u76841.6\u500d\u3002<\/p>\n

\u56fe<\/strong>2.<\/strong> CeOx<\/sub> \/ Au<\/strong>\uff08<\/strong>111<\/strong>\uff09\u548c<\/strong>CO2<\/sub><\/strong>\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u8868\u5f81<\/strong><\/p>\n

\"\"<\/strong><\/p>\n

CeOx-Au\uff08111\uff09\u754c\u976278 K\u5438\u9644CO2<\/sub>\u524d\uff08a\uff0cb\uff09\u540e\uff08c\uff0cd\uff09\u7684STM\u56fe\u50cf\u5bf9\u6bd4\uff1b\uff08b\uff09\u548c\uff08d\uff09\u4e3a\u5bf9\u5e94\u533a\u57df\u7684\u653e\u5927\u56fe\u3002<\/p>\n

\uff08e\uff0cf\uff0978 K \u5ef6\u65f6CeOx<\/sub>\u5438\u6536CO2<\/sub>\u7684\u00a0STM\u56fe\u50cf\u3002\u53ef\u4ee5\u770b\u51faCO2<\/sub>\u5438\u9644\u4ece\u754c\u9762\u5f00\u59cb\uff0c\u6269\u5c55\u5230CeOx<\/sub>\u7684\u8868\u9762\uff0c\u76f4\u5230\u5168\u90e8\u8986\u76d6\u3002<\/p>\n

\u56fe<\/strong>3. CeOx<\/sub> \/ Au<\/strong>\uff08<\/strong>111<\/strong>\uff09\u548c<\/strong>CO2<\/sub> \/ H2<\/sub>O<\/strong>\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528<\/strong><\/p>\n

\"\"<\/strong><\/p>\n

\uff08a\uff09\u66b4\u9732\u4e8eCO2<\/sub>\u548cH2<\/sub>O\u540eCeOx \/ Au\uff08111\uff09\u7684C1s\u5149\u8c31\u53d8\u5316\uff08h\u03bd= 400eV\uff09\uff1b<\/p>\n

\uff081\uff1a\u5728110K\u4e0b\u66b4\u9732\u4e8e15L CO2<\/sub>\u4e2d\uff0c\u968f\u540e\u5728\u7279\u9ad8\u538b\u4e0b\u9000\u706b\u81f3200K\uff081a\uff09\u548c300K\uff081b\uff09\uff1b2\uff1a\u5728110K\u66b4\u9732\u4e8e15 L\u7684CO2<\/sub>\u548c3L\u7684H 2<\/sub> O\uff0c\u7136\u540e\u7279\u9ad8\u538b\u9000\u706b\u81f3200K\uff082a\uff09\u548c300K\uff082b\uff09; 3\uff1a\u5728300 K\u66b4\u9732\u4e8e500L CO2<\/sub>\u548c50L H2<\/sub>O\uff09\u3002<\/p>\n

\uff08b\uff09CeOx<\/sub>\u6c27\u5316\u6001\u53d8\u5316\u7684\u6bd4\u8f83\uff0c\u5bf9\u6bd4\u4e0a\u8ff0\u5904\u7406\u524d\u540e\u5bc6\u5ea6\u6bd4\uff08D\uff08Ce3+<\/sup>\uff09\/ D\uff08Ce4+<\/sup>\uff09\uff09\u7684\u53d8\u5316\u3002<\/p>\n

\u6c34\u5728Ce3+<\/sup>\u754c\u9762\u4f4d\u70b9\u7684\u89e3\u79bb\u4fc3\u8fdb\u8868\u660e\u7f9f\u57fa\u7684\u5f62\u6210\uff0c\u4ece\u800c\u4f7f\u9000\u706b\u8fc7\u7a0b\u4e2d\u6676\u683c\u6c27\u66f4\u5bb9\u6613\u8131\u9664\u3002CO2<\/sub>\u03b4<\/sup>–<\/sup>\u5728CeOx<\/sub> \/ Au\uff08111\uff09\u8868\u9762\u7684\u7a33\u5b9a\u5438\u9644\u53ef\u4fc3\u8fdb\u6c22\u5316\u8fc7\u7a0b\u7684\u8fdb\u884c\u3002<\/p>\n

\u56fe<\/strong>4. CO2<\/sub>RR<\/strong>\u8fc7\u7a0b\u5728<\/strong>Au<\/strong>\uff08<\/strong>111<\/strong>\uff09\u548c<\/strong>Ce3O7H7 \/ Au<\/strong>\uff08<\/strong>111<\/strong>\uff09\u8868\u9762<\/strong>DFT<\/strong>\u8ba1\u7b97<\/strong><\/p>\n

\"\"<\/strong><\/p>\n

\uff08a\uff09\u4e3b\u8981\u4e2d\u95f4\u4f53\u7ed3\u6784\u4f18\u5316\u793a\u610f\u56fe\u3002<\/p>\n

\uff08b\uff09\u81ea\u7531\u80fd\u8ba1\u7b97\u56fe\u3002 \u8d28\u5b50\u5316\u4ea7\u751f*COOH\u7684\u8fc7\u7a0b\u4e3a\u4e3b\u8981\u901f\u63a7\u6b65\u9aa4\uff0c\u8be5\u8fc7\u7a0b\u5728Ce3<\/sub>O7<\/sub>H7<\/sub>\/Au(111)\u8868\u9762\u8f83\u6613\u53d1\u751f\uff0c\u81ea\u7531\u80fd\u4ec50.33eV\u3002\u4e14*COOH \u8f6c\u5316\u4e3a *CO\u4ee5\u53ca*CO\u7684\u8131\u9644\u8fc7\u7a0b\u5728Au\u2212CeOx<\/sub>\u754c\u9762\u5747\u8f83\u6613\u53d1\u751f\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u672c\u6587\u65b0\u53d1\u73b0\u7684Au\u2212CeOx<\/sub>\u50ac\u5316\u5242\u4e0d\u4ec5\u53ef\u6fc0\u6d3b\u5176\u754c\u9762\u4f4d\u70b9CO2<\/sub>\u7684\u6d3b\u6027\u540c\u65f6\u53ef\u4ee5\u4fc3\u8fdbCO2<\/sub>\u5728CeOx<\/sub>\u8868\u9762\u7684\u5438\u9644\uff1bCO2<\/sub>\u03b4<\/sup>–<\/sup>\u7684\u7a33\u5b9a\u5b58\u5728\u4ee5\u53ca*COOH\u5f62\u6210\u81ea\u7531\u80fd\u7684\u964d\u4f4e\u548c\u5438\u9644\u7a33\u5b9a\u6027\u7684\u63d0\u9ad8\u66f4\u6709\u5229\u4e8e\u4fc3\u8fdbCO2<\/sub>RR\u8fc7\u7a0b\u3002\u56e0\u6b64\uff0c\u8be5\u7814\u7a76\u63d0\u51fa\u7684\u91d1\u5c5e\u6c27\u5316\u7269\u754c\u9762\u7684\u72ec\u7279\u50ac\u5316\u6027\u80fd\u5c06\u66f4\u597d\u5730\u4fc3\u8fdb\u4e8c\u6c27\u5316\u78b3\u6392\u7684\u51cf\u6392\uff0c\u4e3a\u8bbe\u8ba1\u9ad8\u6548\u7535\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u65b0\u7684\u9014\u5f84\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Enhancing CO2<\/sub> Electroreduction with the Metal\u2212Oxide Interface<\/a>\uff08JACS\uff0c2017\uff0cDOI: 10.1021\/jacs.7b00102\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4 Starkle\u00a0\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4\u00a0422065952\u201d\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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