{"id":76728,"date":"2017-04-21T06:30:41","date_gmt":"2017-04-20T22:30:41","guid":{"rendered":"\/\/m.iemloyee.com\/?p=76728"},"modified":"2017-04-19T19:44:15","modified_gmt":"2017-04-19T11:44:15","slug":"%e5%8d%97%e4%ba%ac%e5%a4%a7%e5%ad%a6%ef%bc%9a%e5%9f%ba%e4%ba%8e%e5%9b%9b%e7%a1%ab%e5%af%8c%e7%93%a6%e7%83%af%e9%85%8d%e4%bd%93%e7%9a%84%e5%85%89%e7%94%b5%e8%bd%ac%e6%8d%a2%e6%80%a7%e8%87%aa%e6%97%8b","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=76728","title":{"rendered":"Angew. Chem. Int. Ed.\u5357\u4eac\u5927\u5b66\uff1a\u57fa\u4e8e\u56db\u786b\u5bcc\u74e6\u70ef\u914d\u4f53\u7684\u5149\u7535\u8f6c\u6362\u6027\u81ea\u65cb\u4ea4\u53c9Fe(II) -MOF"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u8fd1\u5e74\u6765\uff0c\u5728\u591a\u9886\u57df\u5177\u6709\u6f5c\u5728\u5e94\u7528\u4ef7\u503c\u7684\u591a\u5b54MOFs\u53ca\u5176\u8bbe\u8ba1\u548c\u7814\u7a76\u5f15\u8d77\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u6539\u53d8\u91d1\u5c5e\u4e2d\u5fc3\u548c\u914d\u4f53\u4e3aMOFs\u6750\u6599\u7684\u7ed3\u6784\u7684\u8c03\u63a7\u53ca\u7814\u7a76\u7ed3\u6784-\u6027\u8d28\u5173\u7cfb\u63d0\u4f9b\u4e00\u79cd\u6e20\u9053\u3002\u4eba\u4eec\u7528\u5404\u79cd\u5404\u6837\u7684\u91d1\u5c5e\u4e2d\u5fc3\u4ee5\u4e0d\u540c\u7684\u6761\u4ef6\u5408\u6210\u591a\u529f\u80fdMOFs\u4ece\u800c\u4f7f\u5f97\u6750\u6599\u7684\u7ed3\u6784\u80fd\u6ee1\u8db3\u67d0\u79cd\u5e94\u7528\u6240\u9700\u7684\u6027\u8d28\u3002\u6bd4\u5982\u57fa\u4e8eFeII<\/sup>-\u548cCoII<\/sup>-\u7684\u4e00\u7cfb\u5217MOF\u4e2d\uff0c\u4f4e\u81ea\u65cb(LS)\u548c\u9ad8\u81ea\u65cb(HS)\u6001\u7684\u53ef\u9006\u8f6c\u6362\u4f7f\u5f97\u6750\u6599\u5177\u6709\u81ea\u65cb\u4ea4\u53c9\u6027\uff0c\u4ece\u800c\u5728\u6570\u636e\u50a8\u5b58\u548c\u663e\u793a\u5668\u8bbe\u5907\u7b49\u79d1\u6280\u5e94\u7528\u4e2d\u5177\u6709\u6f5c\u5728\u4ef7\u503c\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5357\u4eac\u5927\u5b66\u5316\u5b66\u5316\u5de5\u5b66\u9662\u5148\u8fdb\u5fae\u7ed3\u6784\u534f\u4f5c\u521b\u65b0\u4e2d\u5fc3\uff0c\u914d\u4f4d\u5316\u5b66\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u5de6\u666f\u6797\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\u5728Angew. Chem. Int. Ed.<\/strong>\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u9898\u4e3a\u201cPhoto- and Electronically Switchable Spin-Crossover Iron(II) Metal\u2013Organic Frameworks Based on a Tetrathiafulvalene Ligand<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u8be5\u7814\u7a76\u7ec4\u901a\u8fc7\u5f15\u5165\u5177\u6709\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u7684\u56db\u786b\u5bcc\u74e6\u70ef\u914d\u4f53(TTF-(py)4<\/sub>)\u548c\u81ea\u65cb\u4ea4\u53c9\u7684\u4e8c\u4ef7\u94c1\u4e2d\u5fc3\u6784\u5efa\u4e86\u4e24\u4f8b\u4e09\u7ef4MOFs\uff0c\u4f7f\u5f97\u8be5\u7c7b\u6750\u6599\u540c\u65f6\u5177\u5907\u70ed\u529b\u5b66\u548c\u5149\u8bf1\u5bfc\u81ea\u65cb\u4ea4\u53c9\u6027(SCO)\u548c\u6c27\u5316\u8fd8\u539f\u6027\u3002\u6b64\u5916\u8be5\u7814\u7a76\u7ec4\u5c06\u8be5\u5355\u6676\u6750\u6599\u5438\u9644I2<\/sub>\u4ece\u800c\u8bf1\u5bfc\u5355\u6676\u5230\u5355\u6676\u7684\u8f6c\u53d8\u5e76\u786e\u5b9a\u4e86\u6700\u7ec8\u7684\u5355\u6676\u7ed3\u6784\u3002\u901a\u8fc7\u8fd9\u79cd\u6c27\u5316\u6027\u63ba\u6742\u4f7f\u5f97\u7531\u6846\u67b6\u7684\u7535\u5b50\u6001\u8c03\u5236\u7684\u5bfc\u7535\u6027\u660e\u663e\u52a0\u5f3a\uff08\u9ad8\u8fbe3\u4e2a\u6570\u91cf\u7ea7\uff09\uff0c\u81ea\u65cb\u4ea4\u53c9\u6027\u4e5f\u56e0\u6b64\u6539\u53d8\uff0c\u5e76\u4e14\u6846\u67b6\u7684\u9ad8\u78c1\u6027\u5f00\u5173\u8868\u73b0\u4e3a\u201c\u5173\u201d\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1\uff1a\u56db\u786b\u5bcc\u74e6\u70ef\u914d\u4f53(TTF-(py)4<\/sub>)\u53ca\u4e0eFeII<\/sup> \u81ea\u7ec4\u88c5\u5f97\u5230\u5316\u5408\u72691\u7684\u5355\u6676\u7ed3\u6784<\/strong><\/p>\n

\"\"<\/sup><\/p>\n

(a)\u56db\u786b\u5bcc\u74e6\u70ef\u914d\u4f53(TTF-(py)4<\/sub>)\u7ed3\u6784\u793a\u610f\u56fe\uff1b<\/p>\n

(b)\u5316\u5408\u72691\u4e2d\u4f4d\u4e8eFeII<\/sup> \u5468\u56f4\u7684\u516b\u9762\u4f53\u914d\u4f4d\u73af\u5883\uff1b<\/p>\n

(c)\u5316\u5408\u72691\u7684\u4e8c\u7ef4\u7a7f\u63d2\u7f51\u683c\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe2\uff1a\u5316\u5408\u72691\u5438\u9644I2<\/sub>\u4ece\u800c\u8bf1\u5bfc\u5355\u6676\u5230\u5355\u6676\u7684\u8f6c\u53d8\u53ca\u5355\u6676\u7ed3\u6784\u53d8\u5316<\/strong><\/p>\n

\"\"<\/p>\n

(a)\u5316\u5408\u72692\u4e2d\u4f4d\u4e8eFeII<\/sup> \u5468\u56f4\u7684\u516b\u9762\u4f53\u914d\u4f4d\u73af\u5883\uff1b<\/p>\n

(b)\u5316\u5408\u72692\u6cbfc\u8f74\u65b9\u5411\u7684\u4e09\u7ef4\u7f51\u683c\u7ed3\u6784\uff1b<\/p>\n

(c)\u5316\u5408\u72692@I2<\/sub>\u6cbfb\u8f74\u65b9\u5411\u7684\u4e09\u7ef4\u7f51\u683c\u7ed3\u6784\u3002<\/p>\n

\u56fe3\uff1a\u8be5\u4f53\u7cfbFeII<\/sup> -MOFs\u7684\u78c1\u6027\u7814\u7a76<\/strong><\/p>\n

\"\"
\n (a)\u5316\u5408\u72691\uff0c2\u548c\u5149\u6fc0\u53d1\u540e\u7684\u5316\u5408\u72692\u968f\u6e29\u5ea6\u53d8\u5316\u7684\u03a7M<\/sub> T\u56fe\uff1b<\/p>\n

(b)\u5316\u5408\u72692\u548c\u5438\u9644I2<\/sub>\u540e\u5316\u5408\u72692@I2<\/sub>\u968f\u6e29\u5ea6\u53d8\u5316\u7684\u03a7M<\/sub> T\u56fe\u3002<\/p>\n

\u56fe4\uff1a\u5316\u5408\u72691\u7684\u5149\u7535\u6027\u8d28<\/strong><\/p>\n

\"\"<\/p>\n

\u4ece0\u52301.3V\u8303\u56f4\u5185\u5316\u5408\u7269\u7684\u7d2b\u5916\u53ef\u89c1\u5149\u8c31\u56fe\u3002<\/p>\n

\u3010\u5c55\u671b\u3011<\/strong><\/p>\n

\u8fd9\u79cd\u901a\u8fc7\u5ba2\u4f53\u8bf1\u5bfc\u548c\u6c27\u5316\u8fd8\u539f\u6001\u8f6c\u6362\u7684\u65b9\u6cd5\u4e3a\u8c03\u8c10\u6846\u67b6\u7684\u81ea\u65cb\u6001\u548c\u5bfc\u7535\u6027\u63d0\u4f9b\u4e00\u79cd\u65b0\u7b56\u7565\u3002\u6216\u8bb8\u5bf9\u4e8e\u8be5\u7c7bMOF\u7684\u7814\u53d1\u5728\u7814\u7a76\u624b\u6bb5\u3001\u65b9\u5411\u548c\u8868\u5f81\u65b9\u5f0f\u4f1a\u6709\u66f4\u5927\u7684\u521b\u65b0\u7a7a\u95f4\u3002<\/p>\n

\u3010\u6587\u732e\u4fe1\u606f\u3011<\/strong><\/p>\n

\u6587\u732e\u8fde\u63a5\uff1a<\/strong>Photo- and Electronically Switchable Spin-Crossover Iron(II) Metal\u2013Organic Frameworks Based on a Tetrathiafulvalene Ligand<\/a>(Angew. Chem. Int. Ed.\uff0c2017\uff0cDOI\uff1a10.1002\/ange.201611824)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u7ec4\u7f51\u8001\u742a\u742a<\/strong>\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002\u6b22\u8fce\u52a0\u5165\u6750\u6599\u4ebaMOF\u5b66\u672f\u4ea4\u6d41\u7fa4\uff08120199039\uff09\uff01<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002\u6750\u6599\u4eba\u7f51\u5c0a\u91cd\u6240\u6709\u8fdb\u884c\u77e5\u8bc6\u4f20\u64ad\u7684\u5a92\u4f53\uff0c\u8f6c\u8f7d\u8bf7\u8054\u7cfbtougao@cailiaoren.com<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u8fd1\u5e74\u6765\uff0c\u5728\u591a\u9886\u57df\u5177\u6709\u6f5c\u5728\u5e94\u7528\u4ef7\u503c\u7684\u591a\u5b54MOFs\u53ca\u5176\u8bbe\u8ba1\u548c\u7814\u7a76\u5f15\u8d77\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u6539\u53d8\u91d1\u5c5e\u4e2d\u5fc3\u548c\u914d\u4f53\u4e3aMOFs\u6750\u6599\u7684\u7ed3\u6784\u7684\u8c03\u63a7\u53ca\u7814\u7a76\u7ed3\u6784-\u6027\u8d28\u5173\u7cfb\u63d0\u4f9b\u4e00\u79cd…<\/p>\n","protected":false},"author":1123,"featured_media":76744,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[245],"class_list":["post-76728","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-mof"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/76728"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/1123"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=76728"}],"version-history":[{"count":8,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/76728\/revisions"}],"predecessor-version":[{"id":76874,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/76728\/revisions\/76874"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/76744"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=76728"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=76728"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=76728"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}