{"id":76725,"date":"2017-04-23T06:30:48","date_gmt":"2017-04-22T22:30:48","guid":{"rendered":"\/\/m.iemloyee.com\/?p=76725"},"modified":"2017-04-23T15:45:49","modified_gmt":"2017-04-23T07:45:49","slug":"angew-chem-int-ed-%ef%bc%9a%e6%97%a0%e6%b6%b2%e4%bd%93%e7%94%b5%e8%a7%a3%e8%b4%a8%e6%9f%94%e6%80%a7li-co2-%e7%94%b5%e6%b1%a0","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=76725","title":{"rendered":"Angew. Chem. Int. Ed.\uff1a\u65e0\u6db2\u4f53\u7535\u89e3\u8d28\u67d4\u6027Li-CO2 \u7535\u6c60"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

CO2<\/sub>\u7b49\u6e29\u5ba4\u6c14\u4f53\u7684\u5927\u91cf\u6392\u653e\u662f\u5f15\u8d77\u5168\u7403\u53d8\u6696\u7684\u4e3b\u8981\u539f\u56e0\u3002\u5728CO2<\/sub>\u7684\u5faa\u73af\u5229\u7528\u65b9\u9762\uff0cLi-CO2<\/sub>\u7535\u6c60\u7531\u4e8e\u5176\u5177\u5907\u80fd\u91cf\u5bc6\u5ea6\u9ad8\u3001\u73af\u5883\u53cb\u597d\u7b49\u4f18\u70b9\uff0c\u56e0\u800c\u5e94\u7528\u524d\u666f\u5f02\u5e38\u5e7f\u9614\u3002\u76ee\u524d\u6240\u62a5\u9053\u7684Li-CO2<\/sub>\u7535\u6c60\u5747\u4f7f\u7528\u6db2\u4f53\u7535\u89e3\u8d28\uff0c\u5b58\u5728\u7535\u89e3\u8d28\u6cc4\u6f0f\u7684\u98ce\u9669\uff0c\u800c\u4e14\u8fd8\u7f3a\u4e4f\u9002\u5408\u7684\u7535\u6781\u7ed3\u6784\uff0c\u56e0\u800c\u6ee1\u8db3\u4e0d\u4e86\u53ef\u7a7f\u6234\u7535\u5b50\u8bbe\u5907\u5bf9\u5b89\u5168\u6027\u548c\u67d4\u6027\u7684\u9700\u6c42\u3002\u5728Li-CO2<\/sub>\u7535\u6c60\u9886\u57df\uff0c\u65e0\u6db2\u4f53\u7535\u89e3\u8d28\u7684\u7814\u53d1\u5bf9\u5177\u6709\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u5168\u56fa\u6001Li-CO2<\/sub>\u7535\u6c60\u800c\u8a00\u662f\u91cd\u4e2d\u4e4b\u91cd\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5357\u5f00\u5927\u5b66\u7684\u9648\u519b\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u5728Angew. Chem. Int. Ed.<\/strong> \u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cFlexible Li-CO2<\/sub> Batteries with Liquid-Free Electrolyte<\/strong>\u201d\u7684\u6587\u7ae0\uff0c\u62a5\u9053\u4e86\u4e00\u79cd\u65e0\u6db2\u4f53\u7535\u89e3\u8d28\u7684\u67d4\u6027Li-CO2<\/sub>\u7535\u6c60\uff0c\u91c7\u7528\u805a\u7532\u57fa\u4e19\u70ef\u9178\u916f(PMA)\/\u805a\u4e59\u4e8c\u9187(PEG)-LiClO4<\/sub>-3 wt% SiO2<\/sub>\u590d\u5408\u805a\u5408\u7269\u7535\u89e3\u8d28(CPE)\u548c\u591a\u5c42\u78b3\u7eb3\u7c73\u7ba1(CNTs)\u7ed3\u6784\u9634\u6781\u3002\u8be5\u7535\u6c60\u7ed3\u6784\u7a33\u5b9a\uff0c\u754c\u9762\u7535\u963b\u8f83\u5c0f\uff0c100\u6b21\u5145\u653e\u7535\u5faa\u73af\u540e\uff0c\u5176\u6bd4\u5bb9\u91cf\u4f9d\u7136\u4fdd\u6301\u4e3a1000 mAhg-1<\/sup>\u3002\u6b64\u5916\uff0c\u7814\u7a76\u4eba\u5458\u5bf9\u5c3a\u5bf8\u4e3a5*16 cm2<\/sup>\u7684\u7ec4\u88c5\u7535\u6c60\u8fdb\u884c\u4e86\u7535\u5316\u5b66\u6027\u80fd\u6d4b\u8bd5\uff0c\u5728\u4e0d\u540c\u5f2f\u66f2\u7a0b\u5ea6(0-360o<\/sup>)\u4e0b\uff0c\u8be5\u7535\u6c60\u6027\u80fd\u4f18\u5f02\uff0c\u5145\u53d1\u7535\u5bb9\u91cf\u53ef\u8fbe993.3 mA\u00b7h\uff0c\u80fd\u91cf\u5bc6\u5ea6\u9ad8\u8fbe521 Wh\u02d9kg-1<\/sup>\uff0c\u5de5\u4f5c\u65f6\u95f4\u957f\u8fbe220 h\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1 <\/strong>\u5168\u56fa\u6001<\/strong>Li-CO2<\/sub><\/strong>\u7535\u6c60\u7684\u7ed3\u6784\u793a\u610f\u56fe\u53ca\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a) <\/strong>Li-CO2<\/sub>\u7535\u6c60\u7ed3\u6784\u793a\u610f\u56fe\uff1a\u9502\u7b94\u4f5c\u4e3a\u8d1f\u6781\uff0cCPE@CNTs\u4f5c\u4e3a\u6b63\u6781\uff1b<\/p>\n

(b) <\/strong>Li\/CPE@CNTs \u7684SEM\u56fe\u50cf\uff1b<\/p>\n

(c,d) <\/strong>\u56fe(b)\u5bf9\u5e94\u7ed3\u6784\u7684EDX\u8868\u5f81\uff1a\u5143\u7d20\u5206\u5e03\u56fe\uff1b<\/p>\n

(e) <\/strong>CNTs\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

(f) <\/strong>CNTs\u7684HRTEM\u56fe\u50cf\uff0c\u6676\u683c\u95f4\u8ddd\u4e3a0.34 nm\uff1b<\/p>\n

(g) <\/strong>CPE@CNTs\u754c\u9762\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

(h,i) <\/strong>\u4e24\u79cd\u4e0d\u540c\u7535\u89e3\u8d28\u7535\u6c60\u7684\u6cc4\u9732\u6d4b\u8bd5\uff1aCPE\u548c1M<\/sub> LiClO4<\/sub>\/TEGDME \u6eb6\u6db2\uff0c(h)\u4e3a\u6d4b\u8bd5\u524d\uff0c(i)\u4e3a\u6d4b\u8bd5\u540e\u3002<\/p>\n

\u56fe<\/strong>2 CPE<\/strong>\u7535\u89e3\u8d28\u7684\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a) <\/strong>CPE\u7684\u5206\u5b50\u7ed3\u6784\u5f0f\uff1b<\/p>\n

(b, c) <\/strong>CPE\u6eb6\u6db2\u3001CNTs\u9634\u6781\u4e0a\u7684CPE\u819c\uff1b<\/p>\n

(d) <\/strong>\u7eb3\u7c73SiO2<\/sub>\u586b\u5145\u6599\u7684\u5c3a\u5bf8\u5206\u5e03\u53caSiO2<\/sub>\u7684HRTEM\u56fe\u50cf\uff1b<\/p>\n

(e) <\/strong>55o<\/sup>C\u4e0b\u586b\u5145\u6599\u7684\u542b\u91cf\u5bf9CPE\u7684Li\u79bb\u5b50\u4f20\u5bfc\u6027\u7684\u5f71\u54cd\u66f2\u7ebf\uff1b<\/p>\n

(f) <\/strong>CPE\u76841<\/sup>H NMR\u5149\u8c31\u56fe\uff1b<\/p>\n

(g, h)<\/strong> CPE\u8584\u819c\u7684SEM\u56fe\u50cf\uff1a(g)\u9876\u89c6\u56fe\u3001(h)\u4fa7\u89c6\u56fe\uff1b<\/p>\n

(i) <\/strong>CPE\u7684\u6768\u6c0f\u6a21\u91cf\u8868\u5f81\uff1b<\/p>\n

(j) <\/strong>CPE\u8868\u9762\u7684\u4e09\u7ef4AFM\u56fe\u50cf\u3002<\/p>\n

\u56fe<\/strong>3 <\/strong>\u5728<\/strong>2.5mA<\/strong>\u4e0b\uff0c<\/strong>Li-CO2<\/sub><\/strong>\u7535\u6c60\u7684\u5f2f\u66f2\u548c\u626d\u8f6c\u6027\u80fd\u6d4b\u8bd5<\/strong><\/p>\n

\"\"<\/p>\n

(a,b)<\/strong> \u65e0\u5f2f\u66f2\u3001\u626d\u8f6c\u72b6\u6001\u4e0b\uff0c\u8be5\u7535\u6c60\u7684\u5faa\u73af\u6d4b\u8bd5\u56fe\uff1b<\/p>\n

(c,d) <\/strong>\u5f2f\u66f2180o<\/sup>\u72b6\u6001\u4e0b\uff0c\u8be5\u7535\u6c60\u7684\u5faa\u73af\u6d4b\u8bd5\u56fe\uff1b<\/p>\n

(e,f)<\/strong> \u626d\u8f6c180o<\/sup>\u72b6\u6001\u4e0b\uff0c\u8be5\u7535\u6c60\u7684\u5faa\u73af\u6d4b\u8bd5\u56fe\u3002<\/p>\n

\u56fe<\/strong>4 <\/strong>\u653e\u7535\u4ea7\u7269\u5206\u6790<\/strong><\/p>\n

\"\"<\/p>\n

(a)<\/strong> \u539f\u4f4d\u62c9\u66fc\u6d4b\u8bd5\u88c5\u7f6e\u7684\u8bbe\u8ba1\uff1b<\/p>\n

(b)<\/strong>\u539f\u4f4d\u62c9\u66fc\u88c5\u7f6e\u7684\u5149\u5b66\u663e\u5fae\u8c31\u56fe\uff0c\u6d4b\u8bd5\u6761\u4ef6\uff1a\u7269\u955c\u653e\u5927\u500d\u6570\u4e3a50\u500d\u3001\u76ee\u955c\u653e\u5927\u500d\u6570\u4e3a10\u500d\uff1b<\/p>\n

(c)<\/strong> \u572850 mAg-1<\/sup>\u4e0b\u7684\u5145\u653e\u7535\u8fc7\u7a0b\uff0c 16\u4e2a\u4e0d\u540c\u72b6\u6001\u53ca\u5176\u5bf9\u5e94\u7684\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\uff1b<\/p>\n

(d)<\/strong>\u5145\u653e\u7535\u524d\u540eCPE@CNTs\u6b63\u6781\u7684XRD\u56fe\u8c31\uff1b<\/p>\n

(e)<\/strong> \u5145\u653e\u7535\u5faa\u73af\u6d4b\u8bd5\u540e\uff0c\u7535\u6c60\u7ec4\u6210\u7ed3\u6784\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

(f) <\/strong>\u7535\u5316\u5b66\u6d4b\u8bd5\u5b8c\u6210\u540e\uff0c\u7c98\u9644\u5728\u4e00\u8d77\u7684\u6b63\u8d1f\u6781\u7535\u5b50\u7167\u7247\uff0cLi\u6b63\u6781\u9644\u7740\u5728CPE@CNTs\u6b63\u6781\u4e4b\u4e0a\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u672c\u6587\u62a5\u9053\u4e86\u4e00\u79cd\u5168\u56fa\u6001Li-CO2<\/sub>\u7535\u6c60\uff0c\u8be5\u7535\u6c60\u91c7\u7528Li\/PMA\/PEG -LiClO4<\/sub>– 3wt% SiO2<\/sub>@CNTs \u4f5c\u4e3a\u7535\u89e3\u8d28-\u6b63\u6781\u7ed3\u6784\uff0c\u5177\u5907\u6bd4\u5bb9\u91cf\u9ad8\u3001\u80fd\u91cf\u5bc6\u5ea6\u5927\u548c\u8fd0\u884c\u65f6\u95f4\u957f\u7b49\u4f18\u70b9\u3002\u6b64\u9879\u6210\u679c\u5bf9\u4e8e\u7814\u7a76\u66f4\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684Li-CO2<\/sub>\u7535\u6c60\uff0c\u63d0\u9ad8\u7535\u6c60\u7684\u5b89\u5168\u6027\u4ee5\u53ca\u67d4\u6027\u5177\u6709\u975e\u5e38\u91cd\u8981\u7684\u610f\u4e49\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Flexible Li-CO2<\/sub> Batteries with Liquid-Free Electrolyte<\/a>\uff08Angew. Chem. Int. Ed.\uff0c2017, DOI:10.1002\/anie.201701928\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u9501\u6653\u9759\u7f16\u8bd1\uff0c\u8d75\u98de\u9f99\u5ba1\u6838\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a> \uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 CO2\u7b49\u6e29\u5ba4\u6c14\u4f53\u7684\u5927\u91cf\u6392\u653e\u662f\u5f15\u8d77\u5168\u7403\u53d8\u6696\u7684\u4e3b\u8981\u539f\u56e0\u3002\u5728CO2\u7684\u5faa\u73af\u5229\u7528\u65b9\u9762\uff0cLi-CO2\u7535\u6c60\u7531\u4e8e\u5176\u5177\u5907\u80fd\u91cf\u5bc6\u5ea6\u9ad8\u3001\u73af\u5883\u53cb\u597d\u7b49\u4f18\u70b9\uff0c\u56e0\u800c\u5e94\u7528\u524d\u666f\u5f02\u5e38\u5e7f\u9614…<\/p>\n","protected":false},"author":230,"featured_media":76730,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-76725","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/76725"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/230"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=76725"}],"version-history":[{"count":7,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/76725\/revisions"}],"predecessor-version":[{"id":77058,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/76725\/revisions\/77058"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/76730"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=76725"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=76725"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=76725"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}