{"id":76140,"date":"2017-04-15T06:30:41","date_gmt":"2017-04-14T22:30:41","guid":{"rendered":"\/\/m.iemloyee.com\/?p=76140"},"modified":"2017-08-04T19:22:36","modified_gmt":"2017-08-04T11:22:36","slug":"%e7%86%8a%e5%ae%87%e6%9d%b0chem-soc-rev-%e6%9c%80%e6%96%b0%e7%bb%bc%e8%bf%b0%ef%bc%9a%e9%85%8d%e4%bd%8d%e5%8c%96%e5%ad%a6%e5%9c%a8%e5%bc%82%e7%9b%b8%e5%85%89%e5%82%ac%e5%8c%96%e5%89%82%e8%ae%be","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=76140","title":{"rendered":"\u718a\u5b87\u6770Chem.Soc.Rev.\u6700\u65b0\u7efc\u8ff0\uff1a\u914d\u4f4d\u5316\u5b66\u5728\u5f02\u76f8\u5149\u50ac\u5316\u5242\u8bbe\u8ba1\u4e2d\u7684\u5e94\u7528\u8fdb\u5c55"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u4f5c\u4e3a\u5149\u50ac\u5316\u9886\u57df\u5185\u7684\u91cd\u8981\u5206\u652f\u4e4b\u4e00\uff0c\u5f02\u76f8\u50ac\u5316\u5177\u5907\u50ac\u5316\u5242\u6613\u5206\u79bb\u3001\u5faa\u73af\u5229\u7528\u7387\u9ad8\u7b49\u4f18\u70b9\uff0c\u56e0\u800c\u5728\u5316\u5b66\u5de5\u4e1a\u4e2d\u5f97\u4ee5\u5e7f\u6cdb\u5e94\u7528\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u5747\u76f8\u50ac\u5316\u5219\u5177\u5907\u50ac\u5316\u6d3b\u6027\u4f18\u5f02\u3001\u4ea7\u7269\u9009\u62e9\u6027\u9ad8\u3001\u5149\u5438\u6536\u53ef\u8c03\u63a7\u7b49\u4f18\u70b9\uff0c\u4f46\u50ac\u5316\u5242\u4e0d\u6613\u56de\u6536\u5229\u7528\uff0c\u56e0\u6b64\u8bbe\u8ba1\u540c\u65f6\u5177\u5907\u4e8c\u8005\u4f18\u70b9\u7684\u50ac\u5316\u5242\u662f\u76ee\u524d\u5149\u50ac\u5316\u9886\u57df\u5185\u7684\u4e3b\u8981\u7814\u7a76\u8d8b\u52bf\uff0c\u5176\u4e2d\u914d\u4f4d\u5316\u5b66\u7684\u5f15\u5165\u4e3a\u8be5\u9879\u8bbe\u8ba1\u7406\u5ff5\u63d0\u4f9b\u4e86\u4e00\u79cd\u73b0\u5b9e\u53ef\u884c\u6027\u3002<\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u4e2d\u56fd\u79d1\u6280\u5927\u5b66\u718a\u5b87\u6770\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u5728<strong>Chemical 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size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/\u7efc\u8ff0\u7ed3\u6784\u56fe.png\" alt=\"\" width=\"700\" height=\"384\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/\u7efc\u8ff0\u7ed3\u6784\u56fe.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/\u7efc\u8ff0\u7ed3\u6784\u56fe-300x165.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p style=\"text-align: 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loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-76176 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-1.png\" alt=\"\" width=\"600\" height=\"349\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-1-300x175.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe1 \u5149\u50ac\u5316\u8fc7\u7a0b\u793a\u610f\u56fe<\/strong><\/p>\n<p>\u5747\u76f8\u50ac\u5316\u4f53\u7cfb\u5728\u50ac\u5316\u52a8\u529b\u5b66\u4e0a\u4e0e\u5f02\u76f8\u50ac\u5316\u4e00\u822c\u65e0\u4e8c\uff0c\u4f46\u7a0d\u6709\u533a\u522b\u7684\u662f\u5728\u5747\u76f8\u50ac\u5316\u4e2d\uff0c\u5f80\u5f80\u4f1a\u6d89\u53ca\u5230\u5206\u5b50\u654f\u5316\u5242\u7684\u5f15\u5165\uff0c\u76f8\u6bd4\u4e8e\u56fa\u4f53\u534a\u5bfc\u4f53\u800c\u8a00\uff0c\u5206\u5b50\u654f\u5316\u5242\u5f80\u5f80\u5360\u636eHOMO\u548cLUMO\u80fd\u7ea7\u3002\u50ac\u5316\u5242\u5438\u6536\u5149\u5b50\u540e\uff0c\u7535\u5b50\u5c31\u4f1a\u4eceLUMO\u6fc0\u53d1\u5230HOMO\uff0c\u4ea7\u751f\u76f8\u5e94\u7684\u5149\u751f\u7535\u5b50\u7a7a\u7a74\u5bf9\uff0c\u7ee7\u800c\u8f6c\u79fb\u5230\u53cd\u5e94\u4f4d\u70b9\uff0c\u53c2\u4e0e\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u3002<\/p>\n<p>\u6574\u4e2a\u5149\u50ac\u5316\u8fc7\u7a0b\u53ef\u4ee5\u5927\u81f4\u5206\u4e3a\u4ee5\u4e0b\u4e09\u4e2a\u9636\u6bb5\uff1a<\/p>\n<p>I\uff0e\u5149\u5438\u6536\u4e2d\u5fc3\u5438\u6536\u5165\u5c04\u5149\u5b50\uff0c\u4ea7\u751f\u7535\u5b50\u7a7a\u7a74\u5bf9\uff1b<\/p>\n<p>II\uff0e\u5149\u751f\u7535\u5b50\u7a7a\u7a74\u5bf9\u7684\u5206\u79bb\u548c\u8f6c\u79fb\u5230\u50ac\u5316\u53cd\u5e94\u4f4d\u70b9\uff1b<\/p>\n<p>III\uff0e\u53cd\u5e94\u7269\u5728\u50ac\u5316\u5242\u8868\u9762\u7684\u5438\u9644\uff0c\u5728\u53cd\u5e94\u4f4d\u70b9\u5904\u53d1\u751f\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\uff1b<\/p>\n<p>\u5149\u5438\u6536\u4f5c\u4e3a\u8be5\u50ac\u5316\u53cd\u5e94\u4e00\u4e2a\u91cd\u8981\u7684\u51b3\u5b9a\u56e0\u7d20\uff0c\u5f80\u5f80\u4e0e\u534a\u5bfc\u4f53\u6750\u6599\u7684\u7981\u5e26\u5bbd\u5ea6\u8054\u7cfb\u5728\u4e00\u8d77\uff0c\u56e0\u800c\u5149\u50ac\u5316\u5242\u5728\u8bbe\u8ba1\u65f6 \uff0c\u901a\u5e38\u4f1a\u8003\u8651\u5230\u6750\u6599\u5bf9\u6574\u4e2a\u592a\u9633\u5149\u8c31\u6bb5\u7684\u5438\u6536\uff0c\u8f83\u5bbd\u7684\u5438\u6536\u6ce2\u6bb5\u53ef\u4ee5\u52a0\u5927\u5bf9\u592a\u9633\u80fd\u7684\u5229\u7528\u7387\u3002\u50ac\u5316\u80fd\u529b\u7684\u5927\u5c0f\u4e0e\u53cd\u5e94\u7269\u7684\u5438\u9644\u4e5f\u5b58\u5728\u4e00\u5b9a\u7684\u76f8\u5e72\u5173\u7cfb\uff0c\u56e0\u800c\u5728\u8bbe\u8ba1\u53cd\u5e94\u4f4d\u70b9\u65f6\uff0c\u4e5f\u4f1a\u8003\u8651\u5728\u5185 \u3002\u6b64\u5916\uff0c\u5149\u751f\u8f7d\u6d41\u5b50\u7684\u5206\u79bb\u548c\u8f93\u8fd0\u5bf9\u4e8e\u50ac\u5316\u53cd\u5e94\u800c\u8a00\uff0c\u5c24\u4e3a\u91cd\u8981\uff0c\u5206\u79bb\u548c\u8f93\u8fd0\u7684\u6548\u7387\u4e0e\u50ac\u5316\u5242\u7684\u50ac\u5316\u6d3b\u6027\u548c\u91cf\u5b50\u6548\u7387\u76f4\u63a5\u76f8\u5173\u3002<\/p>\n<p><strong>3. \u5149\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\u7684\u914d\u4f4d\u5316\u5b66\u8bbe\u8ba1<\/strong><\/p>\n<p>\u5149\u50ac\u5316\u7814\u7a76\u7684\u76ee\u7684\u5728\u4e8e\u8fdb\u4e00\u6b65\u6df1\u5165\u7406\u89e3\u5176\u5de5\u4f5c\u673a\u7406\u548c\u63d0\u9ad8\u53cd\u5e94\u6d3b\u6027\u4e0e\u4ea7\u7269\u9009\u62e9\u6027\u3002\u4e3a\u5b9e\u73b0\u8fd9\u4e00\u76ee\u7684\uff0c\u7814\u7a76\u4eba\u5458\u4e3a\u8bbe\u8ba1\u5177\u5907\u660e\u786e\u50ac\u5316\u4f4d\u70b9\u7684\u5f02\u76f8\u50ac\u5316\u5242\u505a\u4e86\u5927\u91cf\u7684\u7814\u7a76\u3002\u914d\u4f4d\u5316\u5b66\u4e3a\u6d3b\u6027\u4f4d\u70b9\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u4e00\u4e2a\u65b0\u7684\u7b56\u7565\uff0c\u4e3b\u8981\u5305\u542b\u4ee5\u4e0b\u4e09\u65b9\u9762\uff1a\u539f\u5b50\u7ea7\u5206\u6563\u53cd\u5e94\u4f4d\u70b9\u7684\u56fa\u5b9a\u3001\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\u7535\u5b50\u7ed3\u6784\u548c\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u7684\u8c03\u8282\u3002<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-76177 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-2.png\" alt=\"\" width=\"600\" height=\"703\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-2.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-2-256x300.png 256w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>2\u00a0<\/strong><strong>\u5149\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\u7684\u914d\u4f4d\u5316\u5b66\u8bbe\u8ba1<\/strong><\/p>\n<p style=\"text-align: left;\"><strong>\uff08a\uff09<\/strong>\u5728\u534a\u5bfc\u4f53\u8868\u9762\u4e0a\u951a\u5b9a\u5355\u4e2a\u91d1\u5c5e\u539f\u5b50\u7684\u793a\u610f\u56fe<\/p>\n<p style=\"text-align: left;\"><strong>\uff08b\uff09<\/strong>\u5728\u534a\u5bfc\u4f53\u8868\u9762\u4e0a\u6574\u5408\u5206\u5b50\u50ac\u5316\u5242<\/p>\n<p style=\"text-align: left;\"><strong>\uff08c\uff09<\/strong>\u5c06\u91d1\u5c5e\u539f\u5b50\u5206\u6563\u5728\u91d1\u5c5e-\u6709\u673a\u9aa8\u67b6<\/p>\n<p><strong>3.1\u00a0<\/strong><strong>\u539f\u5b50\u7ea7\u5206\u6563\u53cd\u5e94\u4f4d\u70b9\u7684\u56fa\u5b9a<\/strong><\/p>\n<p>\u5728\u8bbe\u8ba1\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\u65f6\uff0c\u5f80\u5f80\u4f1a\u91c7\u7528\u8d35\u91d1\u5c5e\u8d1f\u8f7d\u7684\u5171\u50ac\u5316\u65b9\u5f0f\uff0c\u63d0\u9ad8\u5f02\u76f8\u5149\u50ac\u5316\u5242\u6574\u4f53\u7684\u6548\u7387\uff0c\u5176\u4e2d\u8d35\u91d1\u5c5e\u7eb3\u7c73\u7c92\u5b50\u7684\u5f15\u5165\u4e3b\u8981\u662f\u5145\u5f53\u7535\u5b50\u5438\u6536\u5242\uff0c\u4ece\u800c\u964d\u4f4e\u5149\u751f\u8f7d\u6d41\u5b50\u7684\u590d\u5408\uff0c\u63d0\u4f9b\u9ad8\u6d3b\u6027\u4f4d\u70b9\u4ee5\u964d\u4f4e\u53cd\u5e94\u7684\u6d3b\u5316\u80fd\u3002<\/p>\n<p><strong>3.1.1 <\/strong><strong>\u534a\u5bfc\u4f53\u8868\u9762\u5355\u91d1\u5c5e\u539f\u5b50\u7684\u56fa\u5b9a<\/strong><\/p>\n<p>\u5728\u6c34\u6eb6\u6db2\u4e2d\uff0c\u91d1\u5c5e\u6c27\u5316\u7269\u9897\u7c92\u8868\u9762\u5f80\u5f80\u4f1a\u5305\u8986\u6709\u7f9f\u57fa\u57fa\u56e2\uff0c\u4f9d\u636e\u6eb6\u6db2\u4e0d\u540c\u7684pH\u503c\uff0c\u5176\u8868\u9762\u8fd8\u4f1a\u53d1\u751f\u6781\u5316\uff0c\u4ece\u5e26\u6709\u7535\u8377\u3002\u5728\u78b1\u6027\u6eb6\u6db2\u4e2d\uff0c\u91d1\u5c5e\u6c27\u5316\u7269\u9897\u7c92\u901a\u5e38\u4f1a\u5e26\u6709\u8d1f\u7535\u8377\uff0c\u901a\u8fc7\u8f83\u5f3a\u7684\u9759\u7535\u4f5c\u7528\uff0c\u91d1\u5c5e\u9633\u79bb\u5b50\u4f1a\u5438\u9644\u5230\u9897\u7c92\u8868\u9762\u3002\u7ecf\u8fc7\u540e\u7eed\u7684\u7145\u70e7\u548c\u8fd8\u539f\uff0c\u5355\u91d1\u5c5e\u539f\u5b50\u5c31\u4f1a\u901a\u8fc7\u79bb\u5b50\u952e\u7684\u5f62\u5f0f\u5728\u91d1\u5c5e\u6c27\u5316\u7269\u8868\u9762\u56fa\u5b9a\u4e0b\u6765\u3002\u5229\u7528\u8be5\u65b9\u6cd5\uff0c\u5df2\u7ecf\u5b9e\u73b0\u4e86Pt\u3001Pd\u3001Rh\u3001Ru\u7b49\u8d35\u91d1\u5c5e\u5728\u91d1\u5c5e\u6c27\u5316\u7269\u534a\u5bfc\u4f53\uff08\u5982TiO<sub>2<\/sub>\uff09\u8868\u9762\u7684\u6c89\u79ef\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-76178 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-3.png\" alt=\"\" width=\"600\" height=\"444\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-3.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-3-300x222.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>3 Pd\/TiO<sub>2<\/sub><\/strong><strong>\u590d\u5408\u5149\u50ac\u5316\u5242\u5206\u5e03\u5236\u5907\u793a\u610f\u56fe<\/strong><\/p>\n<p><strong>3.1.2 <\/strong><strong>\u534a\u5bfc\u4f53\u8868\u9762\u5206\u5b50\u50ac\u5316\u5242\u7684\u96c6\u6210<\/strong><\/p>\n<p>\u539f\u5b50\u7ea7\u91d1\u5c5e\u5728\u534a\u5bfc\u4f53\u8868\u9762\u7684\u5206\u6563\u8fd8\u6709\u53e6\u5916\u4e00\u79cd\u5b9e\u73b0\u9014\u5f84\uff0c\u5373\u5355\u6838\u91d1\u5c5e\u7edc\u5408\u7269\u3002\u6839\u636e\u4e0d\u540c\u7684\u5916\u5468\u914d\u4f53\uff0c\u91d1\u5c5e\u7edc\u5408\u50ac\u5316\u5242\u53ef\u5927\u81f4\u5206\u4e3a\u4e09\u7c7b\uff1a\u805a\u5421\u5576\u3001\u5927\u73af\u548c\u81a6\u3002\u91d1\u5c5e\u7edc\u5408\u7269\u5177\u5907\u591a\u91cd\u6c27\u5316\u8fd8\u539f\u6001\uff0c\u4e14\u53ef\u4ee5\u901a\u8fc7\u5e94\u7528\u4e8e\u4e0d\u540c\u50ac\u5316\u53cd\u5e94\u7684\u5916\u5468\u914d\u4f53\u8fdb\u884c\u8c03\u8282\u3002\u4e0e\u5355\u539f\u5b50\u91d1\u5c5e\u52a9\u50ac\u5316\u5242\u7c7b\u4f3c\uff0c\u91d1\u5c5e\u7edc\u5408\u7269\u4e0e\u534a\u5bfc\u4f53\u7684\u96c6\u6210\u88ab\u8ba4\u4e3a\u662f\u8fdb\u4e00\u6b65\u6539\u5584\u5149\u50ac\u5316\u6027\u80fd\u7684\u91cd\u8981\u7b56\u7565\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-76179 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-4.png\" alt=\"\" width=\"600\" height=\"275\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-4.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-4-300x138.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>4 <\/strong><strong>\u91d1\u5c5e\u7edc\u5408\u7269<\/strong><strong>&#8211;<\/strong><strong>\u534a\u5bfc\u4f53\u96c6\u6210\u50ac\u5316\u5242\u7684\u80fd\u7ea7\u793a\u610f\u56fe<\/strong><\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-76180 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-5.png\" alt=\"\" width=\"600\" height=\"1030\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-5.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-5-175x300.png 175w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-5-597x1024.png 597w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>5\u00a0<\/strong><strong>\u4e0d\u540c\u91d1\u5c5e\u7edc\u5408\u7269\u50ac\u5316\u5242\u7684\u5149\u50ac\u5316\u53cd\u5e94\u793a\u610f\u56fe<\/strong><\/p>\n<p><strong>(a)<\/strong> \u6df7\u5408\u78b3\u91cf\u5b50\u70b9(CQD)-Ni\u590d\u5408\u50ac\u5316\u4f53\u7cfb\u4ea7\u6c22<\/p>\n<p><strong>(b)<\/strong> Co\u7edc\u5408\u7269-CdS\u590d\u5408\u4f53\u7cfb\u4ea7\u6c22<\/p>\n<p><strong>(c)<\/strong> Ru\u7edc\u5408\u7269-C<sub>3<\/sub>N<sub>4<\/sub>\u590d\u5408\u5149\u50ac\u5316\u5242\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f<\/p>\n<p><strong>3.1.3 <\/strong><strong>\u91d1\u5c5e\u539f\u5b50\u5728<\/strong><strong>MOFs<\/strong><strong>\u4e2d\u7684\u5206\u6563<\/strong><\/p>\n<p>MOFs\u5177\u5907\u4f18\u5f02\u7684\u5b54\u9699\u5206\u5e03\u7ed3\u6784\u548c\u6613\u884c\u7684\u529f\u80fd\u5316\u8c03\u8282\uff0c\u4e3a\u5355\u539f\u5b50\u91d1\u5c5e\u4f4d\u70b9\u548c\u5355\u6838\u51c6\u91d1\u5c5e\u7edc\u5408\u7269\u7684\u56fa\u5b9a\u63d0\u4f9b\u4e86\u7406\u60f3\u7684\u7ed3\u6784\u652f\u67b6\u3002MOFs\u7684\u4f7f\u7528\u53ef\u4ee5\u6709\u6548\u5730\u9632\u6b62\u539f\u5b50\u7ea7\u5206\u6563\u53cd\u5e94\u4f4d\u70b9\u7684\u6d78\u51fa\uff0c\u901a\u8fc7\u5c06\u6709\u673a\u914d\u4f53\u4e0e\u65e0\u673a\u91d1\u5c5e\u8fde\u63a5\uff0c\u4ece\u800c\u6784\u5efa\u4e86\u4e00\u7c7b\u65b0\u578b\u914d\u4f4d\u805a\u5408\u7269\u3002\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\u53ef\u4ee5\u4f7f\u7528\u6709\u673a\u914d\u4f53\u7684\u5b98\u80fd\u56e2\u56fa\u5b9a\u5728MOF\u5f53\u4e2d\uff0c\u6b64\u5916\uff0c\u91d1\u5c5e\u8fde\u63a5\u70b9\u4e5f\u53ef\u4ee5\u7528\u4f5c\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-76181 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-6.png\" alt=\"\" width=\"600\" height=\"524\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-6.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-6-300x262.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>6 <\/strong><strong>\u5229\u7528<\/strong><strong>MOFs<\/strong><strong>\u56fa\u5b9a\u5355\u91d1\u5c5e\u539f\u5b50\u7684\u793a\u4f8b\u56fe<\/strong><\/p>\n<p><strong>(a)<\/strong>\u539f\u5b50\u7ea7Cu-TiO<sub>2<\/sub> MOFs\u5149\u50ac\u5316\u5242\uff1a TEM\u56fe\u50cf<\/p>\n<p><strong>(b)<\/strong> \u542b\u6709\u6d3b\u6027\u4f4d\u70b9\u7684MOF-525-Co \u7ed3\u6784\u793a\u610f\u56fe<\/p>\n<p><strong>(c)<\/strong> \u81ea\u6108\u5408Pt\u7edc\u5408\u7269MOFs\u5de5\u4f5c\u673a\u7406\u793a\u610f\u56fe<\/p>\n<p><strong>3.2 <\/strong><strong>\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\u7535\u5b50\u7ed3\u6784\u7684\u8c03\u6574<\/strong><\/p>\n<p>\u6d3b\u6027\u4f4d\u70b9\u7684\u7535\u5b50\u7ed3\u6784\u4e0e\u50ac\u5316\u6d3b\u6027\u7684\u5f3a\u5f31\u7d27\u5bc6\u76f8\u5173\uff0c\u901a\u8fc7\u8c03\u8282\u6709\u673a\u914d\u5408\u7269\u7684\u7acb\u4f53\u7535\u5b50\u7ed3\u6784\u6027\u8d28\uff0c\u53ef\u4ee5\u5b9e\u73b0\u50ac\u5316\u5242\u6d3b\u6027\u4f4d\u70b9\u7684\u7535\u5b50\u7ed3\u6784\u8c03\u8282\u3002\u5f53\u5206\u6563\u5728\u50ac\u5316\u5242\u8868\u9762\u7684\u539f\u5b50\u7ea7\u53cd\u5e94\u4f4d\u70b9\u901a\u8fc7\u914d\u5408\u7269\u56fa\u5b9a\u540e\uff0c\u5355\u91d1\u5c5e\u539f\u5b50\u7684\u7535\u5b50\u7ed3\u6784\u5c31\u53ef\u4ee5\u901a\u8fc7\u914d\u5408\u73af\u5883\u8fdb\u884c\u8c03\u8282\uff0c\u91d1\u5c5e\u4f4d\u70b9\u7684\u7535\u5b50\u7ed3\u6784\u4e0e\u914d\u4f4d\u57fa\u56e2\u7684\u5b98\u80fd\u56e2\u6709\u7740\u76f4\u63a5\u5173\u8054\uff0c\u5982\u5305\u542b\u6709\u7ed9\u7535\u5b50\u57fa\u56e2\uff08-CH<sub>3<\/sub>, -NH<sub>2<\/sub>\u548c-NMe<sub>2<\/sub>\uff09\u7684\u914d\u5408\u7269\u548c\u5305\u542b\u6709\u7535\u5b50\u53d7\u4f53\uff08-COOH, -Cl, -NO<sub>2<\/sub> \u548c -CF<sub>3<\/sub>\uff09\u7684\u914d\u5408\u7269\u3002\u5728\u914d\u4f53\u4e2d\u5f15\u5165\u53d6\u4ee3\u57fa\u4f1a\u5bf9\u91d1\u5c5e\u4e2d\u5fc3\u5468\u56f4\u7684\u7535\u5b50\u5bc6\u5ea6\u4ea7\u751f\u5f71\u54cd\uff0c\u8fdb\u4e00\u6b65\u4f1a\u5f71\u54cd\u50ac\u5316\u4f4d\u70b9\u7684\u4eb2\u6838\u6027\uff0c\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u548c\u7a33\u5b9a\u6027\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-76164 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-7.png\" alt=\"\" width=\"600\" height=\"339\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-7.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-7-300x170.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>7\u00a0<\/strong><strong>\u5f15\u5165\u7535\u5b50\u7ed9\u4f53\u6216\u7535\u5b50\u53d7\u4f53\u53d6\u4ee3\u57fa\u7684\u91d1\u5c5e\u914d\u5408\u7269\u793a\u610f\u56fe<\/strong><\/p>\n<p><strong>3.3 <\/strong><strong>\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u7684\u8c03\u8282<\/strong><\/p>\n<p>\u5728\u5149\u50ac\u5316\u53cd\u5e94\u4e2d\uff0c\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u7684\u6fc0\u6d3b\u5fc5\u987b\u4ee5\u50ac\u5316\u5242\u5177\u5907\u8db3\u591f\u5927\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u4e3a\u524d\u63d0\uff0c\u7531\u4e8e\u5206\u6563\u5728\u50ac\u5316\u5242\u8868\u9762\u7684\u539f\u5b50\u7ea7\u53cd\u5e94\u4f4d\u70b9\u88ab\u914d\u5408\u7269\u6240\u56fa\u5b9a\uff0c\u91d1\u5c5e\u7edc\u5408\u7269\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u53ef\u4ee5\u901a\u8fc7\u914d\u4f53\u53d6\u4ee3\u7684\u65b9\u5f0f\u8fdb\u884c\u8c03\u8282\u3002\u901a\u5e38\u7ed9\u7535\u5b50\u53d6\u4ee3\u57fa\u4f1a\u4f7f\u91d1\u5c5e\u7edc\u5408\u7269\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u53d1\u751f\u8d1f\u5411\u504f\u79fb\uff0c\u589e\u5f3a\u7edc\u5408\u7269\u7684\u8fd8\u539f\u80fd\u529b\u3002\u76f8\u53cd\u5730\uff0c\u5438\u7535\u5b50\u53d6\u4ee3\u57fa\u4f1a\u589e\u5f3a\u7edc\u5408\u7269\u7684\u6c27\u5316\u80fd\u529b\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-76165 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-8.png\" alt=\"\" width=\"600\" height=\"475\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-8.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-8-300x238.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>8\u00a0<\/strong><strong>\u534a\u5bfc\u4f53\u5149\u50ac\u5316\u5242\u7684\u80fd\u5e26\u80fd\u7ea7\u56fe\u4ee5\u53ca\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u5339\u914d<\/strong><\/p>\n<p><strong>4. \u5149\u5438\u6536\u7684\u8c03\u63a7<\/strong><\/p>\n<p><strong>4.1 <\/strong><strong>\u5229\u7528\u8868\u9762\u914d\u4f53\u5b9e\u73b0\u5149\u5438\u6536\u8c03\u63a7<\/strong><\/p>\n<p>\u7531\u4e8eTiO<sub>2<\/sub>\u6210\u672c\u4f4e\u3001\u5149\u5316\u5b66\u7a33\u5b9a\u4e14\u65e0\u6bd2\u6027\uff0c\u5176\u4e00\u76f4\u4ee5\u6765\u90fd\u662f\u6700\u53d7\u77a9\u76ee\u7684\u5149\u50ac\u5316\u5242\u6750\u6599\uff0c\u7136\u800c\uff0cTiO<sub>2<\/sub>\u7684\u5e26\u9699\u5bbd\u5ea6\u8f83\u5bbd\uff0c\u56e0\u800c\u5149\u5438\u8303\u56f4\u4ec5\u5728\u7d2b\u5916\u6ce2\u6bb5\u3002\u4e3a\u4e86\u63d0\u9ad8\u592a\u9633\u5149\u7684\u5438\u6536\u5229\u7528\u7387\uff0c\u4f17\u591a\u79d1\u7814\u56e2\u961f\u5c06\u76ee\u5149\u79fb\u5411\u4e86\u53ef\u89c1\u5149\u54cd\u5e94\u7684TiO<sub>2<\/sub>\u5149\u50ac\u5316\u5242\u8bbe\u8ba1\uff0c\u6709\u673a\u914d\u4f53\u7684\u5f15\u5165\u5bf9\u4e8e\u8c03\u8282\u50ac\u5316\u5242\u7684\u5149\u54cd\u5e94\u8303\u56f4\u800c\u8a00\u5c24\u4e3a\u91cd\u8981\u3002\u76ee\u524d\u5173\u4e8e\u5404\u79cd\u70ef\u4e8c\u9187\u914d\u4f53\uff08\u5982\u90bb\u82ef\u4e8c\u915a\uff09\u7684\u62a5\u9053\u5df2\u6570\u4e0d\u80dc\u6570\uff0c\u6700\u8fd1\uff0c\u90e8\u5206\u7814\u7a76\u4eba\u5458\u6210\u529f\u8bbe\u8ba1\u4e86\u7531\u6269\u5c55\u82b3\u65cf\u73af\u6216\u5177\u6709\u5404\u79cd\u7ed9\u7535\u5b50\/\u5438\u7535\u5b50\u53d6\u4ee3\u57fa\u7ec4\u6210\u7684\u6539\u6027\u90bb\u82ef\u4e8c\u915a\u578b\u914d\u4f53\uff0c\u5e76\u7528\u4e8eTiO<sub>2<\/sub>\u7eb3\u7c73\u9897\u7c92\u7684\u8868\u9762\u4fee\u9970\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-76182 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-9.png\" alt=\"\" width=\"600\" height=\"490\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-9.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-9-300x245.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>9 <\/strong><strong>\u70ef\u4e8c\u9187\u5728<\/strong><strong>TiO<sub>2<\/sub><\/strong><strong>\u8868\u9762\u53ef\u80fd\u7684\u914d\u4f4d\u7ed3\u6784\u548c\u7a7a\u95f4\u51e0\u4f55\u6784\u578b<\/strong><\/p>\n<p><strong>(a)<\/strong> \u5206\u5b50\u6a21\u5f0f\uff1b<strong> (b)<\/strong> \u5355\u9f7f\u6a21\u5f0f\uff1b<strong>(c)<\/strong> \u4e8c\u9f7f\u6a21\u5f0f\uff1b<strong>(d)<\/strong> \u87af\u5408\u6a21\u5f0f<\/p>\n<p><strong>4.2 <\/strong><strong>\u8c03\u8282\u7535\u8377\u8f6c\u79fb\u8dc3\u8fc1<\/strong><\/p>\n<p>\u5728\u914d\u5408\u7ed3\u6784\u4e2d\uff0c\u7535\u8377\u7684\u8f6c\u79fb\u4f34\u968f\u7740\u591a\u79cd\u8dc3\u8fc1\u5f62\u5f0f\uff0c\u9664\u4e86\u5185\u5728\u7684\u5e26\u95f4\u8dc3\u8fc1\u4ee5\u5916\uff0c\u5176\u8fd8\u80fd\u4fc3\u8fdb\u5149\u7684\u5438\u6536\u3002\u7535\u8377\u8f6c\u79fb\u8dc3\u8fc1\u80fd\u4e0e\u5e26\u95f4\u8dc3\u8fc1\u5149\u5438\u6536\u5f62\u6210\u4e92\u8865\u5173\u7cfb\uff0c\u4ece\u800c\u5b9e\u73b0\u5bbd\u5e26\u5149\u6536\u96c6\u3002\u5982\u56fe10\u6240\u793a\uff0c\u5728\u975e\u5747\u76f8\u5149\u50ac\u5316\u5242\u4e2d\uff0c\u6d89\u53ca\u5230\u7684\u7535\u8377\u8f6c\u79fb\u8dc3\u8fc1\u5305\u62ec\u91d1\u5c5e-\u914d\u4f53\u7535\u8377\u8f6c\u79fb\uff08MLCT\uff09\u3001\u914d\u4f53\u91d1\u5c5e\u7535\u8377\u8f6c\u79fb\uff08LMCT\uff09\u3001\u914d\u4f53-\u914d\u4f53\u7535\u8377\u8f6c\u79fb\uff08LLCT\uff09\u548c\u91d1\u5c5e-\u91d1\u5c5e\u7535\u8377\u8f6c\u79fb\uff08MMCT\uff09\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-76167 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-10.png\" alt=\"\" width=\"600\" height=\"557\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-10.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-10-300x279.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>10\u00a0<\/strong><strong>\u5f02\u8d28\u5149\u50ac\u5316\u5242\u4e2d\u914d\u4f4d\u7ed3\u6784\u7684\u7535\u8377\u8f6c\u79fb\u8dc3\u8fc1\u7b80\u5316\u539f\u7406\u56fe<\/strong><\/p>\n<p><strong>4.2.1\u00a0<\/strong><strong>\u91d1\u5c5e<\/strong><strong>&#8211;<\/strong><strong>\u914d\u4f53\u7535\u8377\u8f6c\u79fb\uff08<\/strong><strong>MLCT<\/strong><strong>\uff09<\/strong><\/p>\n<p>\u5f53\u91d1\u5c5e\u4e2d\u5fc3\u88ab\u6c27\u5316\u5230\u8f83\u9ad8\u4ef7\u6001\u65f6\uff0cMLCT\u901a\u5e38\u5c31\u4f1a\u53d1\u751f\uff0c\u7535\u5b50\u53d7\u4f53\u914d\u4f53\u5c31\u4f1a\u63d0\u4f9b\u76f8\u5f53\u7a33\u5b9a\u7684\u7a7a\u8f68\u9053\uff0c\u5982CO\u3001 CN\u3001SCN\u7684\u03c0*\u8f68\u9053\u3002\u5728\u8fd9\u79cd\u60c5\u51b5\u4e0b\uff0c\u7535\u5b50\u4f1a\u4ece\u5360\u636e\u7684\u91d1\u5c5e\u5b9a\u57df\u8f68\u9053\u6fc0\u53d1\u5230\u7a7a\u914d\u4f4d\u4f53\u5b9a\u57df\u8f68\u9053\uff0c\u4ece\u800c\u4fc3\u8fdb\u957f\u6ce2\u957f\u5149\u7684\u5438\u6536\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-76168 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-11.png\" alt=\"\" width=\"600\" height=\"634\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-11.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-11-284x300.png 284w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>11 Pt<sup>2+<\/sup>-g-C<sub>3<\/sub>N<sub>4<\/sub><\/strong><strong>\u50ac\u5316\u5242\u4f53\u7cfb\u4e2d\u7684<\/strong><strong>MLCT<\/strong><\/p>\n<p><strong>(a)<\/strong> g-C<sub>3<\/sub>N<sub>4<\/sub>\u4e0ePt<sup>2+<\/sup>\u914d\u4f4d\u7684\u7ed3\u6784\u56fe<\/p>\n<p><strong>(b)<\/strong> \u4e0d\u540cPt\u6d53\u5ea6\u4e0b\uff0cg-C<sub>3<\/sub>N<sub>4<\/sub>\u548cg-C<sub>3<\/sub>N<sub>4<\/sub>-Pt<sup>2+<\/sup>\u7684UV-vis\u5438\u6536\u5149\u8c31<\/p>\n<p><strong>(c)<\/strong> \u5229\u7528\u7b2c\u4e00\u6027\u539f\u7406\u6a21\u62df\uff0c\u6240\u5f97\u7684g-C<sub>3<\/sub>N<sub>4<\/sub>\u548cg-C<sub>3<\/sub>N<sub>4<\/sub>-Pt<sup>2+<\/sup> DOS\u56fe<\/p>\n<p><strong>(d)<\/strong> g-C<sub>3<\/sub>N<sub>4<\/sub>\u548cg-C<sub>3<\/sub>N<sub>4<\/sub>-Pt<sup>2+<\/sup>\u7684\u80fd\u5e26\u5bf9\u51c6\u56fe<\/p>\n<p><strong>(e)<\/strong> \u4ecePt<sup>2+<\/sup>\u8bf1\u5bfc\u7684\u6df7\u5408HOMO\u72b6\u6001\uff08\u5728\u8d39\u7c73\u80fd\u7ea7\u4ee5\u4e0b0-1eV\u7684\u8303\u56f4\u5185\uff09\u5230g-C<sub>3<\/sub>N<sub>4<\/sub>-Pt<sup>2+<\/sup>\u7684LUMO\u5149\u6fc0\u53d1\u7535\u8377\u5bc6\u5ea6\u8dc3\u8fc1<\/p>\n<p><strong>4.2.2\u00a0<\/strong><strong>\u914d\u4f53\u91d1\u5c5e\u7535\u8377\u8f6c\u79fb\uff08<\/strong><strong>LMCT<\/strong><strong>\uff09<\/strong><\/p>\n<p>\u4e0eMLCT\u4e0d\u540c\uff0cLMCT\u8dc3\u8fc1\u901a\u5e38\u53d1\u751f\u5728\u91d1\u5c5e\u4e2d\u5fc3\u88ab\u8fd8\u539f\u4e3a\u8f83\u4f4e\u5316\u5408\u4ef7\u6001\u65f6\uff0c\u7ed9\u7535\u5b50\u914d\u4f53\u53ef\u4ee5\u63d0\u4f9b\u4f9b\u4f53\u8f68\u9053\uff08\u5982p\u7535\u5b50\u6216\u5b64\u7acb\u7535\u5b50\u5bf9\uff09\uff0c\u7535\u5b50\u4f1a\u4ece\u914d\u4f53\u4f9b\u4f53\u8f68\u9053\u5230\u91d1\u5c5e\u53d7\u4f53\u8f68\u9053\u53d1\u751f\u8dc3\u8fc1\uff0c\u4ece\u800c\u5438\u6536\u4f4e\u80fd\u91cf\u5149\u5b50\u3002<\/p>\n<p><strong>4.2.3\u00a0<\/strong><strong>\u914d\u4f53<\/strong><strong>&#8211;<\/strong><strong>\u914d\u4f53\u7535\u8377\u8f6c\u79fb\uff08<\/strong><strong>LLCT<\/strong><strong>\uff09<\/strong><\/p>\n<p>LLCT\u8dc3\u8fc1\u662f\u57fa\u4e8e\u7535\u5b50\u7ed9\u4f53\u548c\u7535\u5b50\u63a5\u53d7\u914d\u4f53\u7684\u5171\u5b58\uff0c\u8fd9\u4e24\u4e2a\u914d\u4f53\u4e0d\u76f4\u63a5\u4e0e\u91d1\u5c5e\u4e2d\u5fc3\u76f8\u4e92\u4f5c\u7528\uff0c\u7535\u5b50\u7ed9\u4f53\u548c\u7535\u5b50\u53d7\u4f53\u914d\u4f53\u540c\u6b65\u53d1\u751f\u6c27\u5316\u548c\u8fd8\u539f\uff0c\u5728\u957f\u6ce2\u957f\u533a\u57df\u5185\u663e\u793a\u9664\u4e86LLCT\u5149\u5438\u6536\u3002\u6b64\u5916\uff0cLLCT\u5728\u5f02\u8d28MOF\u5149\u50ac\u5316\u5242\u4e2d\u5c1a\u672a\u5f97\u5230\u5f88\u597d\u7684\u7814\u7a76\u3002<\/p>\n<p><strong>4.2.4\u00a0<\/strong><strong>\u91d1\u5c5e<\/strong><strong>&#8211;<\/strong><strong>\u91d1\u5c5e\u7535\u8377\u8f6c\u79fb\uff08<\/strong><strong>MMCT<\/strong><strong>\uff09<\/strong><\/p>\n<p>\u5f53\u5177\u6709\u4e0d\u540c\u4ef7\u6001\u7684\u4e24\u4e2a\u91d1\u5c5e\u4e2d\u5fc3\u901a\u8fc7\u6865\u8fde\u914d\u4f53\u5076\u8054\u65f6\uff0c\u5728\u5b83\u4eec\u4e4b\u95f4\u5c31\u4f1a\u53d1\u751fMMCT\u8dc3\u8fc1\uff0c\u4e14\u901a\u5e38\u53d1\u751f\u5728\u591a\u6838\u590d\u5408\u7269\u4e2d\uff0c\u6c27\u4ee3\u6865\u8054\u548c\u65e0\u673a\u6742\u53cc\u6838\u7edc\u5408\u7269\u53ef\u4ee5\u5c06\u5149\u5438\u6536\u4eceUV\u6269\u5c55\u5230\u53ef\u89c1\u5149\u533a\u57df\u3002\u7535\u5b50\u4ece\u7ed9\u4f53\u91d1\u5c5e\u4e2d\u5fc3\uff08\u5982Mn<sup>II<\/sup>\uff0cFe<sup>II<\/sup>\uff0cCo<sup>II<\/sup>\u548cCu<sup>I<\/sup>\uff09\u6fc0\u53d1\u5230\u53d7\u4f53\u91d1\u5c5e\u4e2d\u5fc3\uff08\u5982Zr<sup>VI<\/sup>\uff0cTi<sup>IV<\/sup>\u548cV<sup>IV<\/sup>\uff09\uff0c\u4f9d\u8d56\u4e8e\u901a\u8fc7\u4e0e\u5171\u4ef7\u6c27\u4ee3\u6865s\u952e\u5408\u7684d\u8f68\u9053\u91cd\u53e0\uff0c\u53d1\u751f\u8dc3\u8fc1\u540e\uff0c\u4e24\u4e2a\u91d1\u5c5e\u4e2d\u5fc3\u5206\u522b\u88ab\u8fd8\u539f\u548c\u6c27\u5316\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-76169 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-12.png\" alt=\"\" width=\"600\" height=\"480\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-12.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-12-300x240.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>12 <\/strong><strong>\u53cc\u91d1\u5c5e\u7edc\u5408\u7269\u7684<\/strong><strong>MMCT<\/strong><strong>\u8dc3\u8fc1<\/strong><\/p>\n<p><strong>(a)<\/strong> Zr<sup>I<\/sup>VOCo<sup>II<\/sup>-Zr<sup>III<\/sup>OCo<sup>III<\/sup>\u7684UV-vis\u6f2b\u53cd\u5c04\u5149\u8c31\uff08DRS\uff09\uff0c\u5176\u663e\u793aMMCT\u7684\u5438\u6536\u4ece\u8fd1\u7d2b\u5916\u533a\u5ef6\u4f38\u5230\u7ea6600nm<\/p>\n<p><strong>(b)<\/strong> V<sup>I<\/sup>VOFe<sup>II<\/sup>-VVOFe<sup>I<\/sup> \u7684\u6570\u5b66\u5dee\u7535\u5b50\u5438\u6536\u5149\u8c31\uff0c\u663e\u793a\u5176MMCT\u8dc3\u8fc1\u57282.47eV\uff08502nm\uff09\u6709\u8f83\u5f3a\u7684\u5438\u6536<\/p>\n<p><strong>4.3 <\/strong><strong>\u5206\u5b50\u5149\u654f\u5316\u5242\u7684\u56fa\u5b9a<\/strong><\/p>\n<p>\u5bf9\u534a\u5bfc\u4f53\u5e26\u9699\u8fdb\u884c\u8c03\u8282\u662f\u76ee\u524d\u5e94\u7528\u5e7f\u6cdb\u7684\u63d0\u9ad8\u5149\u5438\u6536\u624b\u6bb5\uff0c\u4f46\u5176\u5f80\u5f80\u4f1a\u5f71\u54cd\u50ac\u5316\u5242\u539f\u6765\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\uff0c\u4f7f\u5f97\u50ac\u5316\u53cd\u5e94\u96be\u4ee5\u53d1\u751f\u3002\u901a\u8fc7\u914d\u4f4d\u5316\u5b66\u5b9e\u73b0\u5bbd\u5e26\u9699\u534a\u5bfc\u4f53\u4e0e\u5206\u5b50\u5149\u654f\u5242\u7684\u6574\u5408\uff0c\u53ef\u4ee5\u5728\u8c03\u8282\u5149\u5438\u6536\u7684\u540c\u65f6\u4e0d\u6539\u53d8\u534a\u5bfc\u4f53\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u3002\u5149\u654f\u5316\u662f\u901a\u8fc7\u6fc0\u53d1\u5149\u654f\u5242\u8fdb\u884c\u5de5\u4f5c\u7684\uff0c\u5149\u751f\u8f7d\u6d41\u5b50\u8fdb\u4e00\u6b65\u4f1a\u8f6c\u79fb\u7ed9\u534a\u5bfc\u4f53\uff0c\u662f\u4e00\u7c7b\u6709\u6548\u63d0\u9ad8\u5149\u5438\u6536\u7684\u624b\u6bb5\u3002\u5c06\u5149\u654f\u5242\u9644\u7740\u5230\u534a\u5bfc\u4f53\u8868\u9762\u4e0a\uff0c\u8fd9\u662f\u4fdd\u6301\u67d3\u6599-\u534a\u5bfc\u4f53\u590d\u5408\u4f53\u7cfb\u6548\u7387\u7684\u5173\u952e\u6240\u5728\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-76170 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-13.png\" alt=\"\" width=\"600\" height=\"708\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-13.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-13-254x300.png 254w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>13 <\/strong><strong>\u540c\u79cd\u4e0d\u540c\u6fc0\u53d1\u7684\u7535\u5b50\u6ce8\u5165\u673a\u5236\u793a\u610f\u56fe<\/strong><\/p>\n<p><strong>5. \u914d\u4f4d\u7ed3\u6784\u4e2d\u7684\u7535\u8377\u8f6c\u79fb\u52a8\u529b\u5b66<\/strong><\/p>\n<p>\u7535\u8377\u8f6c\u79fb\u52a8\u529b\u5b66\u662f\u5c06\u5149\u5438\u6536\u4e0e\u50ac\u5316\u53cd\u5e94\u76f8\u5173\u8054\u7684\u8fc7\u7a0b\uff0c\u8c03\u8282\u6574\u4e2a\u5149\u50ac\u5316\u4f53\u7cfb\u7684\u6548\u7387\u3002\u5149\u751f\u7535\u5b50\u4ece\u5149\u5438\u6536\u4e2d\u5fc3\u5230\u50ac\u5316\u4f4d\u70b9\u5904\u7684\u6709\u6548\u8f6c\u79fb\u5bf9\u4e8e\u5f02\u76f8\u5149\u50ac\u5316\u5242\u7684\u9ad8\u50ac\u5316\u6d3b\u6027\u800c\u8a00\u975e\u5e38\u91cd\u8981\u3002\u4e3a\u4e86\u6700\u5927\u9650\u5ea6\u5730\u63d0\u9ad8\u7b2c3\u8282\u548c\u7b2c4\u8282\u4e2d\u6d89\u53ca\u5230\u7684\u5149\u50ac\u5316\u6a21\u5757\uff0c\u5bf9\u5f02\u76f8\u5149\u50ac\u5316\u914d\u4f4d\u7ed3\u6784\u7684\u7cbe\u786e\u63a7\u5236\u5177\u6709\u5b9e\u9645\u91cd\u8981\u6027\u548c\u6839\u672c\u610f\u4e49\u3002\u8fdb\u4e00\u6b65\u6df1\u5165\u8ba8\u8bba\u7535\u5b50\u8f6c\u79fb\u7684\u5f71\u54cd\u56e0\u7d20\uff0c\u6709\u52a9\u4e8e\u5408\u7406\u8bbe\u8ba1\u548c\u6784\u5efa\u66f4\u4e3a\u6709\u6548\u7684\u6df7\u5408\u5149\u50ac\u5316\u5242\u3002<\/p>\n<p>\u5149\u5438\u6536\u4e2d\u5fc3\u548c\u50ac\u5316\u90e8\u4f4d\u7684\u80fd\u7ea7\u5339\u914d\u4f1a\u589e\u5927\u7535\u5b50\u8f6c\u79fb\u7684\u9a71\u52a8\u529b\u3002\u65e0\u8bba\u662f\u5f15\u5165\u56fa\u5b9a\u7684\u539f\u5b50\u5206\u6563\u53cd\u5e94\u4f4d\u70b9\u6216\u662f\u951a\u5b9a\u5206\u5b50\u5149\u654f\u5242\uff0c\u901a\u5e38\u90fd\u4f1a\u6d89\u53ca\u5230\u6865\u914d\u4f53\u3002\u6865\u914d\u4f53\u6216\u951a\u5b9a\u57fa\u56e2\u4e0d\u4ec5\u4ee3\u8868\u5149\u5438\u6536\u4e2d\u5fc3\u4e0e\u50ac\u5316\u90e8\u4f4d\u4e4b\u95f4\u7684\u5316\u5b66\u8fde\u63a5\uff0c\u800c\u4e14\u5728\u786e\u5b9a\u5176\u7535\u5b50\u8026\u5408\u65b9\u9762\u4e5f\u53d1\u6325\u7740\u91cd\u8981\u7684\u4f5c\u7528\uff0c\u951a\u5b9a\u57fa\u56e2\u7684\u5b58\u5728\u51b3\u5b9a\u4e86\u5149\u50ac\u5316\u4e2d\u7684\u7535\u5b50\u8f6c\u79fb\u901f\u7387\u3002\u5728\u8bbe\u8ba1\u6df7\u5408\u5f02\u76f8\u5149\u50ac\u5316\u5242\u65f6\uff0c\u5149\u5438\u6536\u4e2d\u5fc3\u548c\u8868\u9762\u50ac\u5316\u4f4d\u70b9\u7684\u8ddd\u79bb\u4f1a\u6781\u5927\u5730\u5f71\u54cd\u7535\u8377\u8f6c\u79fb\u52a8\u529b\u5b66\uff0c\u56e0\u800c\u5fc5\u987b\u8003\u8651\u5728\u5185\u3002\u7531\u4e8e\u5728\u67d0\u4e9b\u60c5\u51b5\u4e0b\u6865\u6881\u914d\u4f53\u7528\u4e8e\u8fde\u63a5\u5149\u6355\u83b7\u4e2d\u5fc3\u548c\u50ac\u5316\u4f4d\u70b9\uff0c\u5f53\u6cbf\u7740\u6865\u6881\u4f20\u8f93\u65f6\uff0c\u5149\u6fc0\u53d1\u7684\u7535\u5b50\u548c\u7a7a\u7a74\u4e0d\u53ef\u907f\u514d\u5730\u590d\u5408\u3002 \u5728\u8fd9\u79cd\u60c5\u51b5\u4e0b\uff0c\u7535\u8377\u8f6c\u79fb\u52a8\u529b\u5b66\u53ef\u4ee5\u901a\u8fc7\u6539\u53d8\u6865\u914d\u4f53\u7684\u957f\u5ea6\u6765\u8fdb\u884c\u64cd\u4f5c-\u5149\u5438\u6536\u4e2d\u5fc3\u548c\u50ac\u5316\u4f4d\u70b9\u4e4b\u95f4\u7684\u7269\u7406\u5206\u79bb\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-76171 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-14.png\" alt=\"\" width=\"600\" height=\"781\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-14.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-14-230x300.png 230w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>14<\/strong> <strong>\u914d\u4f4d\u7ed3\u6784\u4e2d\u7684\u7535\u5b50\u8f6c\u79fb<\/strong><\/p>\n<p><strong>(a)<\/strong> TiO<sub>2<\/sub>\u4e0e\u951a\u5b9a\u5206\u5b50\u50ac\u5316\u5242\u95f4\u7684\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u793a\u610f\u56fe\uff0c\u5176\u4e2d\u53d8\u91cf\u4e3a\u50ac\u5316\u5242\u91d1\u5c5e\u4e2d\u5fc3\u4e0e\u951a\u5b9a\u5206\u5b50\u50ac\u5316\u5242\u95f4\u7684\u8ddd\u79bb<\/p>\n<p><strong>(b)<\/strong>\u5206\u5b50\u654f\u5316\u5242\u548c\u91d1\u5c5e\u7edc\u5408\u7269\u95f4\u5f62\u6210\u521a\u6027\u8fde\u63a5\u6865\u6881\u7684\u793a\u610f\u56fe<\/p>\n<p><strong>6. \u914d\u4f4d\u7ed3\u6784\u5149\u50ac\u5316\u5242\u7684\u5148\u8fdb\u5149\u8c31\u8868\u5f81<\/strong><\/p>\n<p><strong>6.1 <\/strong><strong>\u5f02\u76f8\u50ac\u5316\u5242\u7684\u914d\u4f4d\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-76172 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-15.png\" alt=\"\" width=\"600\" height=\"347\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-15.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-15-300x174.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>15 <\/strong><strong>\u76ee\u524d\u914d\u4f4d\u5f02\u76f8\u5149\u50ac\u5316\u5242\u7684\u4e3b\u8981\u7ed3\u6784\u8868\u5f81\u624b\u6bb5<\/strong><\/p>\n<p><strong>6.2 <\/strong><strong>\u914d\u4f4d\u5f02\u76f8\u50ac\u5316\u5242\u7684\u80fd\u5e26\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n<p>\u5149\u50ac\u5316\u5242\u7684\u5149\u5438\u6536\u7531\u5176\u80fd\u5e26\u7ed3\u6784\u51b3\u5b9a\uff0c\u80fd\u5e26\u7ed3\u6784\u7684\u53ef\u9760\u6d4b\u91cf\u5bf9\u6df1\u5165\u7406\u89e3\u914d\u4f4d\u5316\u5b66\u5bf9\u5149\u5438\u6536\u7684\u8c03\u8c10\u4f5c\u7528\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u80fd\u5e26\u7ed3\u6784\u4fe1\u606f\u4e3b\u8981\u5305\u542b\u5e26\u9699\u5bbd\u5ea6\uff0c\u529f\u51fd\u6570\uff08\u5373\u8d39\u7c73\u80fd\u7ea7\u548c\u771f\u7a7a\u5ea6\u4e4b\u5dee\uff09\uff0c\u4ef7\u5e26\u6700\u5927\u503c\uff08VBM\uff09\u548c\u5bfc\u5e26\u6700\u5c0f\u503c\uff08CBM\uff09\u7b49\u3002UV-vis DRS\u5149\u8c31\u5b66\u662f\u76ee\u524d\u6700\u5e38\u7528\u7684\u534a\u5bfc\u4f53\u5e26\u9699\u7684\u6d4b\u8bd5\u6280\u672f\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-76173 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-16.png\" alt=\"\" width=\"600\" height=\"746\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-16.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-16-241x300.png 241w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>16 <\/strong><strong>\u5f02\u76f8\u50ac\u5316\u5242\u7684\u80fd\u5e26\u7ed3\u6784\u8868\u5f81\u6d4b\u8bd5<\/strong><\/p>\n<p><strong>(a)<\/strong> UV-vis\u6f2b\u53d1\u5c04\u5149\u8c31\uff0c\u63d2\u56fe\u4e3a\u50ac\u5316\u5242\u9897\u7c92\u7684\u6570\u5b57\u7167\u7247<\/p>\n<p><strong>(b)<\/strong> \u5229\u7528UV-vis\u8c31\u56fe\u8ba1\u7b97\u4e0d\u540c\u6750\u6599\u7684\u5e26\u9699\u5bbd\u5ea6\uff0cC<sub>3<\/sub>N<sub>4<\/sub>\uff08\u9ed1\u8272\u66f2\u7ebf\uff09\u548cCDots-C<sub>3<\/sub>N<sub>4<\/sub>\uff08\u7ea2\u8272\u66f2\u7ebf\uff09<\/p>\n<p><strong>(c)<\/strong> \u80fd\u5e26\u4f4d\u7f6e\u793a\u610f\u56fe<\/p>\n<p><strong>(d)<\/strong> UPS\u56fe\u8c31<\/p>\n<p><strong>(e)<\/strong> \u4ef7\u5e26\uff08VB\uff09XPS\u5149\u8c31<\/p>\n<p><strong>(f)<\/strong> [Ru(bpy)<sub>3<\/sub>]Cl<sub>2<\/sub>\u5728\u65e0\u6c34\u4e59\u8148\u4e2d\u7684\u7d2b\u5916\u53ef\u89c1\u5438\u6536\u5149\u8c31<\/p>\n<p><strong>6.3 <\/strong><strong>\u914d\u4f4d\u7ed3\u6784\u7684\u7535\u8377\u52a8\u529b\u5b66\u8868\u5f81<\/strong><\/p>\n<p>\u7535\u8377\u52a8\u529b\u5b66\u4f5c\u4e3a\u5149\u5438\u6536\u548c\u50ac\u5316\u53cd\u5e94\u7684\u6865\u6881\uff0c\u5bf9\u5176\u6df1\u5165\u7684\u7406\u89e3\u6709\u76ca\u4e8e\u83b7\u5f97\u7535\u8377\u5206\u79bb\u548c\u7ade\u4e89\u91cd\u7ec4\u7684\u8865\u5145\u548c\u5b9a\u91cf\u4fe1\u606f\uff0c\u4e3a\u4f18\u5316\u6750\u6599\u8bbe\u8ba1\u63d0\u4f9b\u4e00\u5b9a\u7684\u7406\u8bba\u6307\u5bfc\u3002\u76ee\u524d\uff0c\u7528\u4e8e\u8868\u5f81\u914d\u4f4d\u5f02\u76f8\u5149\u50ac\u5316\u5242\u7535\u8377\u52a8\u529b\u5b66\u7684\u4e3b\u8981\u624b\u6bb5\u6709\u4e09\u79cd\uff0c\u4e3a\u65f6\u95f4\u5206\u8fa8\u5149\u8c31\u6280\u672f&#8211;TAS\uff0c\u65f6\u95f4\u76f8\u5173\u5355\u5149\u5b50\u8ba1\u6570\uff08TC-SPC\uff09\u548c\u65f6\u95f4\u5206\u8fa8PL\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-76174 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-17.png\" alt=\"\" width=\"600\" height=\"499\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-17.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Figure-17-300x250.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>17\u00a0<\/strong><strong>\u5f02\u76f8\u50ac\u5316\u5242\u914d\u4f4d\u7ed3\u6784\u7684\u7535\u8377\u52a8\u529b\u5b66\u8868\u5f81<\/strong><\/p>\n<p><strong>(a)<\/strong> TiO<sub>2<\/sub>\u3001Cu<sub>3<\/sub>(BTC)<sub>2<\/sub>\u548cCu<sub>3<\/sub>(BTC)<sub>2<\/sub> @ TiO<sub>2<\/sub>\u590d\u5408\u7ed3\u6784\u7684\u63a2\u9488\u5ef6\u8fdf\u7684\u51fd\u6570\u7684\u77ac\u6001\u5438\u6536\u5149\u8c31\uff0c\u53f3\u56fe\u4e3a\u6240\u6d89\u53ca\u7684\u7535\u5b50\u884c\u4e3a\u793a\u610f\u56fe<\/p>\n<p><strong>(b)<\/strong> \u7a33\u6001PL<\/p>\n<p><strong>(c)<\/strong> \u968f\u52a0\u5165\u91cf\u589e\u52a0\u800c\u53d8\u5316\u7684Co(II)\u7edc\u5408\u7269-\u80f6\u4f53CdTe\u91cf\u5b50\u70b9\u590d\u5408\u50ac\u5316\u5242\u7684\u65f6\u95f4\u5206\u8fa8PL\u5149\u8c31<\/p>\n<p><strong>7. \u914d\u4f4d\u5316\u5b66\u7684\u5149\u50ac\u5316\u5e94\u7528<\/strong><\/p>\n<p>\u867d\u7136\u914d\u4f4d\u5316\u5b66\u7684\u4f5c\u7528\u672a\u80fd\u7a81\u51fa\u8868\u73b0\uff0c\u4f46\u5df2\u7ecf\u6709\u5927\u91cf\u57fa\u4e8e\u914d\u4f4d\u5316\u5b66\u7684\u5404\u79cd\u5f02\u76f8\u5149\u50ac\u5316\u5242\u88ab\u4e89\u76f8\u62a5\u9053\u3002\u914d\u4f4d\u5316\u5b66\u5728\u5f02\u76f8\u5149\u50ac\u5316\u4e2d\u7684\u5e94\u7528\u4e5f\u662f\u6108\u52a0\u5e7f\u6cdb\uff0c\u5bf9\u589e\u5f3a\u50ac\u5316\u5242\u7684\u5149\u50ac\u5316\u6027\u80fd\u53d8\u5f97\u8d8a\u6765\u8d8a\u91cd\u8981\u3002<\/p>\n<p><strong>7.1 <\/strong><strong>\u8d28\u5b50\u8fd8\u539f<\/strong><\/p>\n<p>\u76ee\u524d\uff0c\u8bb8\u591a\u7814\u7a76\u7ec4\u5df2\u7ecf\u5bf9\u5149\u6355\u83b7\u4e2d\u5fc3\u548c\u50ac\u5316\u4f4d\u70b9\u4e4b\u95f4\u7684\u7535\u5b50\u8f6c\u79fb\u591a\u4e86\u5927\u91cf\u7684\u7814\u7a76\uff0c\u8bbe\u8ba1\u4e86\u4e00\u7cfb\u5217\u7684\u57fa\u4e8e\u914d\u4f4d\u5316\u5b66\u7684\u5149\u50ac\u5316\u8d28\u5b50\u8fd8\u539f\u50ac\u5316\u4f53\u7cfb\uff0c\u5176\u4e2d\u914d\u4f4d\u5316\u5b66\u5728\u6027\u80fd\u589e\u5f3a\u4e2d\u8d77\u91cd\u8981\u4f5c\u7528\uff0c\u73b0\u5c06\u8fd1\u671f\u7814\u7a76\u6210\u679c\u7edf\u8ba1\u5982\u4e0b\uff08\u88681\uff09\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-76154 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Table-1.png\" alt=\"\" width=\"700\" height=\"225\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Table-1.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Table-1-300x96.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u8868<\/strong><strong>1 <\/strong><strong>\u76ee\u524d\u5149\u50ac\u5316\u8d28\u5b50\u8fd8\u539f\u7684\u73b0\u72b6\u7edf\u8ba1<\/strong><\/p>\n<p><strong>7.2 <\/strong><strong>\u6c34\u6c27\u5316<\/strong><\/p>\n<p>\u5728\u5b8c\u6574\u7684\u6c34\u5149\u89e3\u53cd\u5e94\u4e2d\uff0c\u4e0e\u8d28\u5b50\u8fd8\u539f\u76f8\u6bd4\uff0c\u6c34\u6c27\u5316\uff08\u5373\u6790\u6c27\u53cd\u5e94\uff09\u662f\u4e00\u4e2a\u66f4\u5177\u6311\u6218\u6027\u548c\u901f\u7387\u9650\u5236\u7684\u534a\u53cd\u5e94\uff0c\u56e0\u4e3a\u5b83\u6d89\u53ca\u56db\u8d28\u5b50\u8026\u5408\u548c\u56db\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\uff0c\u5e76\u4e14\u9700\u8981\u514b\u670d\u9ad8\u80fd\u52bf\u5792\u3002\u5149\u50ac\u5316\u6c34\u88c2\u89e3\u6790\u6c22\u901a\u5e38\u4f9d\u8d56\u4e8e\u727a\u7272\u7535\u5b50\u7ed9\u4f53\uff0c\u6291\u5236\u53cd\u5e94\u4e2d\u7684\u6c34\u6c27\u5316\u8fc7\u7a0b\u3002\u4e3a\u4e86\u5b9e\u9645\u6c34\u6c27\u5316\u7684\u5e94\u7528\u76ee\u7684\uff0c\u8fd8\u9700\u5f00\u53d1\u51fa\u7528\u4e8e\u6574\u4f53\u6c34\u88c2\u89e3\u7684\u5149\u50ac\u5316\u5242\uff0c\u4e14\u6709\u6548\u7684\u6c34\u6c27\u5316\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u5bf9\u4e8e\u5b9e\u73b0\u6c34\u6c27\u5316\u6295\u5165\u5b9e\u9645\u5e94\u7528\u800c\u7136\u4e5f\u662f\u975e\u5e38\u5173\u952e\u7684\u4e00\u6b65\u3002<\/p>\n<p>\u76ee\u524d\uff0c\u7528\u4e8e\u6790\u6c22\u7684\u914d\u4f4d\u5f02\u76f8\u5149\u50ac\u5316\u5242\u5df2\u7ecf\u6709\u5927\u91cf\u7684\u7814\u53d1\uff0c\u4f46\u5bf9\u4e8e\u53e6\u4e00\u534a\u53cd\u5e94\uff0c\u6c34\u6c27\u5316\u5219\u51e0\u4e4e\u6ca1\u6709\u62a5\u9053\uff0c\u90e8\u5206\u539f\u56e0\u53ef\u80fd\u662f\u914d\u4f53\u57fa\u914d\u4f4d\u7ed3\u6784\u5728\u5f3a\u6c27\u5316\u6761\u4ef6\u4e0b\u7a33\u5b9a\u6027\u8f83\u5dee\u3002\u5f02\u76f8\u5149\u50ac\u5316\u5242\u5982TiO<sub>2<\/sub>\u548cWO<sub>3<\/sub>\u7531\u4e8e\u5176\u5339\u914d\u4ef7\u5e26\u7535\u4f4d\uff0c\u5bf9\u6c34\u6c27\u5316\u5177\u6709\u6f5c\u5728\u7684\u5149\u50ac\u5316\u6d3b\u6027\uff0c\u4f46\u8981\u5b9e\u73b0\u8fd9\u4e00\u8fc7\u7a0b\uff0c\u901a\u5e38\u9700\u8981\u4f7f\u7528\u7535\u5b50\u53d7\u4f53\u3002<\/p>\n<p><strong>7.3 CO<sub>2<\/sub><\/strong><strong>\u8fd8\u539f<\/strong><\/p>\n<p>\u5229\u7528\u5149\u50ac\u5316\u624b\u6bb5\u5c06CO<sub>2<\/sub>\u8f6c\u5316\u4e3a\u5316\u5b66\u71c3\u6599\u53ef\u4ee5\u540c\u65f6\u6ee1\u8db3\u65e5\u76ca\u589e\u957f\u7684\u53ef\u518d\u751f\u80fd\u6e90\u9700\u6c42\u548c\u4fc3\u8fdb\u78b3\u5faa\u73af\uff0c\u51cf\u8f7b\u6e29\u5ba4\u6548\u5e94\u3002<\/p>\n<p>\u4e3a\u4e86\u5bfb\u6c42\u66f4\u52a0\u4f18\u5f02\u7684\u5149\u50ac\u5316\u6027\u80fd\uff0c\u79d1\u7814\u4eba\u5458\u5df2\u7ecf\u5bf9\u57fa\u4e8e\u914d\u4f4d\u5316\u5b66\u7684\u5f02\u76f8\u5149\u50ac\u5316\u5242\u8fdb\u884c\u4e86\u5927\u91cf\u7684\u63a2\u7d22\uff0c\u73b0\u5927\u81f4\u7edf\u8ba1\u5982\u4e0b\u5df2\u7ecf\uff08\u88682\uff09\u3002\u5728\u5149\u50ac\u5316CO<sub>2<\/sub>\u8fd8\u539f\u7684\u7814\u7a76\u4e2d\uff0c\u5229\u7528\u540c\u4f4d\u7d20\u6807\u8bb0\u6cd5\uff0c\u5bf9\u4e8e\u786e\u5b9a\u4ea7\u7269\u662f\u771f\u6b63\u6e90\u4e8e<sup>13<\/sup>CO<sub>2<\/sub>\u4ee5\u53ca\u63a2\u7d22\u53cd\u5e94\u673a\u7406\u5c24\u4e3a\u5173\u952e\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-76184 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Table-2.png\" alt=\"\" width=\"700\" height=\"230\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Table-2.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/Table-2-300x99.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u8868<\/strong><strong>2\u00a0<\/strong><strong>\u76ee\u524d\u5149\u50ac\u5316<\/strong><strong>CO<sub>2<\/sub><\/strong><strong>\u8fd8\u539f\u7684\u73b0\u72b6\u7edf\u8ba1<\/strong><\/p>\n<p><strong>7.4 <\/strong><strong>\u5149\u50ac\u5316\u6709\u673a\u5408\u6210<\/strong><\/p>\n<p>\u5728\u975e\u5e38\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\uff0c\u5229\u7528\u592a\u9633\u80fd\u9a71\u52a8\u9009\u62e9\u6027\u6c27\u5316\u8fd8\u539f\u6709\u673a\u53cd\u5e94\uff0c\u5f15\u8d77\u4e86\u79d1\u5b66\u5bb6\u4eec\u7684\u9ad8\u5ea6\u91cd\u89c6\u3002\u5149\u50ac\u5316\u6709\u673a\u53cd\u5e94\u53ef\u4ee5\u5b9e\u73b0\u5ba4\u6e29\u5316\u5b66\u5408\u6210\u4ee5\u53ca\u907f\u514d\u70ed\u8bf1\u5bfc\u7684\u526f\u53cd\u5e94\uff0c\u4e0e\u6df1\u5165\u7814\u7a76\u7684\u8d28\u5b50\u8fd8\u539f\u548c\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u53cd\u5e94\u76f8\u6bd4\uff0c\u914d\u4f4d\u5316\u5b66\u5728\u5149\u50ac\u5316\u6709\u673a\u53cd\u5e94\u4e2d\u7684\u5e94\u7528\u8f83\u5c11\uff0c\u4e0e\u672c\u7814\u7a76\u9886\u57df\u76f8\u5173\u7684\u4e00\u4e9b\u5b9e\u4f8b\u4e3b\u8981\u96c6\u4e2d\u5728\u67d3\u6599\u654f\u5316\u7684\u5f02\u76f8\u5149\u50ac\u5316\u4f53\u7cfb\u4e2d\u3002 \u7136\u800c\uff0c\u914d\u4f4d\u5316\u5b66\u7684\u4f5c\u7528\u5c1a\u672a\u88ab\u88ab\u63d0\u53ca\u548c\u5229\u7528\u3002<\/p>\n<p>\u4e3a\u4e86\u5b9e\u73b0\u53ef\u89c1\u5149\u5e94\u7528\uff0c\u7814\u7a76\u4eba\u5458\u8bbe\u8ba1\u4e86\u4e00\u79cd\u57fa\u4e8e\u914d\u4f4d\u5316\u5b66\u7684\u8fd8\u539f\u785d\u57fa\u82ef\u7684\u5149\u50ac\u5316\u5242\uff0c\u5728\u8bbe\u8ba1\u4e2d\uff0c\u91c7\u7528\u7f9f\u57fa\u8418\u4f5c\u4e3a\u8868\u9762\u9644\u7740\u914d\u4f53\uff0c\u901a\u8fc7\u5f62\u6210\u8868\u9762\u7edc\u5408\u7269\u6765\u6539\u6027TiO<sub>2<\/sub>\u8868\u9762\uff0c\u7ed3\u679c\u53d1\u73b0\u914d\u4f4d\u80fd\u529b\u548c\u5149\u5438\u6536\u6027\u5728\u5f88\u5927\u7a0b\u5ea6\u4e0a\u53d6\u51b3\u4e8e\u951a\u5b9a\u7f9f\u57fa\u7684\u6570\u91cf\u548c\u53d6\u4ee3\u6a21\u5f0f\uff0c\u5177\u6709\u4e24\u4e2a\u76f8\u90bb\u7f9f\u57fa\u7684\u7f9f\u57fa\u8418\u663e\u793a\u51fa\u6bd4\u8f83\u5f3a\u7684\u914d\u4f4d\u80fd\u529b\u548c\u66f4\u5f3a\u70c8\u7684\u53ef\u89c1\u5149\u5438\u6536\u3002<\/p>\n<p><strong>\u3010\u603b\u7ed3\u4e0e\u5c55\u671b\u3011<\/strong><\/p>\n<p>\u5728\u5f02\u76f8\u5149\u50ac\u5316\u5242\u8bbe\u8ba1\u4e2d\uff0c\u914d\u4f4d\u5316\u5b66\u663e\u793a\u51fa\u4e86\u975e\u5e38\u5177\u6709\u524d\u666f\u7684\u5e94\u7528\uff0c\u4e3a\u4f5c\u7528\u50ac\u5316\u5242\u7684\u6539\u6027\u63d0\u4f9b\u4e86\u4e00\u79cd\u6307\u5bfc\u7b56\u7565\uff0c\u4e3b\u8981\u529f\u80fd\u5305\u62ec\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\u7684\u8bbe\u8ba1\uff0c\u8c03\u8282\u5149\u5438\u6536\u548c\u7535\u8377\u52a8\u529b\u5b66\uff0c\u8fd9\u4e5f\u662f\u5149\u50ac\u5316\u7684\u5173\u952e\u3002<\/p>\n<p>\u901a\u8fc7\u5c06\u5206\u5b50\u5316\u5b66\u7684\u6982\u5ff5\u548c\u5de5\u5177\u5f15\u5165\u5230\u8868\u9762\u5316\u5b66\u548c\u5f02\u76f8\u5149\u50ac\u5316\u5f53\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u4eec\u63cf\u7ed8\u51fa\u4e86\u4e00\u526f\u5149\u660e\u7684\u914d\u4f4d\u5316\u5b66\u5e94\u7528\u524d\u666f\u56fe\uff0c\u5229\u7528\u914d\u4f4d\u5316\u5b66\u4fc3\u8fdb\u4e86\u5747\u76f8\u548c\u5f02\u76f8\u5149\u50ac\u5316\u95f4\u7684\u957f\u671f\u8fc7\u6e21\uff0c\u5b9e\u73b0\u4e86\u5747\u76f8\u548c\u5f02\u76f8\u5149\u50ac\u5316\u5242\u7684\u4f18\u70b9\u7684\u7edf\u4e00\u3002<\/p>\n<p>\u968f\u7740\u79d1\u7814\u4eba\u5458\u5bf9\u5149\u50ac\u5316\u7814\u7a76\u5174\u8da3\u7684\u6301\u7eed\u63d0\u5347\u548c\u79d1\u7814\u6210\u679c\u7684\u4e0d\u65ad\u589e\u52a0\uff0c\u53ef\u4ee5\u9884\u6d4b\u5229\u7528\u914d\u4f4d\u5316\u5b66\u4f5c\u4e3a\u6865\u6881\uff0c\u5b9e\u73b0\u5747\u76f8\u5149\u50ac\u5316\u4e0e\u5f02\u76f8\u5149\u50ac\u5316\u7684\u6574\u5408\uff0c\u5c06\u4e24\u4e2a\u5b66\u79d1\u7684\u4f18\u70b9\u7ed3\u5408\u8d77\u6765\uff0c\u6709\u5229\u4e8e\u5149\u50ac\u5316\u9886\u57df\u7684\u53c8\u4e00\u6b21\u9769\u65b0\u3002 \u5229\u7528\u914d\u4f4d\u5316\u5b66\uff0c\u8bbe\u8ba1\u5f02\u76f8\u5149\u50ac\u5316\u5242\u8fd9\u4e00\u7b56\u7565\uff0c\u4e3a\u514b\u670d\u76ee\u524d\u9762\u4e34\u7684\u5149\u50ac\u5316\u74f6\u9888\u95ee\u9898\u63d0\u4f9b\u4e86\u4e00\u4e2a\u73b0\u5b9e\u53ef\u884c\u7684\u8bbe\u8ba1\u65b9\u6848\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><a href=\"http:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2017\/cs\/c6cs00727a#!divAbstract\" target=\"_blank\">Coordination chemistry in the design of heterogeneous photocatalysts<\/a>(Chem. Soc. Rev., 2017, DOI: 10.1039\/c6cs00727a)<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u7ec4 \u6df1\u6d77\u4e07\u91cc \u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n<p>\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u6216\u4e86\u89e3\u65b0\u80fd\u6e90\u5c0f\u7ec4\u62db\u52df\u8be6\u60c5\uff0c\u8bf7\u52a0\u5165\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4\uff08422065952\uff09\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\">\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com<\/p>\n<p><strong>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong><a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\"><strong>\u6d4b\u8bd5\u8c37<\/strong><\/a><strong>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u4f5c\u4e3a\u5149\u50ac\u5316\u9886\u57df\u5185\u7684\u91cd\u8981\u5206\u652f\u4e4b\u4e00\uff0c\u5f02\u76f8\u50ac\u5316\u5177\u5907\u50ac\u5316\u5242\u6613\u5206\u79bb\u3001\u5faa\u73af\u5229\u7528\u7387\u9ad8\u7b49\u4f18\u70b9\uff0c\u56e0\u800c\u5728\u5316\u5b66\u5de5\u4e1a\u4e2d\u5f97\u4ee5\u5e7f\u6cdb\u5e94\u7528\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u5747\u76f8\u50ac\u5316\u5219\u5177\u5907\u50ac\u5316\u6d3b\u6027\u4f18\u5f02\u3001\u4ea7\u7269&#8230;<\/p>\n","protected":false},"author":2219,"featured_media":76175,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[533],"tags":[],"class_list":["post-76140","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zongshu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/76140"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2219"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=76140"}],"version-history":[{"count":6,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/76140\/revisions"}],"predecessor-version":[{"id":76234,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/76140\/revisions\/76234"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/76175"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=76140"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=76140"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=76140"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}