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\u8fd1\u671f\uff0c\u5728<strong>\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u3001\u534e\u5357\u7406\u5de5\u5927\u5b66\u5510\u672c\u5fe0\u9662\u58eb<\/strong>\u548c<strong>\u534e\u5357\u7406\u5de5\u5927\u5b66\u7684\u80e1\u84c9\u84c9\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u5728<strong>JACS<\/strong>\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u5173\u4e8e\u65e0\u91d1\u5c5e\u53c2\u4e0e\u7684\u591a\u7ec4\u5206\u4e32\u8054\u805a\u5408\u53cd\u5e94\u7684\u6587\u7ae0\uff0c\u9898\u76ee\u4e3a\u201c<strong>Metal-Free Multicomponent Tandem Polymerizations of Alkynes, Amines, and Formaldehyde toward Structureand Sequence-Controlled Luminescent Polyheterocycles<\/strong>\u201d\u3002\u7531\u4e59\u7094\u4e8c\u7fa7\u9178\u76d0\u7684\u9ad8\u6548\u65e0\u91d1\u5c5eMCRs\u7684\u542f\u53d1\uff0c\u5510\u672c\u5fe0\u9662\u58eb\u56e2\u961f\u5728\u5ba4\u6e29\u4e0b\u5f00\u53d1\u4e86\u4e59\u7094\u4e8c\u7fa7\u9178\u8102\uff0c\u82b3\u65cf\u4e8c\u80fa\u548c\u7532\u919b\u7684\u65e0\u91d1\u5c5e\u4e00\u9505\u4e09\/\u56db\u7ec4\u5206\u4e32\u8054\u805a\u5408\uff0c\u5408\u6210\u4e86\u9ad8\u5206\u5b50\u91cf\u548c\u9ad8\u4ea7\u91cf\u7684\u591a\u73af\u6742\u73af\u5316\u5408\u7269\u3002\u5927\u591a\u6570\u805a\u5408\u4ec5\u5c06\u5355\u4f53\u7ed3\u6784\u5355\u5143\u8fde\u63a5\u5728\u4e00\u8d77\uff0c\u5176\u4e2d\u5f88\u5c11\u53ef\u4ee5\u539f\u4f4d\u6784\u5efa\u65b0\u7684\u5b98\u80fd\u56e2\u3002\u5728\u8fd9\u4e9bMCTPs\u4e2d\uff0c\u529f\u80fd\u6742\u73af\u76f4\u63a5\u7531\u5e02\u552e\u7684\u5ec9\u4ef7\u7b80\u5355\u7684\u5355\u4f53\u805a\u5408\u5f97\u5230\uff0c\u6240\u5f97\u5230\u7684\u805a\u5408\u7269\u4e0d\u80fd\u901a\u8fc7\u5176\u5b83\u5408\u6210\u65b9\u6cd5\u8fdb\u884c\u3002\u6b64\u5916\uff0c\u4e8c\u53d6\u4ee3\u7684\u5185\u94fe\u7094\u70c3\u7528\u4f5c\u8fd9\u4e9bMCTPs\u4e2d\u7684\u5355\u4f53\uff0c\u800c\u4e0d\u662f\u4f20\u7edf\u7684\u672b\u7aef\u7094\u70c3\uff0c\u5927\u5927\u4e30\u5bcc\u4e86\u5355\u4f53\u54c1\u79cd\u3001\u4ea7\u54c1\u591a\u6837\u6027\u548c\u529f\u80fd\u3002\u5373\u4f7f\u6ca1\u6709\u5178\u578b\u7684\u53d1\u5149\u4f53\u5b58\u5728\u4e8e\u7ed3\u6784\u4e2d\uff0c\u4ece\u6a21\u578b\u5316\u5408\u7269\u548c\u591a\u5143\u6742\u73af\u5316\u5408\u7269\u4e2d\u89c2\u5bdf\u5230\u6709\u8da3\u4e14\u72ec\u7279\u7684\u56fa\u6709\u8367\u5149\u73b0\u8c61\uff0c\u63ed\u793a\u4e86\u65b0\u7684\u53d1\u5149\u673a\u5236\u548c\u53d1\u5149\u4f53\u3002\u8fd9\u4e9b\u53d1\u73b0\u53ef\u80fd\u4e0e\u751f\u7269\u7cfb\u7edf\u4e2d\u666e\u904d\u89c2\u5bdf\u5230\u795e\u79d8\u7684\u81ea\u53d1\u8367\u5149\u73b0\u8c61\u76f8\u5173\uff0c\u5e76\u63ed\u793a\u5176\u6f5c\u5728\u7684\u539f\u56e0\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe1\uff08A\uff09\u5316\u5408\u72694a-b\u548c5a-b\u7684\u5408\u6210\u548c\uff08B\uff09\u63d0\u51fa\u7684MCRs\u7684\u673a\u7406<\/strong><\/p>\n<p><img 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\u5728\u805a\u96c6\u72b6\u6001\u4e0b\uff0c\u805a\u5408\u7269\u94fe\u4e2d\u5927\u91cf\u7684\u7fb0\u57fa\u4ee5\u53ca\u6742\u539f\u5b50\u805a\u96c6\u5728\u4e00\u8d77\u5f62\u6210\u201c\u6742\u539f\u5b50\u7c07\u201d\uff0c\u5176\u53ef\u4ee5\u4f5c\u4e3a\u53d1\u5149\u4f53\u5e76\u4e14\u4f7f\u8367\u5149\u589e\u5f3a\u3002<\/p>\n<p>\n <strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n<p>\u5510\u672c\u5fe0\u56e2\u961f\u63d0\u51fa\u4e86\u5229\u7528\u916f\u57fa\u6d3b\u5316\u7684\u7094\u70c3\u3001\u82b3\u65cf\u4e8c\u80fa\u548c\u7532\u919b\u8fdb\u884c\u7684\u591a\u7ec4\u5206\u65e0\u91d1\u5c5e\u4e00\u9505\u6cd5\u4e32\u8054\u805a\u5408\u53cd\u5e94\uff0c\u9ad8\u6548\u7387\u5e76\u4e14\u7b80\u4fbf\u5730\u5236\u5907\u5177\u6709\u786e\u5b9a\u7ed3\u6784\u3001\u89c4\u5219\u6392\u5217\u987a\u5e8f\u548c\u9ad8\u5206\u5b50\u91cf\u7684\u591a\u73af\u6742\u73af\u805a\u5408\u7269\u3002\u8fd9\u4e9bMCTPs\u4e3a\u5408\u6210\u5e8f\u5217\u63a7\u5236\u7684\u805a\u5408\u7269\u7684\u8f7b\u677e\u6784\u5efa\uff0c\u63d0\u4f9b\u4e86\u5f88\u597d\u7684\u673a\u4f1a\uff0c\u4e3a\u672a\u6765\u5bf9\u805a\u5408\u7269\u6750\u6599\u7684\u5e8f\u5217\u4f9d\u8d56\u6027\u529f\u80fd\u7684\u7814\u7a76\u94fa\u5e73\u9053\u8def\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/pubs.acs.org\/doi\/suppl\/10.1021\/jacs.6b12767\" target=\"_blank\">Metal-Free Multicomponent Tandem Polymerizations of Alkynes, Amines, and Formaldehyde toward Structureand Sequence-Controlled Luminescent Polyheterocycles<\/a><\/strong> (J. Am. Chem. Soc., 2017, DOI:10.1021\/jacs.6b12767 )<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u9ad8\u5206\u5b50\u6750\u6599\u7ec4\u5357\u65b9\u4e00\u661f\u7f16\u8bd1\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002\u53c2\u4e0e\u9ad8\u5206\u5b50\u8bdd\u9898\u8ba8\u8bba\u6216\u4e86\u89e3\u9ad8\u5206\u5b50\u7ec4\u62db\u52df\u8be6\u60c5\uff0c\u8bf7\u52a0\u9ad8\u5206\u5b50\u4ea4\u6d41\u7fa4\uff08298064863\uff09\u3002<\/p>\n<p><strong>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\">\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-75421 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/IMG_0271-3.jpg\" alt=\"\" width=\"258\" height=\"258\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/IMG_0271-3.jpg 258w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/04\/IMG_0271-3-150x150.jpg 150w\" sizes=\"(max-width: 258px) 100vw, 258px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u505a\u4e00\u4e2a\u7231\u5206\u4eab\u7684\u79d1\u7814\u4eba\uff0c\u8bf7\u5173\u6ce8<span style=\"color: #0000ff;\">\u5927\u5206\u5b50<\/span>\u516c\u4f17\u53f7\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u5177\u6709\u4e0d\u540c\u5316\u5b66\u6027\u8d28\u7684\u5355\u4f53\u5355\u5143\u4ee5\u4e00\u5b9a\u7684\u6b21\u5e8f\u8fdb\u884c\u6392\u5217\uff0c\u6240\u5f62\u6210\u7684\u5e8f\u5217\u63a7\u5236\u805a\u5408\u7269\u5bf9\u4e8e\u805a\u5408\u7269\u7684\u7814\u7a76\u662f\u975e\u5e38\u6709\u8da3\u7684\u3002 \u4f17\u6240\u5468\u77e5\u7684\u662f\uff0c\u5e8f\u5217\u63a7\u5236\u7684\u5929\u7136\u805a\u5408\u7269\u6709DNA\uff0cRN&#8230;<\/p>\n","protected":false},"author":24,"featured_media":75413,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[42],"class_list":["post-75411","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-gaofenzi"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/75411"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/24"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=75411"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/75411\/revisions"}],"predecessor-version":[{"id":75456,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/75411\/revisions\/75456"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/75413"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=75411"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=75411"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=75411"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}