{"id":75188,"date":"2017-04-13T06:30:28","date_gmt":"2017-04-12T22:30:28","guid":{"rendered":"\/\/m.iemloyee.com\/?p=75188"},"modified":"2017-04-09T20:24:12","modified_gmt":"2017-04-09T12:24:12","slug":"angew-chem-int-ed-%e5%a4%a7%e8%bf%9e%e7%90%86%e5%b7%a5%e5%a4%a7%e5%ad%a6-%e5%ae%8c%e5%85%a8%e5%8f%af%e5%9b%9e%e6%94%b6%e7%9a%84%e5%8d%95%e4%bd%93%e5%92%8c%e8%81%9a%e7%a2%b3","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=75188","title":{"rendered":"Angew. Chem. Int. Ed.: \u5927\u8fde\u7406\u5de5-\u5b8c\u5168\u53ef\u56de\u6536\u7684\u5355\u4f53\u548c\u805a\u78b3\u9178\u916f"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u56de\u6536\u7684\u7ecf\u6d4e\u6027\u662f\u5efa\u7acb\u53ef\u6301\u7eed\u53d1\u5c55\u4f53\u7cfb\u7684\u5173\u952e\u3002\u5728\u805a\u5408\u7269\u9886\u57df\uff0c\u5c06\u5e9f\u5f03\u7684\u805a\u5408\u7269\u964d\u89e3\u4e3a\u80fd\u518d\u6b21\u53d1\u751f\u805a\u5408\u53cd\u5e94\u7684\u539f\u59cb\u5355\u4f53\u662f\u4e00\u4e2a\u5f88\u91cd\u8981\u7684\u7814\u7a76\u65b9\u5411\u3002\u901a\u5e38\uff0c\u8fd9\u79cd\u964d\u89e3\u7684\u6761\u4ef6\u975e\u5e38\u82db\u523b\uff0c\u4f8b\u5982\u9ad8\u6e29\u3001\u9ad8\u538b\uff0c\u5bfc\u81f4\u6700\u7ec8\u5f97\u5230\u7684\u539f\u59cb\u5355\u4f53\u6536\u7387\u4f4e\u3002\u7814\u7a76\u4eba\u5458\u5728\u8fd9\u4e2a\u9886\u57df\u505a\u4e86\u5927\u91cf\u7684\u7814\u7a76\uff0c\u5f97\u5230\u4e86\u5f88\u591a\u91cd\u8981\u7684\u7814\u7a76\u6210\u679c\u3002\u4f46\u662f\u4ed6\u4eec\u7684\u6210\u679c\u603b\u4f53\u8fd8\u5b58\u5728\u4e00\u4e9b\u4e0d\u8db3\uff0c\u6bd4\u5982\u5f97\u5230\u7684\u539f\u59cb\u5355\u4f53\u6536\u7387\u4f4e\u3001\u4ea7\u7387\u4f4e\u3001\u964d\u89e3\u6e29\u5ea6\u9ad8\u7b49\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u4e00\u79cd\u7b80\u5355\u9ad8\u6548\u7684\u65b9\u6cd5\uff0c\u4f7f\u5e9f\u5f03\u805a\u5408\u7269\u5728\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\uff0c\u964d\u89e3\u4e3a\u76f8\u5e94\u7684\u5355\u4f53\uff0c\u5c31\u975e\u5e38\u7684\u6709\u5fc5\u8981\u4e86\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5927\u8fde\u7406\u5de5\u5927\u5b66\u7684\u5218\u91ce\u535a\u58eb\u548c\u5415\u5c0f\u5175\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\uff0c\u5728\u53cc\u6838\u94ec\u7edc\u5408\u7269\u4e3a\u50ac\u5316\u5242\u7684\u6761\u4ef6\u4e0b\uff0c\u4f7fCO2\u4e0e\u5185\u6d88\u65cb\u73af\u6c27\u5316\u5408\u7269\uff08BEP\uff09\u53d1\u751f\u805a\u5408\u53cd\u5e94\uff0c\u5408\u6210\u4e86\u4e00\u79cd\u53ef\u964d\u89e3\u7684\u3001\u53ef\u5faa\u73af\u56de\u6536\u5229\u7528\u7684\u805a\u78b3\u9178\u916f\u5851\u6599\u3002\u800c\u4e14\uff0c\u5728\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\uff0c\u8fd9\u79cd\u805a\u78b3\u9178\u916f\u5851\u6599\u80fd\u591f\u5faa\u73af\u56de\u6536\u5229\u7528\u8f6c\u5316\u4e3a\u73af\u6c27\u5355\u4f53\uff0c\u8f6c\u5316\u6536\u7387\u9ad8\u3002\u751a\u81f3\uff0c\u8fd9\u79cd\u805a\u5408\/\u964d\u89e3\u7684\u53ef\u9006\u8fc7\u7a0b\u80fd\u591f\u901a\u8fc7\u8c03\u8282\u6e29\u5ea6\u8fdb\u884c\u63a7\u5236\uff0c\u5728\u591a\u6b21\u5faa\u73af\u5229\u7528\u8fc7\u540e\uff0c\u5f97\u5230\u7684\u73af\u6c27\u5355\u4f53\u548c\u805a\u5408\u7269\u4e0d\u4f1a\u53d1\u751f\u4efb\u4f55\u6539\u53d8\u3002\u8fd9\u4e9b\u7279\u6027\u5b8c\u5168\u7b26\u5408\u805a\u5408\u7269\u53ef\u6301\u7eed\u53d1\u5c55\u7406\u5ff5\u7684\u8981\u6c42\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cCompletely Recyclable Monomers and Polycarbonate: Approach to Sustainable Polymers<\/strong>\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728\u8fd1\u671f\u7684Angew. Chem. Int. Ed.<\/strong>\u6742\u5fd7\u4e0a\uff0c<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1 CO2\u4e0eBEP\u751f\u6210\u5b8c\u5168\u53ef\u5faa\u73af\u7684\u805a\u78b3\u9178\u916f\u5851\u6599\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08\u2160\uff09\u4e0a\u56fe\u4e3a\u805a\u78b3\u9178\u916f\u805a\u5408\u7269\u53ca\u5176\u5355\u4f53\u964d\u89e3\uff0f\u805a\u5408\u7684\u8fc7\u7a0b\u53ca\u6761\u4ef6\uff1b<\/p>\n

\uff08\u2161\uff09\u4e0b\u56fe1\u4e3a\u53cc\u6838\u4e09\u4ef7\u94ec\u7edc\u5408\u7269\u50ac\u5316\u5242\uff1b<\/p>\n

\uff08\u2162\uff09\u4e0b\u56fe2\u4e3a\u5355\u6838\u4e09\u4ef7\u94ec\u7edc\u5408\u7269\u50ac\u5316\u5242\u3002<\/p>\n

\u56fe2 \u4e09\u4ef7\u94ec\u7edc\u5408\u7269\u50ac\u5316CO2\/BEP\u53d1\u751f\u805a\u5408\u53cd\u5e94<\/strong><\/p>\n

\"\"<\/p>\n

\uff08\u2160\uff09\u53cd\u5e94\u5728\u7532\u82ef\u6eb6\u6db2\u4e2d\u8fdb\u884c\uff0c\u73af\u6c27\u5316\u5408\u7269\u4e0e\u7532\u82ef\u8d28\u91cf\u6bd4\u4e3a1:1\uff0cBEP\u542b\u91cf1.0g\uff0c\u5bb9\u5668\u4e3a\u9ad8\u538b\u706d\u83cc\u5668\uff0cCO2\u538b\u529b\u4e3a2.0MPa\uff0c1H NMR\u5149\u8c31\u663e\u793a\uff0c\u5f97\u5230\u7684\u805a\u5408\u7269\u7684\u78b3\u9178\u916f\u94fe\u542b\u91cf\u9ad8\u4e8e99%\uff1b<\/p>\n

\uff08\u2161\uff09b\u5904\u50ac\u5316\u5242\u6bd4\u4f8b\u4ee5\u6469\u5c14\u5206\u6570\u8868\u793a\uff1b<\/p>\n

\uff08\u2162\uff09c\u5904\u5468\u8f6c\u9891\u7387\uff08TOF\uff09\u4ee5\u6bcf\u5c0f\u65f6\u4ea7\u54c1\u6469\u5c14\u6570\u4e0e\u50ac\u5316\u5242\u6469\u5c14\u6570\u7684\u6bd4\u503c\u8868\u793a\uff1b<\/p>\n

\uff08\u2163\uff09d\u5904\u805a\u5408\u7269\u9009\u62e9\u6027\u662f\u6839\u636e1H NMR\u5149\u8c31\uff0c\u805a\u78b3\u9178\u916f\u5bf9\u73af\u78b3\u9178\u916f\u7684\u9009\u62e9\u6027\uff1b<\/p>\n

\uff08\u2164\uff09e\u5904\uff0c\u5728THF\u4e2d\uff0c\u5229\u7528\u51dd\u80f6\u6e17\u900f\u8272\u8c31\u6cd5\uff0c\u7136\u540e\u57fa\u4e8e\u805a\u82ef\u4e59\u70ef\u8f83\u6b63\u540e\u5f97\u5230\u7684\u6570\u636e\uff1b<\/p>\n

\uff08\u2165\uff09f\u5904\u5728\u6ca1\u6709\u534f\u540c\u50ac\u5316\u5242\u7684\u6761\u4ef6\u4e0b\u8fdb\u884c\u7684\u53cd\u5e94\uff1b<\/p>\n

\uff08\u2166\uff09g\u5904\u4e0d\u53d1\u751f\u5316\u5b66\u53cd\u5e94\uff1b<\/p>\n

\uff08\u2167\uff09h\u5904CO2\u538b\u529b\u4e3a1.0MPa\u65f6\u7684\u53cd\u5e94\uff1b<\/p>\n

\uff08\u2168\uff09i\u5904\u73af\u6c27\u5316\u5408\u7269\u6ca1\u6709\u53d1\u751f\u53cd\u5e94\uff0c\u73af\u78b3\u9178\u916f\u548c\u4e8c\u9187\u6ca1\u6709\u751f\u6210\u3002<\/p>\n

\u56fe3 BEP\u4e0eCO2\u53d1\u751f\u805a\u5408\uff0f\u5206\u89e3\u53cd\u5e94\u968f\u65f6\u95f4\u7684\u53d8\u5316\u5173\u7cfb\uff08FTIR\u6d4b\u91cf\uff09<\/strong><\/p>\n

\"\"<\/p>\n

vC=O\u5cf0\u503c\u57281755cm\uff0d1\u65f6\u53d1\u751f\u7684\u805a\u5408\u53cd\u5e94\u4e0e\u65f6\u95f4\u7684\u53d8\u5316\u5173\u7cfb\uff1b<\/p>\n

\u56fe4 BEP\u4e0eCO2\u53d1\u751f\u805a\u5408\uff0f\u5206\u89e3\u5faa\u73af\u76841H NMR\u5149\u8c31\u56fe<\/strong><\/p>\n

\"\"
\n \uff08\u2160\uff09A\u8868\u793a\u805a\u5408\u53cd\u5e94\u7b2c\u4e00\u5faa\u73af\u9636\u6bb5P1\uff1b<\/p>\n

\uff08\u2161\uff09B\u8868\u793a\u805a\u5408\u7269\u5206\u89e3\u4e3a\u5355\u4f53\u7684\u53cd\u5e94\u7b2c\u4e00\u5faa\u73af\u9636\u6bb5D1\uff1b<\/p>\n

\uff08\u2162\uff09C\u8868\u793a\u805a\u5408\u53cd\u5e94\u7b2c\u4e8c\u5faa\u73af\u9636\u6bb5P2\uff1b<\/p>\n

\uff08\u2163\uff09D\u8868\u793a\u805a\u5408\u7269\u5206\u89e3\u4e3a\u5355\u4f53\u7684\u53cd\u5e94\u7b2c\u4e8c\u5faa\u73af\u9636\u6bb5D2\u3002<\/p>\n

\u56fe5 \u4e0d\u540c\u4e2d\u95f4\u4ea7\u7269\u53d1\u751f\u53cd\u54ac\u53cd\u5e94\u6a21\u578b<\/strong><\/p>\n

\"\"<\/p>\n

\uff08\u2160\uff091\u8868\u793a\u53cd\u5f0f\u78b3\u9178\u916f\u7684\u751f\u6210\u662f\u5438\u70ed\u53cd\u5e94\uff1b<\/p>\n

\uff08\u2161\uff092\u8868\u793a\u987a\u5f0f\u78b3\u9178\u916f\u7684\u751f\u6210\u662f\u653e\u70ed\u53cd\u5e94\uff1b<\/p>\n

\uff08\u2162\uff093\u8868\u793a\u9187\u76d0\u4e2d\u95f4\u4ea7\u7269\u901a\u8fc7\u53cd\u54ac\u53cd\u5e94\u751f\u6210\u6b21\u7532\u57fa\u78b3\u539f\u5b50\uff0c\u5f97\u5230\u5185\u6d88\u65cb\u73af\u6c27\u5316\u5408\u7269\uff0c\u53cd\u5e94\u81ea\u7531\u80fd\u4e3a12.3 kcalmol\uff0d1\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

1\u3001\u572860\u2103\u548c\u50ac\u5316\u5242\u7684\u6761\u4ef6\u4e0b\uff0c BEP\u4e0eCO2\u53d1\u751f\u805a\u5408\u53cd\u5e94\uff0c\u751f\u6210\u5bf9\u5e94\u7684\u805a\u78b3\u9178\u916f\uff0c\u5f97\u5230\u7684\u805a\u78b3\u9178\u916f\u7684\u78b3\u9178\u916f\u94fe\u542b\u91cf\u9ad8\u4e8e99%\u3001\u805a\u5408\u5206\u6563\u5ea6\u4f4e\uff1b
\n 2\u3001\u5728100\u2103\u7684\u6761\u4ef6\u4e0b\uff0c\u805a\u78b3\u9178\u916f\u8fc5\u901f\u5206\u89e3\uff0c\u5f97\u5230\u76f8\u5e94\u7684\u539f\u5355\u4f53\uff0c\u4e14\u6536\u7387\u9ad8\uff1b
\n 3\u3001\u901a\u8fc7\u8c03\u8282\u53cd\u5e94\u6e29\u5ea6\uff0c\u53ef\u4ee5\u63a7\u5236\u805a\u5408\uff0f\u5206\u89e3\u53cd\u5e94\u8fc7\u7a0b\uff0c\u7ecf\u8fc7\u591a\u6b21\u805a\u5408\uff0f\u5206\u89e3\u5faa\u73af\u540e\uff0c\u5355\u4f53\u548c\u805a\u5408\u7269\u90fd\u4e0d\u4f1a\u53d1\u751f\u4efb\u4f55\u53d8\u5316\uff1b
\n 4\u3001\u6b64\u805a\u78b3\u9178\u916f\u7684\u7279\u6027\u5b8c\u5168\u7b26\u5408\u805a\u5408\u7269\u53ef\u6301\u7eed\u53d1\u5c55\u7406\u5ff5\u7684\u8981\u6c42\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aCompletely Recyclable Monomers and Polycarbonate: Approach to Sustainable Polymers<\/a><\/strong>\uff08Angew. Chem. Int. Ed., 2017, DOI: 10.1002\/anie.201701438\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u9ad8\u5206\u5b50\u5c0f\u7ec4\u718a\u6587\u6770\u63d0\u4f9b\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002\u53c2\u4e0e\u9ad8\u5206\u5b50\u8bdd\u9898\u8ba8\u8bba\u6216\u4e86\u89e3\u9ad8\u5206\u5b50\u7ec4\u62db\u52df\u8be6\u60c5\uff0c\u8bf7\u52a0\u9ad8\u5206\u5b50\u4ea4\u6d41\u7fa4\uff08298064863\uff09\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n

\"\"<\/p>\n

\u505a\u4e00\u4e2a\u7231\u5206\u4eab\u7684\u79d1\u7814\u4eba\uff0c\u8bf7\u5173\u6ce8\u5927\u5206\u5b50<\/span>\u516c\u4f17\u53f7\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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