{"id":73128,"date":"2017-03-28T17:00:16","date_gmt":"2017-03-28T09:00:16","guid":{"rendered":"\/\/m.iemloyee.com\/?p=73128"},"modified":"2017-03-28T17:31:59","modified_gmt":"2017-03-28T09:31:59","slug":"%e5%ad%a6%e6%9c%af%e5%b9%b2%e8%b4%a7%e2%88%a3zno%e5%9c%a8%e6%9f%93%e6%96%99%e9%87%8f%e5%ad%90%e7%82%b9%e6%95%8f%e5%8c%96%e5%a4%aa%e9%98%b3%e8%83%bd%e7%94%b5%e6%b1%a0%e4%b8%ad%e7%9a%84%e5%ba%94","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=73128","title":{"rendered":"\u5b66\u672f\u5e72\u8d27\u2223ZnO\u5728\u67d3\u6599\/\u91cf\u5b50\u70b9\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u7684\u5e94\u7528"},"content":{"rendered":"<p><span style=\"color: #0000ff;\"><strong>\u4e00\u3001\u5f15\u8a00<\/strong><\/span><\/p>\n<p>\u592a\u9633\u80fd\u4f5c\u4e3a\u4e00\u79cd\u6e05\u6d01\u53ef\u518d\u751f\u80fd\u6e90\uff0c\u5408\u7406\u5730\u5f00\u53d1\u5229\u7528\u592a\u9633\u80fd\u6210\u4e3a\u4e86\u5f53\u524d\u56fd\u5185\u5916\u7814\u7a76\u8005\u4eec\u7684\u7814\u7a76\u70ed\u70b9\u3002\u6309\u6750\u6599\u4e0d\u540c\uff0c\u592a\u9633\u80fd\u7535\u6c60\u53ef\u4ee5\u5206\u4e3a\u4e09\u7c7b<sup>[1]<\/sup>\uff1a(1)\u6676\u7845\u592a\u9633\u80fd\u7535\u6c60(\u5305\u62ec\u5355\u6676\u7845\u548c\u591a\u6676\u7845\u592a\u9633\u80fd\u7535\u6c60)\uff1b(2)\u8584\u819c\u592a\u9633\u80fd\u7535\u6c60(\u5982\u975e\u6676\u7845\u8584\u819c\u7535\u6c60\u548c\u591a\u6676\u7845\u8584\u819c\u7535\u6c60)\uff1b(3)\u65b0\u578b\u9ad8\u6548\u5149\u5316\u5b66\u592a\u9633\u80fd\u7535\u6c60(\u5982\u67d3\u6599\u654f\u5316\u7535\u6c60\u3001\u91cf\u5b50\u70b9\u7535\u6c60\u53ca\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7b49)\u3002\u5176\u4e2d\uff0c\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u53d6\u5f97\u4e86\u6301\u7eed\u4e0d\u65ad\u7684\u53d1\u5c55\uff0c\u5176\u5149\u7535\u8f6c\u5316\u6548\u7387\u4ece\u6700\u521d\u76847.1%\u63d0\u9ad8\u81f313%\uff0c\u5177\u6709\u826f\u597d\u7684\u5e94\u7528\u524d\u666f<sup>[2]<\/sup>\u3002\u5728\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60(Dye-Sensitized 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#0000ff;\"><strong>\u4e8c\u3001\u654f\u5316\u7535\u6c60\u5de5\u4f5c\u539f\u7406<\/strong><\/span><\/p>\n<p>\u5728\u654f\u5316\u7535\u6c60\u5de5\u4f5c\u65f6\uff0c\u654f\u5316\u5242\u4e2d\u7684\u57fa\u6001\u7535\u5b50\u53d7\u5149\u6fc0\u53d1\u4ece\u57fa\u6001\u8dc3\u8fc1\u81f3\u6fc0\u53d1\u6001\uff0c\u6fc0\u53d1\u6001\u7684\u7535\u5b50\u8fc5\u901f\u6ce8\u5165\u5230\u5149\u9633\u6781\u6750\u6599\u7684\u5bfc\u5e26\u4e2d\uff0c\u518d\u901a\u8fc7\u5916\u7535\u8def\u5230\u8fbe\u5bf9\u7535\u6781\uff0c\u800c\u6c27\u5316\u6001\u7684\u654f\u5316\u5242\u5219\u88ab\u7535\u89e3\u6db2\u4e2d\u7684\u8fd8\u539f\u6001\u79bb\u5b50\u8fd8\u539f\uff0c\u4ee5\u6b64\u5b8c\u6210\u4e00\u4e2a\u5de5\u4f5c\u5faa\u73af<sup>[3]<\/sup>\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-73142\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/1-21.png\" alt=\"\" width=\"600\" height=\"272\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/1-21.png 791w, 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ZnO\u7a33\u5b9a\u6027\u4e0d\u9ad8\uff0c\u5bb9\u6613\u88ab\u7535\u89e3\u6db2\u8150\u8680\uff0c\u4f7f\u5f97\u7535\u6c60\u6548\u7387\u4e0b\u964d\uff0c\u5bff\u547d\u7f29\u77ed\uff1b(2)\u819c\u8868\u9762\u7535\u5b50\u7684\u590d\u5408\u60c5\u51b5\u8f83\u4e25\u91cd\uff1b(3)\u6355\u83b7\u5149\u80fd\u529b\u8f83\u4f4e\u7b49\u7f3a\u70b9\u3002\u4f18\u5316\u7684\u4e3b\u8981\u65b9\u5411\u96c6\u4e2d\u5728\u6539\u53d8\u7eb3\u7c73ZnO\u7684\u7ed3\u6784\uff0c\u4ee5\u51cf\u5c11\u5149\u9633\u6781\u819c\u8868\u9762\u7f3a\u9677\u3001\u63d0\u9ad8\u7535\u5b50\u4f20\u8f93\u80fd\u529b\u5e76\u964d\u4f4e\u7535\u5b50\u7684\u590d\u5408\u3002<\/p>\n<p><span style=\"color: #0000ff;\"><strong>\u4e09\u3001\u5355\u4e00\u7ed3\u6784<\/strong><strong>ZnO<\/strong><strong>\u7eb3\u7c73\u6750\u6599<\/strong><\/span><\/p>\n<p>\u5355\u4e00\u7ed3\u6784\u7684ZnO\u6750\u6599(\u5982\u7eb3\u7c73\u9897\u7c92\u3001\u7eb3\u7c73\u7ebf\u548c\u7eb3\u7c73\u7247\u7b49)\u5236\u5907\u7b80\u5355\uff0c\u4f46\u662f\u53d7\u6750\u6599\u7ed3\u6784\u6240\u9650\uff0c\u5176\u6bd4\u8868\u9762\u79ef\u8f83\u4f4e\uff0c\u4f7f\u5f97\u654f\u5316\u5242\u7684\u6c89\u79ef\u91cf\u8f83\u5c11\uff0c\u65e0\u6cd5\u6355\u83b7\u8db3\u591f\u7684\u5149\u5b50\uff0c\u5f71\u54cd\u7535\u6c60\u6548\u7387\u7684\u63d0\u9ad8\u3002\u76ee\u524d\uff0c\u5355\u4e00\u7ed3\u6784ZnO\u7eb3\u7c73\u6750\u6599\u4f5c\u4e3a\u5149\u9633\u6781\u7684\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u5149\u7535\u8f6c\u6362\u6548\u7387\u8f83\u4f4e\uff0c\u56e0\u6b64\u5f88\u5c11\u91c7\u7528\u5355\u4e00\u7ed3\u6784ZnO\u7eb3\u7c73\u6750\u6599\u4f5c\u4e3a\u592a\u9633\u80fd\u7535\u6c60\u7684\u5149\u9633\u6781\u3002<\/p>\n<p>\u5355\u4e00\u7ed3\u6784\u7684\u7eb3\u7c73ZnO\u6750\u6599\u59820\u7ef4\u7684\u7eb3\u7c73\u9897\u7c92(ZnO 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NP\u6750\u6599\u5236\u5f97\u7684\u654f\u5316\u7535\u6c60\u6548\u7387\u5e76\u4e0d\u9ad8\u3002\u7eb3\u7c73\u7ebf\u5219\u7531\u4e8e\u5176\u72ec\u7279\u7684\u7ebf\u6027\u7ed3\u6784\uff0c\u65e2\u589e\u52a0\u4e86\u6bd4\u8868\u9762\u79ef\uff0c\u53c8\u4e3a\u7535\u5b50\u7684\u4f20\u9012\u63d0\u4f9b\u4e86\u4e00\u6761\u76f4\u63a5\u7684\u901a\u9053\uff0c\u4ece\u800c\u63d0\u9ad8\u4e86\u7535\u5b50\u7684\u4f20\u9012\u6548\u7387\u3002\u540c\u65f6\u72ec\u7acb\u7684\u7ebf\u6027\u6750\u6599\u4e5f\u907f\u514d\u4e86\u76f8\u4e92\u4e4b\u95f4\u7684\u7535\u5b50\u590d\u5408\uff0c\u4ece\u800c\u63d0\u9ad8\u4e86QDSSCs\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u3002\u5c06\u666e\u901a\u7684NW\u7ed3\u6784\u8c03\u6574\u4e3a\u591a\u5b54\u7ed3\u6784\uff0c\u5e76\u5e94\u7528\u4e8eDSSCs\u4e2d\uff0c\u4e0e\u666e\u901aNW\u6750\u6599\u5236\u5f97\u7684DSSCs\u8fdb\u884c\u6bd4\u8f83\u540e\u8bc1\u5b9e\uff0c\u591a\u5b54\u7ed3\u6784\u4f7fNW\u7684\u6bd4\u8868\u9762\u79ef\u8fc5\u901f\u589e\u52a0\uff0c\u5236\u5f97\u7684DSSCs\u7684\u6548\u7387\u4e5f\u6709\u4e86\u660e\u663e\u7684\u63d0\u9ad8<sup>[6]<\/sup>\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-73132\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/4-10.png\" alt=\"\" width=\"600\" height=\"291\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/4-10.png 620w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/4-10-300x146.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe2 \u4ee3\u8868\u6027ZnO NW\u9635\u5217\u7684SEM<sup>[7]<\/sup><\/p>\n<p>\u9664\u7eb3\u7c73\u7ebf\u5916\uff0c\u5728\u739b\u7459\u7814\u94b5\u4e2d\u5c06Zn( NO<sub>3<\/sub>)<sub>2<\/sub>6H<sub>2<\/sub>O\u548cNaOH \u7c89\u672b\u6df7\u5408\u7814\u78e8\uff0c\u5236\u5f97ZnO\u7eb3\u7c73\u7247\u6750\u6599<sup>[8]<\/sup>\u3002\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0cZnO\u7eb3\u7c73\u7247\u4e4b\u95f4\u4e92\u76f8\u8fde\u63a5\u7684\u7ed3\u6784\u6709\u52a9\u4e8e\u7535\u5b50\u7684\u4f20\u8f93\u3002\u6b64\u5916\uff0c\u7814\u7a76\u4eba\u5458\u8fd8\u53d1\u73b0\u70ed\u5904\u7406\u7684\u6e29\u5ea6\u5bf9\u6700\u7ec8\u5236\u5f97\u7684ZnO\u7eb3\u7c73\u7247\u5149\u9633\u6781\u7684\u6027\u80fd\u6709\u8f83\u5927\u7684\u5f71\u54cd\uff0c\u539f\u56e0\u5728\u4e8e\u70ed\u5904\u7406\u6e29\u5ea6\u4e00\u65b9\u9762\u4f1a\u5f71\u54cd\u819c\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u5373\u968f\u7740\u6e29\u5ea6\u4e0a\u5347\uff0c\u6bd4\u8868\u9762\u79ef\u9010\u6e10\u4e0b\u964d\uff0c\u800c\u53e6\u4e00\u65b9\u9762\u53c8\u53ef\u4ee5\u901a\u8fc7\u5347\u9ad8\u6e29\u5ea6\u6253\u901a\u751a\u81f3\u62d3\u5bbd\u67d3\u6599\u6c89\u79ef\u7684\u901a\u9053\uff0c\u4ece\u800c\u5728\u589e\u52a0\u67d3\u6599\u6c89\u79ef\u91cf\u7684\u540c\u65f6\u53c8\u5229\u4e8e\u7535\u5b50\u7684\u4f20\u8f93\uff0c\u964d\u4f4e\u7535\u8377\u590d\u5408\u51e0\u7387\uff0c\u4ece\u800c\u63d0\u9ad8\u7535\u6c60\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-73133 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/5-11.png\" alt=\"\" width=\"538\" height=\"271\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/5-11.png 538w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/5-11-300x151.png 300w\" sizes=\"(max-width: 538px) 100vw, 538px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe3 (a)\u9ad8\u5ea6\u6df7\u4e71\u7eb3\u7c73\u5806\u780c\u7ed3\u6784SEM\uff1b(b)\u5149\u9633\u6781\u5178\u578b\u7ed3\u6784\u793a\u610f\u56fe<sup>[8]<\/sup><\/p>\n<p><span style=\"color: #0000ff;\"><strong>\u56db\u3001<\/strong><strong>ZnO<\/strong><strong>\u591a\u7ea7\u590d\u5408\u7ed3\u6784\u6750\u6599<\/strong><\/span><\/p>\n<p>\u4e3a\u4e86\u5f25\u8865\u5355\u4e00\u7ed3\u6784\u6bd4\u8868\u9762\u79ef\u8f83\u4f4e\u7684\u4e0d\u8db3\uff0c\u7814\u7a76\u4eba\u5458\u5c1d\u8bd5\u5c06\u4e0d\u540c\u7ed3\u6784\u7684ZnO\u7eb3\u7c73\u6750\u6599\u8fdb\u884c\u7ec4\u5408\u4ee5\u5f97\u5230\u591a\u7ea7\u590d\u5408\u7ed3\u6784\u3002\u591a\u7ea7\u590d\u5408\u7ed3\u6784\u6750\u6599\u5177\u6709\u975e\u5e38\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u4ee5\u591a\u7ea7\u590d\u5408\u7ed3\u6784\u6750\u6599\u5236\u5907\u5149\u9633\u6781\uff0c\u6709\u5229\u4e8e\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u7684\u5149\u6355\u83b7\u3001\u8f7d\u6d41\u5b50\u5206\u79bb\u548c\u518d\u7ed3\u5408\u3001\u7535\u8377\u8fc1\u79fb\u7b49\u8fc7\u7a0b\uff0c\u5e76\u53ef\u4ee5\u50ac\u5316\u7535\u6c60\u4e2d\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\uff0c\u4ece\u800c\u63d0\u9ad8\u592a\u9633\u80fd\u7535\u6c60\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u3002\u7528\u4f5c\u5149\u9633\u6781\u7684\u591a\u7ea7\u590d\u5408\u7ed3\u6784\u6750\u6599\u901a\u5e38\u7531\u4e00\u7ef4\u6750\u6599(\u5982\u7eb3\u7c73\u68d2\u3001\u7eb3\u7c73\u7ebf\u3001\u7eb3\u7c73\u7ba1\u3001\u7eb3\u7c73\u5e26\u7b49)\u6216\u4e8c\u7ef4\u6750\u6599(\u7eb3\u7c73\u7247)\u7ec4\u5408\u800c\u6210\u3002\u591a\u7ea7\u590d\u5408\u7ed3\u6784\u53ef\u4ee5\u663e\u8457\u5730\u63d0\u9ad8\u5149\u9633\u6781\u7684\u5149\u654f\u5242\u5438\u9644\u91cf\u3001\u589e\u5927\u56fa-\u6db2\u754c\u9762\u3001\u4fc3\u8fdb\u7535\u8377\u8f6c\u79fb\u548c\u7269\u8d28\u8f6c\u79fb\u5e76\u63d0\u9ad8\u5149\u6355\u83b7\u80fd\u529b\uff0c\u4ece\u800c\u6709\u6548\u5730\u63d0\u5347\u592a\u9633\u80fd\u7535\u6c60\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u3002ZnO\u4e09\u7ef4\u7eb3\u7c73\u7ed3\u6784\u6750\u6599\u7684\u5236\u5907\u65b9\u6cd5\u901a\u5e38\u53ef\u5206\u4e3a\u4e24\u79cd\uff1a\u7269\u7406\u65b9\u6cd5\u548c\u5316\u5b66\u65b9\u6cd5\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-73134\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/6-6.png\" alt=\"\" width=\"466\" height=\"300\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/6-6.png 719w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/6-6-300x193.png 300w\" sizes=\"(max-width: 466px) 100vw, 466px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe4 \u591a\u7ea7\u590d\u5408\u7ed3\u6784\u6750\u6599\u5236\u5907\u793a\u610f\u56fe\u53ca\u5176\u6027\u80fd<sup>[5]<\/sup><\/p>\n<p><strong>4.1 \u7269\u7406\u65b9\u6cd5<\/strong><\/p>\n<p>\u76ee\u524d\uff0c\u6587\u732e\u4e0a\u5df2\u6709\u62a5\u9053\u91c7\u7528\u7269\u7406\u65b9\u6cd5\u5236\u5907\u591a\u5c42ZnO\u5149\u9633\u6781\u819c\u7ed3\u6784\u7684\u7535\u6c60\u3002\u5982\u901a\u8fc7\u53e0\u52a0\u7684\u65b9\u5f0f\u6765\u5236\u5907ZnO\u5149\u9633\u6781\u819c<sup>[9]<\/sup>\uff0c\u5373\u5148\u5728ITO-PET\u73bb\u7483\u4e0a\u9884\u6d82\u4e00\u5c42\u76f4\u5f845 nm\u7684ZnO NP\uff0c\u518d\u522e\u6d82\u4e00\u5c42\u76f4\u5f84\u4e3a20 nm\u7684ZnO NP\uff0c\u6700\u540e\u901a\u8fc7\u4f7f\u7528\u5ba4\u6e29\u4e0b\u7684\u5316\u5b66\u6d74\u6cd5\uff0c\u5728ZnO\u819c\u4e0a\u751f\u957f\u51fa\u4e00\u5c42\u7531\u7eb3\u7c73\u9897\u7c92\u548c\u7eb3\u7c73\u805a\u96c6\u4f53\u6784\u6210\u7684ZnO\u591a\u7ea7\u590d\u5408\u7ed3\u6784\u3002\u901a\u8fc7\u4e0a\u8ff0\u51e0\u79cd\u4e0d\u540c\u7eb3\u7c73\u7ed3\u6784\u7684\u53e0\u52a0\uff0cZnO\u5149\u9633\u6781\u7684\u6bd4\u8868\u9762\u79ef\u5f97\u5230\u4e86\u589e\u52a0\uff0c\u4ece\u800c\u589e\u52a0\u4e86\u592a\u9633\u80fd\u7535\u6c60\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u3002\u6b64\u5916\uff0c\u5728\u819c\u8868\u9762\u522e\u6d82ZnO\u6563\u5c04\u5c42\uff0c\u53ef\u4ee5\u63d0\u9ad8\u7535\u6c60\u5149\u7535\u8f6c\u6362\u6548\u7387\uff1b\u6539\u53d8\u6563\u5c04\u5c42\u539a\u5ea6\uff0c\u53ef\u4ee5\u6539\u53d8\u592a\u9633\u80fd\u7535\u6c60\u7684\u77ed\u8def\u7535\u6d41\u5bc6\u5ea6\u3002<\/p>\n<p><strong>4.2 \u5316\u5b66\u65b9\u6cd5<\/strong><\/p>\n<p>\u4e0e\u7269\u7406\u65b9\u6cd5\u76f8\u6bd4\uff0c\u5316\u5b66\u65b9\u6cd5\u5236\u5907\u7684\u591a\u7ea7\u590d\u5408\u7ed3\u6784ZnO\u6750\u6599\u6027\u80fd\u66f4\u52a0\u4f18\u826f\u3002\u4f7f\u7528\u5316\u5b66\u65b9\u6cd5\u53ef\u4ee5\u5c06\u4e0d\u540c\u7684ZnO\u7ed3\u6784\u76f4\u63a5\u751f\u957f\u5728\u5149\u9633\u6781\u57fa\u5e95\u4e0a\uff0c\u6216\u662f\u5408\u6210\u591a\u79cd\u7ed3\u6784\u590d\u5408\u7684\u7eb3\u7c73\u6750\u6599\u7136\u540e\u522e\u6d82\u5728\u5149\u9633\u6781\u57fa\u5e95\u4e0a\u5236\u5907\u5f97\u5230\u591a\u7ea7\u7ed3\u6784\u7eb3\u7c73\u819c\u3002\u4e0e\u7269\u7406\u624b\u6bb5\u76f8\u6bd4\uff0c\u5316\u5b66\u65b9\u6cd5\u5236\u5907\u7684\u4e0d\u540c\u7ed3\u6784\u4e4b\u95f4\u901a\u8fc7\u5316\u5b66\u952e\u8fdb\u884c\u8fde\u63a5\uff0c\u5176\u76f8\u4e92\u4e4b\u95f4\u7684\u8054\u7cfb\u66f4\u4e3a\u7d27\u5bc6\uff0c\u56e0\u6b64\u53ef\u4ee5\u51cf\u5c11\u5149\u9633\u6781\u6750\u6599\u4e2d\u7684\u7f3a\u9677\uff0c\u6709\u5229\u4e8e\u7535\u5b50\u7684\u4f20\u8f93\uff0c\u518d\u52a0\u4e0a\u4e0d\u540c\u7ed3\u6784\u5404\u81ea\u7684\u4f18\u52bf\uff0c\u4f7f\u5176\u5728\u5149\u7535\u6c60\u4e2d\u53d1\u6325\u51fa\u72ec\u7279\u7684\u6027\u80fd\u3002<\/p>\n<p>\u591a\u7ea7\u590d\u5408\u7ed3\u6784\u4e0d\u4ec5\u53ef\u4ee5\u63d0\u9ad8ZnO\u5149\u9633\u6781\u6750\u6599\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u8fd8\u53ef\u4ee5\u63d0\u9ad8\u7535\u5b50\u5728\u5149\u9633\u6781\u4e2d\u7684\u4f20\u8f93\u80fd\u529b\u3002\u901a\u8fc7\u5c06ZnO\u79cd\u5b50\u6eb6\u6db2\u6d82\u8986\u5728ITO\u73bb\u7483\u4e0a\uff0c\u4f7f\u5f97ZnO\u7eb3\u7c73\u68d2(ZnO NRs)\u53ef\u4ee5\u751f\u957f\u5728ITO\u7684\u8868\u9762\uff0c\u7136\u540e\u518d\u5c06\u5176\u6d78\u5165\u7528\u4e8e\u5236\u5907ZnO NSs\u7684\u524d\u9a71\u4f53\u6eb6\u6db2\u4e2d\uff0c\u4f7fZnO NRs\u8868\u9762\u88abZnO NSs\u8986\u76d6\uff0c\u6700\u7ec8\u5f97\u5230\u4e86\u6c89\u79efZnO NRs-NSs\u7ed3\u6784\u7684QDSSCs\u7684\u5149\u9633\u6781<sup>[10]<\/sup>\u3002\u8be5\u7ed3\u6784\u660e\u663e\u7684\u589e\u52a0\u4e86QDs\u7684\u6c89\u79ef\u91cf\uff0c\u8fd8\u53ef\u4ee5\u63d0\u9ad8\u7535\u5b50\u5bff\u547d\u5e76\u964d\u4f4e\u7535\u8377\u7684\u590d\u5408\u3002\u5728ZnO NSs\u5236\u5907\u8fc7\u7a0b\u4e2d\uff0c\u5f53\u6df7\u5408\u6eb6\u6db2\u7684\u6e29\u5ea6\u753160\u00b0C\u5347\u523070\u00b0C\u540e\uff0c\u751f\u6210\u7684\u7eb3\u7c73\u7247\u7ed3\u6784\u5c06\u5f00\u59cb\u805a\u96c6\uff0c\u5f62\u6210\u7531\u7247\u72b6\u7ed3\u6784\u7ec4\u5408\u7684\u5fae\u7403( ZnO MSs)\uff0c\u6b64\u7ed3\u6784\u88ab\u5e94\u7528\u5728QDSSCs\u4e2d\uff0c\u5e76\u5c06\u5176\u4e0eZnO NP\u8fdb\u884c\u7ed3\u5408\uff0c\u4ee5\u6b64\u63d0\u9ad8\u4e86\u5149\u9633\u6781\u819c\u7684\u6563\u5c04\u80fd\u529b\u3002<\/p>\n<p>\u4e3a\u4e86\u6539\u5584\u7531\u4e8eZnO\u7a33\u5b9a\u6027\u8f83\u5dee\uff0c\u6613\u4e0e\u7535\u89e3\u6db2\u53cd\u5e94\u5bfc\u81f4\u7535\u8377\u590d\u5408\u4e25\u91cd\u7684\u73b0\u8c61\uff0c\u7814\u7a76\u4eba\u5458\u5bf9\u5236\u5907\u597d\u7684ZnO NPs\/MSs\u8868\u9762\u8fdb\u884c\u4e86\u6539\u6027<sup>[11]<\/sup>\uff0c\u5728ZnO\u7684\u5149\u9633\u6781\u8868\u9762\u6c89\u79ef\u4e86\u4e00\u5c42TiO<sub>2<\/sub>\uff0c\u4f7f\u5f97ZnO MSs\u7684\u7eb3\u7c73\u7247\u7684\u8868\u9762\u53d8\u5f97\u66f4\u4e3a\u5149\u6ed1\u3002\u7814\u7a76\u8868\u660e\uff0c\u5236\u5907\u597d\u7684TiO<sub>2<\/sub>\u963b\u9694\u5c42\u6709\u6548\u5730\u963b\u65ad\u4e86\u7535\u5b50\u7531ZnO\u5411\u7535\u89e3\u6db2\u548c QDs\u7684\u590d\u5408\uff0c\u964d\u4f4e\u4e86\u7535\u8377\u7684\u590d\u5408\uff0c\u7535\u6c60\u7684\u586b\u5145\u56e0\u5b50\u548c\u8f6c\u6362\u6548\u7387\u90fd\u6709\u4e86\u660e\u663e\u63d0\u9ad8\u3002<\/p>\n<p>\u4e0a\u8ff0\u7684\u5149\u9633\u6781\u819c\u662f\u901a\u8fc7\u5c06\u4e0d\u540c\u7ed3\u6784\u7684ZnO\u7eb3\u7c73\u6750\u6599\uff0c\u901a\u8fc7\u5316\u5b66\u53cd\u5e94\u9010\u5c42\u6c89\u79ef\u5728\u5149\u9633\u6781\u57fa\u5e95\u4e0a\u5236\u5907\u6240\u5f97\u5230\u3002\u9664\u6b64\u4e4b\u5916\uff0c\u8fd8\u53ef\u4ee5\u901a\u8fc7\u6539\u8fdb\u5408\u6210\u5de5\u827a\uff0c\u76f4\u63a5\u5408\u6210\u51fa\u591a\u7ea7\u7eb3\u7c73\u6750\u6599\u3002\u5982\u901a\u8fc7\u6301\u7eed\u7684\u52a0\u70ed\u6405\u62cc\uff0c\u53ef\u4ee5\u5728\u6eb6\u6db2\u4e2d\u76f4\u63a5\u5408\u6210\u7531ZnO\u9897\u7c92\u805a\u96c6\u800c\u6210\u7684ZnO\u805a\u96c6\u4f53\u3002\u7531\u5355\u4e00\u7eb3\u7c73\u7ebf\u7ed3\u6784\u5236\u5907\u7684\u590d\u6742\u7eb3\u7c73\u6811\u578b\u7ed3\u6784\u5149\u9633\u6781\u819c\uff0c\u53ef\u4ee5\u5f88\u597d\u7684\u5f25\u8865\u4e86\u7eb3\u7c73\u7ebf\u6bd4\u8868\u9762\u79ef\u4e0d\u8db3\uff0c\u540c\u65f6\uff0c\u4f7f\u5f97\u5149\u9633\u6781\u7535\u5b50\u590d\u5408\u673a\u4f1a\u8fdb\u4e00\u6b65\u51cf\u5c0f\uff0c\u6240\u5236\u5907\u7684\u57fa\u4e8eZnO\u7eb3\u7c73\u68ee\u6797\u7ed3\u6784\u7684\u7535\u6c60\u5149\u7535\u6548\u7387\uff0c\u8fbe\u5230\u4e86\u666e\u901a\u7eb3\u7c73\u7ebf\u7ed3\u6784\u7684\u7535\u6c60\u6548\u73875\u500d\u4ee5\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-73135\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/7-5.png\" alt=\"\" width=\"229\" height=\"300\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/7-5.png 456w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/7-5-229x300.png 229w\" sizes=\"(max-width: 229px) 100vw, 229px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe5 (a)\u591a\u7ea7\u5206\u652fZnO\u7eb3\u7c73\u7ebf\u5236\u5907\u6d41\u7a0b\u793a\u610f\u56fe; (b)\u5206\u652fZnO\u7eb3\u7c73\u7ebfSEM\u56fe; (e) ITO\u57fa\u5e95\u7eb3\u7c73\u7ebf\u5236\u5907\u6d41\u7a0b\u793a\u610f\u56fe<sup>[5]<\/sup><\/p>\n<p>\u9664\u4e86\u4f7f\u7528\u5316\u5b66\u5408\u6210\u65b9\u6cd5\u5236\u5907\u5177\u6709\u8f83\u5927\u6bd4\u8868\u9762\u79ef\u7684ZnO\u591a\u7ea7\u590d\u5408\u7ed3\u6784\u4ee5\u5916\uff0c\u8fd8\u53ef\u4ee5\u91c7\u7528\u7535\u6c89\u79ef\u7684\u65b9\u5f0f\u76f4\u63a5\u5728ITO\u73bb\u7483\u4e0a\u5236\u5907\u51faZnO\u7eb3\u7c73\u6750\u6599<sup>[12]<\/sup>\uff0c\u5e76\u4e14\u901a\u8fc7\u8c03\u8282\u5236\u5907\u5408\u6210\u539f\u6599ZnCl<sub>2<\/sub>\u7684\u6d53\u5ea6\uff0c\u63a7\u5236\u4e86ZnO\u6750\u6599\u7684\u7ed3\u6784\uff0c\u5373\u5f53ZnCl<sub>2<\/sub>\u6eb6\u6db2\u6d53\u5ea6\u589e\u52a0\u81f3\u4e00\u5b9a\u503c\u540e\uff0cZnO\u6750\u6599\u4ece\u7eb3\u7c73\u68d2\u7ed3\u6784\u8f6c\u53d8\u4e3a\u7eb3\u7c73\u7247\u7ed3\u6784\uff0c\u5e76\u8fdb\u4e00\u6b65\u5f62\u62103D\u7684NS\u7f51\u7edc\u7ed3\u6784\uff0c\u6210\u529f\u63d0\u9ad8\u4e86DSSCs\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u3002\u7535\u6c60\u6027\u80fd\u7684\u63d0\u9ad8\u4e3b\u8981\u5f52\u529f\u4e8e\u7247\u72b6\u7ed3\u6784\u5bf9\u6bd4\u8868\u9762\u79ef\u7684\u589e\u52a0\u4f5c\u7528\u3002\u5728\u7535\u6c60\u6548\u7387\u7684\u63d0\u9ad8\u65b9\u9762\uff0c\u901a\u8fc7\u6c34\u70ed\u6cd5\u5236\u5907\u7684ZnO\u7eb3\u7c73\u82b1\u7ed3\u6784\u4e5f\u8868\u73b0\u4f18\u5f02\u3002<\/p>\n<p><span style=\"color: #0000ff;\"><strong>\u4e94\u3001\u603b\u7ed3<\/strong><\/span><\/p>\n<p>\u901a\u8fc7\u8c03\u63a7ZnO\u7eb3\u7c73\u7ed3\u6784\u7684\u5f62\u8c8c\uff0c\u5236\u5907\u5177\u6709\u8f83\u9ad8\u6bd4\u8868\u9762\u79ef\u7684\u5149\u9633\u6781\u6750\u6599\u66f4\u6709\u5229\u4e8e\u654f\u5316\u5242\u7684\u5438\u9644\uff0c\u4ece\u800c\u63d0\u9ad8\u7535\u6781\u5bf9\u592a\u9633\u5149\u7684\u6355\u83b7\u80fd\u529b\uff0c\u8fdb\u800c\u63d0\u5347\u7535\u6c60\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u3002\u7279\u6b8a\u7684\u7eb3\u7c73\u7ed3\u6784\u53ef\u4ee5\u51cf\u5c11ZnO\u819c\u8868\u9762\u7f3a\u9677\u7684\u6570\u91cf\uff0c\u51cf\u5c11\u7535\u8377\u590d\u5408\u3002ZnO\u4f5c\u4e3a\u5149\u9633\u6781\u6750\u6599\u5236\u5907\u7684\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u6548\u7387\u76f8\u6bd4\u4e8eTiO<sub>2<\/sub>\u7684\u7535\u6c60\u6548\u7387\u4ecd\u7136\u8f83\u4f4e\uff0c\u8fd9\u4e5f\u662f\u76ee\u524d\u7814\u7a76\u4e9f\u9700\u89e3\u51b3\u7684\u95ee\u9898\u3002\u901a\u8fc7\u6539\u53d8ZnO\u7eb3\u7c73\u6750\u6599\u7684\u7ed3\u6784\u53ca\u8868\u9762\u5904\u7406\uff0c\u6709\u671b\u80fd\u591f\u8fbe\u5230\u8f83\u9ad8\u7684\u654f\u5316\u5242\u8d1f\u8f7d\u548c\u8f83\u5c0f\u7684\u7535\u8377\u590d\u5408\uff0c\u4ece\u800c\u6781\u5927\u7684\u63d0\u9ad8\u654f\u5316\u7535\u6c60\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u3002<\/p>\n<p><strong>\u9644\uff1a<\/strong><strong>ZnO<\/strong><strong>\u7eb3\u7c73\u6750\u6599<\/strong><strong>SEM<\/strong><strong>\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-73136\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/8-5.png\" alt=\"\" width=\"500\" height=\"279\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/8-5.png 876w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/8-5-300x167.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/8-5-768x428.png 768w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-73137 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/9-7.png\" alt=\"\" width=\"500\" height=\"143\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/9-7.png 877w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/9-7-300x86.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/9-7-768x220.png 768w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-73138\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/10-5.png\" alt=\"\" width=\"500\" height=\"295\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/10-5.png 879w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/10-5-300x177.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/10-5-768x453.png 768w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-73139\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/11-4.png\" alt=\"\" width=\"500\" height=\"296\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/11-4.png 885w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/11-4-300x178.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/11-4-768x455.png 768w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-73140\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/12-5.png\" alt=\"\" width=\"500\" height=\"145\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/12-5.png 885w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/12-5-300x87.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/12-5-768x222.png 768w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-73141\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/13-2.png\" alt=\"\" width=\"500\" height=\"288\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/13-2.png 886w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/13-2-300x173.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/03\/13-2-768x443.png 768w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe6 \u89c1\u4e8e\u62a5\u9053\u7684ZnO\u7eb3\u7c73\u6750\u6599SEM<sup>[13]<\/sup><\/p>\n<p><strong>\u53c2\u8003\u6587\u732e\uff1a<\/strong><\/p>\n<p>[1] \u5218\u8d85, \u8c2d\u745e\u7434, \u66fe\u4fde\u8861\u7b49. \u7845\u7eb3\u7c73\u6676\u7684\u5236\u5907\u53ca\u5176\u5728\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u7684\u5e94\u7528\u7814\u7a76[J]. \u5316\u5b66\u8fdb\u5c55, 2015, 27(9): 1302-1312.<\/p>\n<p>[2] \u80e1\u749f\u7490, \u5f90\u5a77\u5a77, \u9648\u7acb\u65b0\u7b49. \u7eb3\u7c73ZnO\u6750\u6599\u5728\u67d3\u6599\/\u91cf\u5b50\u70b9\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u7684\u7814\u7a76\u8fdb\u5c55[J]. \u529f\u80fd\u6750\u6599, 2016, 12(47): 12083-12089.<\/p>\n<p>[3] Yella A, Lee H W, Tsao H N, et al. Porphyrin-Sensitized Solar Cells with Cobalt (II\/III)\u2013Based Redox Electrolyte Exceed 12 Percent Efficiency [J]. Science, 2011, 334(6056): 629-634.<\/p>\n<p>[4] P.V. Kamat, Acc. Chem. Res. 45 (2012) 1906\u20131915.<\/p>\n<p>[5] Jian-Kun Sun, Yan Jiang, Xinhua Zhong, et al. Three-dimensional nanostructured electrodes for efficient quantum-dot-sensitized solar cells [J]. Nano Energy 32(2017): 130-156.<\/p>\n<p>[6] Chen L, Li X, Qu L, et al. Facile and fast one-pot synthesis of ultra-long porous ZnO nanowire arrays for efficient dye-sensitized solar cells [J]. J Alloy Compd, 2014, 586: 766-772.<\/p>\n<p>[7] Syrrokostas G, Govatsi K, Yannopoulos S N. High-Quality, Reproducible ZnO Nanowire Arrays Obtained by a Multiparameter Optimization of Chemical Bath Deposition Growth[J]. Crystal Growth &amp; Design, 2016, 16(4): 2140-2150.<\/p>\n<p>[8] Shi Y, Wang K, Du Y, et al. Solid-state synthesis of ZnO nanostructures for quasi-solid dye-sensitized solar cells with high efficiencies up to 6.46% [J]. Adv Mater, 2013, 25(32): 4413-4419.<\/p>\n<p>[9] Lin SY, Wu J J. Chemical assembly of zinc oxide aggregated anodes on plastic substrates at room temperature for flexible dye-sensitized solar cells [J]. Electrochim Acta, 2015, 152: 61-67.<\/p>\n<p>[10] Tian J, Uchaker E, Zhang Q, et al. Hierarchically structured ZnO nanorods-nanosheets for improved quantum-dot-sensitized solar cells [J]. ACS Appl Mater Inter, 2014, 6(6): 4466-4472.<\/p>\n<p>[11] Tian J, Lv L, Wang X, et al. Microsphere light-scattering layer assembled by ZnO nanosheets for the construction of high efficiency quantum dots sensitized solar cells [J]. J Phys Chem C, 2014, 118(30): 16611-16617.<\/p>\n<p>[12] Xie Y L, Yuan J, Song P, et al. Growth of ZnO nanorods and nanosheets by electrodeposition and their applications in dye-sensitized solar cells [J]. J Mater Sci-Mater El, 26(6): 3868-3873.<\/p>\n<p>[13] Vittal R, Ho K C. Zinc oxide based dye-sensitized solar cells: A review [J]. 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