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\u4e00\u3001\u5f15\u8a00<\/strong><\/span><\/p>\n

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\u4e8c\u3001\u4e0a\u4e0b\u8f6c\u6362\u53d1\u5149\u6280\u672f<\/strong><\/span><\/p>\n

2.1 <\/strong>\u4e0a\u4e0b\u8f6c\u6362\u53d1\u5149\u673a\u5236<\/strong><\/p>\n

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\"\"<\/p>\n

\u56fe1 \u4e0a\u8f6c\u6362\u673a\u5236\u7b80\u56fe[2]<\/sup><\/p>\n

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\"\"<\/p>\n

\u56fe2 \u4e0b\u8f6c\u6362\u673a\u5236\u793a\u610f\u56fe[5]<\/sup><\/p>\n

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\u8fd1\u5e74\u6765\uff0c\u4e0b\u8f6c\u6362\u53d1\u5149\u6750\u6599\u56e0\u5176\u53ef\u4ee5\u8c03\u5236\u592a\u9633\u80fd\u7535\u6c60\u7684\u5438\u6536\u5149\u8c31\uff0c\u63d0\u9ad8\u592a\u9633\u80fd\u7535\u6c60\u7684\u80fd\u91cf\u8f6c\u5316\u6548\u7387\uff0c\u5f15\u8d77\u4eba\u4eec\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002Eu3+<\/sup>\u79bb\u5b50\u56e0\u5176\u5728\u7d2b\u5916\u5149\u533a\u6709\u7535\u8377\u8fc1\u79fb\u5438\u6536\u5e26\uff0c\u6613\u88ab\u7d2b\u5916\u5149\u6fc0\u53d1\uff0c\u4e14\u53d1\u5c04\u8c31\u7ebf\u4e3b\u8981\u4f4d\u4e8e400-700 nm\u800c\u5e38\u88ab\u7528\u4e8e\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u3002Yb3+<\/sup>\u79bb\u5b50\u4e5f\u56e0\u5176\u80fd\u5728\u7845\u7684\u7981\u5e26\u5bbd\u5ea6\u9644\u8fd1\u53d1\u5c04\u8fd1\u7ea2\u5916\u5149\u5b50\uff0c\u6210\u4e3a\u65b0\u5174\u7684\u8fd1\u7ea2\u5916\u4e0b\u8f6c\u6362\u6750\u6599\u7684\u7814\u7a76\u70ed\u70b9\u3002\u8ba1\u7b97\u8868\u660e\uff0c\u5229\u7528\u4e0b\u8f6c\u6362\u53ef\u4ee5\u4f7f\u592a\u9633\u80fd\u7535\u6c60\u80fd\u91cf\u8f6c\u5316\u6548\u7387\u7684\u6781\u9650\u53ef\u8fbe38.6%\u3002<\/p>\n

2.2 <\/strong>\u4e0a\u4e0b\u8f6c\u6362\u53d1\u5149\u6750\u6599\u57fa\u8d28<\/strong><\/p>\n

\u76ee\u524d\u7814\u7a76\u8f83\u591a\u7684\u57fa\u8d28\u4e3b\u8981\u5305\u62ec\u5364\u5316\u7269\u3001\u6c1f\u5316\u7269\u3001\u6c27\u5316\u7269\u3001\u786b\u5316\u7269\u53ca\u7a00\u571f\u79bb\u5b50\u6709\u673a\u914d\u5408\u7269\u7b49\u3002<\/p>\n

(1)\u5364\u5316\u7269\uff1a\u632f\u52a8\u80fd\u8f83\u4f4e\uff0c\u53ef\u4ee5\u964d\u4f4e\u591a\u58f0\u5b50\u5f1b\u8c6b\u8fc7\u7a0b\u7684\u5f71\u54cd\uff0c\u589e\u5f3a\u4ea4\u53c9\u5f1b\u8c6b\u8fc7\u7a0b\uff0c\u4ece\u800c\u63d0\u9ad8\u4e0a\u8f6c\u6362\u6548\u7387\u3002\u6b64\u7c7b\u5316\u5408\u7269(\u5982Cs3<\/sub>RE2<\/sub>X9<\/sub>\uff0cRE\u4e3a\u9567\u7cfb\u79bb\u5b50\uff0cX\u4e3aCl\uff0cBr\uff0cI)\u5728\u4e0a\u8f6c\u6362\u6fc0\u5149\u53ca\u78f7\u5149\u4f53\u6750\u6599\u4e2d\u7684\u5e94\u7528\u5177\u6709\u76f8\u5f53\u7684\u6f5c\u529b\u3002<\/p>\n

(2)\u6c1f\u5316\u7269\uff1a\u900f\u5149\u6027\u8303\u56f4\u5e7f\uff0c\u4e14\u5176\u8f83\u4f4e\u7684\u58f0\u5b50\u80fd\u91cf\uff0c\u4f7f\u5f97\u7a00\u571f\u79bb\u5b50\u7684\u80fd\u7ea7\u5728\u5176\u4e2d\u5177\u6709\u8f83\u957f\u7684\u5bff\u547d\uff0c\u80fd\u591f\u5f62\u6210\u66f4\u591a\u7684\u4e9a\u7a33\u80fd\u7ea7\uff0c\u5177\u6709\u4e30\u5bcc\u7684\u6fc0\u5149\u8dc3\u8fc1\u3002\u5e38\u89c1\u7684\u6c1f\u5316\u7269\u6709\uff1aLaF3<\/sub>\uff0cYF3<\/sub>\u548cNaYF4<\/sub>\u7b49\u3002\u5176\u4e2dYF3<\/sub>\u56e0\u5176\u80fd\u5e26\u5bbd\u5ea6\u5927\uff0cY3+<\/sup>\u79bb\u5b50\u5bb9\u6613\u88ab\u5176\u4ed6\u4e09\u4ef7\u79bb\u5b50\u53d6\u4ee3\u7b49\u4f18\u70b9\u800c\u6210\u4e3a\u7814\u7a76\u70ed\u70b9\u3002\u6c1f\u5316\u7269\u7684\u7ed3\u6784\u7a33\u5b9a\u3001\u53d1\u5149\u80fd\u7ea7\u7a84\u3001\u91cf\u5b50\u4ea7\u7387\u9ad8\u3001\u6613\u63ba\u6742\u7a00\u571f\u79bb\u5b50\u4e14\u58f0\u5b50\u80fd\u91cf\u4f4e\u3001\u632f\u52a8\u80fd\u91cf\u5c0f\uff0c\u53ef\u964d\u4f4e\u7a00\u571f\u79bb\u5b50\u7684\u65e0\u8f90\u5c04\u8dc3\u8fc1\u51e0\u7387\uff0c\u51cf\u5c11\u80fd\u91cf\u635f\u5931\uff0c\u63d0\u9ad8\u7a00\u571f\u79bb\u5b50\u7684\u53d1\u5149\u6548\u7387\u3002<\/p>\n

(3)\u6c27\u5316\u7269(\u5982Y2<\/sub>O3<\/sub>\u3001Gd2<\/sub>O3<\/sub>\u7b49)\uff1a\u5236\u5907\u5de5\u827a\u7b80\u5355\u3001\u7a33\u5b9a\u6027\u597d\u3001\u70ed\u80c0\u7cfb\u6570\u5c0f\u3001\u73af\u5883\u6761\u4ef6\u8981\u6c42\u4f4e\uff0c\u4f46\u6c27\u5316\u7269\u57fa\u8d28\u7684\u58f0\u5b50\u80fd\u91cf\u8f83\u9ad8\uff0c\u4e0d\u5229\u4e8e\u7a00\u571f\u79bb\u5b50\u53d1\u5149\u3002<\/p>\n

(4)\u786b\u5316\u7269\u6750\u6599(\u5982CdS\u91cf\u5b50\u70b9)\uff1a\u58f0\u5b50\u80fd\u91cf\u8f83\u4f4e\uff0c\u4f46\u6613\u53d7\u6c27\u548c\u6c34\u7684\u5f71\u54cd\uff0c\u56e0\u6b64\uff0c\u5fc5\u987b\u5728\u5bc6\u5c01\u6761\u4ef6\u4e0b\u5236\u5907\u3002\u7814\u7a76\u53d1\u73b0\u91cf\u5b50\u70b9\u5177\u6709\u826f\u597d\u7684\u5149\u7a33\u5b9a\u6027\uff0c\u5176\u5438\u6536\u548c\u53d1\u5c04\u53ef\u4ee5\u901a\u8fc7\u63a7\u5236\u9897\u7c92\u7684\u5927\u5c0f\u6765\u8c03\u8282\uff0c\u4f46\u5176\u53d1\u5149\u91cf\u5b50\u6548\u7387\u8f83\u4f4e\uff0c\u5b58\u5728\u81ea\u5438\u6536\u73b0\u8c61\u3002<\/p>\n

(5) \u7a00\u571f\u79bb\u5b50\u6709\u673a\u914d\u5408\u7269\uff1a\u53d1\u5149\u6548\u7387\u9ad8\u3001\u5355\u8272\u6027\u597d\u3001\u8367\u5149\u5bff\u547d\u957f\u3001\u65af\u6258\u514b\u65af\u4f4d\u79fb\u5927\u7b49\u3002\u4f46\u662f\u5b83\u7684\u5149\u7a33\u5b9a\u6027\u53ca\u70ed\u7a33\u5b9a\u6027\u8f83\u5dee\uff0c\u6613\u53d7\u5468\u56f4\u731d\u706d\u5242\u7684\u5f71\u54cd\uff0c\u4ea7\u751f\u975e\u8f90\u5c04\u591a\u6781\u58f0\u5b50\u8870\u53d8\uff0c\u4f7f\u5f97\u53d1\u5149\u5f3a\u5ea6\u9010\u6e10\u964d\u4f4e\u3002\u76ee\u524d\u7814\u7a76\u8f83\u591a\u7684\u662f\u4ee5Tb3+<\/sup>\u548cEu3+<\/sup>\u4e3a\u53d1\u5149\u4e2d\u5fc3\u7684\u7a00\u571f\u914d\u5408\u7269\u7684\u5408\u6210\u53ca\u53d1\u5149\u6027\u80fd\u3002<\/p>\n

2.3 <\/strong>\u53d1\u5149\u6750\u6599\u5236\u5907\u65b9\u6cd5<\/strong><\/p>\n

\u5e38\u89c1\u7684\u5236\u5907\u7a00\u571f\u53d1\u5149\u6750\u6599\u7684\u65b9\u6cd5\u5305\u62ec\u6eb6\u80f6-\u51dd\u80f6\u6cd5\u3001\u4f4e\u6e29\u71c3\u70e7\u6cd5\u3001\u5316\u5b66\u6c89\u6dc0\u6cd5\u3001\u5fae\u4e73\u6db2\u6cd5\u3001\u6c34\u70ed\u6cd5\u3001\u9ad8\u6e29\u56fa\u76f8\u6cd5\uff0c\u5176\u4e2d\u6c34\u70ed\u6cd5\u7531\u4e8e\u53cd\u5e94\u6c14\u6c1b\u53ef\u63a7\u3001\u5236\u5907\u7684\u53d1\u5149\u7c89\u7ed3\u6676\u5ea6\u597d\u3001\u7c92\u5f84\u5c0f\u4e14\u5747\u5300\u3001\u53ef\u964d\u4f4e\u6750\u6599\u7684\u53d1\u5149\u635f\u5931\u7b49\u4f18\u70b9\u5e38\u7528\u4e8e\u7a00\u571f\u53d1\u5149\u6750\u6599\u7684\u5408\u6210\u3002<\/p>\n

(1)\u6eb6\u80f6-\u51dd\u80f6\u6cd5\uff1a\u6db2\u76f8\u4e0b\u5c06\u5316\u5408\u7269\u524d\u9a71\u4f53\u5747\u5300\u6df7\u5408\uff0c\u52a0\u5165\u7edc\u5408\u5242\u7b49\u6dfb\u52a0\u5242\uff0c\u5e76\u5728\u5408\u9002\u7684\u6e29\u5ea6\u53ca\u9178\u78b1\u6761\u4ef6\u4e0b\u8fdb\u884c\u6c34\u89e3\u3001\u7f29\u5408\u53cd\u5e94\uff0c\u5f62\u6210\u900f\u660e\u6eb6\u80f6\u4f53\u7cfb\uff0c\u6eb6\u80f6\u7ecf\u9648\u5316\u80f6\u7c92\u95f4\u7f13\u6162\u805a\u5408\uff0c\u5f62\u6210\u51dd\u80f6\u3002\u51dd\u80f6\u7ecf\u5e72\u71e5\u3001\u70e7\u7ed3\u5236\u5907\u51fa\u6240\u9700\u6750\u6599\u3002\u6eb6\u80f6-\u51dd\u80f6\u6cd5\u5236\u5907\u7684\u53d1\u5149\u6750\u6599\u5177\u6709\u6df7\u5408\u5747\u5300\u6027\u597d\u3001\u7eaf\u5ea6\u9ad8\u3001\u70ed\u5904\u7406\u6e29\u5ea6\u4f4e\u3001\u5236\u5907\u7b80\u5355\u3001\u53d1\u5149\u6548\u7387\u9ad8\u7b49\u7279\u70b9\uff0c\u5e38\u7528\u4e8e\u6c27\u5316\u7269\u57fa\u8d28\u53d1\u5149\u6750\u6599\u548c\u7a00\u571f\u914d\u5408\u7269\u6742\u5316\u53d1\u5149\u6750\u6599\u7684\u5236\u5907\u3002\u4f46\u5176\u53cd\u5e94\u5468\u671f\u8f83\u957f\u4e14\u51dd\u80f6\u5728\u5e72\u71e5\u8fc7\u7a0b\u4e2d\u6536\u7f29\u3002<\/p>\n

(2)\u4f4e\u6e29\u71c3\u70e7\u6cd5\uff1a\u5c06\u91d1\u5c5e\u785d\u9178\u76d0\u548c\u6709\u673a\u67d3\u6599\u6eb6\u5165\u6c34\u4e2d\uff0c\u7136\u540e\u8fc5\u901f\u52a0\u70ed\u76f4\u81f3\u6eb6\u6db2\u81ea\u71c3\uff0c\u6574\u4e2a\u71c3\u70e7\u8fc7\u7a0b\u5728\u51e0\u5206\u949f\u5185\u7ed3\u675f\uff0c\u5176\u4ea7\u7269\u5373\u4e3a\u6240\u9700\u6750\u6599\u3002\u71c3\u70e7\u6cd5\u7684\u7279\u70b9\u662f\u64cd\u4f5c\u7b80\u4fbf\u3001\u53cd\u5e94\u6e29\u5ea6\u4f4e\u3001\u53cd\u5e94\u8fc5\u901f\u3001\u4ea7\u54c1\u7eaf\u5ea6\u9ad8\u3001\u53d1\u5149\u4eae\u5ea6\u4e0d\u6613\u53d7\u7834\u574f\u3001\u8282\u7701\u80fd\u6e90\u4e14\u964d\u4f4e\u6210\u672c\u3002\u8be5\u65b9\u6cd5\u5236\u5f97\u7684\u7c89\u4f53\u7c92\u5ea6\u5c0f\u3001\u6bd4\u8868\u9762\u79ef\u5927\u3001\u7814\u78e8\u540e\u53d1\u5149\u4eae\u5ea6\u4e0b\u964d\u4e0d\u5927\uff0c\u4e3b\u8981\u5e94\u7528\u4e8e\u6c27\u5316\u7269\u3001\u787c\u9178\u76d0\u548c\u7845\u9178\u76d0\u7b49\u8367\u5149\u7c89\u7684\u5408\u6210\uff0c\u91c7\u7528\u6b64\u6cd5\u53ef\u4ee5\u83b7\u5f97\u5177\u6709\u5f3a\u4ecb\u89c2\u6548\u5e94\u7684 Gd2<\/sub>O3<\/sub>\uff1aEu3+<\/sup>\u7eb3\u7c73\u6750\u6599\u3002<\/p>\n

(3)\u5316\u5b66\u6c89\u6dc0\u6cd5\uff1a\u5411\u539f\u6599\u6eb6\u6db2\u4e2d\u6dfb\u52a0\u6c89\u6dc0\u5242\uff0c\u4f7f\u6eb6\u6db2\u4e2d\u7684\u9634\u79bb\u5b50\u5f62\u6210\u6c89\u6dc0\u7269\uff0c\u7136\u540e\u7ecf\u8fc7\u6ee4\u3001\u6d17\u6da4\u3001\u5e72\u71e5\u3001\u52a0\u70ed\u5206\u89e3\u7b49\u5de5\u827a\u83b7\u5f97\u7684\u7eb3\u7c73\u53d1\u5149\u7c89\u3002\u6b64\u6cd5\u5de5\u827a\u6613\u4e8e\u63a7\u5236\uff0c\u662f\u5236\u5907\u6c27\u5316\u7269\u53d1\u5149\u6750\u6599\u7684\u4e00\u79cd\u6709\u6548\u65b9\u6cd5\uff0c\u4e5f\u662f\u89c4\u6a21\u5316\u751f\u4ea7\u4e2d\u5e94\u7528\u6700\u591a\u7684\u4e00\u79cd\u3002\u8fd0\u7528\u8be5\u65b9\u6cd5\u53ef\u4ee5\u5236\u5907\u51fa\u5206\u6563\u6027\u826f\u597d\u7684Y2<\/sub>O3<\/sub>\uff1aEu3+<\/sup>\u7eb3\u7c73\u5fae\u7c92\u3002<\/p>\n

(4)\u5fae\u4e73\u6db2\u6cd5\uff1a\u4e24\u79cd\u4e92\u4e0d\u76f8\u6eb6\u7684\u6eb6\u5242\u5728\u8868\u9762\u6d3b\u6027\u5242\u7684\u4f5c\u7528\u4e0b\u5f62\u6210\u5747\u5300\u4e73\u6db2\uff0c\u4f7f\u524d\u9a71\u7269\u5728\u6db2\u6ef4\u4e2d\u6210\u6838\u3001\u751f\u957f\u3001\u805a\u7ed3\u3001\u56e2\u805a\uff0c\u5f62\u6210\u7403\u5f62\u9897\u7c92\u7684\u8fc7\u7a0b\uff0c\u7c92\u5f84\u7684\u5927\u5c0f\u53ef\u901a\u8fc7\u8c03\u8282\u6db2\u6ef4\u7684\u5927\u5c0f\u6765\u63a7\u5236\u3002\u8be5\u65b9\u6cd5\u5b9e\u9a8c\u88c5\u7f6e\u7b80\u5355\u3001\u6613\u64cd\u4f5c\uff0c\u5236\u5907\u51fa\u7684\u7c92\u5b50\u4e3a\u7eb3\u7c73\u7ea7\u5355\u5206\u6563\u6027\u9897\u7c92\u3002\u4f46\u5176\u4ea7\u91cf\u5c11\u4e14\u6709\u673a\u6eb6\u5242\u9700\u6c42\u91cf\u5927\uff0c\u4e0d\u5b9c\u7528\u6765\u5927\u91cf\u5236\u5907\u6750\u6599.<\/p>\n

(5)\u6c34\u70ed\u6cd5\uff1a\u9ad8\u6e29\u9ad8\u538b\u53cd\u5e94\u6761\u4ef6\u4e0b\uff0c\u4ee5\u6c34\u4e3a\u53cd\u5e94\u4ecb\u8d28\uff0c\u901a\u8fc7\u5bf9\u5316\u5b66\u53cd\u5e94\u548c\u7269\u7406\u8fc7\u7a0b\u7684\u63a7\u5236\uff0c\u83b7\u5f97\u671f\u671b\u7684\u5c3a\u5bf8\u548c\u5f62\u8c8c\u7684\u7eb3\u7c73\u6750\u6599\u7684\u8fc7\u7a0b\u3002\u4e0e\u4e00\u822c\u6e7f\u5316\u5b66\u6cd5\u76f8\u6bd4\uff0c\u6c34\u70ed\u6cd5\u53cd\u5e94\u6761\u4ef6\u66f4\u6e29\u548c\u3001\u5236\u5907\u7684\u7c89\u4f53\u6676\u7c92\u53d1\u80b2\u5b8c\u6574\u3001\u7ed3\u6676\u5ea6\u597d\u3001\u7c92\u5f84\u5c0f\u4e14\u5206\u5e03\u5747\u5300\uff1b\u65e0\u9700\u7145\u70e7\u548c\u7814\u78e8\u5904\u7406\uff0c\u907f\u514d\u4e86\u6676\u7c92\u56e2\u805a\u548c\u7ed3\u6784\u7f3a\u9677\uff0c\u964d\u4f4e\u4e86\u53d1\u5149\u635f\u5931\uff1b\u53cd\u5e94\u6c14\u6c1b\u53ef\u63a7\u5236\uff0c\u901a\u8fc7\u63d0\u4f9b\u9002\u5f53\u7684\u6c27\u5316\u8fd8\u539f\u6c14\u6c1b\uff0c\u53ef\u4ee5\u83b7\u5f97\u5176\u4ed6\u65b9\u6cd5\u96be\u4ee5\u8fbe\u5230\u7684\u4e9a\u7a33\u76f8\u3002\u6c34\u70ed\u6cd5\u662f\u4e00\u79cd\u6781\u5177\u6f5c\u529b\u7684\u5408\u6210\u65b9\u6cd5\uff0c\u5177\u6709\u5f88\u5927\u7684\u7814\u7a76\u7a7a\u95f4\u3002<\/p>\n

\u00a0(6)\u9ad8\u6e29\u56fa\u76f8\u6cd5\uff1a\u5236\u5907\u53d1\u5149\u6750\u6599\u6700\u7b80\u5355\u4e14\u5e38\u7528\u7684\u65b9\u6cd5\uff0c\u5c06\u91d1\u5c5e\u76d0\u6216\u91d1\u5c5e\u6c27\u5316\u7269\u7814\u78e8\u540e\u6309\u5316\u5b66\u8ba1\u91cf\u6bd4\u6df7\u5408\u5747\u5300\uff0c\u901a\u8fc7\u9ad8\u6e29\u7145\u70e7\uff0c\u5f97\u5230\u5177\u6709\u4e00\u5b9a\u7c92\u5ea6\u7684\u53d1\u5149\u7c89\u3002\u901a\u5e38\uff0c\u56fa\u76f8\u53cd\u5e94\u53d6\u51b3\u4e8e\u6750\u6599\u7684\u6676\u4f53\u7ed3\u6784\u548c\u7f3a\u9677\u7ed3\u6784\u3002\u56fa\u76f8\u53cd\u5e94\u662f\u901a\u8fc7\u9897\u7c92\u754c\u9762\u8fdb\u884c\u7684\uff0c\u5c06\u53cd\u5e94\u7269\u7814\u78e8\u5e76\u5747\u5300\u6df7\u5408\uff0c\u53ef\u4ee5\u589e\u5927\u53cd\u5e94\u7269\u4e4b\u95f4\u7684\u63a5\u89e6\u9762\u79ef\uff0c\u4f7f\u539f\u5b50\u6216\u79bb\u5b50\u7684\u6269\u6563\u8f93\u8fd0\u6bd4\u8f83\u5bb9\u6613\u8fdb\u884c\uff0c\u4f7f\u53cd\u5e94\u901f\u7387\u589e\u5927\u3002\u56fa\u76f8\u6cd5\u5236\u5907\u7684\u7c89\u4f53\u9897\u7c92\u95f4\u65e0\u56e2\u805a\u3001\u586b\u5145\u6027\u597d\u3001\u4ea7\u91cf\u5927\u4e14\u5236\u5907\u5de5\u827a\u7b80\u5355\u3002<\/p>\n

\u4e09\u3001\u4e0a\u4e0b\u8f6c\u6362\u5728\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u7684\u5e94\u7528<\/strong><\/span><\/p>\n

3.1 <\/strong>\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u7684\u80fd\u91cf\u635f\u8017<\/strong><\/p>\n

\u6548\u7387\u6781\u9650\u662f\u592a\u9633\u80fd\u7535\u6c60\u53d1\u5c55\u7684\u74f6\u9888\uff0c\u70ed\u529b\u5b66\u5b9a\u5f8b\u6307\u51fa\u592a\u9633\u80fd\u7535\u6c60\u5149\u7535\u8f6c\u6362\u6548\u7387\u7684\u7406\u8bba\u6781\u9650\u4e3a86.8%\uff0c\u800c\u76ee\u524d\u5360\u636e\u5149\u4f0f\u5e02\u573a\u7684\u5355\u6676\u7845\u592a\u9633\u80fd\u7535\u6c60\u7684\u6781\u9650\u6548\u7387\u53ea\u670929%\u3002\u539f\u56e0\u662f\u5355\u7ed3\u592a\u9633\u80fd\u7535\u6c60\u5728\u5149\u7535\u8f6c\u6362\u8fc7\u7a0b\u4e2d\u6709\u80fd\u91cf\u635f\u8017\uff0c\u5982\u56fe3\u6240\u793a\u3002\u5176\u4e2d\uff0c\u7531\u4e8e\u5149\u8c31\u4e0d\u5339\u914d\u9020\u6210\u7684\u6676\u683c\u70ed\u632f\u52a8\u548c\u4f20\u9001\u635f\u5931(\u2460\u2461)\u5360\u603b\u635f\u8017\u768470%\u4ee5\u4e0a\uff0c\u662f\u4e3b\u8981\u7684\u80fd\u91cf\u635f\u5931\u3002\u51cf\u5c11\u4e0a\u8ff0\u80fd\u91cf\u635f\u8017\u7684\u4e24\u79cd\u57fa\u672c\u65b9\u6cd5\uff1a(1)\u6539\u8fdb\u592a\u9633\u80fd\u7535\u6c60\uff0c\u8ba9\u5176\u66f4\u597d\u5730\u5229\u7528\u592a\u9633\u5149\u8c31\uff1b(2)\u8ba9\u5165\u5c04\u592a\u9633\u5149\u8c31\u66f4\u597d\u5730\u4e0e\u592a\u9633\u80fd\u7535\u6c60\u7684\u5149\u8c31\u5438\u6536\u7279\u6027\u76f8\u5339\u914d\u3002\u65b9\u6cd5\u4e00\u5df2\u6210\u529f\u5e94\u7528\u4e8e\u591a\u7ed3\u4e32\u8054\u592a\u9633\u80fd\u7535\u6c60\u4e2d\uff0c\u6548\u7387\u5df2\u8d85\u8fc740%\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3 \u592a\u9633\u80fd\u7535\u6c60\u7684\u80fd\u91cf\u635f\u8017\uff1a\u2460\u6676\u683c\u70ed\u635f\u8017\uff1b\u2461\u4f20\u9001\u635f\u8017\uff1b\u2462\u590d\u5408\u635f\u8017\uff1b\u2463\u6c47\u63a5\u635f\u8017\uff1b\u2464\u63a5\u89e6\u7535\u538b\u635f\u8017[6]<\/sup><\/p>\n

\u4f20\u7edf\u592a\u9633\u80fd\u7535\u6c60\u4e2d\uff0c\u5e26\u9699\u4e2d\u7684\u5149\u4f20\u9001\u635f\u8017\u662f\u4e3b\u8981\u80fd\u91cf\u635f\u8017\u4e4b\u4e00\u3002\u5728\u592a\u9633\u80fd\u7535\u6c60\u6750\u6599\u4e2d\u63ba\u5165\u6742\u8d28\u79bb\u5b50\uff0c\u6539\u53d8\u5176\u80fd\u5e26\u9699\uff0c\u53ef\u4ee5\u964d\u4f4e\u4f20\u9001\u635f\u8017\uff1b\u53e6\u4e00\u79cd\u964d\u4f4e\u4f20\u9001\u635f\u8017\u7684\u65b9\u6cd5\u662f\u628a\u4f4e\u80fd\u5149\u5b50\u8f6c\u6362\u6210\u53ef\u88ab\u592a\u9633\u80fd\u7535\u6c60\u5438\u6536\u5229\u7528\u7684\u9ad8\u80fd\u5149\u5b50\u3002\u4f20\u7edf\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u53e6\u4e00\u4e2a\u4e3b\u8981\u80fd\u91cf\u635f\u8017\u662f\u8f7d\u6d41\u5b50\u5438\u6536\u9ad8\u80fd\u91cf\u7684\u5149\u5b50\u5e76\u4ee5\u70ed\u91cf\u7684\u5f62\u5f0f\u635f\u8017\u6389\u3002\u592a\u9633\u80fd\u7535\u6c60\u5438\u6536\u5149\u5b50\u4ea7\u751f\u500d\u589e\u7535\u5b50-\u7a7a\u7a74\u5bf9\u7684\u8fc7\u7a0b\u4e2d\uff0c\u7535\u79bb\u7684\u5f71\u54cd\u81f3\u5173\u91cd\u8981\u3002<\/p>\n

3.2 <\/strong>\u4e0a<\/strong>\/<\/strong>\u4e0b\u8f6c\u6362\u5728\u7535\u6c60\u4e2d\u7684\u5e94\u7528\u6a21\u578b<\/strong><\/p>\n

\u4e0a\u8f6c\u6362\u6a21\u578b\u4e2d\uff0c\u8f6c\u6362\u5c42\u4f4d\u4e8e\u592a\u9633\u80fd\u7535\u6c60\u7684\u5e95\u90e8\u4e0e\u592a\u9633\u80fd\u7535\u6c60\u76f8\u4e92\u72ec\u7acb\uff0c\u53cd\u5c04\u5c42\u5728\u4e0a\u8f6c\u6362\u5c42\u7684\u4e0b\u9762\uff0c\u80fd\u5c06\u672a\u88ab\u592a\u9633\u80fd\u7535\u6c60\u5438\u6536\u7684\u5149\u5b50\u91cd\u65b0\u5438\u6536\uff0c\u7136\u540e\u901a\u8fc7\u4e24\u4e2a\u6216\u4e24\u4e2a\u4ee5\u4e0a\u8fde\u7eed\u8dc3\u8fc1\u4ea7\u751f\u7535\u5b50-\u7a7a\u7a74\u5bf9\u3002\u7535\u5b50-\u7a7a\u7a74\u5bf9\u518d\u901a\u8fc7\u8f90\u5c04\u5e26\u5e26\u95f4\u8dc3\u8fc1\u8fdb\u884c\u590d\u5408\uff0c\u968f\u540e\u53d1\u5c04\u51fa\u80fd\u91cf\u4e0e\u80fd\u5e26\u9699\u76f8\u5339\u914d\u7684\u5149\u5b50\u3002\u4e0a\u8f6c\u6362\u6a21\u578b\u7684\u4f18\u70b9\u4e3a\uff1a(1)\u5bf9\u4e0a\u8f6c\u6362\u53d1\u5149\u5df2\u5177\u5907\u8db3\u591f\u7684\u7814\u7a76\u57fa\u7840\uff1b(2)\u4e0a\u8f6c\u6362\u5c42\u53ef\u7f6e\u4e8e\u592a\u9633\u80fd\u7535\u6c60\u7684\u5e95\u90e8\uff0c\u4e0d\u4f1a\u5f71\u54cd\u592a\u9633\u80fd\u7535\u6c60\u5bf9\u80fd\u91cf\u9ad8\u4e8eEg<\/sub>\u7684\u5149\u5b50\u7684\u5438\u6536\uff1b(3)\u53cd\u5c04\u5c42\u7684\u5f15\u5165\u907f\u514d\u4e86\u5149\u9003\u9038\u3002\u4f46\u4e0a\u8f6c\u6362\u9700\u8981\u5f88\u5927\u7684\u5165\u5c04\u529f\u7387\uff0c\u539f\u56e0\u662f\u4e0a\u8f6c\u6362\u662f\u4e00\u4e2a\u975e\u7ebf\u6027\u5149\u5b66\u8fc7\u7a0b\u3002\u6700\u9002\u5408\u7528\u4e0a\u8f6c\u6362\u6765\u63d0\u9ad8\u6548\u7387\u7684\u592a\u9633\u80fd\u7535\u6c60\u6709\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u3001\u975e\u6676\u7845\u592a\u9633\u80fd\u7535\u6c60\u7b49\u3002<\/p>\n

\"\"<\/p>\n

\u56fe4 \u63d0\u9ad8\u592a\u9633\u80fd\u7535\u6c60\u6548\u7387\u7684a)\u4e0a\u8f6c\u6362\u6a21\u578b; b)\u4e0b\u8f6c\u6362\u6a21\u578b[7]<\/sup><\/p>\n

\u4e0b\u8f6c\u6362\u6a21\u578b\u4e2d\uff0c\u8f6c\u6362\u5c42\u4f4d\u4e8e\u592a\u9633\u80fd\u7535\u6c60\u7684\u8868\u5c42\uff0c\u4e0b\u8f6c\u6362\u5c42\u5438\u6536\u9ad8\u80fd\u5149\u5b50\uff0c\u53d1\u5c04\u51fa\u4f4e\u80fd\u5149\u5b50\uff0c\u7136\u540e\u8fd9\u4e9b\u4f4e\u80fd\u5149\u5b50\u88ab\u592a\u9633\u80fd\u7535\u6c60\u5438\u6536\uff0c\u4ea7\u751f\u7535\u5b50-\u7a7a\u7a74\u5bf9\u3002\u4e0b\u8f6c\u6362\u6a21\u578b\u662f\u76ee\u524d\u6700\u9002\u7528\u4e8e\u63d0\u9ad8\u7845\u592a\u9633\u80fd\u7535\u6c60\u6548\u7387\u7684\u65b9\u6cd5\u4e4b\u4e00[8]<\/sup>\u3002<\/p>\n

3.3 <\/strong>\u4e0a\u8f6c\u6362\u53d1\u5149\u6750\u6599\u5728<\/strong>DSC<\/strong>\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n

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[1] Mathew S, Yella A, Gao P, et al. Dye-sensitized solar cells with 13% efficiency achieved through the molecular engineering of porphyrin sensitizers [J]. Nature chemistry, 2014, 6(3): 242-247.<\/p>\n

[2] \u59dc\u73b2, \u9619\u4e9a\u840d, \u4e01\u52c7\u7b49. \u4e0a\/\u4e0b\u8f6c\u6362\u6750\u6599\u5728\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u7684\u5e94\u7528\u8fdb\u5c55[J]. 2016, 28(5): 637-646.<\/p>\n

[3] Wang Z S, Yamaguchi T, Sugihara H, Arakawa H. Langmuir, 2005, 21: 4272.<\/p>\n

[4] Bloembergen N. Phys. Rev. Lett., 1959, 2: 84.<\/p>\n

[5] Wegh R T, Donker H, Oskam K D, Meijerink A. Science, 1999, 283: 663.<\/p>\n

[6] Richards B S. Sol. Energ. Mat. Sol. C., 2006, 90: 2329.<\/p>\n

[7] Trupke T, Green M A, Wurfel P. Appl. Phys. Lett., 2002, 92(7): 4117.<\/p>\n

[8] Zhang Q Y, Huang X Y. Prog. Mater. Sci., 2010, 55: 353.<\/p>\n

[9] Kay A, Gratzel M. Chem. Mater., 2002, 14: 2930.<\/p>\n

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