{"id":72243,"date":"2017-03-24T14:00:46","date_gmt":"2017-03-24T06:00:46","guid":{"rendered":"\/\/m.iemloyee.com\/?p=72243"},"modified":"2017-03-21T13:52:59","modified_gmt":"2017-03-21T05:52:59","slug":"%e6%b9%96%e5%8d%97%e5%a4%a7%e5%ad%a6adv-energy-mater-%ef%bc%9a%e8%bd%af%e7%a2%b3%e9%a6%96%e6%ac%a1%e7%94%a8%e4%bd%9c%e9%92%a0%e5%9f%ba%e5%8f%8c%e7%a6%bb%e5%ad%90%e5%85%a8%e7%94%b5%e6%b1%a0%e8%b4%9f","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=72243","title":{"rendered":"\u6e56\u5357\u5927\u5b66Adv. Energy Mater.\uff1a\u8f6f\u78b3\u9996\u6b21\u7528\u4f5c\u94a0\u57fa\u53cc\u79bb\u5b50\u5168\u7535\u6c60\u8d1f\u6781\u6750\u6599\uff0c\u6bd4\u5bb9\u91cf\u53ef\u8fbe103 mAh\u2022g-1"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u5f53\u4eca\u53ef\u5145\u7535\u7535\u6c60\u4f53\u7cfb\u4e2d\uff0c\u53cc\u79bb\u5b50\u7535\u6c60 (DIBs) \u4ee5\u5176\u9ad8\u5bb9\u91cf\u3001\u4f4e\u6210\u672c\u7b49\u4f18\u70b9\uff0c\u5728\u7535\u6c60\u9886\u57df\u5907\u53d7\u5173\u6ce8\u3002\u76ee\u524d\uff0c\u5bf9\u4e8eDIBs\u6b63\u6781\u6750\u6599\uff0c\u5982\u77f3\u58a8\u3001MOF\u3001\u78b3\u9ed1\u7b49\u5df2\u6709\u4e86\u4e0d\u5c11\u62a5\u9053\u3002\u540c\u65f6\uff0c\u5bfb\u6c42\u4e00\u79cd\u79bb\u5b50\u5c3a\u5bf8\u9002\u5b9c\u3001\u4f4e\u6210\u672c\u7684\u9633\u79bb\u5b50\u6765\u4ee3\u66ff\u4f20\u7edf\u7684\u9502\u79bb\u5b50\uff0c\u5bf9\u4e8eDIBs\u800c\u8a00\u4e5f\u975e\u5e38\u91cd\u8981\u3002\u5728\u81ea\u7136\u754c\u4e2d\uff0c\u94a0\u79bb\u5b50\u542b\u91cf\u4e30\u5bcc\uff0c\u4f46\u79bb\u5b50\u534a\u5f84\u6bd4\u9502\u79bb\u5b50\u7a0d\u5927\uff0c\u5728\u77f3\u58a8\u4e2d\u7684\u5d4c\u5165\u3001\u8131\u5d4c\u6027\u80fd\u8f83\u5dee\uff0c\u56e0\u800c\u76ee\u524d\u5173\u4e8e\u94a0\u57fa\u53cc\u79bb\u5b50\u7535\u6c60 (NDIBs) \u7684\u7814\u7a76\u4f9d\u7136\u5c40\u9650\u4e8e\u534a\u7535\u6c60\u5c42\u9762\u3002\u6b64\u5916\uff0c NDIBs\u8d1f\u6781\u6750\u6599\u7684\u62a5\u9053\u4e5f\u662f\u8f83\u4e3a\u7f55\u89c1\uff0c\u56e0\u6b64\u5176\u8d1f\u6781\u6750\u6599\u7684\u8bbe\u8ba1\u539f\u7406\u4f9d\u7136\u6709\u5f85\u63a2\u7d22\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u6700\u8fd1\uff0c\u6e56\u5357\u5927\u5b66\u9c81\u5175\u5b89\u6559\u6388<\/strong>\u548c\u8bb8\u5fd7\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u5728Adv. Energy Mater.<\/strong>\u4e0a\u8054\u5408\u53d1\u8868\u4e86\u4e00\u7bc7\u540d\u4e3a\u201cSoft Carbon as Anode for High-Performance Sodium-Based Dual Ion Full Battery<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u672c\u6587\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u9996\u6b21\u91c7\u7528\u8f6f\u78b3(soft carbon, SC)\u4f5c\u4e3aNDIBs\u7684\u8d1f\u6781\u6750\u6599\u8fdb\u884c\u7535\u6c60\u7ec4\u88c5\u2014\u2014 SC (\u8d1f\u6781)| 1 M NaPF6<\/sub> EC:DMC (6:4, v\/v) (\u7535\u89e3\u8d28)| \u77f3\u58a8 (\u6b63\u6781)\u3002\u7ecf\u5145\u53d1\u7535\u6d4b\u8bd5\uff0c\u9996\u6b21\u653e\u7535\u5bb9\u91cf\u53ef\u8fbe103 mAh\u00b7g-1<\/sup>,\u5728200 mA\u00b7g-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u653e\u7535\u7535\u538b\u5e73\u53f0\u5927\u7ea6\u4e3a3.58 V; \u57281000 mA\u00b7g-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c800\u4e2a\u5145\u653e\u7535\u5faa\u73af\u540e\uff0c\u6bd4\u5bb9\u91cf\u4f9d\u7136\u53ef\u8fbe54 mAh\u00b7g-1<\/sup>\u3002\u4e3a\u7b2c\u4e8c\u6b21\u653e\u7535\u5bb9\u91cf(66.0 mAh\u00b7g-1<\/sup>)\u768481.8%\uff0c\u6b64\u5916\uff0c\u8be5\u7535\u6c60\u8fd8\u5177\u5907\u4f18\u8d8a\u7684\u5145\u653e\u7535\u500d\u7387(200-2000 mA\u00b7g-1<\/sup>)\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1\u00a0 <\/strong>\u8f6f\u78b3<\/strong>(SC)<\/strong>\u6750\u6599\u7684\u5f62\u8c8c\u53ca\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a-b) \u00a0<\/strong>TEM\u548cHRTEM\u8868\u5f81\u56fe\u50cf\uff1b<\/p>\n

c-d) \u00a0<\/strong>XRD\u3001\u62c9\u66fc\u56fe\u8c31\uff1b<\/p>\n

e) <\/strong>\u9ad8\u5206\u8fa8 C 1s XPS \u8c31\u7ebf\uff1b<\/p>\n

f) <\/strong>N2<\/sub>\u7684\u7b49\u6e29\u5438\u9644\u66f2\u7ebf\uff0c\u63d2\u56fe\u4e3a\u5b54\u5f84\u5206\u5e03\u56fe\uff1b<\/p>\n

g-i) \u00a0<\/strong>DES\u5143\u7d20\u5206\u5e03\u8c31\u56fe\uff1a(h) C\uff0c(i) O\uff1b<\/p>\n

\u56fe<\/strong>2\u00a0 NDIBs<\/strong>\u7535\u5316\u5b66\u6027\u80fd\u6d4b\u8bd5<\/strong><\/p>\n

\"\"<\/p>\n

a) <\/strong>5 mV\u00b7s-1<\/sup>\u626b\u63cf\u901f\u7387\u4e0b\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

b) <\/strong>\u5145\u653e\u7535\u66f2\u7ebf\uff0c\u63d2\u56fe\u4e3a\u5bf9\u5e94\u7684dQ<\/em>\/dV <\/em>\u66f2\u7ebf\uff1b<\/p>\n

c) <\/strong>\u5404\u4e2a\u5145\u7535\u622a\u65ad\u7535\u538b(4.3-4.75 V)\u4e0b\u7684\u5faa\u73af\u66f2\u7ebf\uff1b<\/p>\n

d) <\/strong>\u5404\u4e2a\u653e\u7535\u622a\u65ad\u7535\u538b(3.0-1.0 V)\u4e0b\u7684\u5faa\u73af\u66f2\u7ebf\uff1b<\/p>\n

e-f) \u00a0<\/strong>2.0-4.7 V\u622a\u65ad\u7535\u538b\u4e0b\u7684\u500d\u7387\u66f2\u7ebf\u548c\u5bb9\u91cf\u5faa\u73af\u66f2\u7ebf\uff1b<\/p>\n

\u56fe<\/strong>3\u00a0 <\/strong>\u4e0d\u540c\u5145\u653e\u7535\u72b6\u6001\u4e0b\u7684\u7535\u6781\u6750\u6599\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a) <\/strong>NDIBs\u7684\u521d\u59cb\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

b) <\/strong>\u521d\u59cb\u5145\u653e\u7535\u5faa\u73af\u7684\u975e\u539f\u4f4dXRD\u56fe\u8c31\u2014\u2014\u77f3\u58a8\u7535\u6781\uff1b<\/p>\n

c-f)\u00a0 <\/strong>\u4e0d\u540c\u72b6\u6001\u4e0b\u7684SC \u7535\u6781HRTEM\u56fe\u50cf\uff1a(c) \u5145\u7535\u81f34.7 V(1st cycle)\uff0c(d) \u653e\u7535\u81f32.0 V(1st cycle)\uff0c(e) \u5145\u7535\u81f34.7 V(100th cycle) \uff0c(f) \u653e\u7535\u81f32.0 V(100th cycle)\uff1b<\/p>\n

g-j) \u00a0<\/strong>\u5145\u7535\u81f34.7 V \u65f6\uff0cSC\u7535\u6781\u6750\u6599\u7684\u5143\u7d20(C\u3001O\u3001Na)\u5206\u5e03\u8c31\u56fe\uff1b<\/p>\n

\u56fe<\/strong>4\u00a0 <\/strong>\u5404\u4e2a\u72b6\u6001\u4e0b<\/strong>NDIBs<\/strong>\u793a\u610f\u56fe<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

\u4e94\u4e2a\u72b6\u6001\u4e0b\u7684NDIBs\u793a\u610f\u56fe\uff1a\u521d\u59cb\u3001\u5145\u7535\u3001\u5145\u7535\u5b8c\u6210\u3001\u653e\u7535\u3001\u653e\u7535\u7ed3\u675f;<\/p>\n

\u3010\u603b\u7ed3\u4e0e\u5c55\u671b\u3011<\/strong><\/p>\n

\u8f6f\u78b3\u9996\u6b21\u88ab\u7528\u4f5c\u94a0\u57fa\u53cc\u79bb\u5b50\u5168\u7535\u6c60\u8d1f\u6781\u6750\u6599\uff0c\u4e0d\u4ec5\u8868\u73b0\u51fa\u4e86\u4f18\u826f\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u800c\u4e14\u964d\u4f4e\u4e86NDIBs\u6210\u672c\u3002\u5728200 mA\u00b7g-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u9996\u6b21\u653e\u7535\u5bb9\u91cf\u53ef\u8fbe103 mAh\u00b7g-1<\/sup>, \u800c\u4e14\u5177\u5907\u8f83\u9ad8\u7684\u653e\u7535\u5e73\u53f0\uff083.58 V\uff09\u3001\u4f18\u826f\u7684\u5145\u53d1\u7535\u500d\u7387\uff0c\u5faa\u73af\u7a33\u5b9a\u6027\u4f18\u5f02\uff0c1000 mA\u00b7g-1<\/sup>\u4e0b\uff0c800\u4e2a\u5faa\u73af\u540e\u7684\u6bd4\u5bb9\u91cf\u4f9d\u7136\u53ef\u8fbe81.8%\uff0c\u4ec5\u4ec5\u53ea\u67090.023 % cycle-1<\/sup>\u7684\u5bb9\u91cf\u8870\u51cf\u3002<\/p>\n

\u4ee5\u4e0a\u6570\u636e\u8868\u660e\uff0c\u5728\u80fd\u6e90\u5b58\u50a8\u9886\u57df\u5185\uff0cNDIBs\u9887\u5177\u53d1\u5c55\u6f5c\u529b\u3002\u672c\u6587\u4e2d\uff0c\u8f6f\u78b3\u7684\u5e94\u7528\u53ef\u4ee5\u4e3aNDIBs\u8d1f\u6781\u6750\u6599\u7684\u8fdb\u4e00\u6b65\u7814\u53d1\u63d0\u4f9b\u4e00\u5b9a\u7684\u7406\u8bba\u6307\u5bfc\u3002<\/p>\n

\u539f\u6587\u94fe\u63a5\uff1a<\/strong>Soft Carbon as Anode for High-Performance Sodium-Based<\/a>Dual Ion Full Battery<\/a>\u00a0(Adv. Energy Mater.\uff0c2017\uff0cDOI:\u00a010.1002\/ aenm.201602778)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u7ec4 \u6df1\u6d77\u4e07\u91cc \u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065952\u201d\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u5f53\u4eca\u53ef\u5145\u7535\u7535\u6c60\u4f53\u7cfb\u4e2d\uff0c\u53cc\u79bb\u5b50\u7535\u6c60 (DIBs) \u4ee5\u5176\u9ad8\u5bb9\u91cf\u3001\u4f4e\u6210\u672c\u7b49\u4f18\u70b9\uff0c\u5728\u7535\u6c60\u9886\u57df\u5907\u53d7\u5173\u6ce8\u3002\u76ee\u524d\uff0c\u5bf9\u4e8eDIBs\u6b63\u6781\u6750\u6599\uff0c\u5982\u77f3\u58a8\u3001MOF\u3001\u78b3\u9ed1\u7b49\u5df2\u6709\u4e86…<\/p>\n","protected":false},"author":2219,"featured_media":72247,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[1434,1435],"class_list":["post-72243","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-1434","tag-luanbing"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/72243"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2219"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=72243"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/72243\/revisions"}],"predecessor-version":[{"id":72415,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/72243\/revisions\/72415"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/72247"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=72243"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=72243"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=72243"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}