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2\u3001\u6539\u8fdb\u65b9\u6cd5<\/strong><\/p>\n

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1\u3001\u5f71\u54cd\u56e0\u7d20<\/strong><\/p>\n

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2\u3001\u6539\u8fdb\u65b9\u6cd5<\/strong><\/p>\n

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\u76ee\u524d\uff0c\u786b\u5316\u7269\u7535\u89e3\u8d28\u7684\u7814\u7a76\u4e3b\u8981\u96c6\u4e2d\u5728Li2<\/sub>S-P2<\/sub>S5<\/sub>\u4e8c\u5143\u4f53\u7cfb\u548cLi2<\/sub>S-MS2<\/sub>-P2<\/sub>S5<\/sub>(M=Ge\uff0cSi\uff0cSn\uff0cAl\u6216P)\u4e09\u5143\u4f53\u7cfb\u3002\u7531\u4e8e\u786b\u5316\u7269\u7535\u89e3\u8d28\u4ec5\u4ec5\u901a\u8fc7\u51b7\u538b\u5c31\u80fd\u660e\u663e\u964d\u4f4e\u6676\u754c\u7535\u963b\uff0c\u56e0\u6b64\u5177\u6709\u826f\u597d\u7684\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\u7387\u3002
\n ITO\u7b49[21]<\/sup>\u91c7\u7528\u6db2\u76f8\u5408\u6210\u6cd5\u5c06\u539f\u6599\u6309\u6bd4\u4f8b\u6df7\u5408\u540e\uff0c\u6301\u7eed\u6405\u62cc3 h\uff0c\u5e72\u71e5\u540e\u5c06\u975e\u6676\u4ea7\u7269\u5728\u7ed3\u6676\u6e29\u5ea6\u9644\u8fd1\u70e7\u7ed3\u4e00\u6bb5\u65f6\u95f4\uff0c\u83b7\u5f97\u6676\u76f8\u7ec4\u6210\u4e3aLi7<\/sub>P3<\/sub>S11<\/sub>\u7ed3\u6676\u6001\u7535\u89e3\u8d28\u3002\u82e5\u5728300\u2103\u4e0b\u70ed\u5904\u7406\u6837\u54c1\u5219\u4f1a\u51fa\u73b0Li4<\/sub>P2<\/sub>S6<\/sub>\uff0c\u8fd9\u662f\u56e0\u4e3a\u5728\u9ad8\u6e29\u4e0bLi7<\/sub>P3<\/sub>S11<\/sub>\u8f6c\u53d8\u6210\u70ed\u529b\u5b66\u7a33\u5b9a\u3001\u7535\u5bfc\u7387\u8f83\u4f4e\u7684Li4<\/sub>P2<\/sub>S6<\/sub>\u3002<\/p>\n

MINAMI\u7b49[22-23]<\/sup>\u5206\u522b\u91c7\u7528\u4f20\u7edf\u7684\u7194\u878d\u6dec\u51b7\u6cd5\u548c\u673a\u68b0\u7403\u78e8\u6280\u672f\u5236\u5907\u7ec4\u6210\u4e3a70Li2<\/sub>S\u202230P2<\/sub>S5<\/sub>\u73bb\u7483\u7535\u89e3\u8d28\uff0c\u7136\u540e\u5728\u6676\u5316\u6e29\u5ea6\u9644\u8fd1\u70ed\u5904\u7406\u4e00\u6bb5\u65f6\u95f4\u83b7\u5f97\u73bb\u7483\u9676\u74f7\u7535\u89e3\u8d28\u3002<\/p>\n

\u2461\u6676\u4f53\u578b<\/strong><\/p>\n

KOTOBUKI\u7b49[24]<\/sup>\u63a2\u7a76\u4e86\u63ba\u6742\u5c11\u91cf\u7684Al2<\/sub>03<\/sub>\u5bf9Li7<\/sub>La3<\/sub>Zr2<\/sub>O12<\/sub>\u7535\u89e3\u8d28\u7684\u5f71\u54cd\u3002\u5b9e\u9a8c\u53d1\u73b0\uff0cAl2<\/sub>O3<\/sub>\u4f5c\u4e3a\u70e7\u7ed3\u52a9\u5242\u80fd\u591f\u6709\u6548\u964d\u4f4e\u70e7\u7ed3\u6e29\u5ea6\uff0c\u540c\u65f6\u63d0\u9ad8\u7535\u89e3\u8d28\u7684\u7535\u5bfc\u7387\uff0c\u800c\u4e14\u4e0d\u4f1a\u5f71\u54cdLi7<\/sub>La3<\/sub>Zr2<\/sub>O12<\/sub>\u7535\u89e3\u8d28\u5bf9\u91d1\u5c5e\u9502\u7684\u7a33\u5b9a\u6027\u3002<\/p>\n

BUSCHMANN\u7b49[25]<\/sup>\u7814\u7a76\u53d1\u73b0\uff0c\u5c11\u91cf\u7684Al\u548cTa\u5171\u63ba\u6742\u5e76\u4ee5\u65e0\u5b9a\u5f62\u6001\u5b58\u5728\u4e8e\u6b8b\u4f59\u76f8\u6216\u6676\u754c\u4f4d\u7f6e\uff0c\u80fd\u591f\u63d0\u9ad8\u6750\u6599\u7684\u81f4\u5bc6\u5ea6\u3001\u964d\u4f4e\u6676\u754c\u7535\u963b\u3002<\/p>\n

WOLFENSTINE\u7b49[26]<\/sup>\u91c7\u7528\u70ed\u538b\u6cd5\u5236\u5907\u5f97\u5230\u81f4\u5bc6\u5ea6\u9ad8\u7684\u56db\u65b9\u76f8\u77f3\u69b4\u77f3\u578b\u7535\u89e3\u8d28\u6750\u6599\uff0c\u6750\u6599\u76f8\u5bf9\u5bc6\u5ea6\u8f83\u56fa\u76f8\u70e7\u7ed3\u6cd5\u6709\u663e\u8457\u63d0\u9ad8\u3002\u4f46\u662f\u56db\u65b9\u76f8\u4e2d\u5b58\u5728\u5b6a\u6676\uff0c\u5b6a\u6676\u6676\u754c\u5bf9\u7535\u89e3\u8d28\u603b\u963b\u6297\u8d21\u732e\u8f83\u5927\uff0c\u56e0\u6b64\u56db\u65b9\u76f8\u6bd4\u7acb\u65b9\u76f8\u7535\u89e3\u8d28\u7684\u7535\u5bfc\u7387\u4f4e\u3002<\/p>\n

KOTOBUKI\u7b49[27]<\/sup>\u91c7\u7528\u5171\u6c89\u6dc0\u6cd5\u6765\u5236\u5907\u9897\u7c92\u5c3a\u5bf8\u5747\u5300\u7684NASICON\u578b\u7535\u89e3\u8d28\u6750\u6599\uff0c\u540c\u65f6\u53d1\u73b0\uff0c\u7119\u70e7\u6e29\u5ea6\u548c\u7119\u70e7\u65f6\u95f4\u4e25\u91cd\u5f71\u54cd\u7535\u89e3\u8d28\u7684\u7535\u5bfc\u7387\u3002<\/p>\n

XU\u7b49[28-29]<\/sup>\u4f7f\u7528\u7eb3\u7c73\u9897\u7c92\u7ed3\u5408\u653e\u7535\u7b49\u79bb\u5b50\u4f53\u70e7\u7ed3\u6280\u672f(SPS)\uff0c\u964d\u4f4e\u70e7\u7ed3\u6e29\u5ea6\u7684\u540c\u65f6\u63d0\u9ad8\u6750\u6599\u81f4\u5bc6\u5ea6\uff0c\u964d\u4f4e\u56fa\u4f53\u7535\u89e3\u8d28\u4e2d\u6676\u754c\u7684\u542b\u91cf\u3002\u4ed6\u4eec\u8fd8\u7814\u7a76\u4e86\u9502\u8fc7\u91cf\u5bf9\u7535\u89e3\u8d28\u70e7\u7ed3\u6027\u80fd\u7684\u5f71\u54cd\u3002\u5b9e\u9a8c\u53d1\u73b0\uff0c\u9002\u91cf\u7684\u9502\u8fc7\u91cf\u53ef\u4ee5\u4f5c\u4e3a\u6210\u6838\u5242\uff0c\u5728\u70ed\u5904\u7406\u8fc7\u7a0b\u4e2d\u4fc3\u8fdb\u73bb\u7483\u6001\u7269\u8d28\u5f62\u6838\u957f\u5927\uff0c\u6709\u52a9\u4e8e\u63d0\u9ad8\u7535\u89e3\u8d28\u7684\u81f4\u5bc6\u5ea6\uff0c\u5f53Li2<\/sub>0\u63ba\u6742\u91cf\u4e3a0.05 mol\u65f6\uff0cLi1.5<\/sub>Al0.5<\/sub>Ge1.5<\/sub>(PO4<\/sub>)3<\/sub>\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\u7387\u4e3a7.25\u00d710-4<\/sup> S\/cm\u3002\u4f46\u662f\uff0c\u5f53\u9502\u8fc7\u91cf\u8d85\u51fa\u4e00\u5b9a\u8303\u56f4\uff0c\u4f1a\u9020\u6210\u6676\u7c92\u5f02\u5e38\u957f\u5927\uff0c\u7535\u89e3\u8d28\u5185\u90e8\u51fa\u73b0\u88c2\u7eb9\uff0c\u76f8\u5bf9\u5bc6\u5ea6\u964d\u4f4e\u3002<\/p>\n

\u65e0\u673a\u5168\u56fa\u6001\u7535\u89e3\u8d28\u9ad8\u7684\u673a\u68b0\u5f3a\u5ea6\u548c\u5bbd\u7684\u6e29\u5ea6\u9002\u5e94\u8303\u56f4\u662f\u89e3\u51b3\u73b0\u6709\u9502\u7535\u6c60\u5b89\u5168\u6027\u95ee\u9898\u7684\u5173\u952e\u6240\u5728\u3002\u76ee\u524d\uff0c\u5168\u56fa\u6001\u7535\u89e3\u8d28\u7684\u7814\u7a76\u4e3b\u8981\u96c6\u4e2d\u5728\u5f00\u53d1\u9ad8\u7535\u5bfc\u7387\u7684\u65e0\u673a\u7535\u89e3\u8d28\u548c\u6709\u673a\u4e00\u65e0\u673a\u590d\u5408\u7535\u89e3\u8d28\u3002\u786b\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u5177\u6709\u8f83\u9ad8\u7684\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\u7387\uff0c\u4f46\u662f\u5176\u73af\u5883\u7a33\u5b9a\u6027\u5dee\u3002\u6c27\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u5316\u5b66\u7a33\u5b9a\u6027\u597d\uff0c\u4f46\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\u7387\u8f83\u4f4e\uff0c\u67d0\u4e9b\u9ad8\u4ef7\u9633\u79bb\u5b50\u4f1a\u4e0e\u91d1\u5c5e\u9502\u53d1\u751f\u53cd\u5e94\u3002\u6709\u673a\u4e00\u65e0\u673a\u590d\u5408\u7535\u89e3\u8d28\u517c\u5177\u6709\u673a\u7269\u826f\u597d\u7684\u67d4\u6027\u548c\u65e0\u673a\u7269\u9ad8\u7684\u673a\u68b0\u5f3a\u5ea6\uff0c\u4f46\u662f\u7531\u4e8e\u805a\u5408\u7269\u57fa\u4f53\u7684\u7535\u5bfc\u7387\u4f4e\uff0c\u4e14\u4f4e\u6e29\u73af\u5883\u4e0b\u6613\u7ed3\u6676\uff0c\u56e0\u6b64\u590d\u5408\u7535\u89e3\u8d28\u7684\u5ba4\u6e29\u7535\u5bfc\u7387\u8f83\u4f4e\u3002\u5c3d\u7ba1\u5168\u56fa\u6001\u9502\u7535\u6c60\u5177\u6709\u66f4\u9ad8\u7684\u5b89\u5168\u6027\u80fd\u548c\u66f4\u957f\u7684\u5faa\u73af\u5bff\u547d\uff0c\u6709\u671b\u5728\u50a8\u80fd\u548c\u52a8\u529b\u9886\u57df\u4e2d\u5e94\u7528\uff0c\u4f46\u662f\u7535\u89e3\u8d28\u4e0e\u7535\u6781\u7684\u754c\u9762\u76f8\u5bb9\u6027\u548c\u7a33\u5b9a\u6027\u5374\u9650\u5236\u4e86\u5168\u56fa\u6001\u9502\u7535\u6c60\u7684\u53d1\u5c55\u3002\u4e3a\u5b9e\u73b0\u5168\u56fa\u6001\u9502\u7535\u6c60\u7684\u5b9e\u9645\u5e94\u7528\uff0c\u5f52\u4e00\u5316\u7684\u754c\u9762\u7535\u963b\u671f\u671b\u503c\u5927\u7ea6\u5728100 \u03a9\u2022cm2<\/sup>\u4ee5\u5185\uff0c\u800c\u76ee\u524d\u7684\u754c\u9762\u7535\u963b\u503c\u5728200 \u03a9\u2022cm2<\/sup>\u5de6\u53f3\u3002\u56e0\u6b64\uff0c\u5982\u4f55\u901a\u8fc7\u5f15\u5165\u7a33\u5b9a\u7684\u5bfc\u7535\u7f13\u51b2\u5c42\u6d88\u9664\u6216\u51cf\u5f31\u7a7a\u95f4\u7535\u8377\u5c42\u6548\u5e94\uff0c\u6291\u5236\u754c\u9762\u5c42\u751f\u6210\uff0c\u964d\u4f4e\u754c\u9762\u7535\u963b\uff0c\u662f\u672a\u6765\u5168\u56fa\u6001\u9502\u7535\u6c60\u9886\u57df\u9762\u4e34\u7684\u5171\u540c\u6311\u6218\u3002<\/p>\n

\u53c2\u8003\u6587\u732e<\/strong><\/p>\n

[1] \u5f20\u8212, \u738b\u5c11\u98de, \u51cc\u4ed5\u521a,\u7b49. \u9502\u79bb\u5b50\u7535\u6c60\u57fa\u7840\u79d1\u5b66\u95ee\u9898(X)\u2014\u2014\u5168\u56fa\u6001\u9502\u79bb\u5b50\u7535\u6c60[J]. \u50a8\u80fd\u79d1\u5b66\u4e0e\u6280\u672f, 2014, 3(4):376-394.
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