{"id":71548,"date":"2017-03-20T06:30:09","date_gmt":"2017-03-19T22:30:09","guid":{"rendered":"\/\/m.iemloyee.com\/?p=71548"},"modified":"2017-03-17T23:25:04","modified_gmt":"2017-03-17T15:25:04","slug":"%e5%ad%a6%e6%9c%af%e5%b9%b2%e8%b4%a7%e4%b8%a8%e8%ae%ba%e9%92%b4%e5%9f%ba%e5%8f%8c%e9%87%91%e5%b1%9e%e6%b0%a7%e5%8c%96%e7%89%a9%e5%82%a8%e8%83%bd%e6%9d%90%e6%96%99%e7%9a%84%e9%ab%98%e6%95%88%e5%88%b6","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=71548","title":{"rendered":"\u5b66\u672f\u5e72\u8d27\u4e28\u8bba\u94b4\u57fa\u53cc\u91d1\u5c5e\u6c27\u5316\u7269\u50a8\u80fd\u6750\u6599\u7684\u9ad8\u6548\u5236\u5907\u548c\u7535\u5316\u5b66\u5e94\u7528"},"content":{"rendered":"

\u4e00\u3001\u5f15\u8a00<\/strong><\/span><\/p>\n

\u94b4\u91d1\u5c5e\u6c27\u5316\u7269\u4f5c\u4e3a\u4e00\u7c7b\u5178\u578b\u7684\u50a8\u80fd\u6750\u6599\uff0c\u65e2\u53ef\u4ee5\u7528\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\uff0c\u53c8\u53ef\u4ee5\u7528\u4e8e\u8d85\u7ea7\u7535\u5bb9\u5668\u7535\u6781\u6750\u6599\uff0c\u56e0\u800c\u5907\u53d7\u5173\u6ce8 \u3002\u5728\u4f5c\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\u65f6\uff0c\u5177\u6709\u8f83\u9ad8\u7684\u7406\u8bba\u6bd4\u5bb9\u91cf\uff0c\u4f46\u5145\u653e\u7535\u4f53\u79ef\u53d8\u5316\u8f83\u5927\u3001\u6750\u6599\u5bfc\u7535\u6027\u8f83\u5dee\uff1b\u5728\u4f5c\u4e3a\u8d85\u7ea7\u7535\u5bb9\u5668\u7535\u6781\u6750\u6599\u65f6\uff0c\u867d\u7136\u7406\u8bba\u6bd4\u7535\u5bb9\u8f83\u9ad8\uff0c\u4f46\u7535\u963b\u504f\u5927\u3001\u6210\u672c\u8f83\u9ad8\uff0c\u56e0\u800c\u5236\u7ea6\u4e86\u5176\u53d1\u5c55\u3002<\/p>\n

\u901a\u8fc7\u5f15\u5165\u6d3b\u6cfc\u4e14\u76f8\u5bf9\u5ec9\u4ef7\u7684\u91d1\u5c5e\u5143\u7d20\uff0c\u5982\u954d\u3001\u950c\u3001\u9530\u3001\u94dc\u3001\u94c1\u3001\u9541\u7b49\uff0c\u4e0e\u94b4\u3001\u6c27\u7ec4\u6210\u65b0\u7684\u53cc\u91d1\u5c5e\u6c27\u5316\u7269\uff0c\u662f\u4e00\u4e2a\u975e\u5e38\u6709\u4ef7\u503c\u7684\u7814\u7a76\u65b9\u5411\u3002\u5728\u7ee7\u627f\u5355\u4e00\u94b4\u91d1\u5c5e\u6c27\u5316\u7269\u7684\u9ad8\u6bd4\u5bb9\u91cf\u3001\u9ad8\u6bd4\u7535\u5bb9\u4f18\u70b9\u7684\u540c\u65f6\uff0c\u6539\u6027\u5143\u7d20\u7684\u5f15\u5165\u53c8\u63d0\u9ad8\u4e86\u6750\u6599\u7684\u7ed3\u6784\u7a33\u5b9a\u6027\u3001\u5bfc\u7535\u6027\u7b49\uff0c\u4f7f\u5176\u500d\u7387\u6027\u80fd\u3001\u5faa\u73af\u7a33\u5b9a\u6027\u7b49\u5f97\u5230\u540c\u6b65\u63d0\u9ad8\u3002\u901a\u8fc7\u6750\u6599\u7eb3\u7c73\u5316\u3001\u7279\u6b8a\u5f62\u8c8c\u6784\u7b51\u3001\u590d\u5408\u5316\u7b49\u624b\u6bb5\uff0c\u5bf9\u8be5\u94b4\u57fa\u53cc\u91d1\u5c5e\u6c27\u5316\u7269\u8fdb\u884c\u6539\u6027\uff0c\u7814\u7a76\u5176\u5fae\u89c2\u7ed3\u6784\u4e0e\u7535\u5316\u5b66\u6027\u80fd\u3001\u53cd\u5e94\u673a\u7406\u4e4b\u95f4\u7684\u5173\u7cfb\uff0c\u80fd\u591f\u6709\u52a9\u4e8e\u63a8\u52a8\u94b4\u57fa\u53cc\u91d1\u5c5e\u6c27\u5316\u7269\u6750\u6599\u7684\u5b9e\u9645\u5e94\u7528\u3002<\/p>\n

\u4e8c\u3001\u94b4\u57fa\u53cc\u91d1\u5c5e\u6c27\u5316\u7269\u7684\u7814\u7a76\u8fdb\u5c55<\/strong><\/span><\/p>\n

\u94b4\u57fa\u53cc\u91d1\u5c5e\u6c27\u5316\u7269\u662f\u4e00\u7c7b\u5177\u5907\u5c16\u6676\u77f3\u7ed3\u6784\u7684\u6c27\u5316\u7269\u6750\u6599\uff0c\u662f\u4e00\u7c7b\u7279\u6b8a\u7684\u79bb\u5b50\u6676\u4f53\uff0c\u7ed3\u6784\u901a\u5f0f\u4e3aACo2<\/sub>O4<\/sub>\uff0c\u5176\u4e2dA\u4e3a\u4e8c\u4ef7\u91d1\u5c5e\u79bb\u5b50\uff0c\u5982Mg2+<\/sup>\uff0cZn2+<\/sup>\uff0cFe2+<\/sup>\uff0cNi2+<\/sup>\uff0cMn2+<\/sup>\uff0cCo2+<\/sup>\uff0cCd2+<\/sup>\u7b49\u3002\u7ed3\u6784\u4e2d O2\u2013<\/sup>\u4f5c\u7acb\u65b9\u5bc6\u5806\u79ef\uff0c\u5176\u4e2d Co3+<\/sup>\u79bb\u5b50\u5219\u586b\u5145\u5728\u5728\u516b\u9762\u4f53\u4e2d\u5fc3\uff0cA2+<\/sup>\u79bb\u5b50\u586b\u5145\u5728\u56db\u9762\u4f53\u4e2d\u5fc3\uff0c\u5373 Co3+<\/sup>\u79bb\u5b50\u5219\u4e3a 6 \u914d\u4f4d\uff0c\u800cA2+<\/sup>\u79bb\u5b50\u4e3a 4 \u914d\u4f4d\u3002\u8fd1\u5e74\u6765\uff0c\u5728\u9502\u79bb\u5b50\u7535\u6c60\u548c\u8d85\u7ea7\u7535\u5bb9\u5668\u9886\u57df\u5185\uff0c\u5177\u6709\u5c16\u6676\u77f3\u7ed3\u6784\u7684\u94b4\u57fa\u53cc\u91d1\u5c5e\u6c27\u5316\u7269\u5f15\u8d77\u4e86\u7535\u6781\u6750\u6599\u7814\u7a76\u9886\u57df\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u4e0b\u6587\u5c31\u51e0\u79cd\u5e38\u89c1\u7684\u94b4\u57fa\u53cc\u91d1\u5c5e\u6c27\u5316\u7269\u6750\u6599\uff08\u5982\u56fe1\u6240\u793a\uff09\uff0c\u5bf9\u5176\u505a\u4e00\u7b80\u5355\u7684\u8bba\u8ff0\u3002<\/p>\n

\"\"<\/p>\n

\u56fe1\u00a0 \u5404\u79cd\u94b4\u57fa\u91d1\u5c5e\u6c27\u5316\u7269\u6bd4\u7535\u5bb9\u503c\u7684\u6bd4\u8f83<\/p>\n

1. \u00a0\u94b4\u9178\u954d\uff08<\/strong>NiCo2<\/sub>O4<\/sub><\/strong>\uff09<\/strong><\/p>\n

\u954d\u4e0e\u94b4\u7684\u6027\u8d28\u76f8\u4f3c\uff0c\u4e14\u90fd\u5177\u6709\u8d5d\u7535\u5bb9\u6027\u8d28\uff0c\u6545\u94b4\u3001\u954d\u53cc\u91d1\u5c5e\u6c27\u5316\u7269\u7684\u5236\u5907\u76f8\u5bf9\u8f83\u7b80\u5355\uff0c\u6613\u5f62\u6210\u5355\u4e00\u7eaf\u76f8\u3002\u76ee\u524d\u5236\u5907NiCo2<\/sub>O4<\/sub>\u5e38\u7528\u65b9\u6cd5\u662f\u6eb6\u5242\u70ed\u6cd5\u548c\u6c34\u70ed\u6cd5\uff0c\u5176\u4ed6\u65b9\u6cd5\u5305\u62ec\u6eb6\u80f6\u51dd\u80f6\u6cd5\u3001\u6db2\u76f8\u6c89\u6dc0\u6cd5\u3001\u6a21\u677f\u6cd5\u3001\u9759\u7535\u7eba\u4e1d\u6cd5\u7b49\u3002\u5236\u5907\u7684NiCo2<\/sub>O4<\/sub>\u5fae\u89c2\u7ed3\u6784\u5404\u5f02\uff0c\u5305\u62ec\u7eb3\u7c73\u7ebf\u3001\u7eb3\u7c73\u68d2\u3001\u7eb3\u7c73\u7247\u3001\u6d77\u80c6\u72b6\u3001\u5fae\u7403\u3001\u4e09\u7ef4\u82b1\u72b6\u3001\u591a\u5b54\u7f51\u72b6\u3001\u73ca\u745a\u72b6\u7b49\u3002NiCo2<\/sub>O4<\/sub>\u4e0d\u4ec5\u5177\u6709\u4e86Co3<\/sub>O4<\/sub>\u7684\u9ad8\u5ea6\u7a33\u5b9a\u6027\u80fd\u548c\u9ad8\u500d\u7387\u6027\u80fd\uff0c\u800c\u4e14\u53c8\u62e5\u6709NiO\u7684\u9ad8\u6bd4\u7535\u5bb9\u6027\uff0c\u56e0\u800c\u4e3b\u8981\u7528\u4f5c\u8d85\u7ea7\u7535\u5bb9\u5668\u7535\u6781\u6750\u6599\uff0c\u5728\u9502\u79bb\u5b50\u7535\u6c60\u9886\u57df\u7814\u7a76\u76f8\u5bf9\u8f83\u5c11\u3002Lu\u7b49\u5229\u7528\u786c\u6a21\u677f\u6cd5\u5408\u6210\u5f97\u5230\u4e86\u4e00\u79cd\u65b0\u578b\u7684NiCo2<\/sub>O4<\/sub>\u7535\u6781\u6750\u6599\uff08\u5177\u6709\u9ad8\u5ea6\u6709\u5e8f\u4ecb\u5b54\u7ed3\u6784\uff09\uff0c\u7ecf\u8fc7\u4f4e\u6e29\u7145\u70e7\u7b49\u6b65\u9aa4\u63a7\u5236\u6750\u6599\u7684\u7ed3\u6676\u5ea6\uff0c\u5728170\u2103\u4e0b\u83b7\u5f97\u7684\u7535\u6781\u6750\u6599\u572828.6 A\u00b7g-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u6761\u4ef6\u4e0b\uff0c\u8868\u73b0\u51fa\u9ad8\u8fbe612 F\u00b7g-1\u7684\u6bd4\u7535\u5bb9\u503c\u3002Yuan\u7b49\u628a\u5236\u5907\u7684\u8d85\u8584NiCo2<\/sub>O4<\/sub>\u7eb3\u7c73\u7247(2~5 nm)\u56fa\u5b9a\u5230\u954d\u7b94\u4e0a\u3002\u572820 A\u00b7g-1<\/sup>\u6761\u4ef6\u4e0b\uff0c\u5176\u6bd4\u7535\u5bb9\u9ad8\u8fbe1450 F\u00b7g-1<\/sup>(\u5982\u56fe2)\u3002An\u7b49\u5229\u7528\u6eb6\u5242\u70ed\u6cd5\u6210\u529f\u5408\u6210\u4e86\u4e09\u7ef4\u7684\u82b1\u72b6\u94b4\u9178\u954d\u591a\u7ea7\u7ed3\u6784\uff0c\u8fd9\u79cd\u82b1\u72b6\u591a\u7ea7\u7ed3\u6784\u662f\u7531\u5916\u56f4\u4f17\u591a\u7684\u7eb3\u7c73\u7247\u56f4\u7ed5\u4e00\u4e2a\u4e2d\u5fc3\u805a\u96c6\u800c\u5f97\u5230\uff0c\u76f4\u5f84\u7ea6\u4e3a500 nm\u3002\u8be5\u82b1\u72b6\u591a\u7ea7\u7ed3\u6784\u7eb3\u7c73\u6750\u6599\u5177\u6709\u591a\u5b54\u7ed3\u6784\uff0c\u800c\u4e14\u5b83\u7684\u6bd4\u8868\u9762\u79ef\u9ad8\u8fbe212.6 m2<\/sup>\u00b7g\u20131<\/sup>\uff0c\u5728\u7535\u6d41\u5bc6\u5ea6\u5206\u522b\u4e3a 1\uff0c10 A\u00b7g\u20131<\/sup>\u65f6\u5404\u81ea\u5177\u67091191.2\uff0c755.2 F\u00b7g\u20131<\/sup>\u7684\u6bd4\u7535\u5bb9\uff0c\u5c55\u73b0\u51fa\u4e86\u826f\u597d\u7684\u500d\u7387\u6027\u80fd\u53ca\u7a33\u5b9a\u6027\u80fd\u3002<\/p>\n

\"\"<\/p>\n

\u56fe2 \u00a0(a, b) NiCo2<\/sub>O4<\/sub>\u7684SEM\u56fe\u7247; (c, d) NiCo2<\/sub>O4<\/sub>\u7684\u7535\u5316\u5b66\u6027\u80fd\u66f2\u7ebf\u3002<\/p>\n

\u540c\u65f6\uff0cNiCo2<\/sub>O4<\/sub>\u4e5f\u53ef\u7528\u4f5c\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\u3002Li\u7b49\u901a\u8fc7\u6eb6\u5242\u70ed\u6cd5\u5408\u6210\u4e86\u5355\u5206\u6563NiCo2<\/sub>O4<\/sub>\u4ecb\u5b54\u5fae\u7403(\u76f4\u5f842~3 \u03bcm\uff0c\u5e73\u5747\u5b54\u5f8414.5 nm)\u3002\u57280.2 A\u00b7g-1<\/sup>\u6761\u4ef6\u4e0b\uff0c30\u6b21\u5faa\u73af\u540e\uff0c\u653e\u7535\u6bd4\u5bb9\u91cf\u4ecd\u9ad8\u8fbe1198 mAh\u00b7g-1<\/sup>\uff1b\u5728\u5927\u7535\u6d410.8 A\u00b7g-1<\/sup>\u6761\u4ef6\u4e0b\uff0c500\u6b21\u5faa\u73af\u540e\uff0c\u53ef\u9006\u6bd4\u5bb9\u91cf\u4ecd\u7ef4\u6301\u5728705 mAh\u00b7g-1<\/sup>\u3002Chen \u7b49\u901a\u8fc7\u6a21\u677f\u6cd5\u5b9a\u5411\u751f\u957f\u4e86NiCo2<\/sub>O4<\/sub>\u7eb3\u7c73\u7ebf\u9635\u5217 (\u957f2.0 \u03bcm\uff0c\u76f4\u5f8450~80 nm)\u3002\u5728100 mA\u00b7g-1<\/sup>\u6761\u4ef6\u4e0b\uff0c\u9996\u6b21\u653e\u7535\u6bd4\u5bb9\u91cf\u4e3a2025 mAh\u00b7g-1<\/sup>\uff0c\u4f46\u5bb9\u91cf\u4fdd\u6301\u7387\u4e00\u822c\u3002<\/p>\n

2. \u00a0\u94b4\u9178\u950c\uff08<\/strong>ZnCo2<\/sub>O4<\/sub><\/strong>\uff09<\/strong><\/p>\n

\u94b4\u9178\u950c\u7ed3\u6784\u7a33\u5b9a\uff0c\u7269\u7406\u6027\u80fd\u4e30\u5bcc\uff0c\u662f\u4e00\u79cd\u5178\u578b\u7684\u4e09\u5143\u5c16\u6676\u77f3\u7ed3\u6784\u7684\u6c27\u5316\u7269\u3002\u5728\u9502\u79bb\u5b50\u7535\u6c60\u6750\u6599\u65b9\u9762\uff0c\u5176\u8868\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u8d28\uff1a\u53ef\u9006\u80fd\u529b\u3001\u5faa\u73af\u7a33\u5b9a\u6027\u4ee5\u53ca\u7eff\u8272\u6e05\u6d01\u7b49\uff0c\u4e3b\u8981\u7528\u4f5c\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\uff0c\u5728\u8d85\u7ea7\u7535\u5bb9\u5668\u4e2d\u7684\u7814\u7a76\u8f83\u5c11\u3002<\/p>\n

\u76ee\u524d\uff0cZnCo2<\/sub>O4<\/sub>\u7684\u5e38\u7528\u5236\u5907\u65b9\u6cd5\u4ecd\u7136\u662f\u6c34\u70ed\u6cd5\u3001\u6eb6\u5242\u70ed\u6cd5\u53ca\u70ed\u5206\u89e3\u6cd5\uff0c\u5176\u4ed6\u65b9\u6cd5\u5305\u62ec\u6a21\u677f\u6cd5\u3001\u9759\u7535\u7eba\u4e1d\u6cd5\u7b49\u3002ZnCo2<\/sub>O4<\/sub>\u7684\u5fae\u89c2\u7ed3\u6784\u4e3b\u8981\u4e3a\u5e38\u89c4\u7684\u68d2\u72b6\u3001\u7247\u72b6\u3001\u7403\u72b6\u53ca\u9635\u5217\u3002ZnCo2<\/sub>O4<\/sub>\u7684\u7535\u5316\u5b66\u6027\u80fd (\u7279\u522b\u662f\u500d\u7387\u6027\u80fd) \u8981\u660e\u663e\u4f18\u4e8e\u5355\u4e00\u7684Co3O4\u4e0eCoO\uff0c\u4f46\u5176\u6bd4\u5bb9\u91cf\u8981\u7565\u4f4e\u4e8eNiCo2<\/sub>O4<\/sub>\u3002Liu\u7b49\u901a\u8fc7\u6c34\u70ed\u6cd5\u5408\u6210ZnCo2<\/sub>O4<\/sub>\u7eb3\u7c73\u68d2(\u76f4\u5f84 15~22 nm\uff0c\u957f\u5ea6 150~200 nm)\u3002\u57280.2 mA\u00b7cm-2<\/sup>\u6761\u4ef6\u4e0b\uff0c\u521d\u59cb\u653e\u7535\u6bd4\u5bb9\u91cf\u4e3a1509 mAh\u00b7g-1\uff0c50\u6b21\u5faa\u73af\u540e\uff0c\u5bb9\u91cf\u4e3a767 mAh\u00b7g-1<\/sup>\uff1b\u4e14EIS\u6570\u636e\u8868\u660e\u5176\u5177\u6709\u8f83\u4f4e\u7684\u8868\u5c42\u7535\u963b(\u7ea6\u4e3a192 \u03a9)\u3002Du\u7b49\u901a\u8fc7\u5e38\u6e29\u6db2\u76f8\u6c89\u6dc0\u53ca\u70ed\u5206\u89e3\u6cd5\u5236\u5907\u4e86\u591a\u5b54\u68d2\u72b6ZnCo2<\/sub>O4<\/sub> (\u957f\u51e0\u5fae\u7c73\uff0c\u76f4\u5f84100~300 nm)\uff0c\u5e76\u53d1\u73b0\u7145\u70e7\u6e29\u5ea6\u5f71\u54cd\u5176\u7535\u5316\u5b66\u6027\u80fd\u3002\u5728100 mA\u00b7g-1<\/sup>\u6761\u4ef6\u4e0b\uff0c500 \u2103\u7145\u70e7\u6240\u5f97\u6750\u6599\u7684\u7535\u5316\u5b66\u6027\u80fd\u66f4\u597d\uff0c\u5176\u9996\u6b21\u653e\u7535\u6bd4\u5bb9\u91cf\u9ad8\u8fbe1331.5 mAh\u00b7g-1<\/sup>\uff0c\u5982\u56fe3\u6240\u793a\u3002Zhu\u7b49\u91c7\u7528\u5fae\u6ce2\u6cd5\u5408\u6210\u4e86\u4e8c\u7ef4\u8d85\u8584ZnCo2<\/sub>O4<\/sub>\u7eb3\u7c73\u5c42\u72b6\u7269(\u6bd4\u8868\u9762\u79ef\u9ad8\u8fbe181m2<\/sub>\u00b7g-1<\/sup>)\u3002\u5728200 mA\u00b7g-1<\/sup>\u6761\u4ef6\u4e0b\uff0c200\u6b21\u5faa\u73af\u540e\uff0c\u53ef\u9006\u6bd4\u5bb9\u91cf\u4ecd\u4fdd\u6301\u7ea6\u4e3a960 mAh\u00b7g-1<\/sup>\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3\u00a0 (a, b) ZnCo2<\/sub>O4<\/sub>\u7684SEM\u56fe\u4e0eTEM\u56fe; (c) ZnCo2<\/sub>O4<\/sub>\u7684\u7535\u5316\u5b66\u6027\u80fd\u66f2\u7ebf\u3002<\/p>\n

ZnCo2<\/sub>O4<\/sub>\u5728\u8d85\u7ea7\u7535\u5bb9\u5668\u9886\u57df\u5e94\u7528\u5982\u4e0b\uff1aHuang\u7b49\u901a\u8fc7\u6c34\u70ed\u6cd5\u5236\u5907\u4e86\u68d2\u72b6ZnCo2<\/sub>O4<\/sub>\u9897\u7c92(27 nm)\u3002\u5176\u57281 A\u00b7g-1<\/sup>\u6761\u4ef6\u4e0b\uff0c\u6bd4\u7535\u5bb9\u4e3a604.5 F\u00b7g-1<\/sup>\uff0c3000\u6b21\u5faa\u73af\u540e\uff0c\u6bd4\u7535\u5bb9\u4fdd\u6301\u7387\u4e3a95.6%\u3002Bao\u7b49\u901a\u8fc7\u6a21\u677f\u6cd5\u5728Ni\u7b94\u4e0a\u5747\u5300\u751f\u957f\u4e86\u4ecb\u5b54ZnCo2<\/sub>O4<\/sub>\u7eb3\u7c73\u7247\u9635\u5217\u3002\u5176\u572830 A\u00b7g-1<\/sup>\u6761\u4ef6\u4e0b\uff0c\u6bd4\u7535\u5bb9\u4e3a1850 F\u00b7g-1<\/sup>\uff0c1500\u6b21\u5faa\u73af\u540e\uff0c\u6bd4\u7535\u5bb9\u4fdd\u6301\u7387\u4e3a96.3%\u3002<\/p>\n

3. \u00a0\u94b4\u9178\u9530\uff08<\/strong>MnCo2<\/sub>O4<\/sub><\/strong>\uff09<\/strong><\/p>\n

\u9530\u7684\u4ef7\u6001\u8f83\u591a\uff0c\u52a0\u5165\u9530\u5143\u7d20\u5f62\u6210\u94b4\u3001\u9530\u4e8c\u5143\u6c27\u5316\u7269\uff0c\u6613\u4ea7\u751f\u539f\u5b50\u7a7a\u4f4d\u3001\u5360\u4f4d\u7b49\u7ed3\u6784\uff0c\u53ef\u4fc3\u8fdb\u9502\u79bb\u5b50\u7684\u8fc1\u79fb\uff0c\u63d0\u5347\u7535\u5316\u5b66\u6027\u80fd\uff0c\u56e0\u800c\u591a\u7528\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\u7535\u6781\u6750\u6599\u3002Huang\u7b49\u901a\u8fc7\u6c34\u70ed\u6cd5\u5408\u6210\u4e86\u5177\u6709\u6838\u58f3\u7ed3\u6784\u4e0e\u6d53\u5ea6\u68af\u5ea6\u7684MnCo2<\/sub>O4<\/sub>\u5fae\u7c73\u692d\u7403(\u957f\u8f742.5~4.5 \u03bcm\uff0c\u77ed\u8f741.5~2.5 \u03bcm\uff1b\u5916\u58f3\u5c42\u539a\u5ea6\uff0c200~300 nm\uff1b\u5916\u58f3\u5c42\u94b4\u542b\u91cf\u8981\u9ad8\u4e8e\u5185\u6838)\u3002 \u57280.1\u548c0.4 A\u00b7g-1<\/sup>\u6761\u4ef6\u4e0b\uff0c\u9996\u6b21\u653e\u7535\u6bd4\u5bb9\u91cf\u5206\u522b\u4e3a1433.3\u548c1248.4 mAh\u00b7g-1<\/sup>\uff1b60\u6b21\u5faa\u73af\u540e\uff0c\u53ef\u9006\u6bd4\u5bb9\u91cf\u5206\u522b\u7ef4\u6301\u5728900\u548c620 mAh\u00b7g-1\u3002Liu\u7b49\u901a\u8fc7\u6c34\u70ed\u6cd5\u5236\u5907\u4e86\u7eb3\u7c73\u5c3a\u5bf8\u7684MnCo2<\/sub>O4<\/sub> (10~20 nm)\uff0cXPS\u8868\u5f81\u7ed3\u679c\u663e\u793aMn\u548cCo\u7684\u5316\u5408\u4ef7\u5206\u522b\u662f+4\u548c+2\u3002\u57280.2 mA\u00b7cm-2<\/sup>\u6761\u4ef6\u4e0b\uff0c\u9996\u6b21\u653e\u7535\u6bd4\u5bb9\u91cf\u8fbe\u52301448 mAh\u00b7g-1<\/sup>\u3002Li\u7b49\u901a\u8fc7\u70ed\u5206\u89e3\u6cd5\u5236\u5907\u4e86\u7c7b\u4f3c\u7684\u4e2d\u7a7a\u7ed3\u6784MnCo2<\/sub>O4<\/sub>\u4e9a\u5fae\u7c73\u7403(\u76f4\u5f84250 nm)\u3002\u901a\u8fc7\u63a7\u5236\u5347\u6e29\u901f\u7387\uff0c\u5206\u522b\u5f97\u5230\u4e86\u4ecb\u5b54\u7403\u3001\u4e2d\u7a7a\u7403\u3001\u86cb\u9ec4-\u58f3\u7403\u3001\u53cc\u58f3\u7403\u3001\u591a\u5c42\u58f3\u7403\u7b49\u3002\u57280.4 A\u00b7g-1<\/sup>\u6761\u4ef6\u4e0b\uff0c\u9996\u6b21\u653e\u7535\u6bd4\u5bb9\u91cf\u6700\u9ad8\u80fd\u8fbe\u52301425 mAh\u00b7g-1<\/sup>\uff1b100 \u6b21\u5faa\u73af\u540e\uff0c\u53ef\u9006\u6bd4\u5bb9\u91cf\u6700\u5927\u4e3a850 mAh\u00b7g-1<\/sup>(\u5982\u56fe 4\u6240\u793a)\u3002<\/p>\n

\"\"<\/p>\n

\u56fe4\u00a0 (a-e) MnCo2<\/sub>O4<\/sub>\u7684SEM\u56fe; (f) MnCo2<\/sub>O4<\/sub>\u7684\u7535\u5316\u5b66\u6027\u80fd\u66f2\u7ebf\u3002<\/p>\n

\u5728\u8d85\u7ea7\u7535\u5bb9\u5668\u9886\u57df\u5185\uff0c\u90e8\u5206\u79d1\u7814\u4eba\u5458\u4e5f\u5bf9MnCo2<\/sub>O4<\/sub>\u4f5c\u4e86\u4e00\u7cfb\u5217\u7684\u7814\u7a76\u3002\u5982Venkatach-alam\u7b49\u91c7\u7528\u6c34\u70ed\u6cd5\u5408\u6210MnCo2<\/sub>O4<\/sub>\u7eb3\u7c73\u7ebf\u3002\u57280.5 A\u00b7g-1<\/sup>\u6761\u4ef6\u4e0b\uff0c\u5176\u9996\u6b21\u6bd4\u7535\u5bb9\u4e3a718.8 F\u00b7g-1<\/sup>\uff1b\u57282 A\u00b7g-1<\/sup>\u6761\u4ef6\u4e0b\uff0c1000\u6b21\u5faa\u73af\u540e\uff0c\u6bd4\u7535\u5bb9\u4e3a500 F\u00b7g-1<\/sup>\u3002Sahoo\u7b49\u91c7\u7528\u6a21\u677f\u6cd5\u5408\u6210MnCo2<\/sub>O4<\/sub>\u7eb3\u7c73\u7247\u9635\u5217(\u539a\u5ea610~40 nm\uff0c\u957f\u5ea61~2 \u03bcm)\u3002\u57280.25 A\u00b7g-1<\/sup> \u6761\u4ef6\u4e0b\uff0c\u5176\u9996\u6b21\u6bd4\u7535\u5bb9\u4e3a250 F\u00b7g-1<\/sup>\uff0c1000\u6b21\u5faa\u73af\u540e\uff0c\u6bd4\u7535\u5bb9\u65e0\u8870\u51cf\u3002<\/p>\n

\u76f8\u5bf9\u4e8eNiCo2<\/sub>O4<\/sub>\u4e0eZnCo2<\/sub>O4<\/sub>\uff0cMnCo2<\/sub>O4<\/sub>\u7684\u7814\u7a76\u8f83\u5c11\uff0c\u8fd9\u53ef\u80fd\u662f\u7531\u4e8e\u9530\u5143\u7d20\u7684\u4ef7\u6001\u8f83\u591a\uff0c\u6613\u4ea7\u751fMn2<\/sub>O3<\/sub>\u3001MnO2<\/sub>\u7b49\u6742\u8d28\uff0c\u7eaf\u76f8\u7684MnCo2<\/sub>O4<\/sub>\u8f83\u96be\u5408\u6210\u3002\u5176\u5408\u6210\u65b9\u6cd5\u4e3b\u8981\u4e3a\u6c34\u70ed\u6cd5\u3001\u6eb6\u5242\u70ed\u6cd5\u4e0e\u70ed\u5206\u89e3\u6cd5\u7b49\uff1b\u7ed3\u6784\u4e3a\u5e38\u89c1\u7684\u7403\u5f62\uff0c\u5176\u4ed6\u7279\u6b8a\u5f62\u8c8c\u8f83\u5c11\uff1b\u4e14\u4e3b\u8981\u5e94\u7528\u5728\u9502\u79bb\u5b50\u7535\u6c60\u9886\u57df\uff0c\u8d85\u7ea7\u7535\u5bb9\u5668\u7814\u7a76\u8f83\u5c11\u3002\u4ece\u56fe1\u53ef\u77e5\uff0cMnCo2<\/sub>O4<\/sub>\u7684\u7406\u8bba\u6bd4\u7535\u5bb9\u6700\u5927\uff0c\u4f46\u662f\u5b9e\u9a8c\u62a5\u9053\u6700\u5927\u6bd4\u7535\u5bb9\u6750\u6599\u662fNiCo2<\/sub>O4<\/sub>\u3002\u53ef\u89c1\u6750\u6599\u7684\u5236\u5907\u5de5\u827a\u4ee5\u53ca\u5176\u751f\u957f\u7684\u7ed3\u6676\u5f62\u6001\u5bf9\u6bd4\u7535\u5bb9\u5f71\u54cd\u5f88\u5927\uff0c\u5982\u4f55\u80fd\u5f00\u53d1\u5408\u7406\u7684\u5236\u5907\u5de5\u827a\u53ca\u65b9\u6cd5\u4e5f\u662f\u5f00\u53d1\u9ad8\u6bd4\u7535\u5bb9\u7535\u6781\u6750\u6599\u7684\u91cd\u8981\u7814\u7a76\u5185\u5bb9\u3002<\/p>\n

4. \u00a0\u5176\u5b83\u94b4\u57fa\u53cc\u91d1\u5c5e\u6c27\u5316\u7269\uff08<\/strong>MCo2<\/sub>O4<\/sub><\/strong>\uff09<\/strong><\/p>\n

\u9664\u4e86\u5e38\u89c1\u7684Ni\u3001Zn\u3001Mn\u4e0eCo\u5f62\u6210\u53cc\u91d1\u5c5e\u6c27\u5316\u7269\uff0c\u8fd8\u6709Fe\u3001Mg\u3001Cu\u7b49\u91d1\u5c5e\u4e5f\u80fd\u4e0eCo\u5f62\u6210\u53cc\u91d1\u5c5e\u6c27\u5316\u7269\u3002Sharma\u7b49\u901a\u8fc7\u5c3f\u7d20\u71c3\u548c\u8349\u9178\u5206\u89e3\u7684\u65b9\u6cd5\u5408\u6210\u4e86FeCo2<\/sub>O4<\/sub>\u548cMgCo2<\/sub>O4<\/sub>\u3002\u572860 mA\u00b7g-1\u6761\u4ef6\u4e0b\uff0cFeCo2<\/sub>O4<\/sub>\u7684\u9996\u6b21\u6bd4\u5bb9\u91cf\u4e3a 827 m Ah\u00b7g-1\uff0cMgCo2<\/sub>O4<\/sub>\u7684\u9996\u6b21\u6bd4\u5bb9\u91cf\u4e3a 736 mAh\u00b7g-1\uff1b50\u6b21\u5faa\u73af\u540e\uff0cFeCo2<\/sub>O4<\/sub>\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u7ea690%\uff0c\u800cMgCo2<\/sub>O4<\/sub>\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u8f83\u5dee\uff1b\u8be5\u7ed3\u679c\u8868\u660eFe\u4f5c\u4e3a\u590d\u5408\u5143\u7d20\u8981\u6bd4Mg\u7684\u6548\u679c\u66f4\u597d\u3002Pendashteh\u7b49\u91c7\u7528\u6a21\u677f\u6cd5\u5408\u6210\u4e86\u591a\u5b54CuCo2<\/sub>O4<\/sub>\u7eb3\u7c73\u7ebf\u9635\u5217\u3002 \u57282 A\u00b7g-1<\/sup> \u6761\u4ef6\u4e0b\uff0c\u5176\u9996\u6b21\u6bd4\u7535\u5bb9\u7ea6\u4e3a3000 F\u00b7g-1<\/sup>\uff0c\u63a5\u8fd1\u7406\u8bba\u503c\u3002Chen\u7b49\u91c7\u7528\u6a21\u677f\u6cd5\u5408\u6210\u4e86\u7c7b\u4f3c\u7684CuCo2<\/sub>O4<\/sub>\u7eb3\u7c73\u7ebf\u9635\u5217\u3002\u57281.7 A\u00b7g-1<\/sup>\u6761\u4ef6\u4e0b\uff0c\u5176\u9996\u6b21\u6bd4\u7535\u5bb9\u7ea6\u4e3a611 F\u00b7g-1<\/sup>\uff0c8000\u6b21\u5faa\u73af\u540e\uff0c\u5176\u6bd4\u7535\u5bb9\u4fdd\u6301\u7387\u4e3a94.8%\u3002<\/p>\n

MCo2<\/sub>O4<\/sub>\u7684\u7814\u7a76\u8981\u8fdc\u8fdc\u5c11\u7528NiCo2<\/sub>O4<\/sub>\u3001ZnCo2<\/sub>O4<\/sub>\u4e0eMnCo2<\/sub>O4<\/sub>\u3002\u5176\u5408\u6210\u65b9\u6cd5\u4e3b\u8981\u4e3a\u70ed\u5206\u89e3\u6cd5\u4e0e\u6a21\u677f\u6cd5\u7b49\uff0c\u5fae\u89c2\u7ed3\u6784\u7684\u8bbe\u8ba1\u6784\u7b51\u8f83\u5c11\uff0c\u5728\u7535\u5316\u5b66\u50a8\u80fd\u9886\u57df\u7684\u5e94\u7528\u624d\u521a\u521a\u8d77\u6b65\u3002<\/p>\n

\u4e09\u3001\u94b4\u57fa\u53cc\u91d1\u5c5e\u6c27\u5316\u7269\u590d\u5408\u6750\u6599\u7684\u7814\u7a76\u8fdb\u5c55<\/strong><\/span><\/p>\n

\u5728\u94b4\u57fa\u53cc\u91d1\u5c5e\u6c27\u5316\u7269\u7684\u57fa\u7840\u4e0a\uff0c\u901a\u8fc7\u590d\u5408\u6539\u6027\u53ef\u8fdb\u4e00\u6b65\u63d0\u9ad8\u5176\u7535\u5316\u5b66\u6027\u80fd\u3002He\u7b49\u901a\u8fc7\u6c34\u70ed\u6cd5\u5c06 NiCo2<\/sub>O4<\/sub>\u7eb3\u7c73\u7ebf\u8d1f\u8f7d\u5728\u8fd8\u539f\u6c27\u5316\u77f3\u58a8\u70ef (Reduced Graphene Oxide, RGO)\u4e0a\u5f97\u5230\u4e86NiCo2<\/sub>O4<\/sub>@RGO\u590d\u5408\u6750\u6599\u3002\u57281 A\u00b7g-1<\/sup>\u7684\u6761\u4ef6\u4e0b\uff0c\u6bd4\u7535\u5bb9\u9ad8\u8fbe737 F\u00b7g-1<\/sup>\uff1b\u57284 A\u00b7g-1<\/sup>\u7684\u6761\u4ef6\u4e0b\uff0c3000\u6b21\u5faa\u73af\u540e\uff0c\u6bd4\u7535\u5bb9\u635f\u5931\u4ec5\u4e3a6%\u3002Zhou\u7b49\u901a\u8fc7\u7c7b\u4f3c\u6a21\u677f\u6cd5\u5728\u954d\u7b94\u4e0a\u5236\u5907\u4e86\u4e09\u7ef4\u7ed3\u6784NiCo2<\/sub>O4<\/sub>\/\u77f3\u58a8\u70ef\u590d\u5408\u6750\u6599\u3002\u57286\u548c200 A\u00b7g-1<\/sup>\u7684\u6761\u4ef6\u4e0b\uff0c\u9996\u6b21\u6bd4\u7535\u5bb9\u5206\u522b\u4e3a2173\u548c954 F\u00b7g-1<\/sup>\uff1b\u5728100A\u00b7g-1<\/sup>\u6761\u4ef6\u4e0b\uff0c14000\u6b21\u5faa\u73af\u540e\uff0c\u6bd4\u7535\u5bb9\u4fdd\u6301\u7387\u4e3a94% \u3002Zhai\u7b49\u91c7\u7528\u6c34\u70ed\u6cd5\u5236\u5907\u4e86NiCo2O4\/MnCo2O4\u4e9a\u5fae\u7c73\u7403(\u76f4\u5f84\u7ea61 \u03bcm)\u3002\u57281 A\u00b7 g-1\u6761\u4ef6\u4e0b\uff0c600\u6b21\u5faa\u73af\u540e\uff0c\u53ef\u9006\u6bd4\u5bb9\u91cf\u4e3a 1009 mAh\u00b7g-1\uff1b\u57285 A\u00b7g-1<\/sup>\u6761\u4ef6\u4e0b\uff0c\u9996\u6b21\u6bd4\u7535\u5bb9\u4e3a911.3 F\u00b7g-1<\/sup>\uff0c1000\u6b21\u5faa\u73af\u540e\uff0c\u6bd4\u7535\u5bb9\u4e3a800 F\u00b7g-1<\/sup>\u3002<\/p>\n

Chen\u7b49\u901a\u8fc7\u6a21\u677f\u6cd5\u5728\u954d\u7b94\u4e0a\u751f\u957f\u5f62\u6210\u4e86NiCo2<\/sub>O4<\/sub>\/\u77f3\u58a8\u70ef\u7eb3\u7c73\u7247\u9635\u5217\u3002\u5728100 mA\u00b7g-1<\/sup>\u6761\u4ef6\u4e0b\uff0c\u9996\u6b21\u653e\u7535\u6bd4\u5bb9\u91cf\u4e3a 1216 mAh\u00b7g-1<\/sup>\uff0c80\u6b21\u5faa\u73af\u540e,\u53ef\u9006\u6bd4\u5bb9\u91cf\u4ecd\u5927\u4e8e800 mAh\u00b7g-1<\/sup>(\u5982\u56fe5\u6240\u793a)\u3002Peng\u7b49\u901a\u8fc7\u6a21\u677f\u6cd5\u5236\u5907\u4e86NiCo2<\/sub>O4<\/sub>\/C\u7eb3\u7c73\u9635\u5217 (\u957f2.5 \u03bcm\uff0c\u76f4\u5f8410~30nm)\u3002 \u5728 2 A\u00b7g-1<\/sup>\u6761\u4ef6\u4e0b\uff0c\u9996\u6b21\u653e\u7535\u6bd4\u5bb9\u91cf\u4e3a664 mAh\u00b7g-1<\/sup>\uff1b\u5728100 mA\u00b7g-1<\/sup>\u6761\u4ef6\u4e0b\uff0c200\u6b21\u5faa\u73af\u540e\uff0c\u6bd4\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a97%\u3002<\/p>\n

\"\"<\/p>\n

\u56fe5\u00a0 (a) NiCo2<\/sub>O4<\/sub>\/\u77f3\u58a8\u70ef\u7684TEM\u56fe; (b) NiCo2<\/sub>O4<\/sub>\/\u77f3\u58a8\u70ef\u7684\u7535\u5316\u5b66\u6027\u80fd\u66f2\u7ebf\u3002<\/p>\n

\u94b4\u57fa\u53cc\u91d1\u5c5e\u6c27\u5316\u7269\u4e3b\u8981\u901a\u8fc7\u4e0e\u77f3\u58a8\u70ef\u3001\u78b3\u7eb3\u7c73\u7ba1\u3001\u78b3\u7b49\u70ad\u7d20\u7c7b\u6750\u6599\u590d\u5408\u3002 \u78b3\u7d20\u7c7b\u6750\u6599\u4e0d\u4ec5\u53ef\u4ee5\u5f25\u8865\u91d1\u5c5e\u6c27\u5316\u7269\u6027\u5bfc\u7535\u5dee\u7684\u7f3a\u9677\uff0c \u4e5f\u53ef\u4ee5\u7f13\u51b2\u53cc\u91d1\u5c5e\u6c27\u5316\u7269\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u7684\u4f53\u79ef\u53d8\u5316\uff0c\u589e\u5927\u53cc\u91d1\u5c5e\u6c27\u5316\u7269\u6750\u6599\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u80fd\u548c\u500d\u7387\u6027\u80fd\uff1b\u540c\u65f6\uff0c\u78b3\u7d20\u7c7b\u6750\u6599\u81ea\u8eab\u53ef\u8d21\u732e\u4e00\u5b9a\u7684\u6bd4\u7535\u5bb9\u6216\u6bd4\u5bb9\u91cf\u3002<\/p>\n

\u56db\u3001\u603b\u7ed3\u4e0e\u5c55\u671b<\/strong><\/span><\/p>\n

\u5f53\u524d\u7684\u94b4\u57fa\u53cc\u91d1\u5c5e\u6c27\u5316\u7269\u4e3b\u8981\u56f4\u7ed5\u7740 \u201c\u5236\u5907\u65b9\u6cd5-\u5fae\u89c2\u7ed3\u6784\u63a7\u5236-\u7535\u5316\u5b66\u6027\u80fd-\u673a\u7406\u5206\u6790\u201d\u8fd9\u4e00\u8def\u7ebf\u5c55\u5f00\u3002NiCo2<\/sub>O4<\/sub>\u3001ZnCo2<\/sub>O4<\/sub>\u3001MnCo2<\/sub>O4<\/sub>\u7b49\u94b4\u57fa\u53cc\u91d1\u5c5e\u6c27\u5316\u7269\u7684\u7535\u5316\u5b66\u6027\u80fd (\u5c24\u5176\u662f\u500d\u7387\u6027\u80fd\u53ca\u5faa\u73af\u5bff\u547d) \u5728\u4e00\u5b9a\u7a0b\u5ea6\u4e0a\u8981\u4f18\u4e8e\u5355\u4e00\u94b4\u91d1\u5c5e\u6c27\u5316\u7269(Co3O4\u3001CoO\u7b49)\uff0c\u8d77\u5230\u4e86\u6539\u6027\u7684\u4f5c\u7528\uff1b\u901a\u8fc7\u4e0e\u78b3\u7d20\u7c7b\u3001\u91d1\u5c5e\u53ca\u5176\u4ed6\u91d1\u5c5e\u6c27\u5316\u7269\u590d\u5408\uff0c\u80fd\u8fdb\u4e00\u6b65\u63d0\u9ad8\u5176\u7535\u5316\u5b66\u6027\u80fd\u3002\u9274\u4e8e\u94b4\u57fa\u53cc\u91d1\u5c5e\u6c27\u5316\u7269\u7684\u8bf8\u591a\u4f18\u70b9\uff0c\u5176\u5728\u9502\u79bb\u5b50\u7535\u6c60\u3001\u8d85\u7ea7\u7535\u5bb9\u5668\u3001\u65b0\u578b\u94a0\u79bb\u5b50\u7535\u6c60\u7b49\u80fd\u6e90\u5b58\u50a8\u8bbe\u5907\u9886\u57df\u6709\u8f83\u5927\u7684\u5e94\u7528\u6f5c\u529b\u548c\u4f18\u52bf\u3002\u4e3a\u4e86\u5145\u5206\u53d1\u6325\u94b4\u57fa\u91d1\u5c5e\u6c27\u5316\u7269\u4f5c\u4e3a\u7535\u6781\u6750\u6599\u7684\u4f18\u5f02\u6027\u80fd\uff0c\u8fd8\u9700\u8981\u901a\u8fc7\u5b9e\u9a8c\u7814\u7a76\u4e0d\u65ad\u5b8c\u5584\u76f8\u5173\u7406\u8bba\u5e76\u7814\u53d1\u51fa\u66f4\u5408\u7406\u7684\u5408\u6210\u5de5\u827a\u3002<\/p>\n

\u76f8\u5173\u6587\u732e\uff1a<\/strong><\/p>\n

[1] \u9ec4\u56fd\u52c7, \u5f90\u76db\u660e, \u6768\u8d8a\u7b49. \u94b4\u57fa\u53cc\u91d1\u5c5e\u6c27\u5316\u7269\u7684\u5236\u5907\u53ca\u5176\u5728\u7535\u5316\u5b66\u50a8\u80fd\u9886\u57df\u7684\u5e94\u7528[J]. \u65e0\u673a\u5316\u5b66\u5b66\u62a5, 2016, 32(10): 1693-1703.<\/p>\n

[2] \u8bb8\u5bb6\u80dc, \u5b8b\u5fe0\u7b11, \u5f20\u6770\u7b49. \u5c16\u6676\u77f3\u7ed3\u6784\u7684\u94b4\u57fa\u91d1\u5c5e\u6c27\u5316\u7269\u8d85\u7ea7\u7535\u5bb9\u5668\u7535\u6781\u6750\u6599\u7684\u7814\u7a76\u8fdb\u5c55[J]. \u7535\u5b50\u5143\u4ef6\u4e0e\u6750\u6599, 2016, 35(3):1-6.<\/p>\n

[3] Lu Q, Chen Y, Li W, et al. J. Mater. Chem. A, 2013, 6(1): 2331-2336.<\/p>\n

[4]Yuan C Z, Li J Y, Hou L R, et al. Adv. Funct. Mater., 2012, 22:4592-4597.<\/p>\n

[5] An C, Wang Y, Huang Y, et al. Crystengcomm., 2014, 16(3): 385-392.<\/p>\n

[6]Li J F, Xiong S L, Liu Y R, et al. ACS Appl. Mater. Interfaces, 2013,5:981-988<\/p>\n

[7]Chen G H, Yang J, Tang J J, et al. RSC Adv., 2015,5:23067-23072<\/p>\n

[8]Liu H W, Liu J. Electrochim. Acta, 2013,92:371-375<\/p>\n

[9]Du N, Xu Y F, Zhang H, et al. Inorg. Chem., 2011,50:3320-3324<\/p>\n

[10]Zhu Y Q, Cao C B, Zhang J T, et al. J. Mater. Chem. A, 2015,3:9556-9564<\/p>\n

[11]Huang T F, Zhao C H, Zheng R J, et al. Ionics, 2015,21: 3109-3115<\/p>\n

[12]Bao F X, Wang X F, Zhao X D, et al. RSC Adv., 2014,4: 2393-2397<\/p>\n

[13]Huang G Y, Xu S M, Xu Z H, et al. ACS Appl. Mater. Interfaces, 2014,6:21325-21334<\/p>\n

[14]Liu H W, Wang J. J. Electron. Mater., 2012,41:3107-3110<\/p>\n

[15]Li J F, Wang J Z, Liang X, et al. ACS Appl. Mater. Interfaces, 2014,6:24-30<\/p>\n

[16]Venkatachalama V, Alsalme A, Alghamdi A, et al. J. Electroanal. Chem., 2015,756:94-100<\/p>\n

[17]Sahoo S, Naik K K, Rout C S. Nanotechnology, 2015,26: 455401-455409<\/p>\n

[18]Sharma Y, Sharma N, Rao S G V, et al. Solid State Ionics, 2008,179:587-597<\/p>\n

[19]Pendashteh A, Moosavifard S E, Rahmanifar S M, et al. Chem. Mater., 2015,27:3919-3926<\/p>\n

[20]Chen H Y, Chen X H, Zeng Y, et al. RSC Adv., 2015,5:70494-70497<\/p>\n

[21]He G Y, Wang L, Chen H Q, et al. Mater. Lett., 2013,98:164-167<\/p>\n

[22]Zhou J, Huang Y, Cao X H, et al. Nanoscale, 2015,7:7035-7039<\/p>\n

[23]Zhai Y J, Mao H Z, Liu P, et al. J. Mater. Chem. A, 2015,3:16142-16149<\/p>\n

[24]Chen Y J, Zhu J, Qu B H, et al. Nano Energy, 2014,3:88-94<\/p>\n

[25]Peng L, Zhang H J, Bai Y J, et al. J. Mater. Chem. A, 2015, 3:22094-22101<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u7ec4 \u6df1\u6d77\u4e07\u91cc \u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u6750\u6599\u4eba\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u4eba\u7f51\u5411\u5404\u5927\u56e2\u961f\u8bda\u5fc3\u7ea6\u7a3f\uff0c\u8bfe\u9898\u7ec4\u6700\u65b0\u6210\u679c\u3001\u65b9\u5411\u603b\u7ed3\u3001\u56e2\u961f\u8bbf\u8c08\u3001\u5b9e\u9a8c\u6280\u80fd\u7b49\u7686\u53ef\u6295\u7a3f\uff0c\u8bf7\u8054\u7cfb\uff1a\u90ae\u7bb1tougao@cailiaoren.com \u6216 QQ\uff1a97482208\u3002<\/p>\n

\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e<\/strong>\u6750\u6599\u4eba<\/strong><\/a>\u3001\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u4e00\u3001\u5f15\u8a00 \u94b4\u91d1\u5c5e\u6c27\u5316\u7269\u4f5c\u4e3a\u4e00\u7c7b\u5178\u578b\u7684\u50a8\u80fd\u6750\u6599\uff0c\u65e2\u53ef\u4ee5\u7528\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\uff0c\u53c8\u53ef\u4ee5\u7528\u4e8e\u8d85\u7ea7\u7535\u5bb9\u5668\u7535\u6781\u6750\u6599\uff0c\u56e0\u800c\u5907\u53d7\u5173\u6ce8 \u3002\u5728\u4f5c\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\u65f6\uff0c\u5177\u6709\u8f83\u9ad8\u7684…<\/p>\n","protected":false},"author":2219,"featured_media":71554,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[4],"tags":[],"class_list":["post-71548","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-ganhuo"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/71548"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2219"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=71548"}],"version-history":[{"count":7,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/71548\/revisions"}],"predecessor-version":[{"id":71954,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/71548\/revisions\/71954"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/71554"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=71548"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=71548"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=71548"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}