{"id":71325,"date":"2017-03-19T06:30:05","date_gmt":"2017-03-18T22:30:05","guid":{"rendered":"\/\/m.iemloyee.com\/?p=71325"},"modified":"2017-03-19T14:47:07","modified_gmt":"2017-03-19T06:47:07","slug":"%e5%ad%a6%e6%9c%af%e5%b9%b2%e8%b4%a7%e2%88%a3%e6%9c%89%e6%9c%ba%e5%8d%a4%e5%8c%96%e9%93%85%e9%92%99%e9%92%9b%e7%9f%bf%e5%a4%aa%e9%98%b3%e8%83%bd%e7%94%b5%e6%b1%a0","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=71325","title":{"rendered":"\u5b66\u672f\u5e72\u8d27\u2223\u4e00\u6587\u4e86\u89e3\u6709\u673a\u5364\u5316\u94c5\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60"},"content":{"rendered":"

\u4e00\u3001\u5f15\u8a00<\/strong><\/span><\/p>\n

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<\/sup>
\n \u4e8c\u3001\u6709\u673a\u91d1\u5c5e\u5364\u5316\u7269<\/strong><\/span><\/p>\n

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\"\"<\/p>\n

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\"\"<\/p>\n

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\u4e09\u3001\u6709\u673a\u5364\u5316\u94c5<\/strong><\/span><\/p>\n

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\u6709\u673a\u5364\u5316\u94c5\u5305\u62ec\u4e09\u7c7b\uff1a<\/p>\n

(1)\u6709\u673a\u7898\u5316\u94c5\uff1a\u7532\u80fa\u7898\u94c5(MAPbI3<\/sub>, MA=CH3<\/sub>NH3<\/sub>+<\/sup>)\u662f\u5e94\u7528\u4e8e\u5149\u7535\u8f6c\u5316\u6700\u6210\u529f\u7684\u9499\u949b\u77ff\u6750\u6599\uff0c\u5e26\u5bbd\u4e3a1.55 eV\uff1b<\/p>\n

(2)\u6709\u673a\u6eb4\u5316\u94c5\uff1a\u7532\u80fa\u6eb4\u94c5(MAPbBr3<\/sub>)\u4e0e\u7898\u5316\u7269\u76f8\u6bd4\uff0c\u8f93\u51fa\u7684\u7535\u538b\u66f4\u9ad8\uff0c\u4f46\u5149\u5438\u6536\u80fd\u529b\u51cf\u5f31\uff1b<\/p>\n

(3)\u6df7\u5408\u5364\u7d20\u79bb\u5b50\u5364\u5316\u94c5\uff1a\u6df7\u5408\u5364\u5316\u94c5(MAPb3-x<\/sub>Clx<\/sub>)\u4e2dCl–<\/sup>\u63ba\u6742\u9020\u6210\u6676\u683c\u626d\u66f2\uff0c\u589e\u52a0\u4e86\u6709\u673a\u5364\u5316\u94c5\u819c\u5c42\u7684\u73af\u5883\u7a33\u5b9a\u6027\u548c\u5bfc\u7535\u6027\uff0c\u5ef6\u957f\u4e86\u7535\u8377\u6269\u6563\u957f\u5ea6\uff0c\u4f46\u5bf9\u5149\u5b66\u6027\u8d28\u65e0\u660e\u663e\u5f71\u54cd\u3002<\/p>\n

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(1) \u654f\u5316\u7c7b\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60<\/p>\n

\u654f\u5316\u7c7b\u9499\u949b\u77ff\u578b\u592a\u9633\u7535\u6c60\u7531\u5bfc\u7535\u73bb\u7483(FTO)\u5c42\u3001\u963b\u9694\u5c42\u3001\u9499\u949b\u77ff\u67d3\u6599\u5438\u9644(\u6c27\u5316\u7269\u5c42\/\u7535\u5b50\u4f20\u8f93+\u9499\u949b\u77ff)\u5c42\u3001\u7a7a\u7a74\u4f20\u8f93(HTM)\u5c42\u548c\u5bf9\u7535\u6781\u7b49\u6784\u6210\uff0c\u5982\u56fe3\u6240\u793a\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3 \u654f\u5316\u7c7b\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7ed3\u6784\u793a\u610f\u56fe[6]<\/sup><\/p>\n

\u5149\u7535\u8f6c\u5316\u7684\u57fa\u672c\u8fc7\u7a0b\u662f\u9499\u949b\u77ff\u5c42\u5438\u6536\u5149\u5b50\u540e\u6fc0\u53d1\u4ea7\u751f\u7535\u5b50\u548c\u7a7a\u7a74\u5bf9\uff0c\u7535\u5b50\u548c\u7a7a\u7a74\u5206\u522b\u901a\u8fc7\u7535\u5b50\u4f20\u8f93\u5c42\u548cHTM\u5c42\u6ce8\u5165\u5230FTO\u9633\u6781\u548c\u91d1\u5c5e\u9634\u6781\uff0c\u8fde\u63a5\u5916\u7535\u8def\u4ece\u800c\u5728\u4e24\u7535\u6781\u95f4\u4ea7\u751f\u7535\u6d41\uff0c\u5982\u56fe4\u6240\u793a\u3002\u654f\u5316\u7c7b\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u4e2d\uff0c\u4e0d\u540c\u6676\u578b\u7ed3\u6784\u7684TiO2<\/sub>\u88ab\u7528\u4e8e\u7535\u5b50\u4f20\u8f93\u5c42\uff0c\u5982\u9510\u949b\u77ff\u578b\u548c\u91d1\u7ea2\u77f3\u578b\u3002\u4e24\u8005\u5149\u7535\u8f6c\u5316\u6548\u7387\u7684\u5dee\u522b\u662f\u7531\u4e8e\u91d1\u7ea2\u77f3\u6676\u578bTiO2<\/sub>\u6bd4\u9510\u949b\u77ff\u6676\u578bTiO2<\/sub>\u7535\u5b50\u4f20\u8f93\u66f4\u6162\uff0c\u7535\u5b50\u5bff\u547d\u66f4\u957f\uff0c\u76f8\u5e94\u7535\u6c60\u7684\u7535\u538b\u8f83\u4f4e\u3002\u4e00\u7ef4\u7ed3\u6784\u7684TiO2<\/sub>\u4e5f\u88ab\u5e94\u7528\u4e8e\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u4e2d\uff0c\u53d1\u73b0\u968f\u7740\u4e00\u7ef4\u7ed3\u6784\u957f\u5ea6\u7684\u589e\u52a0\uff0c\u5149\u7535\u8f6c\u5316\u6548\u7387\u5148\u589e\u52a0\u540e\u51cf\u5c0f\uff0c\u8bf4\u660e\u7535\u5b50\u4f20\u8f93\u548c\u67d3\u6599\u8d1f\u8f7d\u91cf\u4e4b\u95f4\u5b58\u5728\u7740\u4e00\u4e2a\u5e73\u8861\u3002<\/p>\n

\"\"<\/p>\n

\u56fe4 \u654f\u5316\u7c7b\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5de5\u4f5c\u539f\u7406\u793a\u610f\u56fe[7]<\/sup><\/p>\n

(2) \u4ecb\u89c2\u8d85\u7ea7\u7ed3\u6784\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60<\/p>\n

\u6b64\u79cd\u7535\u6c60\u7531FTO\u5c42\u3001\u81f4\u5bc6\u5c42TiO2<\/sub>\u3001\u91d1\u5c5e\u6c27\u5316\u7269\u652f\u67b6(\u5982Al2<\/sub>O3<\/sub>\u5c42)\u3001\u9499\u949b\u77ff\u5c42\u3001HTM\u5c42\u3001\u91d1\u6216\u94f6\u7535\u6781\u7ec4\u6210\uff0c\u5982\u56fe5\u6240\u793a\u3002<\/p>\n

\"\"<\/p>\n

\u56fe5 \u4ecb\u89c2\u8d85\u7ea7\u7ed3\u6784\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7ed3\u6784\u793a\u610f\u56fe[7]<\/sup><\/p>\n

\u5728\u8fd9\u79cd\u7535\u6c60\u7ed3\u6784\u4e2d\uff0c\u91d1\u5c5e\u6c27\u5316\u7269\u6750\u6599(\u5982Al2<\/sub>O3<\/sub>)\u4f5c\u4e3a\u7edd\u7f18\u5c42\u5e76\u672a\u53c2\u4e0e\u5230\u7535\u6c60\u53cd\u5e94\u7684\u4efb\u4f55\u6b65\u9aa4\uff0c\u4ec5\u8d77\u8d1f\u8f7d\u9499\u949b\u77ff\u7684\u652f\u67b6\u5c42\u4f5c\u7528\u3002\u9499\u949b\u77ff\u4e0d\u53ea\u8d77\u5230\u4e86\u5438\u6536\u5149\u80fd\u5e76\u8f6c\u5316\u4e3a\u7535\u80fd\u7684\u4f5c\u7528\uff0c\u8fd8\u8d77\u5230\u4e86\u7535\u5b50\u4f20\u8f93\u7684\u4f5c\u7528\uff0c\u5c06\u5149\u751f\u7535\u5b50\u901a\u8fc7\u81f4\u5bc6\u5c42\u4e0e\u5bfc\u7535\u73bb\u7483\u4f20\u8f93\u5230\u5916\u7535\u8def\u5f62\u6210\u56de\u8def\uff0c\u5982\u56fe6\u6240\u793a\u3002<\/p>\n

\"\"<\/p>\n

\u56fe6 \u4ecb\u89c2\u8d85\u7ea7\u7ed3\u6784\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5de5\u4f5c\u539f\u7406\u793a\u610f\u56fe[7]<\/sup><\/p>\n

\u4ecb\u89c2\u8d85\u7ea7\u7ed3\u6784\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u4e2d\uff0c\u9499\u949b\u77ff\u5c42\u4e0e\u91d1\u5c5e\u7535\u6781\u5c42\u76f4\u63a5\u63a5\u89e6\u5c06\u4f1a\u5bfc\u81f4\u77ed\u8def\u7535\u6d41\u7684\u4ea7\u751f\uff0c\u589e\u52a0\u7a7a\u7a74\u4f20\u8f93\u5c42\u7684\u539a\u5ea6\u53ef\u4ee5\u6709\u6548\u89e3\u51b3\u8fd9\u4e2a\u95ee\u9898\u3002\u4f46\u662f\uff0c\u7a7a\u7a74\u4f20\u8f93\u5c42\u539a\u5ea6\u8fc7\u5927\u53c8\u5c06\u4f1a\u5bfc\u81f4\u7535\u6c60\u4e32\u8054\u7535\u963b\u7684\u589e\u52a0\uff0c\u5728\u6291\u5236\u77ed\u8def\u7535\u6d41\u60c5\u51b5\u4e0b\uff0c\u5c3d\u91cf\u51cf\u5c0f\u4e32\u8054\u7535\u963b\u5c06\u6709\u52a9\u4e8e\u63d0\u9ad8\u7535\u6c60\u5149\u7535\u8f6c\u5316\u6548\u7387\u3002\u53e6\u5916\uff0c\u8c03\u6574\u7535\u6c60\u7ed3\u6784\u589e\u52a0\u5e26\u8fb9\u5149\u5438\u6536\u4e5f\u5c06\u6709\u52a9\u4e8e\u63d0\u9ad8\u7535\u6c60\u7684\u5149\u7535\u8f6c\u5316\u6548\u7387\u3002<\/p>\n

(3) \u5e73\u9762\u5f02\u8d28\u7ed3\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60<\/p>\n

\u6309\u7167\u5e73\u9762\u7ed3\u6784\u7684\u5dee\u522b\uff0c\u5e73\u9762\u5f02\u8d28\u7ed3\u578b\u9499\u949b\u77ff\u7535\u6c60\u53ef\u4ee5\u5927\u81f4\u5206\u4e3a\u4e24\u7c7b\uff1a\u4e00\u7c7b\u662fp-i-n\u578b\u7ed3\u6784\u7535\u6c60\uff1b\u4e00\u79cd\u662fp-n\u578b\u7ed3\u6784\u7535\u6c60\u3002p-i-n\u578b\u7ed3\u6784\u662f\u5c06\u9499\u949b\u77ff\u5c42\u5939\u5728p\u578b\u548cn\u578b\u8f7d\u6d41\u5b50\u4f20\u8f93\u5c42\u4e2d\u95f4\uff0c\u5982\u56fe7\u6240\u793a\u3002\u8be5\u79cd\u7ed3\u6784\u4e2d\u9499\u949b\u77ff\u5c42\u4f5c\u4e3a\u5149\u7535\u8f6c\u5316\u5c42\uff0c\u4e0e\u4e4b\u63a5\u89e6\u7684\u4e24\u5c42\u5206\u522b\u5b8c\u6210\u7535\u5b50\u548c\u7a7a\u7a74\u7684\u4f20\u8f93\u3002<\/p>\n

\"\"<\/p>\n

\u56fe7 p-i-n\u578b\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7ed3\u6784\u793a\u610f\u56fe[8,9]<\/sup>\uff0c\u5de6\uff1a\u5e73\u9762\u5f02\u8d28\u7ed3\u6784\uff1b\u53f3\uff1a\u53cd\u5e73\u9762\u5f02\u8d28\u7ed3\u6784<\/p>\n

p-n\u578b\u7ed3\u6784\u7684\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u662f\u5c06\u4e00\u5c42n\u578b\u534a\u5bfc\u4f53\u6750\u6599\u6216p\u578b\u534a\u5bfc\u4f53\u6750\u6599\u4e0e\u9499\u949b\u77ff\u76f8\u7ed3\u5408\uff0c\u5982\u56fe8\u6240\u793a\uff0c\u4f7f\u5f97\u9499\u949b\u77ff\u540c\u65f6\u53d1\u6325\u5149\u7535\u8f6c\u5316\u548c\u7535\u5b50\u6216\u7a7a\u7a74\u4f20\u8f93\u80fd\u529b\u3002<\/p>\n

\"\"<\/p>\n

\u56fe8 p- n\u578b\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7ed3\u6784\u793a\u610f\u56fe[10-12]<\/sup>\uff0c\u5de6\uff1a\u9499\u949b\u77ff\u5c42\u4f5c\u4e3a\u5149\u5438\u6536\u5c42\u548c\u7535\u5b50\u4f20\u8f93\u5c42\uff1b\u53f3\uff1a\u9499\u949b\u77ff\u5c42\u4f5c\u4e3a\u5149\u5438\u6536\u5c42\u548c\u7a7a\u7a74\u4f20\u8f93\u5c42<\/p>\n

\u4e0e\u8bb8\u591a\u7ecf\u5178\u7684\u534a\u5bfc\u4f53\u805a\u5408\u7269\u6750\u6599(\u6fc0\u5b50\u6269\u6563\u957f\u5ea6\u7ea6\u4e3a10 nm)\u76f8\u6bd4\uff0c\u6709\u673a\u5364\u5316\u94c5\u5982CH3<\/sub>NH3<\/sub>Pb3-x<\/sub>Clx<\/sub>\u7684\u6fc0\u5b50\u6269\u6563\u957f\u5ea6\u8d85\u8fc71\u03bcm\uff0c\u5728\u4e0d\u5f71\u54cd\u6fc0\u5b50\u4f20\u8f93\u7684\u524d\u63d0\u4e0b\u53ef\u4ee5\u6709\u8db3\u591f\u539a\u7684\u6709\u673a\u5364\u5316\u94c5\u5c42\u4ee5\u5b9e\u73b0\u5145\u8db3\u7684\u5149\u5438\u6536\uff0c\u8fd9\u662f\u5e73\u9762\u5f02\u8d28\u7ed3\u7ed3\u6784\u5f97\u4ee5\u5b9e\u73b0\u7684\u57fa\u7840\u3002\u975e\u5e73\u9762\u7ed3\u6784\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u4e2d\uff0c\u5b58\u5728\u7740\u7a7a\u7a74\u4f20\u8f93\u6750\u6599\u5728\u5b54\u9053\u4e2d\u7684\u6e17\u900f\u4e0d\u5747\u5300\u7684\u95ee\u9898\u3002\u800c\u5e73\u9762\u7ed3\u6784\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5219\u6709\u6548\u907f\u514d\u4e86\u8fd9\u4e2a\u95ee\u9898\u3002<\/p>\n

\u53d7\u805a\u5408\u7269\u7535\u6c60\u7ed3\u6784\u7684\u542f\u53d1\uff0c\u5e73\u9762\u5f02\u8d28\u7ed3\u7ed3\u6784\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u4e5f\u53ef\u4ee5\u91c7\u7528\u53cd\u5f0f\u7ed3\u6784\u3002\u8be5\u7c7b\u7535\u6c60\u7ed3\u6784\u4e2d\uff0c\u7a7a\u7a74\u4f20\u8f93\u5230\u5bfc\u7535\u73bb\u7483\u5c42\uff0c\u800c\u7535\u5b50\u4f20\u8f93\u5230\u91d1\u5c5e\u7535\u6781\u5c42\u3002\u6700\u5e38\u7528\u7684HTM\u662fPEDOT\uff1aPSS(\u805a3, 4-\u4e59\u6491\u4e8c\u6c27\u567b\u5429\/\u805a\u82ef\u4e59\u70ef\u78fa\u9178\u76d0)\uff0c\u7535\u5b50\u4f20\u8f93\u5c42\u901a\u5e38\u4e3aC60<\/sub>\u884d\u751f\u7269\u3002\u800c\u57fa\u4e8e\u805a\u5408\u7269\u7535\u6c60\u6280\u672f\u7684\u67d4\u6027\u57fa\u5e95\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5e94\u7528\u8303\u56f4\u5c06\u4f1a\u66f4\u52a0\u5e7f\u6cdb\uff0c\u6709\u671b\u5e94\u7528\u4e8e\u6c11\u7528\u4f4f\u5b85\u7684\u5c4b\u9876\u3001\u7a97\u6237\u7b49\u5904\u3002<\/p>\n

\u4e94\u3001\u6709\u673a\u5364\u5316\u94c5\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u7814\u7a76\u8d8b\u52bf<\/strong><\/span><\/p>\n

5.1 \u6709\u673a\u5364\u5316\u94c5\u9499\u949b\u77ff\u6750\u6599<\/strong><\/p>\n

(1)\u5c06\u4e0d\u540c\u5364\u7d20\u79bb\u5b50\u8fdb\u884c\u7ed3\u5408\u4e0d\u540c\u5364\u7d20\u79bb\u5b50\u8fdb\u884c\u7ed3\u5408\uff0c\u53ef\u4ee5\u6709\u6548\u8c03\u8282\u6709\u673a\u5364\u5316\u94c5\u7684\u5149\u5438\u6536\u3001\u7a33\u5b9a\u6027\u4ee5\u53ca\u5e26\u9699\u5bbd\u5ea6\uff0c\u5b9e\u73b0\u5149\u7535\u8f6c\u5316\u6548\u7387\u7684\u4f18\u5316\u3002<\/p>\n

(2)\u901a\u8fc7\u7814\u7a76\u7532\u80fa\u57fa\u3001\u4e59\u80fa\u57fa\u548c\u8112\u80fa\u57fa\u4e09\u7c7b\u6709\u673a\u80fa\u79bb\u5b50\u5bf9\u4e8e\u6709\u673a\u5364\u5316\u94c5\u7ed3\u6784\u7684\u5f71\u54cd\uff0c\u53d1\u73b0\u7532\u80fa\u57fa\u548c\u8112\u80fa\u57fa\u9002\u5408\u4e8e\u6709\u673a\u5364\u5316\u94c5\u3002\u4e24\u79cd\u6709\u673a\u79bb\u5b50\u7684\u7ed3\u5408\u66f4\u6709\u5229\u4e8e\u63d0\u5347\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u6027\u80fd\u3002<\/p>\n

5.2 \u6709\u673a\u5364\u5316\u94c5\u9499\u949b\u77ff\u7535\u6c60\u5236\u4f5c\u5de5\u827a<\/strong><\/p>\n

\u5f00\u53d1\u4f4e\u6e29\u5236\u4f5c\u5de5\u827a\u53ef\u6709\u6548\u964d\u4f4e\u7535\u6c60\u751f\u4ea7\u7684\u6210\u672c\uff1b\u5728\u975e\u5e73\u9762\u7ed3\u6784\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u4e2d\uff0c\u6709\u673a\u5364\u5316\u94c5\u5728\u5b54\u9699\u4e2d\u7684\u586b\u5145\u5bf9\u5149\u7535\u8f6c\u5316\u6548\u7387\u6709\u5f88\u5927\u5f71\u54cd\uff0c\u56e0\u6b64\u6709\u673a\u5364\u5316\u94c5\u6c89\u79ef\u5de5\u827a\u5bf9\u7535\u6c60\u6027\u80fd\u4e5f\u6709\u5f88\u5927\u5f71\u54cd\u3002\u76ee\u524d\u6709\u673a\u5364\u5316\u94c5\u6c89\u79ef\u5de5\u827a\u6709\u4e00\u6b65\u6c89\u79ef\u6cd5\u3001\u4e24\u6b65\u6c89\u79ef\u6cd5\u3001\u53cc\u6e90\u84b8\u9540\u6c89\u79ef\u6cd5\u548c\u84b8\u9540\u8f85\u52a9\u6eb6\u6db2\u6c89\u79ef\u6cd5\u7b49\u3002\u4e00\u6b65\u548c\u4e24\u6b65\u6eb6\u6db2\u6cd5\u662f\u76f8\u5bf9\u7b80\u5355\u7684\u5236\u5907\u65b9\u6cd5\uff0c\u800c\u4e14\u53ef\u7528\u4e8e\u5236\u5907\u9ad8\u6027\u80fd\u7535\u6c60\u3002\u9499\u949b\u77ff\u6676\u7c92\u5f62\u8c8c\u96be\u4ee5\u63a7\u5236\u662f\u5bfc\u81f4\u5668\u4ef6\u53ef\u91cd\u590d\u6027\u5dee\u7684\u91cd\u8981\u539f\u56e0\u3002\u5236\u5907\u6676\u7c92\u5927\u5c0f\u5206\u5e03\u5747\u5300\u7684\u9ad8\u8d28\u91cf\u3001\u5927\u9762\u79ef\u9499\u949b\u77ff\u8584\u819c\u662f\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u5173\u952e\u4e4b\u4e00\u3002<\/p>\n

\"\"<\/p>\n

\u56fe9\u4e00\u6b65\u6eb6\u6db2\u6cd5\u548c\u4e24\u6b65\u6eb6\u6db2\u6cd5\u5de5\u827a\u793a\u610f\u56fe[13]<\/sup><\/p>\n

5.3 HTM\u5c42\u548c\u5bf9\u7535\u6781<\/strong><\/p>\n

Spiro-OMeTAD\u662f\u76ee\u524d\u6700\u5e38\u7528\u7684HTM\u5c42\u6750\u6599\uff0c\u4f46\u5176\u4ef7\u683c\u6602\u8d35\uff0c\u5bfb\u627e\u4ef7\u683c\u4f4e\u5ec9\u7684\u66ff\u4ee3\u54c1\u5bf9\u4e8e\u6210\u672c\u7684\u964d\u4f4e\u5341\u5206\u91cd\u8981\u3002\u4e5f\u6709\u4e0d\u542bHTM\u5c42\u7684\u7535\u6c60\u7ed3\u6784\uff0c\u964d\u4f4e\u6210\u672c\u7684\u540c\u65f6\u4e5f\u907f\u514d\u4e86 HTM\u6e17\u900f\u4e0d\u5747\u5300\u5bf9\u7535\u6c60\u5149\u7535\u8f6c\u5316\u6548\u7387\u7684\u4e0d\u5229\u5f71\u54cd\u3002\u6709\u673a\u5364\u5316\u94c5\u9499\u949b\u77ff\u7535\u6c60\u4e2d\u7684\u5bf9\u7535\u6781\u5927\u591a\u91c7\u7528\u91d1\u6216\u94f6\uff0c\u6210\u672c\u76f8\u5bf9\u8f83\u9ad8\u3002\u91c7\u7528\u78b3\u7535\u6781\uff0c\u53ef\u4ee5\u6709\u6548\u964d\u4f4e\u6210\u672c\u3002<\/p>\n

5.4 \u5e73\u9762\u5f02\u8d28\u7ed3\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60<\/strong><\/p>\n

\u654f\u5316\u7c7b\u6709\u673a\u5364\u5316\u94c5\u9499\u949b\u77ff\u7535\u6c60\u7531\u4e8e\u91c7\u7528\u4e86\u6c27\u5316\u7269\u5c42\uff0c\u5fc5\u987b\u8003\u8651\u5230\u6e17\u900f\u95ee\u9898\uff0c\u800c\u4e14\u5f88\u591a\u9700\u8981\u8d85\u8fc7500\u00b0C\u7684\u70e7\u7ed3\u8fc7\u7a0b\u3002\u5c06\u975e\u5e73\u9762\u7ed3\u6784\u66ff\u6362\u4e3a\u5e73\u9762\u5f02\u8d28\u7ed3\u7ed3\u6784\uff0c\u53ef\u6709\u6548\u5730\u51cf\u5c11\u5236\u4f5c\u8fc7\u7a0b\u7684\u590d\u6742\u6027\uff0c\u4e5f\u589e\u52a0\u754c\u9762\u7684\u4e00\u81f4\u6027\u548c\u9499\u949b\u77ff\u6676\u4f53\u7684\u5747\u5300\u6027\u3002<\/p>\n

5.5 \u5927\u9762\u79ef\u7535\u6c60<\/strong><\/p>\n

\u00a0\u00a0\u00a0 \u9ad8\u6548\u7387\u5927\u9762\u79ef(>1 cm2<\/sup>)\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u5f00\u53d1\u662f\u5b9e\u73b0\u5176\u5e02\u573a\u5316\u5e94\u7528\u7684\u5173\u952e\uff0c\u4f46\u7531\u4e8e\u6709\u673a\u5364\u5316\u94c5\u9499\u949b\u77ff\u592a\u9633\u80fd\u5b58\u5728\u5747\u5300\u6027\u3001\u4e00\u81f4\u6027\u5dee\u7b49\u95ee\u9898\uff0c\u4f7f\u5f97\u5927\u9762\u79ef\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u6548\u7387\u96be\u4ee5\u63d0\u9ad8\u3002\u901a\u8fc7\u4f18\u5316\u7535\u6c60\u7ed3\u6784\u5e03\u5c40\u3001\u4f18\u5316\u754c\u9762\u5de5\u7a0b\u53ca\u7535\u6c60\u5236\u9020\u5de5\u827a\uff0c\u6700\u65b0\u62a5\u9053\u7684\u5927\u9762\u79ef\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u8fbe\u523019.6%[15]<\/sup>\u3002<\/p>\n

\"\" \"\"\u00a0\u00a0\u00a0\u00a0\u00a0\u56fe10 \u9499\u949b\u77ff\u8584\u819c\u6c89\u79ef\u5de5\u827a\u53ca\u5668\u4ef6\u7ed3\u6784\u793a\u610f\u56fe[14]<\/sup><\/p>\n

5.6 \u6709\u673a\u5364\u5316\u94c5\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u673a\u7406\u7814\u7a76<\/strong><\/p>\n

\u754c\u9762\u7684\u5747\u4e00\u6027\u548c\u8fde\u7eed\u6027\u5bf9\u7535\u6c60\u7684\u5149\u7535\u8f6c\u5316\u6548\u7387\u6709\u91cd\u8981\u5f71\u54cd\uff0c\u9499\u949b\u77ff\u7684\u7a33\u5b9a\u6027\u95ee\u9898\u4e5f\u662f\u4e9f\u5f85\u89e3\u51b3\u7684\u95ee\u9898\u4e4b\u4e00\u3002\u975e\u5e73\u9762\u7ed3\u6784\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u4e2d\uff0c\u91c7\u7528TiO2<\/sub>\uff0c\u53ef\u80fd\u7684\u7535\u5b50\u4f20\u8f93\u8def\u5f84\u5c06\u4f1a\u6709\u4e24\u6761\uff0c\u5373\u7535\u5b50\u901a\u8fc7TiO2<\/sub>\u5c42\u6216\u9499\u949b\u77ff\u5c42\u8fdb\u884c\u4f20\u8f93\uff0c\u4f46\u662f\u7a76\u7adf\u54ea\u79cd\u4f20\u8f93\u8d77\u5230\u4e3b\u8981\u4f5c\u7528\uff0c\u76ee\u524d\u8fd8\u4e0d\u6e05\u695a\u3002\u5982\u679c\u91c7\u7528Al2<\/sub>O3<\/sub>\uff0c\u5219\u7535\u5b50\u5c06\u4ec5\u4ec5\u901a\u8fc7\u9499\u949b\u77ff\u5c42\u8fdb\u884c\u4f20\u8f93\uff0c\u4f46\u662fAl2<\/sub>O3<\/sub>\u7a76\u7adf\u8d77\u5230\u4ec0\u4e48\u5177\u4f53\u4f5c\u7528\uff0c\u7814\u7a76\u8fd8\u4e0d\u900f\u5f7b\u3002\u5e73\u9762\u5f02\u8d28\u7ed3\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u907f\u514d\u4e86\u9499\u949b\u77ff\u5c42\u548c\u7a7a\u7a74\u4f20\u8f93\u5c42\u5728\u6c27\u5316\u7269\u5c42\u4e2d\u6e17\u900f\u95ee\u9898\u5bf9\u7535\u6c60\u7684\u5f71\u54cd\uff0c\u8f7d\u6d41\u5b50\u590d\u5408\u73b0\u8c61\u5f97\u5230\u6291\u5236\uff0c\u7535\u6c60\u91cd\u73b0\u6027\u826f\u597d\u3002<\/p>\n

\u516d\u3001\u603b\u7ed3<\/strong><\/span><\/p>\n

\u4ece2009\u5e74\u81f3\u4eca\uff0c\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5149\u7535\u8f6c\u5316\u6548\u7387\u5c31\u4ece\u539f\u6765\u7684\u4f4e\u4e8e3.8%\u8fc5\u901f\u63d0\u9ad8\u5230\u4e8620.1%[1]<\/sup>\uff0c\u53ef\u89c1\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u5de8\u5927\u6f5c\u529b\u3002\u4f46\u662f\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u8981\u60f3\u5b9e\u73b0\u5546\u4e1a\u5316\uff0c\u8fd8\u9700\u8981\u89e3\u51b3\u4e00\u7cfb\u5217\u95ee\u9898\u3002<\/p>\n

\u5b9e\u9645\u5e94\u7528\u5f53\u4e2d\uff0c\u63d0\u9ad8\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7a33\u5b9a\u6027\uff0c\u964d\u4f4e\u5149\u7535\u8f6c\u5316\u6548\u7387\u8870\u51cf\u901f\u5ea6\uff0c\u80fd\u591f\u6709\u6548\u964d\u4f4e\u6210\u672c\u3002\u6709\u673a\u5364\u5316\u94c5\u6781\u6613\u5728\u6c34\u6c7d\u5b58\u5728\u7684\u6761\u4ef6\u4e0b\u5206\u89e3\uff0c\u907f\u514d\u9499\u949b\u77ff\u7535\u6c60\u6750\u6599\u7684\u5206\u89e3\u7684\u601d\u8def\u4e3b\u8981\u662f\u963b\u6b62\u9499\u949b\u77ff\u5c42\u4e0e\u6c34\u7684\u63a5\u89e6\uff0c\u53ef\u4ee5\u901a\u8fc7\u5728\u9499\u949b\u77ff\u5c42\u8868\u9762\u589e\u52a0\u4fdd\u62a4\u5c42\u6216\u758f\u6c34\u5c42\uff0c\u5c01\u88c5\u7684\u529e\u6cd5\u6765\u89e3\u51b3\u3002\u4f46\u662f\uff0c\u589e\u52a0\u4fdd\u62a4\u5c42\u6216\u5c01\u88c5\u4f1a\u589e\u52a0\u5b9e\u9645\u64cd\u4f5c\u4e2d\u7684\u6210\u672c\u548c\u96be\u5ea6\uff0c\u6240\u4ee5\u66f4\u597d\u5730\u7814\u7a76\u5206\u89e3\u673a\u7406\uff0c\u6539\u8fdb\u9499\u949b\u77ff\u5c42\u672c\u8eab\u7684\u7ed3\u6784\u662f\u89e3\u51b3\u8fd9\u4e2a\u95ee\u9898\u7684\u66f4\u597d\u529e\u6cd5\u3002\u9009\u62e9\u66f4\u52a0\u7a33\u5b9a\u7684\u3001\u4f20\u8f93\u6548\u679c\u66f4\u597d\u7684\u7a7a\u7a74\u4f20\u8f93\u6750\u6599\u662f\u4fdd\u6301\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7a33\u5b9a\u6027\u7684\u5fc5\u7136\u9009\u62e9\u3002<\/p>\n

\u76ee\u524d\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u751f\u4ea7\u91c7\u7528\u7684\u5de5\u827a\u6761\u4ef6\u8981\u6c42\u63a7\u5236\u6e7f\u5ea6\uff0c\u751a\u81f3\u662f\u5728\u60f0\u6027\u6c14\u4f53\u4fdd\u62a4\u6761\u4ef6\u4e0b\u5b8c\u6210\u88c5\u914d\uff0c\u8fd9\u662f\u5b9e\u73b0\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5de5\u4e1a\u5316\u751f\u4ea7\u7684\u4e00\u5927\u95ee\u9898\u3002\u53e6\u5916\uff0c\u76ee\u524d\u751f\u4ea7\u9499\u949b\u77ff\u5c42\u5236\u5907\u7684\u65b9\u6cd5\u5de5\u5e8f\u8fd8\u8f83\u4e3a\u590d\u6742\uff0c\u4e0d\u9002\u5408\u5de5\u4e1a\u5316\u5927\u89c4\u6a21\u751f\u4ea7\u3002\u6210\u672c\u65b9\u9762\uff0c\u5e38\u7528\u7684\u7a7a\u7a74\u4f20\u8f93\u6750\u6599 Spiro-OMeTAD\u548cAu\u3001Ag\u5bf9\u7535\u6781\u6750\u6599\u7684\u6210\u672c\u76f8\u5bf9\u8f83\u9ad8\uff0c\u76ee\u524d\u5f00\u53d1\u7684\u66ff\u4ee3\u6750\u6599\u5728\u7535\u6c60\u6027\u80fd\u65b9\u9762\u8868\u73b0\u8f83\u5dee\u3002\u6b64\u5916\uff0c\u5bfb\u627ePb\u5143\u7d20\u7684\u66ff\u4ee3\u5143\u7d20\u4f9d\u7136\u4efb\u91cd\u800c\u9053\u8fdc\u3002<\/p>\n

\u76f8\u8f83\u4e8e\u975e\u5e73\u9762\u7ed3\u6784\uff0c\u5e73\u9762\u7ed3\u6784\u7684\u592a\u9633\u80fd\u7535\u6c60\u5177\u6709\u751f\u4ea7\u5de5\u827a\u7b80\u5355\u7684\u4f18\u52bf\uff0c\u66f4\u6709\u5229\u4e8e\u5b9e\u73b0\u5de5\u4e1a\u5316\u751f\u4ea7\u3002\u5176\u4e2d\uff0c\u67d4\u6027\u57fa\u5e95\u7684\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5177\u6709\u53ef\u4ee5\u5b9e\u73b0\u4f4e\u6e29\u8fde\u7eed\u4f4e\u6210\u672c\u751f\u4ea7\u7684\u826f\u597d\u6f5c\u8d28\uff0c\u4f46\u76ee\u524d\u67d4\u6027\u57fa\u5e95\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u57fa\u5e95\u5927\u90fd\u91c7\u7528ITO\u73bb\u7483\u548c\u5851\u6599\u7ed3\u5408\u6750\u6599\uff0c\u800c\u94df\u7684\u6210\u672c\u76f8\u5bf9\u8f83\u9ad8\u3002ITO\u5bf9\u66f2\u6320\u7684\u8010\u53d7\u7a0b\u5ea6\u6709\u9650\uff0c\u4e0e\u4e4b\u7ed3\u5408\u7684\u5851\u6599\u6750\u6599\u5bf9\u70ed\u7684\u8010\u53d7\u6027\u6709\u9650\uff0c\u900f\u5149\u6027\u8f83\u73bb\u7483\u800c\u8a00\u8f83\u5dee\u3002\u540c\u65f6\uff0c\u67d4\u6027\u57fa\u5e95\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5149\u7535\u8f6c\u5316\u6548\u7387\u8ddd\u79bb\u521a\u6027\u592a\u9633\u80fd\u7535\u6c60\u5149\u7535\u8f6c\u5316\u6548\u7387\u8fd8\u6709\u4e00\u5b9a\u7684\u5dee\u8ddd\u3002\u5982\u4f55\u6709\u6548\u5236\u5907\u5f97\u5230\u9ad8\u6548\u7684\u5927\u9762\u79ef\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u662f\u4e00\u4e2a\u5f88\u6709\u5b9e\u9645\u610f\u4e49\u7684\u8bfe\u9898\u3002<\/p>\n

\u53c2\u8003\u6587\u732e<\/strong><\/p>\n

[1] \u741a\u6210\u529f, \u5f20\u5b9d, \u51af\u4e9a\u9752. \u6709\u673a\u5364\u5316\u7269\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60[J]. \u5316\u5b66\u8fdb\u5c55, 2016, 28(2\/3): 219-231.<\/p>\n

[2] Tan, H., et al., Efficient and stable solution-processed planar perovskite solar cells via contact passivation.<\/em> Science, 2017.<\/p>\n

[3] \u6768\u82f1, \u9ad8\u83c1, \u5d14\u5609\u745e\u7b49. \u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u7814\u7a76\u8fdb\u5c55[J]. \u65e0\u673a\u6750\u6599\u5b66\u62a5, 2015, 30(11): 1131-1138.<\/p>\n

[4] Zhou H, Chen Q, Li G, Luo S, Song T, Duan H S, Hong Z, You J, Liu Y, Yang Y. Science, 2014, 345: 542.<\/p>\n

[5] Tanaka K, Takahashi T, Ban T, Kondo T, Uchida K, Miura N. Solid State Commun., 2003, 127: 619.<\/p>\n

[6] Burschka J, Pellet N, Moon S J, Humphry-Baker R, Gao P, Nazeeruddin M K. Gratzel M. Nature, 2013, 499: 316.<\/p>\n

[7] Lee M M, Teuscher J, Miyasaka T, Murakami T N, Snaith H J. Science, 2012, 338: 643.<\/p>\n

[8] Bi D, Moon S J, Haggman L, Boschloo G, Yang L, Johansson E M J, Nazeeruddin M K, Gratzel M, Hagfeldt A. RSC Adv., 2013, 3: 18762.<\/p>\n

[9] Zhang W, Saliba M, Stranks S D, Sun Y, Shi X, Wiesner U, Snaith H J. Nano Lett., 2013, 13: 4505.<\/p>\n

[10] Eperon G E, Stranks S D, Menelaou C, Johnston M B, Herz L M, Snaith H J. Energ. Environ. Sci., 2014, 7: 982.<\/p>\n

[11] Chen C, Li C, Li F, Wu F, Tan F, Zhai Y, Zhang W. Nanoscale Res. Lett., 2014, 9: 457.<\/p>\n

[12] Ku Z, Rong Y, Xu M, Liu T, Han H. Sci. Rep., 2013, 3: 3132.<\/p>\n

[13] Jung H S, Park N G. Perovskite solar cells: from materials to devices [J]. small, 2015, 11(1): 10-25.<\/p>\n

[14] Li X, Bi D, Yi C, et al. A vacuum flash\u2013assisted solution process for high-efficiency large-area perovskite solar cells [J]. Science, 2016, \u00a0\u00a0\u00a0\u00a0353(6294): 58-62.<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u5e72\u8d27\u7ec4\u7530\u601d\u5b87\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

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